CA2029806A1 - Heat-curable coating compositions - Google Patents

Heat-curable coating compositions

Info

Publication number
CA2029806A1
CA2029806A1 CA002029806A CA2029806A CA2029806A1 CA 2029806 A1 CA2029806 A1 CA 2029806A1 CA 002029806 A CA002029806 A CA 002029806A CA 2029806 A CA2029806 A CA 2029806A CA 2029806 A1 CA2029806 A1 CA 2029806A1
Authority
CA
Canada
Prior art keywords
groups
coating compositions
nco groups
polyurethane
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002029806A
Other languages
French (fr)
Other versions
CA2029806C (en
Inventor
Josef Pedain
Wilhelm Thoma
Walter Schroer
Waldemar Kling
Manfred Dietrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of CA2029806A1 publication Critical patent/CA2029806A1/en
Application granted granted Critical
Publication of CA2029806C publication Critical patent/CA2029806C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The present invention relates to heat-curable coating compositions containing A) a prepolymer having an average of 2-4 ketoxime-blocked NCO
groups, having an average molecular weight of 500-15,000 and prepared from aliphatic, cycloaliphatic and aromatic polyisocyanates and one or more polyhydroxy components which contain 0 to 30% by weight of ethylene oxide units and B) a crosslinking agent of the formula (see formula I) wherein R and R1 represent H or C1-C4-alkyl, the ratio of equivalents of blocked NCO groups in A) to NH2 groups in B) being 1.35:1 to 0.95:1, characterized in that at least one of the polyhydroxy compounds used for the preparation of the prepolymer contains, in stable dispersion, a polyurethane, a polyurethane-urea and/or a polyurea, which is substantially free from NCO groups, hydroxyl groups and amino groups and which are synthesized from aromatic, aliphatic and/or cycloaliphatic diisocyanates and from diamines, hydrazine and/or diols, provided that at least one of these components carries a radical having hydrophilic characteristics.
The present invention also relates to the use of these coating compositions in a process for the coating, particularly water vapor-permeable coating, of substrates, preferably textile sheet-like structures and leather,
CA002029806A 1989-12-02 1990-11-13 Heat-curable coating compositions Expired - Fee Related CA2029806C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3939964A DE3939964A1 (en) 1989-12-02 1989-12-02 HAZARDOUS COATING COMPOSITIONS
DEP3939964.8 1989-12-08

Publications (2)

Publication Number Publication Date
CA2029806A1 true CA2029806A1 (en) 1991-06-09
CA2029806C CA2029806C (en) 2002-02-19

Family

ID=6394719

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002029806A Expired - Fee Related CA2029806C (en) 1989-12-02 1990-11-13 Heat-curable coating compositions

Country Status (7)

Country Link
US (1) US5276125A (en)
EP (1) EP0431386B1 (en)
JP (1) JPH03190981A (en)
AT (1) ATE112295T1 (en)
CA (1) CA2029806C (en)
DE (2) DE3939964A1 (en)
ES (1) ES2059960T3 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4125454A1 (en) * 1991-08-01 1993-02-04 Bayer Ag COATING AGENTS AND THEIR USE FOR PRODUCING WATER VAPOR-PERMEABLE COATINGS
US6143496A (en) * 1997-04-17 2000-11-07 Cytonix Corporation Method of sampling, amplifying and quantifying segment of nucleic acid, polymerase chain reaction assembly having nanoliter-sized sample chambers, and method of filling assembly
US20040132367A1 (en) * 1999-07-02 2004-07-08 Moshe Rock Multi-layer garment system
US6565727B1 (en) * 1999-01-25 2003-05-20 Nanolytics, Inc. Actuators for microfluidics without moving parts
DE19919163A1 (en) * 1999-04-28 2000-11-02 Bayer Ag Binders containing isocyanate
DE10201545A1 (en) * 2002-01-17 2003-07-31 Bayer Ag Stabilized aqueous crosslinker dispersions
US6911132B2 (en) 2002-09-24 2005-06-28 Duke University Apparatus for manipulating droplets by electrowetting-based techniques
US7329545B2 (en) 2002-09-24 2008-02-12 Duke University Methods for sampling a liquid flow
BRPI0607213B1 (en) * 2005-01-28 2017-04-04 Univ Duke droplet handling apparatus on a printed circuit board
JP5174820B2 (en) * 2006-09-05 2013-04-03 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Aqueous composition of sagging inhibitor
US8268246B2 (en) * 2007-08-09 2012-09-18 Advanced Liquid Logic Inc PCB droplet actuator fabrication
US8772197B2 (en) * 2007-08-17 2014-07-08 Massachusetts Institute Of Technology Compositions for chemical and biological defense
KR101731127B1 (en) * 2009-02-26 2017-04-27 우베 고산 가부시키가이샤 Aqueous polyurethane resin dispersion and method for producing same
EP2514778B1 (en) * 2009-09-28 2013-10-16 Coatings Foreign IP Co. LLC Liquid two-component coating compositions
DE102011077213A1 (en) * 2011-06-08 2012-12-13 Bayer Material Science Ag Polyurethane polymers
DE102011077200A1 (en) * 2011-06-08 2012-12-13 Bayer Materialscience Aktiengesellschaft adhesives
US9315616B2 (en) 2011-07-26 2016-04-19 Dow Global Technologies Llc Blocked prepolymers and acrylic plastisol compositions comprising the blocked prepolymers
TWI583552B (en) * 2014-10-23 2017-05-21 Everest Textile Co Ltd A cloth containing a moisture-permeable low-expansion hydrophilic resin coating and a method thereof Method
ES2845608T3 (en) * 2015-03-03 2021-07-27 Evonik Operations Gmbh Production of porous polyurethane layers

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1220384B (en) * 1962-03-03 1966-07-07 Bayer Ag Use of polyurethane crosslinked with sulfur as a leather substitute
BE630578A (en) * 1963-04-05
US3634544A (en) * 1968-05-01 1972-01-11 Ajinomoto Kk Process for preparing films of poly-gamma-methyl glutamate modified with polyurethane resin
DE1949060A1 (en) * 1968-09-30 1970-05-06 Ajinomoto Kk Process for the preparation of block copolymers
JPS54961B1 (en) * 1969-04-24 1979-01-18
US4108814A (en) * 1974-09-28 1978-08-22 Bayer Aktiengesellschaft Aqueous polyurethane dispersions from solvent-free prepolymers using sulfonate diols
DE2550797C2 (en) * 1975-11-12 1983-02-03 Bayer Ag, 5090 Leverkusen Stable dispersions of polyisocyanate polyaddition products, processes for their production and processes for the production of polyurethane plastics
US4034349A (en) * 1976-01-29 1977-07-05 Sperry Rand Corporation Apparatus for processing interrupts in microprocessing systems
DE2902090A1 (en) * 1979-01-19 1980-07-24 Bayer Ag HEAT-CURABLE COATING MEASURES AND METHOD FOR COATING SUBSTRATES
GB2087909B (en) * 1980-11-22 1984-11-07 Shirley Inst Breathable non-porous polyurethane film
DE3108953A1 (en) * 1981-03-10 1982-09-30 Herberts Gmbh, 5600 Wuppertal HEAT-CURABLE COATING MEASURES, THEIR USE AND METHOD FOR COATING SUBSTRATES
DE3227065A1 (en) * 1982-07-20 1984-01-26 Bayer Ag, 5090 Leverkusen MIXED FLEECE
JPS5936781A (en) * 1982-08-23 1984-02-29 セイコ−化成株式会社 Simulated leather
JPS619423A (en) * 1984-06-22 1986-01-17 Toyo Tire & Rubber Co Ltd Polyurethane polymer
DE3500337A1 (en) * 1985-01-08 1986-07-10 Bayer Ag, 5090 Leverkusen STABLE DISPERSIONS OF POLYHANE SUBSTANCES AND / OR POLYHYDRAZODICARBONAMIDES IN HIGHLY MOLECULAR, HYDROXYL COMPOUNDS AT LEAST ONE HYDROXYL GROUP, A METHOD FOR THE PRODUCTION THEREOF AND THEIR PLANT
DE3522978A1 (en) * 1985-06-27 1987-01-15 Bayer Ag METHOD FOR PRODUCING LIGHT-FAST, SOLVENT-RESISTANT POLYURETHANE URBAN ELASTOMER COATINGS IN THE REACTIVE COATING PROCESS
DE3741538A1 (en) * 1987-12-08 1989-06-22 Bayer Ag POLYURETHANE URBS
DE3800435A1 (en) * 1988-01-09 1989-07-20 Bayer Ag METHOD FOR COATING WITH POLYURETHANE UREAS

Also Published As

Publication number Publication date
DE59007333D1 (en) 1994-11-03
EP0431386A2 (en) 1991-06-12
ES2059960T3 (en) 1994-11-16
EP0431386B1 (en) 1994-09-28
CA2029806C (en) 2002-02-19
US5276125A (en) 1994-01-04
DE3939964A1 (en) 1991-06-06
ATE112295T1 (en) 1994-10-15
JPH03190981A (en) 1991-08-20
EP0431386A3 (en) 1991-08-07

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