CA1341189C - Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for the protection of hair against atmospheric agressions, and particularly against light, and process for hairprotection with this compound - Google Patents
Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for the protection of hair against atmospheric agressions, and particularly against light, and process for hairprotection with this compound Download PDFInfo
- Publication number
- CA1341189C CA1341189C CA000590897A CA590897A CA1341189C CA 1341189 C CA1341189 C CA 1341189C CA 000590897 A CA000590897 A CA 000590897A CA 590897 A CA590897 A CA 590897A CA 1341189 C CA1341189 C CA 1341189C
- Authority
- CA
- Canada
- Prior art keywords
- fact
- composition
- hair
- composition according
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 25
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 title claims description 19
- 238000000034 method Methods 0.000 title claims description 8
- 150000001875 compounds Chemical class 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims abstract description 125
- 239000002253 acid Substances 0.000 claims abstract description 27
- 239000002537 cosmetic Substances 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 230000001476 alcoholic effect Effects 0.000 claims abstract description 12
- 125000002091 cationic group Chemical group 0.000 claims description 16
- 125000000129 anionic group Chemical group 0.000 claims description 13
- 239000007921 spray Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006260 foam Substances 0.000 claims description 12
- 239000003380 propellant Substances 0.000 claims description 12
- 239000002562 thickening agent Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000002453 shampoo Substances 0.000 claims description 10
- 239000002304 perfume Substances 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- 239000003755 preservative agent Substances 0.000 claims description 8
- -1 thickened or not Substances 0.000 claims description 8
- 229920006318 anionic polymer Polymers 0.000 claims description 7
- 239000002671 adjuvant Substances 0.000 claims description 6
- 239000000443 aerosol Substances 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 4
- 239000004872 foam stabilizing agent Substances 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- 239000002609 medium Substances 0.000 claims description 4
- 239000003352 sequestering agent Substances 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 229920006317 cationic polymer Polymers 0.000 claims description 3
- 239000003093 cationic surfactant Substances 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 3
- 239000004922 lacquer Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 229920000831 ionic polymer Polymers 0.000 claims 1
- 230000029219 regulation of pH Effects 0.000 claims 1
- 102000011782 Keratins Human genes 0.000 abstract description 7
- 108010076876 Keratins Proteins 0.000 abstract description 7
- 230000016571 aggressive behavior Effects 0.000 abstract description 6
- 206010001488 Aggression Diseases 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 5
- 238000006731 degradation reaction Methods 0.000 abstract description 5
- 239000000499 gel Substances 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000006210 lotion Substances 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 239000008266 hair spray Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 239000001272 nitrous oxide Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- MPOIUZCYWIPYNC-UHFFFAOYSA-N (2-hydroxyphenyl)-(4-methoxyphenyl)methanone Chemical compound C1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1O MPOIUZCYWIPYNC-UHFFFAOYSA-N 0.000 description 1
- VVMKVFQYONGBPV-MKWAYWHRSA-N (z)-4-butoxy-4-oxobut-2-enoic acid;methoxyethene Chemical compound COC=C.CCCCOC(=O)\C=C/C(O)=O VVMKVFQYONGBPV-MKWAYWHRSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- DWYHDSLIWMUSOO-UHFFFAOYSA-N 2-phenyl-1h-benzimidazole Chemical compound C1=CC=CC=C1C1=NC2=CC=CC=C2N1 DWYHDSLIWMUSOO-UHFFFAOYSA-N 0.000 description 1
- NSAOIAYLNQLPAZ-UHFFFAOYSA-N 4-hydroxy-5-(2-hydroxy-4-methoxy-5-sulfobenzoyl)-2-methoxybenzenesulfonic acid;sodium Chemical compound [Na].[Na].C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC(S(O)(=O)=O)=C(OC)C=C1O NSAOIAYLNQLPAZ-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 1
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- HFOCWJOSEKOCFM-UHFFFAOYSA-N S(=O)(=O)(OCCOC(C1=CC=C(C=C1)N(C)C)=O)C1=CC=C(C)C=C1 Chemical compound S(=O)(=O)(OCCOC(C1=CC=C(C=C1)N(C)C)=O)C1=CC=C(C)C=C1 HFOCWJOSEKOCFM-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid Chemical class OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940100608 glycol distearate Drugs 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N hydrochloric acid Substances Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
L'invention concerne une composition cosmétique destinée au traitement des cheveux, contenant dans un support aqueux, alcoolique ou hydroalcoolique, cosmétiquement acceptable, à titre d'agent de protection de la kératine des cheveux contre les agressions atmosphériques, l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou l'un de ses sels dans une proportion au moins égale à 0,3% en poids d'acide libre, par rapport au poids total de la composition. La composition selon l'invention permet de préserver les propriétés mécaniques des cheveux de la dégradation par les agressions atmosphériques.The invention relates to a cosmetic composition intended for the treatment of hair, containing in an aqueous, alcoholic or hydroalcoholic support, cosmetically acceptable, as an agent for protecting hair keratin against atmospheric attack, 2-hydroxy acid. 4-methoxybenzophenone-5-sulfonic acid or one of its salts in a proportion at least equal to 0.3% by weight of free acid, relative to the total weight of the composition. The composition according to the invention makes it possible to preserve the mechanical properties of the hair from degradation by atmospheric aggressions.
Description
La présente invention concerne l'utilisation de l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique et de ses sels en tant qu'agents de protection de la kératine des cheveux contre les agressions atmosphériques, et en particulier contre la lumière, les compositions cosméti-ques contenant de tels agents et un procédé de protection des cheveux contre les agressions atmosphériques, et en particulier contre la lumière.
On sait depuis longtemps que la lumière agresse la kératine des cheveux. De nombreuses publications divulguent que la lumière naturelle détruit certains aminoacides des cheveux et qu'en altérant la fibre capillaire, elle en diminue les propriêtés mécaniques; par diminution des propriétés mécaniques, on entend principa lement la diminution du palier à 15g d'extension.
Le palier à 15$ d'extension est le poids qu'il faut appliquer à un cheveu mouillé d'une longueur donnée pour l'allonger de 15~. Plus le poids est élevé, plus le cheveu est élastique et rësistant.
Pour lutter contre l'agression de la këratine des cheveux par la lumière, on a déjà proposé d'utiliser des substances susceptibles de filtrer les radiations lumineuses. En particulier, on a essayé des agents filtrants bien connus de la technique, tels que des dérivés de la benzophénone, par exemple la 2-hydroxy-4- ' méthoxybenzophénone, et la 2,2'-dihydroxy-4,4'-diméthoxy-5,5'-disulfobenzophénone disodique ou encore des dérivés du dibenzoylméthane, par exemple le 4-tert-butyl-4'-méthoxydibenzoylméthane ou l'acide p-aminobenzoique et ses dérivés tels que le p-diméthylaminobenzoate de 2-éthyl-hexyle, le tosylate de (4'-diméthylaminobenzoyloxyéthyl)-dimëthylalkyl (C16-C18) ammonium (ESCALOL 537 Q); marque de commerce, des cinnamates tels que le p-méthoxycinnamate de 2-éthylhexyle ou encore l'acide 2-phénylbenzimidazole-5-sulfonique.
Cependant, ces substances filtrantes ne se sont pas révélëes efficaces pour préserver les propriétés mécaniques des cheveux, à savoir leur élasticité, contre les effets nëfastes de la lumière.
I1 est, au contraire, apparu que leur présence dans certaines compositions cosmétiques pouvait même accentuer la dégradation des propriétés mécaniques, notamment la diminution du palier à lSô d'extension.
La Demanderesse a maintenant découvert, de façon tout à fait surprenante, que l'acide 2-hydroxy-4-méthoxy-benzophénone-5-sulfonique vendu par exemple sous la marque de commerce UVINUL MS 40 par la Société BASF, ou ses sels, pouvaient. préserver les propriétés mëcaniques des cheveux de la dégradation par la lumière. Cette propriété a pu étre mise en évidence par exposition en lumière naturelle (milieu ensoleillë) et enlumiëre artificielle (émetteur au xénon d'un appareil de vieilissement accéléré du type SUNTEST HANAU (marque de commerce)).
La présente invention a donc pour objet l'utilisa-tion de l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfoni-que ou de ses sels en tant qu'agents de protection des propriétés mécaniques des cheveux, et essentiellement du palier à 15~ d'extension au mouillé, contre la dégradation provoquée par les agressions atmosphériques, et en particulier par la lumière.
_ 2 _ 134 1e9 Plus précisement, l'invention a pour objet une composition cosmétique destinëe au traitement des cheveux, caractérisée par le fait qu'elle contient dans un support aqueux, alcoolique ou hydroalcoolique, cosmétiquement acceptable, à titre d'agent de protection de la këratine des cheveux contre les agressions atmosphériques, l'acide The present invention relates to the use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts as keratin protective agents hair against atmospheric aggressions, and particularly against light, cosmetic compositions containing such agents and a method of protection hair against atmospheric aggressions, and especially against light.
We have known for a long time that light attacks the hair keratin. Many publications disclose that natural light destroys some amino acids of the hair and that by altering the fiber capillary, it decreases its mechanical properties; through decrease in mechanical properties, we mean principa The decrease in the level to 15g extension.
The step at $ 15 extension is the weight it must be applied to a wet hair of a given length to lengthen it by 15 ~. The higher the weight, the more hair is elastic and resistant.
To fight against the aggression of keratin of hair by light, we have already proposed using substances capable of filtering out radiation bright. In particular, we tried agents filters well known in the art, such as benzophenone derivatives, for example 2-hydroxy-4- ' methoxybenzophenone, and 2,2'-dihydroxy-4,4'-dimethoxy-5,5'-disulfobenzophenone disodium or derivatives thereof dibenzoylmethane, for example 4-tert-butyl-4'-methoxydibenzoylmethane or p-aminobenzoic acid and its derivatives such as 2-ethyl p-dimethylaminobenzoate hexyl, (4'-dimethylaminobenzoyloxyethyl) tosylate -dimethylalkyl (C16-C18) ammonium (ESCALOL 537 Q); Mark commercial, cinnamates such as p-methoxycinnamate 2-ethylhexyl or 2-phenylbenzimidazole acid-5-sulfonic.
However, these filtering substances are not not proven effective in preserving properties hair mechanics, namely their elasticity, against the harmful effects of light.
On the contrary, it appeared that their presence in some cosmetic compositions could even accentuate the degradation of mechanical properties, in particular the reduction of the plateau at lSô extension.
The Applicant has now discovered, so quite surprisingly, that 2-hydroxy-4-methoxy-benzophenone-5-sulfonic sold for example under the brand commercial UVINUL MS 40 by BASF, or its salts, could. preserving the mechanical properties of hair of degradation by light. This property could be highlighted by exposure to natural light (sunny environment) and artificial light (transmitter at xenon of an accelerated aging device of the type SUNTEST HANAU (trademark).
The present invention therefore relates to the use of tion of 2-hydroxy-4-methoxybenzophenone-5-sulfoni-that or its salts as agents for the protection of mechanical properties of hair, and mainly of level at 15 ~ wet extension, against degradation caused by atmospheric aggressions, and especially by light.
_ 2 _ 134 1e9 More precisely, the subject of the invention is a cosmetic composition intended for hair treatment, characterized by the fact that it contains in a support aqueous, alcoholic or hydroalcoholic, cosmetically acceptable as a këratine protection agent hair against atmospheric aggressions, acid
2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou l'un de ses sels dans une proportion au moins égale à 0,3~ en poids d'acide libre, par rapport au poids total de la composition.
Par sels de l'acide sulfonique précité, on entend plus particuliërement les sels métalliques tels que les sels alcalins ou alcalino-terreux, les sels d'ammonium et d'amines.
Les compositions cosmétiques conformes â la présente invention contiennent l'acide 2-hydroxy-4-mé-thoxybenzophénone-5-sulfonique ou l'.un de ses sels dans des proportions au moins égales à 0,3~ en poids d'acide libre, et de préférence comprises entre 0,3 et 9~ en poids -d'acide libre, par rapport au poids total de la composi-tion. La concentration minimale de,0,3~ correspond à une concentration molaire pour 100 g de composition d'environ 1 millimole d'acide qui peut étre utilisé sous forme libre, ou salifié par un hydroxyde. métallique, l'ammonia-que ou une amine.
L'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfoni-que ou ses sels selon l'invention peuvent être utilisés pour protéger les cheveux naturels ou sensibilisés. On entend par "cheveux sensibilisés", des cheveux ayant subi un traitement de permanente, de coloration ou de décoloration. 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or one of its salts in a proportion at least equal to 0.3 ~ in weight of free acid, based on the total weight of the composition.
By the salts of the above-mentioned sulfonic acid is meant more particularly metallic salts such as alkaline or alkaline earth salts, ammonium salts and amines.
The cosmetic compositions in accordance with the present invention contain 2-hydroxy-4-me-thoxybenzophenone-5-sulfonic acid or one of its salts in proportions at least equal to 0.3 ~ by weight of acid free, and preferably between 0.3 and 9 ~ by weight -free acid, based on the total weight of the compound tion. The minimum concentration of 0.3 ~ corresponds to a molar concentration per 100 g of composition of approximately 1 millimole of acid which can be used in the form free, or salified with hydroxide. metallic, ammonia-that or an amine.
2-hydroxy-4-methoxybenzophenone-5-sulfoni- acid that or its salts according to the invention can be used to protect natural or sensitized hair. We "sensitized hair" means hair which has undergone a treatment of perm, coloring or discoloration.
- 3 -1~4~ ~a9 Les compositions cosmétiques pour cheveux, utilisées conformément à l'invention pour les protéger contre la dégradation par la lumière et contenant à titre de composé actif l'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique ou ses sels, peuvent se présenter sous forme de solutions aqueuses, alcooliques ou hydroalcooliques (l'alcool étant. le plus souvent un alcanol inférieur tel que l'éthanol ou l'isopropanol), épaissies ou non, de gels, de mousses aérosols ou de sprays et contenir les adjuvants habituellement utilisés dans les compositions capillaires et adaptés à l'application envisagée.
Ces compositions peuvent ètre ou non suivies d'un rinçage et peuvent constituer des shampooings, des après-shampooings, des produits à rincer â appliquer avant ou après shampooing, avant ou après coloration ou décoloration, avant ou après permanente ou défrisage, des compositions non rincées telles que des lotions, gels, sprays ou mousses pour la mise en plis, pour le brushing, des laques ou sprays pour le maintien de la coiffure et des compositions restructurantes.
Lorsque les compositions cosmétiques utilisée selon l'invention constituent des compositions non suivies d'un rinçage, l'acide 2-hydroxy-4-mëthoxybenzophénone-5-sulfonique ou ses sels, en tant qu'agent actif préservant les propriétés mécaniques des cheveux contre la lumière, est présent à raison de 0,3 à 5$ en poids d'acide libre par rapport au poids total de la composition, et de préférence à raison de 0,3 à 3,5$ en poids d'acide libre.
Lorsque les compositions cosmétiques utilisées selon l'invention, constituent des compositions suivies d'un rinçage, l'acide 2-hydroxy-4-mét.hoxybenzophénone-5 - 3 -1 ~ 4 ~ ~ a9 Cosmetic compositions for hair, used in accordance with the invention to protect them against degradation by light and containing as of active compound 2-hydroxy-4-methoxybenzophenone acid-5-sulfonic acid or its salts, may be in the form aqueous, alcoholic or hydroalcoholic solutions (alcohol being most often a lower alkanol such than ethanol or isopropanol), thickened or not, of gels, aerosol sprays or sprays and contain the adjuvants usually used in the compositions capillaries and suitable for the intended application.
These compositions may or may not be followed by a rinse and may constitute shampoos, conditioners, rinse-off products to apply before or after shampooing, before or after coloring or discoloration, before or after permanent or straightening, of leave-on compositions such as lotions, gels, sprays or foams for styling, for brushing, hairsprays or sprays for maintaining the hairstyle and restructuring compositions.
When the cosmetic compositions used according to the invention constitute compositions not followed a rinse, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts, as an active preserving agent the mechanical properties of hair against light, is present at $ 0.3 to $ 5 by weight of free acid relative to the total weight of the composition, and preferably 0.3 to 3.5 $ by weight of free acid.
When the cosmetic compositions used according to the invention, constitute controlled compositions of a rinse, 2-hydroxy-4-met.hoxybenzophenone-5 acid
- 4 -sulfonique ou ses sels est présent â raison de 0,5 à 9~ en poids d'acide libre, et de préférence de 0,5 â 6~ en poids d'acide libre, par rapport au poids total de la composi-tion.
Les compositions cosmétiques pour cheveux selon l'invention ont un pH compris de préférence entre 2 et 9 et plus particulièrement entre 4 et 8.
Les compositions cosmétiques utilisées selon l'invention peuvent également renfermer des agents cosmétiques bien connus dans la technique sous réserve qu'ils n'altèrent pas eux-mêmes les propriétés mécaniques de la kératine des cheveux.
Les adjuvants ou agents cosmétiques généralement présents dans les compositions cosmêtiques utilisées selon l'invention sont par exemple des agents de surface cationiques, anioniques, amphotères, non-ioniques ou leurs mélanges, des épaississants, des polymères anioniques, non-ioniques, amphotères, cationiques ou leurs mélanges, des adoucissants, des conservateurs, des agents de moussage, des stabilisateurs de mousse, des électrolytes, des agents de régulation de pH, des agents anti-gras, des agents séquestrants, des parfums, des colorants, des propulseurs, des solvants organiques.
Les agents tensio-actifs cationiques, anioniques, non-ioniques, amphotères ou leurs mélanges sont générale-ment utilisés dans des proportions de 0,1 à 50~ en poids, et de préférence de 0,5 à 30~ en poids, par rapport au poids total de la.composition.
Lorsque lés compositions cosmétiques pour cheveux utilisées selon l'invention constituent des shampooings, ceux-ci sont essentiellement caractérisés par le fait - 4 -sulfonic acid or its salts is present at a rate of 0.5 to 9 ~
weight of free acid, preferably 0.5 to 6 ~ by weight free acid, based on the total weight of the compound tion.
Cosmetic compositions for hair according to the invention have a pH preferably between 2 and 9 and more particularly between 4 and 8.
The cosmetic compositions used according to the invention may also contain agents cosmetics well known in the art subject that they do not alter the mechanical properties themselves hair keratin.
Cosmetic adjuvants or agents generally present in the cosmetic compositions used according to the invention are for example surfactants cationic, anionic, amphoteric, nonionic or their blends, thickeners, anionic polymers, non-ionic, amphoteric, cationic or their mixtures, fabric softeners, preservatives, foaming, foam stabilizers, electrolytes, pH regulating agents, anti-fat agents, sequestering agents, perfumes, dyes, propellants, organic solvents.
Cationic, anionic surfactants, non-ionic, amphoteric or mixtures thereof are generally-ment used in proportions of 0.1 to 50 ~ by weight, and preferably from 0.5 to 30 ~ by weight, relative to the total weight of the composition.
When the cosmetic compositions for hair used according to the invention constitute shampoos, these are essentially characterized by the fact
- 5 -qu'ils contiennent, outre l'acide sulfonique ou ses sels ci-dessus défini, au moins un agent de surface anionique, non-ionique, cationique, amphotère ou un mélange de tels agents de surface, en milieu aqueux. Les shampooings peuvent également contenir différents adjuvants tels que des colorants, des conservateurs, des agents épaissis-sants, des agents stabilisateurs de mousse, des synergis-tes, des agents adoucissants, des électrolytes, des séquestrants, une ou plusieurs résines cosmétiques, des parfums, des essences naturelles ainsi que tout autre adjuvant utilisé habituellement dans un shampooing. Dans ces shampooings, la concentration d'agent de surface est gênéralement comprise entre 2 et 50~ en poids. Leur pH
est généralement compris entre 3 et 9.
Lorsque les compositions utilisées selon l'invention constituent des compositions non rincées -lotion, gel, mousse, spray ou laque pour le brushing, pour la mise en plis, pour coiffer ou traiter la chevelure -elles comprennent généralement, dans un milieu aqueux, alcoolique ou hydroalcoolique, outre l'acide sulfonique ou ses sels, au moins un polymère cationique, anionique, 'I non-ionique, amphotèx-e ou un mélange de tels polymêres i 1 dans des quantités comprises gênéralement entre 0,1 et 10~
i et de préférence entre 0,1 et 3~ en poids, et éventuelle-ment des agents anti-moussants.
Lorsque les compositions capillaires selon l'invention constituent des lotions rincées, appelées ëgalement "rinse"., elles sont appliquées avant ou après coloration ou décoloration, avant ou après permanente, avant ou après shampooing ou entre deux temps de a i shampooing, puis rincées après un temps de pose. - 5 -that they contain, in addition to sulfonic acid or its salts above defined, at least one anionic surfactant, non-ionic, cationic, amphoteric or a mixture of such surfactants, in an aqueous medium. Shampoos may also contain different adjuvants such as dyes, preservatives, thickening agents foam stabilizers, synergists, tes, softeners, electrolytes, sequestering agents, one or more cosmetic resins, perfumes, natural essences as well as any other adjuvant usually used in a shampoo. In these shampoos, the concentration of surfactant is generally between 2 and 50 ~ by weight. Their pH
is generally between 3 and 9.
When the compositions used according to the invention constitute leave-in compositions -lotion, gel, mousse, spray or hairspray for brushing, for styling, to style or treat the hair -they generally include, in an aqueous medium, alcoholic or hydroalcoholic, in addition to sulfonic acid or its salts, at least one cationic, anionic polymer, 'I non-ionic, amphotèx-e or a mixture of such polymers i 1 in quantities generally between 0.1 and 10 ~
i and preferably between 0.1 and 3 ~ by weight, and optionally-anti-foaming agents.
When the hair compositions according to the invention constitute rinsed lotions, called also "rinse"., they are applied before or after coloring or discoloration, before or after perm, before or after shampooing or between two times of at i shampoo, then rinse off after an exposure time.
- 6 -Ces compositions peuvent étre des solutions aqueuses ou hydroalcooliques comprenant éventuellement des tensio-actifs; elles peuvent être aussi des gels. Ces compositions peuvent également étre pressurisées en aérosol sous forme de sprays ou mousses.
Dans ces compositions rincées, la concentration en agents tensio-actifs peut varier entre 0,1 et 10~, et de préférence entre 0,5 et 7~ en poids. Elles peuvent également contenir des polymères non-ioniques, cationi-ques, anioniques, amphotères ou leurs mélanges.
Quand les compositions capillaires se présentent sous forme de gels, à rincer ou non, elles contiennent des épaississants en présence ou non de solvants.
Les êpaississants peuvent étre l'alginate de sodium, la gomme arabique ou la gomme de xanthane ou des dérivés cellulosiques tels que la méthyl cellulose, l'hydroxyméthyl cellulose, l'hydroxyéthyl cellulose, l'hydroxypropyl cellulose, la carboxyméthyl cellulose ou des polymères carboxyliques tels que ceux vendus sous la marque de commerce CARBOPOL. On peut également obtenir un épaississement des lotions par mélange de polyéthylène glycol et de stêarate ou distéarate de polyéthylène glycol ou par un mélange d'esters phosphoriques et d'amides. La concentration en épaississant peut.varier de 0,1 à 30~, et de préférence de 0,2 â 15~ en poids, par rapport au poids total de la composition.
On peut utiliser également un agent êpaississant qui résulte de. l'interaction ionique d'un polymère cationique constitué par un copolymëre de cellulose ou d'un dérivé de cellulose greffês par un sel de monomère hydrosoluble d'ammonium quaternaire (vendus sous la marque de commerce CELQUAT H 100 ou CELQUAT L 200) et d'un polymêre anionique carboxylique ayant une viscosité
capillaire absolue dans le diméthylformamide ou le méthanol à une concentration de 5~ et à 30°C, inférieure ou égale à 30.10 3 Pa.s.
Cet épaississant est décrit dans le brevet français No. 2.598.611.
Quand les compositions capillaires se prêsentent sous forme de mousses, à rincer ou non, elles contiennent un agent de moussage en milieu aqueux ou hydroalcoolique, en présence d'un gaz propulseur.
Comme agent de moussage, on peut utiliser des tensio-actifs anioniques, non-ioniques, cationiques, amphotêres ou leurs mélanges, des polymères non ioniques, anioniques, cationiques ou leurs mélanges, de l'alcool polyvinylique issu de polyacétate de vinyle hydrolysé
dont le taux d'hydrolyse est égal ou inférieur à 97~ comme décrit dans le brevet français No. 2.598.613.
Pour former une mousse, on préfère utiliser une association de polymère cationique et de polymère anionique, au moins l'un des deux polymères étant moussant en solution aqueuse. De telles associations sont décrites dans le brevet français No. 2.505.348.
Les gaz propulseurs utilisés pour pressuriser ces compositions destinées à formèr des mousses, sont présents dans des proportions ne dépassant pas 25~ et de préférence 15â par rapport au poids total de la composition. On peut utiliser à titre de gaz propulseur le gaz carbonique, l'azote, le protoxyde d'azote, les hydrocarbures volatils tels que le butane, l'isobutane, le propane et leurs mélanges, les hydrocarbures chlorés et/ou fluorés non hydrolysables tels que ceux vendus sous la marque de commerce FREON ou DYMEL par la Société DU PONT de NEMOURS.
Lorsque la composition se présente sous forme de spray ou de laque, elle renferme dans un milieu alcoolique ou hydroalcoolique, une rësine filmogène en présence êventuellement d'un gaz propulseur. On utilise de préférence, comme résine filmogène, un polymère anionique contenant des unités d'acides acrylique ou méthacrylique, d'acide crotonique ou d'acide °<,~-dicarboxyliques insaturés.
Les agents propulseurs utilisés dans ces formulations sous forme de laques peuvent étre choisis parmi les hydrocarbures volatils tels que le n-butane, propane, l'isobutane ou leurs mélanges ou un mélange de ces hydrocarbures avec des hydrocarbures chlorés et/ou fluorés tels que,les composés vendus sous la marque de commerce FREON ou DYMEL par la Société DU PONT de NEMOURS
et plus particulièrement les hycrocarbures fluorochlorés _ tels que le monoflurotrichloromêthane,le difluorodichloro-mêthane, le tétrafluorodichloroéthane ou les mélanges de ces derniers.
Ils peuvent ëgalement ètre choisis parmi les hydrocarbures chlorês et/ou fluorés susdécrits et leurs mêlanges, le diméthyléther, le gaz carbonique ou le protoxyde d'azote.
La phase propulsive, dans ces compositions de laque représente 30 à 80~ du poids total de la composition pressurisée.
Quand les compositions capillaires de l'invention constituent des lotions restructurantes, elles contiennent des produits renforçant la chaine kératinique des cheveux.
A cette classe de produits appartiennent les dérivés méthylolés tels que ceux décrits dans les brevets français Nos. 1.527.085 et 1.519.979.
La présente invention vise également un procédé de protection de la kératine des cheveux contre les agressions atmosphériques, et en particulier contre la lumière, consistant à appliquer sur les cheveux au moins 30 mg/g de cheveux d'une composition cosmétique contenant au moins 0,3~ en poids d'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique éventuellement salifié, dans un support aqueux, alcoolique ou hydroalcoolique, cosmétiquement acceptable.
Selon un mode de réalisation préféré, la composition cosmétique contient 0,3 à 9~ en poids d'acide 2-hydroxy-4-méthoxybenzophénone-5-sulfonique qui peut étre neutralisé par un hydroxyde métallique, l'ammoniaque ou une amine. -Les exemples suivants illustrent l'inventàon sans pour autant la limiter.
On prëpare un shampooing protecteur des cheveux de composition suivante: , - Acide 2-hydroxy-4 méthoxy-benzophénone-5-sulfonique vendu sous la marque de commerce UVINUL MS 40 par la Société BASE 1 g - Alkyl (C12-C14) éther sulfate de sodium oxyéthyléné à 2,2 moles d'oxyde d'éthylène en solution aqueuse à
25~ de matière active (MA) 6,2 g MA
- Diéthanolamide de coprah vendu sous la marque de commerce COMPERLAN KD par la Société HENKEL 4 g ' - Acide chlorhydrique qs pH : 5 - Conservateur, colorant, parfum qs 100 g - Eau qsp Sur des cheveux décolorés ayant êté lavés cinq fois à l'aide de ce shampooing, puis exposés 120 heures au Suntest, on constate une amélioration importante de la valeur moyenne du palier à 15~ d'extension au mouillé par rapport à des cheveux décolorés ayant subi un traitement analogue mais avec la base de shampooing sans UVINUL MS
40.
L'êpreuve du Suntest s'effectue à l'aide d'un appareil "SUNTEST HANAU" qui est constitué d'un émetteur r.
au Xénon et d'un système de filtres produisant un rayonnement correspondant dans une très large mesure au rayonnement solaire. Le rayonnement ênergétique est de 585 W/M2 environ dans le domaine de longueurs d'ondes comprises entre 300 et 830 nm (rayonnement global).
On prëpare une mousse de coiffage protectrice des cheveux de composition suivante:
- Copolymère vinylméthyléther~anhydride maléfique monoestérifiê avec le butanol, vendu à 50~ de matiëre active (MA) dans l'éthanol sous la marque de commerce GANTREZ ES 425 par la Société GENERAL
ANILIN 0,6 g MA
- Hydroxyéthylcellulose greffée par du chlorure de diallyldiméthyl ammonium, vendue sous la marque de commerce CELQUAT
L 200_par la Sociétê NATIONAL STARCH 0,5 g - Polymère cationique siliconê vendu sous la marque de commerce UCAR SILICONE ALE en solution aqueuse à 35~ de matière active (MA) 56 par la Sociétë UNION CARBIDE 0,2 g MA
- Acide 2-hydroxy-4 méthoxybenzophénone-5-sulfonique vendu sous la marque de commerce UVINUL MS 40 par la Société
BASF 0,5 g - Alcool éthylique qs . 10°
- 2-amino-2-méthyl-propan-1-ol qs pH : 7,5 - Parfum, colorant, conservateur qs - Eau qsp 100 g On conditionne la composition ci-dessus dans un dispositif aérosol:
- Composition 90 g - FREONS 12/114 (5743 en poids) 10 g -Total 100 g FREON 12 - difluorodichlorométhane.
FREON 114 = 1,2-dichlorotétrafluoroéthane.
Des cheveux naturels permanentés reçoivent une application de cette mousse puis, sans rinçage consécutif, sont soumis à 180 heures d'exposition au Suntest, comme décrit à l'exemple 1.
Par rapport à des cheveux de mème nature traitês de façon analogue mais à l'aide d'une mousse ne renfermant pas d "'UVINUL MS 40", on enregistre une amélioration significative de la valeur moyenne du palier à 15~
d'extension au mouillé.
On prpare un gel de coiffage prot ecteur des cheveux de composition suivante:
- Acide 2-hydroxy-4-mthoxybenzophnone-5-sulfonique vendu sous la marque de commerce UNIVUL MS 40 par la Socit BASF 0,3 g - Copolymre acide mthacrylique/mthacrylate de mthyle 50/50 0,8 g MA
- Hydroxythylcellulose greffe par du chlorure de diallyldimthyl ammonium vendue sous la marque de commerce CELQUAT
L 200 par la Socit NATIONAL STARCH 0,8 g - Polymre cationique silicon vendu par la Socit DOW CORNING sous la marque de commerce EMULSION CATIONIQUE
DC 929 en solution aqueuse 35~ de matire active (MA) 0,3 g MA
- 2-amino-2-mthyl propan-1-ol qs pH: 7,5 - Alcool thylique qs :10 - Parfum, colorant,' conservateur qs - Eau qsp 100 g On 'traite des cheveux dcolors, par trois applications avec ce gel de coiffage, puis, sans les rincer, on les soumet 120 heures d'exposition au Suntest.
Comparativement à des cheveux de méme nature, traités de la même façon mais â l'aide dudit gel sans UVINUL MS 40, on constate une amélioration significative de la valeur moyenne du palier à 15~ d'extension au mouillé.
On prépare le spray de coiffage de composition suivante:
- Terpolymère acide crotonique/4-tert.butyl benzoate de vinyl/acétate de vinyle/
(10/25/65), préparé suivant le brevet français No. 2.439.798 (ex. 19) 6 g - 2-amino-2 méthyl propan-1-ol qs pour neutralisation - Acide 2-hydroxy-4-méthoxybenzophënone-5-sulfonique vendu sous la marque de commerce UVINUL MS 40 par la Société BASF . 1 g - Parfum qs - Alcool éthylique qsp 100 g -On conditionne la composition ci-dessus dans un flacon pompe.
Une application de ce spray de coiffage sur des cheveux décolorés que l'on ne rince pas et que l'on soumet ensuite à 120 heures d'exposition au Suntest permet d'améliorer de façon très appréciable la valeur moyenne du palier à 15~ d'extension au mouillé par rapport à des cheveux de méme nature, ayant subi un traitement analogue â l'aide d'un spray de composition identique sans UVINUL
MS 40.
On prépare un gel fluide de coiffage protecteur des cheveux de composition suivante:
- Acide polyacrylique réticulé PM : 4 000 000, vendu sous la marque de commerce CARBOPOL
940 par la Société GOODRICH 1 g - Acide 2-hydroxy-4-méthoxy benzophénone-5-sulfonique vendu sous la marque de commerce UVINUL MS 40 par la Sociêté BASF 0,3 g - Sel pentasodique de l'acide diéthylène triamino pentacétique 0,2 g - Triêthanolamine qs pH : 7 - Parfum, colorant, qs - Eau qsp 100 g Comme à l'exemple 3, on constate une amélioration de la valeur moyenne du palier à 15's d'extension au mouillé. - 6 -These compositions can be solutions aqueous or hydroalcoholic, optionally comprising surfactants; they can also be gels. These compositions can also be pressurized in aerosol in the form of sprays or foams.
In these rinsed compositions, the concentration of surfactants can vary between 0.1 and 10 ~, and preferably between 0.5 and 7 ~ by weight. They can also contain nonionic polymers, cationi-ques, anionic, amphoteric or mixtures thereof.
When hair compositions arise in the form of gels, to rinse or not, they contain thickeners with or without solvents.
Thickeners can be alginate sodium, gum arabic or xanthan gum or cellulose derivatives such as methyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, carboxymethyl cellulose or carboxylic polymers such as those sold under the CARBOPOL trademark. You can also get a thickening of lotions by mixing polyethylene glycol and polyethylene glycol stearate or distearate or by a mixture of phosphoric esters and amides. The thickener concentration can vary from 0.1 to 30 ~, and preferably 0.2 to 15 ~ by weight, based on the weight total of the composition.
A thickening agent can also be used which results from. the ionic interaction of a polymer cationic consisting of a cellulose copolymer or a cellulose derivative grafted with a monomer salt water-soluble quaternary ammonium (sold under the brand CELQUAT H 100 or CELQUAT L 200) and a anionic carboxylic polymer having a viscosity absolute capillary in dimethylformamide or methanol at a concentration of 5 ~ and at 30 ° C, lower or equal to 30.10 3 Pa.s.
This thickener is described in the patent French No. 2.598.611.
When the hair compositions appear in the form of foams, to rinse or not, they contain a foaming agent in an aqueous or hydroalcoholic medium, in the presence of a propellant.
As the foaming agent, anionic, nonionic, cationic surfactants, amphoteric or their mixtures, nonionic polymers, anionic, cationic or mixtures thereof, alcohol polyvinyl from hydrolyzed polyvinyl acetate whose hydrolysis rate is equal to or less than 97 ~ as described in French patent No. 2,598,613.
To form a foam, it is preferable to use a combination of cationic polymer and polymer anionic, at least one of the two polymers being foaming in aqueous solution. Such associations are described in French Patent No. 2,505,348.
The propellants used to pressurize these compositions intended to form foams, are present in proportions not exceeding 25 ~ and preferably 15â relative to the total weight of the composition. We can use carbon dioxide as a propellant, nitrogen, nitrous oxide, volatile hydrocarbons such as butane, isobutane, propane and their mixtures, non-chlorinated and / or fluorinated hydrocarbons hydrolyzable such as those sold under the brand name FREON or DYMEL trade by the DU PONT de NEMOURS Company.
When the composition is in the form of spray or hairspray, it contains in an alcoholic medium or hydroalcoholic, a film-forming resin in the presence possibly a propellant. We use preferably, as film-forming resin, an anionic polymer containing acrylic or methacrylic acid units, crotonic acid or ° <, ~ -dicarboxylic acid unsaturated.
The propellants used in these lacquer formulations can be chosen among volatile hydrocarbons such as n-butane, propane, isobutane or mixtures thereof or a mixture of these hydrocarbons with chlorinated hydrocarbons and / or fluorinated such as, the compounds sold under the brand of FREON or DYMEL trade by the DU PONT de NEMOURS Company and more particularly fluorochlorinated hycrocarbons _ such as monoflurotrichloromethane, difluorodichloro-methane, tetrafluorodichloroethane or mixtures of these latter.
They can also be chosen from chlorinated and / or fluorinated hydrocarbons described above and their mixtures, dimethyl ether, carbon dioxide or nitrous oxide.
The propellant phase, in these compositions of lacquer represents 30 to 80 ~ of the total weight of the composition pressurized.
When the hair compositions of the invention constitute restructuring lotions, they contain products strengthening the keratin chain of the hair.
To this class of products belong the derivatives methylolés such as those described in French patents Our. 1,527,085 and 1,519,979.
The present invention also relates to a method of protection of hair keratin against attack atmospheric, and in particular against light, consisting in applying to the hair at least 30 mg / g of hair of a cosmetic composition containing at least 0.3 ~ by weight of 2-hydroxy-4-methoxybenzophenone-5- acid optionally salified sulphonic, in an aqueous support, alcoholic or hydroalcoholic, cosmetically acceptable.
According to a preferred embodiment, the cosmetic composition contains 0.3 to 9 ~ by weight of acid 2-hydroxy-4-methoxybenzophenone-5-sulfonic which may be neutralized by a metallic hydroxide, ammonia or an amine. -The following examples illustrate the invention without however limit it.
We prepare a protective shampoo for the hair of following composition:, - 2-Hydroxy-4 methoxy acid-benzophenone-5-sulfonic sold under the trademark UVINUL MS 40 by the company BASE 1 g - Alkyl (C12-C14) ether sulfate oxyethylenated sodium to 2.2 moles of oxide ethylene in aqueous solution to 25 ~ active ingredient (MA) 6.2 g MA
- Coconut diethanolamide sold under the COMPERLAN KD trademark by HENKEL 4 g '- Hydrochloric acid qs pH: 5 - Preservative, colorant, perfume qs 100g - Water qs On bleached hair that has been washed five times using this shampoo and then exposed 120 hours to Suntest, there is a significant improvement in the average value of the bearing at 15 ~ wet extension by compared to bleached hair having undergone treatment analogous but with the shampoo base without UVINUL MS
40.
The Suntest test is carried out using a "SUNTEST HANAU" device which consists of a transmitter r.
with Xenon and a filter system producing a radiation corresponding to a very large extent to solar radiation. The energy radiation is 585 W / M2 approximately in the wavelength range between 300 and 830 nm (global radiation).
We prepare a protective styling foam for hair of the following composition:
- Vinylmethyl ether ~ anhydride copolymer maleficent monoesterified with butanol, sold at 50 ~ active ingredient (MA) in ethanol under the trademark GANTREZ ES 425 by GENERAL
ANILIN 0.6 g MA
- Hydroxyethylcellulose grafted with diallyldimethyl ammonium chloride, sold under the trademark CELQUAT
L 200_by Société NATIONAL STARCH 0.5 g - Cationic silicone polymer sold under the trademark UCAR SILICONE ALE in 35 ~ aqueous solution of active ingredient (MA) 56 by UNION CARBIDE 0.2 g MA
- 2-Hydroxy-4-methoxybenzophenone-5- acid sulfonic sold under the brand of UVINUL MS 40 trade by the Company BASF 0.5 g - Ethyl alcohol qs. 10 °
- 2-amino-2-methyl-propan-1-ol qs pH: 7.5 - Perfume, color, preservative qs - Water qs 100 g We condition the above composition in a aerosol device:
- Composition 90 g - FREONS 12/114 (5743 by weight) 10 g -Total 100 g FREON 12 - difluorodichloromethane.
FREON 114 = 1,2-dichlorotetrafluoroethane.
Permed natural hair receives a application of this foam then, without subsequent rinsing, are subject to 180 hours of exposure at Suntest, as described in Example 1.
Compared to treated hair of the same nature similarly but using a foam that does not contain no "UVINUL MS 40", there is an improvement significant of the average value of the plateau at 15 ~
wet extension.
We prepare a protective styling gel hair of the following composition:
- 2-hydroxy-4-mthoxybenzophnone-5- acid sulfonic sold under the brand of UNIVUL MS 40 by Socit BASF 0.3 g - Methacrylic acid / methacrylate copolymer of methyl 50/50 0.8 g MA
- Hydroxythylcellulose grafted with diallyldimthyl ammonium chloride sold under the trademark CELQUAT
L 200 by SOCit NATIONAL STARCH 0.8 g - Cationic silicone polymer sold by the DOW CORNING Company under the trademark CATIONIC EMULSION
DC 929 in 35 ~ aqueous solution of active ingredient (AD) 0.3 g AD
- 2-amino-2-methyl propan-1-ol qs pH: 7.5 - Thyl alcohol qs: 10 - Perfume, colorant, 'preservative qs - Water qs 100 g We treat colored hair, in threes applications with this styling gel, then without rinse, subject them to 120 hours of exposure at Suntest.
Compared to hair of the same kind, treated in the same way but using said gel without UVINUL MS 40, there is a significant improvement of the average value of the plateau at 15 ~ extension at wet.
The composition styling spray is prepared next:
- Crotonic acid / 4-tert.butyl terpolymer vinyl benzoate / vinyl acetate /
(10/25/65), prepared according to the patent French No. 2,439,798 (ex. 19) 6 g - 2-amino-2 methyl propan-1-ol qs for neutralization - 2-Hydroxy-4-methoxybenzophenone-5- acid sulfonic sold under the trademark UVINUL MS 40 by BASF. 1 g - Perfume qs - Ethyl alcohol qs 100 g -We condition the above composition in a pump bottle.
An application of this styling spray on bleached hair that is not rinsed and submitted then at 120 hours of exposure to Suntest allows significantly improve the average value of the level at 15 ~ wet extension compared to hair of the same nature, having undergone a similar treatment using a spray of identical composition without UVINUL
MS 40.
We prepare a fluid protective styling gel hair of the following composition:
- Crosslinked polyacrylic acid PM: 4,000,000, sold under the CARBOPOL trademark 940 by the company GOODRICH 1 g - 2-Hydroxy-4-methoxy benzophenone-5- acid sulfonic sold under the trademark UVINUL MS 40 by BASF Company 0.3 g - Pentasodium salt of diethylene acid 0.2 g triamino pentacetic - Triethanolamine qs pH: 7 - Perfume, color, qs - Water qs 100 g As in Example 3, there is an improvement of the average value of the bearing at 15's extension at wet.
Claims (32)
caractérisé par le fait qu'il consiste à appliquer sur les cheveux au moins 30 mg/g de cheveux d'une composition cosmétique telle que définie dans les revendications 8 ou 9. 30. Method for protecting mechanical properties hair, and mainly the plateau at 15% extension in the wet, against atmospheric attack.
characterized by the fact that it consists in applying to the hair at least 30 mg / g of hair of a composition cosmetic as defined in claims 8 or 9.
cheveux au moins 30 mg/g de cheveux d'une composition cosmétique telle que définie dans les revendications 13, 14 ou 19. 31. Process for protecting mechanical properties hair, and mainly the plateau at 15% extension in the wet, against atmospheric attack, characterized by the fact that it consists in applying to the ~
hair at least 30 mg / g of hair of a composition cosmetic as defined in claims 13, 14 or 19.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU87130A LU87130A1 (en) | 1988-02-11 | 1988-02-11 | USE OF 2-HYDROXY-4-METHOBENZOPHENONE-5-SULFONIC ACID OR ITS SALTS FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING THE SAME |
| LU87130 | 1988-02-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1341189C true CA1341189C (en) | 2001-02-27 |
Family
ID=19731022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000590897A Expired - Fee Related CA1341189C (en) | 1988-02-11 | 1989-02-13 | Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for the protection of hair against atmospheric agressions, and particularly against light, and process for hairprotection with this compound |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JP2720884B2 (en) |
| AT (1) | ATA19489A (en) |
| BE (1) | BE1003099A5 (en) |
| CA (1) | CA1341189C (en) |
| CH (1) | CH678010A5 (en) |
| DE (1) | DE3943861B4 (en) |
| FR (1) | FR2627085B1 (en) |
| GB (1) | GB2215602B (en) |
| IT (1) | IT1232710B (en) |
| LU (1) | LU87130A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5186928A (en) * | 1989-02-20 | 1993-02-16 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Shampoo composition |
| GB8903777D0 (en) * | 1989-02-20 | 1989-04-05 | Unilever Plc | Shampoo composition |
| US5045307A (en) * | 1990-01-09 | 1991-09-03 | Colgate-Palmolive Company | Composition that protects dyed hair from fading |
| JPH05286830A (en) * | 1992-04-10 | 1993-11-02 | Kao Corp | Hair treating agent composition |
| ATE140382T1 (en) * | 1991-08-14 | 1996-08-15 | Kao Corp | HAIR CARE PRODUCTS |
| FR2719468B1 (en) * | 1994-05-05 | 1996-05-31 | Oreal | Cosmetic compositions based on certain bioflavonoids and uses in particular in the hair field. |
| US8790623B2 (en) | 2005-01-18 | 2014-07-29 | Il'Oreal | Composition for treating keratin fibers, comprising at least one aromatic alcohol, at least one aromatic carboxylic acid, and at least one protecting agent |
| FR2880801B1 (en) | 2005-01-18 | 2008-12-19 | Oreal | COMPOSITION FOR TREATING KERATIN FIBERS COMPRISING AROMATIC ALCOHOL, AROMATIC CARBOXYLIC ACID AND PROTECTIVE AGENT |
| FR2887440B1 (en) | 2005-06-28 | 2009-07-10 | Oreal | PROCESS FOR PHOTOPROTECTIVE TREATMENT OF KERATIN FIBERS BY HEAT APPLICATION |
| US7998464B2 (en) | 2005-09-29 | 2011-08-16 | L'oreal S.A. | Process for the photoprotective treatment of artificially dyed keratin fibers by application of a liquid water/steam mixture |
| FR2940068A1 (en) * | 2008-12-22 | 2010-06-25 | Oreal | Composition, useful for e.g. cleaning keratin materials, comprises anionic surfactants, carboxylic anionic surfactants, amphoteric and/or zwitterionic surfactants, alkyl(poly)glycoside nonionic surfactants, cationic polymers, and filters |
| FR2955255B1 (en) | 2010-01-15 | 2012-02-24 | Oreal | COSMETIC COMPOSITION COMPRISING A HYDROPHILIC GRAFT POLYSACCHARIDE AND COSMETIC TREATMENT METHOD |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3577528A (en) * | 1966-05-27 | 1971-05-04 | Zotos Int Inc | Two phase hair conditioner compositions |
| DE2046818A1 (en) * | 1970-09-23 | 1972-03-30 | Wella Ag, 6100 Darmstadt | Hair dyeing and setting preparations - contng benzimidazole benzophenone and phenylglyoxylic acid derivs |
| US3670074A (en) * | 1971-01-22 | 1972-06-13 | Cyril Doner | Sunscreen formulation containing triethanolamine neutralized 2-hydroxy-4-methoxy-benzophenone-5-sulfonic acid |
| FR2509989A1 (en) * | 1981-07-27 | 1983-01-28 | Oreal | Cosmetic contg. water soluble sunscreening agent - in aq. phase of water in oil dispersion |
| US4567038A (en) * | 1985-03-06 | 1986-01-28 | Revlon, Inc. | Sunscreen composition for hair protection |
-
1988
- 1988-02-11 LU LU87130A patent/LU87130A1/en unknown
-
1989
- 1989-01-31 AT AT0019489A patent/ATA19489A/en not_active Application Discontinuation
- 1989-02-09 CH CH444/89A patent/CH678010A5/fr not_active IP Right Cessation
- 1989-02-09 FR FR8901704A patent/FR2627085B1/en not_active Expired - Lifetime
- 1989-02-10 GB GB8903068A patent/GB2215602B/en not_active Expired - Lifetime
- 1989-02-10 BE BE8900134A patent/BE1003099A5/en not_active IP Right Cessation
- 1989-02-10 JP JP1032572A patent/JP2720884B2/en not_active Expired - Fee Related
- 1989-02-10 IT IT8967073A patent/IT1232710B/en active
- 1989-02-10 DE DE3943861A patent/DE3943861B4/en not_active Expired - Lifetime
- 1989-02-13 CA CA000590897A patent/CA1341189C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| GB2215602B (en) | 1991-10-02 |
| GB2215602A (en) | 1989-09-27 |
| ATA19489A (en) | 1997-09-15 |
| IT8967073A0 (en) | 1989-02-10 |
| LU87130A1 (en) | 1989-09-20 |
| FR2627085A1 (en) | 1989-08-18 |
| JP2720884B2 (en) | 1998-03-04 |
| IT1232710B (en) | 1992-03-04 |
| FR2627085B1 (en) | 1994-10-28 |
| GB8903068D0 (en) | 1989-03-30 |
| BE1003099A5 (en) | 1991-11-26 |
| CH678010A5 (en) | 1991-07-31 |
| DE3943861B4 (en) | 2013-08-08 |
| JPH01294613A (en) | 1989-11-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1158560A (en) | Composition for the treatment of keratinous fibers containing amphoteric polymers and anionic polymers | |
| EP0953334B1 (en) | Composition for dying keratinous fibres with a direct cationic dye and a substantive polymer | |
| EP0761199B1 (en) | Cosmetic composition having fixing and conditioning properties containing a particular acrylic copolymer | |
| EP0577519B1 (en) | Cosmetic composition containing maltodextrin for dressing and/or for fixing the hair | |
| EP1779896A2 (en) | Cosmetic composition comprising at least a fixing polymer and an ionic or non ionic surfactant | |
| CA1341189C (en) | Use of 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid or its salts for the protection of hair against atmospheric agressions, and particularly against light, and process for hairprotection with this compound | |
| CH651749A5 (en) | COMPOSITION FOR THE TREATMENT OF KERATINIC FIBERS BASED ON AMPHOTERIC POLYMERS AND CATIONIC POLYMERS. | |
| CA2324302A1 (en) | Poly-aminoacid derivatives and their use in compositions for treating keratinous fibres | |
| CA1341193C (en) | Capillary cosmetic composition containing hydroxyalkyl polyorganosiloxanes | |
| BE1000613A5 (en) | USE OF POLYAMINOAMIDES FOR THE PROTECTION OF HAIR AGAINST ATMOSPHERIC AGGRESSIONS, AND PARTICULARLY AGAINST LIGHT, AND METHOD FOR PROTECTING HAIR USING SUCH POLYAMINOAMIDES. | |
| EP0504040B1 (en) | Use of lactoferrin to protect hair keratin from atmospheric aggressions, particularly light, and process for protecting the hair using this compound | |
| FR2566268A1 (en) | NOVEL COSMETIC COMPOSITIONS FOR DELAYING THE APPEARANCE OF A FATTY ASPECT OF THE HAIR, AND USE THEREOF | |
| US5240695A (en) | Use of 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its salts for protecting the hair against environmental attacking agents, and especially against light and process for protecting the hair using the compound | |
| CA1310914C (en) | Use of 4-(2-oxo-3-bornylidenemethyl)benzenesulfonic acid or its salts for the protection of hair against atmospheric attack and particularly against light, and process for the protection of hair using this compound | |
| FR2740034A1 (en) | COMPOSITION FOR THE TREATMENT OF KERATINIC MATERIALS COMPRISING AT LEAST ONE FIXING POLYMER AND AT LEAST ONE CERAMID-LIKE COMPOUND AND METHODS | |
| FR2709955A1 (en) | Cosmetic compositions containing a polysiloxane-polyoxyalkylene linear block copolymer and an amphoteric polymer, and their uses | |
| US5227153A (en) | Use of 4-(2-oxo-3-bornylidenemethyl)benzenesulfphonic acid or its salts for the protection of hair against environmental attacking agents, and in particular against light, and process for the protection of hair using this compound | |
| CA1310586C (en) | Cosmetic compound used to fix an hairdo, containing an oxazoline polymer and a 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, or its salt | |
| EP1240888A1 (en) | A hair-treatment composition containing a polysaccharide grafted by a polysiloxane and a fixing polymer | |
| FR2783166A1 (en) | Capillary-action cosmetic composition, for hair conditioning and-or styling, contains at least one dimethiconol-isophorone diisocyanate copolymer and at least one arylated silicon compound | |
| EP0618794B1 (en) | Use of 4- (2-oxo-3-bornylidene)methyl]-phenyltrimethylammonium methyl sulphate composition for permanent hair shaping, affording protection from the ravages of the weather, and especially light | |
| EP1447076A1 (en) | Use of fullerene solutions for conditioning hair | |
| FR2795951A1 (en) | Cosmetic composition for treating keratinic material, e.g. as a shampoo, comprises a cosmetic medium, a fructane with an amine group(s) and a protector(s) | |
| DE3904054A1 (en) | USE OF 2-HYDROXY-4-METHOXYBENZOPHENONE-5-SULFONIC ACID OR SALTS THEREOF FOR PROTECTING THE HAIR FROM ATMOSPHERIC INJURIES, ESPECIALLY TO LIGHT, AND PROCESS FOR PROTECTING THE HAIR USING THIS LINK |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |