CA1339540C - Methods and devices used in the microwave heating of foods and other materials - Google Patents

Methods and devices used in the microwave heating of foods and other materials

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Publication number
CA1339540C
CA1339540C CA000590564A CA590564A CA1339540C CA 1339540 C CA1339540 C CA 1339540C CA 000590564 A CA000590564 A CA 000590564A CA 590564 A CA590564 A CA 590564A CA 1339540 C CA1339540 C CA 1339540C
Authority
CA
Canada
Prior art keywords
microwave
article
surface layer
apertures
aperture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA000590564A
Other languages
French (fr)
Inventor
Richard M. Keefer
Cindy Marie Lacroix
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rio Tinto Alcan International Ltd
Original Assignee
Alcan International Ltd Canada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alcan International Ltd Canada filed Critical Alcan International Ltd Canada
Priority to CA000590564A priority Critical patent/CA1339540C/en
Priority to ZA90446A priority patent/ZA90446B/en
Priority to DE69014331T priority patent/DE69014331T2/en
Priority to AT90300997T priority patent/ATE114598T1/en
Priority to EP90300997A priority patent/EP0382399B1/en
Priority to NO90900546A priority patent/NO900546L/en
Priority to BR909000574A priority patent/BR9000574A/en
Priority to AU49171/90A priority patent/AU628918B2/en
Priority to FI900648A priority patent/FI900648A0/en
Priority to JP2031351A priority patent/JP3049071B2/en
Priority to US08/015,311 priority patent/US5519195A/en
Application granted granted Critical
Publication of CA1339540C publication Critical patent/CA1339540C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/34Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
    • B65D81/3446Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
    • B65D81/3453Rigid containers, e.g. trays, bottles, boxes, cups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3439Means for affecting the heating or cooking properties
    • B65D2581/344Geometry or shape factors influencing the microwave heating properties
    • B65D2581/34413-D geometry or shape factors, e.g. depth-wise
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3486Dielectric characteristics of microwave reactive packaging
    • B65D2581/3487Reflection, Absorption and Transmission [RAT] properties of the microwave reactive package
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2581/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D2581/34Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
    • B65D2581/3437Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
    • B65D2581/3486Dielectric characteristics of microwave reactive packaging
    • B65D2581/3489Microwave reflector, i.e. microwave shield

Abstract

A method and device for enhancing the heating of a surface layer of an article being heated by microwave energy is characterised by directing the energy through the surface layer into a main portion of the article in such a manner that the modes of the energy are in cut-off in the surface layer.

Description

Methods and devices used in the microwave heating of foods and other materials This invention relates to methods and devices for modifying microwave energy fields, having utility in the microwave heating of bodies of material exemplified by (but not limited to) foodstuffs.
It is well known that the conventional microwave cooking or heating of a food load does not provide effective browning or crispening of the food surfaces.
Those food products that have a surface composed of a material different from that of the main portion of the food article, such as a crust or a layer of batter or breading, for example a pie or a breaded fish fillet, require this separate surface layer to reach a higher temperature than the bulk of the food, in order that such surface layer be browned or crispened. For this reason, a conventional convection oven set at a relatively high temperature has been the traditional method of cooking such food products.
There are also other types of food articles in which the nature of the surface layer is essentially the same as that of the main portion of the article, but it nevertheless requires to be browned and/or crispened.
Examples in this category are the undersurface of a pizza, 13 39 a 40 the two surfaces of a pancake, hash brown potatoes or french fried potatoes.
The conventional method of trying to meet this need in microwave cooking has been by means of devices known as susceptors. A susceptor is a device that incorporates lossy material, i.e. material that absorbs the microwave energy to become heated. This device is then placed close to the surface layer to be browned or crispened so that the heat in the susceptor is transferred by conduction and radiation to this surface layer. This process necessarily requires the temperature of the susceptor to be higher than that of the surface layer in order for the heat to flow into such layer. It has been found that there are practical disadvantages in heating the susceptor to the necessary high temperatures. There is always the risk of overheating and of breakdown of the material of the susceptor, and even the generation of toxic products.
An example of one method of attempting to achieve this type of surface heating effect has been suggested by W.A.
Brastad et al in United States Patent No. 4,230,924 issued October 28, 1980. This proposal involves wrapping the food product in a flexible sheet of dielectric material that functions as a substrate to carry a thin metallic coating that is subdivided into a number of individual metal islands separated by non-metallic gaps formed by - exposed strips of the dielectric material of the substrate.
When a food load wrapped in such a flexible sheet is exposed to microwave energy in a microwave oven, some of the energy passes through the sheet to heat the food load dielectrically in the usual manner, while some of the energy is converted in the metallic islands into thermal energy, i.e. the islands act as susceptors, so that, provided the islands are closely adjacent to a surface of the food load, the heat generated in the islands will be transferred directly by conduction to the food surface to 1339~40 elevate its temperature and thus achieve a browning or crispening effect. The mentioned patent discloses that the microwave-transparency of the wrapping can be varied in order to adapt to the requirements of a particular food article by modifying the ratio between the dielectric (bulk) heating and the thermal heating generated in the wrapping and transferred therefrom to the food surface.
In other words, the wrapping described in this prior ~- patent simultaneously acts as a microwave-transparent covering for part of the energy, and as a susceptor, i.e.
a structure that absorbs microwave energy and hence becomes heated, for the remainder of the applied energy.
Another known type of susceptor is that embedded in a cooking utensil, such as a frying pan or baking dish. The utensil can be placed in a microwave oven, initially with or without food in it. The susceptor in the utensil absorbs microwave energy, so that the cooking surface of the utensil becomes heated to a high temperature. When the food is added, or if it has been present from the outset, its bulk is heated dielectrically in the usual manner in a microwave oven and its surface is browned or crispened by the cooking surface of the utensil.
In contrast to the concept of using a susceptor to heat a surface layer of a food article, either directly by a wrapping, or indirectly through a preheated dish, the present invention provides an arrangement in which the surface layer of the article to be heated as well as its main portion beneath the surface layer continue to be heated dielectrically, i.e. by the microwave energy, without first converting such energy into heat in a susceptor. According to the invention, the microwave energy field is so altered that the dielectric heating effect within the surface layer is enhanced relative to the dielectric heating effect in the main portion of the article. As a result, the surface layer reaches a higher 1339 ;~0 -temperature. In the case of a food article, this non-uniformity of 'neating results in browning and/or ~crispening of the surface layer.
The surface layer of the food article may be a top layer (for example, a pie crust), or a bottom layer tfor example, a pizza base), or both top and bottom layers (for example, a breaded f ish fillet).
According to the invention the desired enhanced heating effect within the surface layer is achieved by means of a so-called mode-filtering structure that causes the micro-wave energy to enter the absorber (foodstuff or other body to be heated) in the form of cut-off propagation (herein sometimes also referred to as "evanescent propagationn), thus causing the heating effect to be concentrated at the absorber surface adjacent the mode-filtering structure.
The term "mode-filtering" is employed to refer to accentuation of the transmission of higher order modes while reflecting fundamental modes.
~ icrowaves that are in cut-off are referred to as propagating evanescently because they decay exponentially.
Due to this strong decay of evanescent microwaves, the ratio of surface to bulk field intensities (or heating) is increased. Analogously with the skin effect observed at high frequencies in conductors, more energy is deposited on the surface layer than in the bulk from the modes of microwave energy that propagate through the apertures in cut-off in the surface layer.
The device~employed for this purpose, in accordance with the invention, consists of a sheet of microwave transparent material provided with substantially non-absorptive conductive material defining either an island-aperture array or an array of annuli defining apertures, the dimensions of the annuli or of the gaps between the islands and the apertures being such as to achieve the desired absorption profile.
The apertures will be of such dimensions that, at the frequency of the microwave energy and with the sheet located adjacent the surface layer of the article to 1339~0 be heated, the modes of energy that propagate through the apertures will be in cut-off in the surface layer.
Such modes may or ~ay not be in cut-off in the main portion (bulK) of the article lying beneath the surface layer.
A device according to the invention can be located on a separate sheet of microwave-transparent material, or it can be embodied in a container for the article, e.g. as a bottom wall or lid of such container. In the latter case, small holes for venting steam and/or for draining liquids such as fat can be provided in the container structure.
The present arrangement readily lends itself to the provision of such venting and draining holes, whereas it would be difficult to incorporate this feature into a standard susceptor or the devices described by the aforemented U.S. patent.
The term "container" as used herein embraces all manner of elements or devices (including, but not limited to, flat sheets, laminar members, pouches, pans, lidded containers, etc.) that at least partially enclose, contain, hold, support, or are supported by, the foodstuff or other material during heating in a microwave oven.
The invention also relates to a method of enhancing the heating of a surface layer of an article being heated by microwave energy by utilizing the foregoing concept of arranging the energy to be in cut-off in at least the surface layer.
In those instances where the surface layer is formed of the same substance as the main portion of the article, the modes of micr~wave energy that propagate through the apertures will be in cut off for both the surface layer and the main portion. As a result, attenuation will be higher per unit distance into the article, but there will still be a greater heating effect in tne surface layer due to evanescent propagation. The fact that the propagation 13 39~40 into the main portion is also evanescent will result in less depth of heating in such main portion, but this feature may well be acceptable in practice if the product is a thin one, e.g. pizza, pancake, sliced potato etc.
It is known that the generation or enhancement of ~odes of the microwave energy of higher order than the fundamental modes propagating in the article to be heated can enhance the uniformity of heating of the article in its lateral dimension. See for example U.S. patent No.
4,866,234 of R.M. Keefer issued September 12, 1989 (European patent application 86304880 filed June 24, 1986 and published December 30, 198~ under No. 206,811).
See also European applications of R.M. Reefer published November 19, 1987 under No. 246041; published May 24, 1989 under No. 317203 and published June 22, 1988 under No.
271981.
It should be ex~lained that the term "mode" is used in this specification and claims in its art-recognized sense, as meaning one of several states of electromagnetic wave oscillation that may be sustained in a given resonant system at a fixed frequency, each such state or type of vibration (i.e. each mode) being characterised by its own particular electric and magnetic field configurations or patterns. The fundamental modes, i.e. normally the 1-0 mode and the 0-1 mode in a rectangular system, of a body of material to be heated, or of such body and a container in which it is located, are c'naracterised by an electric field pattern (power distribution) typically concentrated around the edge (as viewed in a horizontal plane) of the body of the substance to be heated, or around the periphery of its container when the substance is enclosed by and fills a container, these fundamental modes predominating in a system that does not include any higher order mode generating means. The fundamental modes are thus defined by the geometry of the container and the contained body of material to be heated, or alternatively by such body itself 133~540 when it constitutes a separate article that is not placed in a container.
A mode of a higher order than that of the fundamental - modes is a mode for which the electric field pattern (again, for convenience of description, considered as viewed in a horizontal plane) corresponds to each of a repeating series of areas smaller than that circumscribed by the electric field pattern of the fundamental modes.
Each such electric field pattern may be visualized, with some simplification but nevertheless usefully, as corresponding to a closed loop in the horizontal plane.
The preferred embodiments of the present invention combine the uniformity of heating of the load in the lateral dimensions that can be achieved with the generation of higher order modes, with the desired disuniformity of heating in the direction perpendicular to the lateral dimensions of the load, i.e. in the direction perpendicular to the surface of the load, as is required for the surface to be browned or crispened.
In the accompanying drawings:
Fig. 1 is a top plan view of an example of a mode-filtering structure embodying the present invention in a particular form;
Fig. 2 is a fragmentary sectional view taken along the line 2-2 of Fig. l;
- Fig. 3 is a fragmentary top plan view, similar to Fig.
1, of another embodiment of mode-filtering structure of the invention;
Fig. 4 is a fragmentary sectional view taken along the line 4-4 of Fig. 3;
Fig. 5 is a perspective view of a microwave heating container, for holding a body of foodstuff, incorporating an embodiment of mode-filtering structure of the invention generally similar to that of Fig. l;
Fig. 6 is a fragmentary elevational sectional view of the same container, taken along the line 6-6 of Fig. 5;

- 8 - 1 3 3 9 5 q O

Fig. 7 is a view similar to Fig. 6 of a modified container incorporating two of the mode-filtering structures of the invention;
Figs. 8, 9 and 10 are fragmentary elevational sectional views of the container lids and mode filters of three additional embodiments of the invention;
Fig. 11 is a top plan view of a container of circular plan, embodying the invention;
Fig. 12 is a top plan view of a further embodiment of the mode-filtering structure of the invention, having ~tility, for example, with a container as shown in Fig. 5;
Fig. 13 is a perspective view of another container incorporating an emboaiment of the invention;
Figs. 14 through 22 are fragmentary plan views of further configurations of mode filters in accordance with the invention;
Fig. 23 is a fragmentary perspective view of yet anocher container em~odying the invention;
Fig. 24 is a fragmentary perspective view of another embodiment of the invention;
Fig. 25 is a fragmentary elevational sectional view of a curved microwave heating container lid incorporating a mode filter in accordance with the invention;
Fig. 26 is a similar view oE a curved container lid incorporating another mode filter in accordance with the invention;
Figs. 27 and 28 are fragmentary sectional elevational views of mode~filters in accordance with the invention, formed in container bottoms;
Fig. 29 is a top plan view of the container tray of still another em~odiment of the invention;
Fig. 30 is a sectional elevational view of the tray of Fig. 29;

1~39540 Figs. 31 and 32 are fragmentary perspective views of two additional embodiments of the mode-filtering structures of the invention;
Fig. 33 is a view, similar to Figs. 14-22, of yet another mode filter in accordance with the invention;
Figs. 34-36 are graphs illustrating the relationship between absorption profile and cut-off of an induced mode;
Fig. 37 is a perspective view of a device according to one embodiment of the invention, illustrating a manner of using such device;
Figs. 38-41 are fragmentary plan views of alternative embodiments;
Fig. 42 is an illustrative diagram;
Fig. 43 is a diagram explaining an experiment;
Fig. 44A and 44B are graphs showing the results of this experiment; and Figs. 45-48 show different arrays that were used in Experiment 3 described below.
The embodiment of the invention illustrated in Figs.
1 and 2 is a mode-filtering structure including a flat sheet 20 (shown as rectangular) of microwave-transparent material such as a suitable plastic, which may, in one illustrative example, be the flat top portion of a microwave heating container lid. In this embodiment, a single mode filter 22 is mounted on a flat surface of - the sheet 20. Specifically, an electrically conductiveplate 24 (e.g., a plate of household-gauge aluminum foil, or of so-called converter gauge foil, the thickness of which would typically range between 6 and 7 microns) is bonded to the sheet top surface, the outer dimensions of this plate being about equal to the latter surface so that the plate 24 extends substantially over the entire sheet in a horizontal plane. This plate is formed with a plurality of apertures 26 each with a 13395~0 - lC --clased perlphery of generally rectangular confiquration;
a 5 x 4 array of t~enty apert~res is shown, with all a~
the apertures bein5 identical in size and spaced apart from each other and from the auter periphery o~ the plate ~y strip or ~ullion portions Z8 a~ the plate.
The ape~ ~~L e3 are e~uidistantly spaced in an arran~-ment that is symmetrical with respect to the plate Z4 and shest 20.
The mode filter 22 also includes a plurality a~
electrically conductive islands 30, which in this par-ticular ~mhqA iment are identical to each other in shape and dl -~cions and are aqain conveniently fa~ricated af hausehald-gauge all~in~ foil, bonded to the same sheet surface as the plate 24. These islands 30 are equal i~
num~er to the apertures 26, and have closed generally r2ctanqu1ar peripheries substanlially confor~ing in shape to the aperture peripheries ~ut are smaller in area than the apeL~u~3; the islands 30 are respectively dispased within (and in register with) the apertures 26, sa that the periphery of each island 3~ is substantially unifor~ly spaced from the surrounding aperture periph-ery, and defines therewith a rectang~lar annular gap 32 (which, in thLs embadinent, is of su~stantially uni~or~
width) closed or spanned ~y the microwave-trans3issive dielectric material of the sheet 20. Thus a 5 x 4 array of twenty spaced, unifor~ly and sy~metrically distri~ut-ed rectan5ular annular gaps 32 is provided in the made-filterin~ structure. It will be seen that these gaps constitute essentially the only microwave-transmissive arezs or windows in the entire structure, since the s~.eet 20 is other~ise covered by the conductive plate 22.
In a specific dimensional exanple of the embodiment of Figs. 1 and 2, each o~ the apertures 26 is a 2.20 x 1.8 cm rectangle, the strips Z8 between apertu.es (on 133~540 bcth the long and short sides of the apertures) being a . s C3 in witth. Each of the conductive islands 3 0 is a 1.70 x 1.3 cm ractangle, and is centered in its assaci-ated aperture so as ta def ine therewith a rectang~lar annular gap 12 having a unifo~ width of ~.25 c~ on alL
sides. ThQ outer end columns o~ ~our apertures aree spaced 1.0 c~ from the short side edges 24a of the plate 24, and the outer s~de rows of fi~e apeL~u~e5 are spaced 1.5 cm ~rc~ the long side edges 24b of the plate 24, which has 2.0 cm-radiused corners.
~ single mode filter as exemplLfied ~y the a~ove-desc~i~ed emkadiment of Figs. 1-2 may be used (by way o~
non-limiting example) with metallic, co~p~site, or microwave-transparent containers, includins those de-scr~bed in one or more c~ the aforementioned cop~n~in~
applications. In some inst~c~s, the use of metallic cont~ s is pre~erred, because radiation entering the cont~l n~r is then forced to inter7ct with the mode filter. By contrast, when a mcde ~ilter is use~ with a microwa~e-transparent container, it exerts little in-fluenc on radiaticn entering the container through the other s~rfacas not ad~acent to it.
To constituto a mcde filter as in the abcve-de-scribed ~ho~i~ent cf the invention, an ar~ay of one or more metallic islands ("island array") is superimposed on an array af one or more correspandinq apertures ("ape-ture,array") o~ a metallic area or plate. Bcth the island and aperture arrays may be constructed (as by die-cutting) from aluminum foil, for example. When used with a metallic container, the mode filter is pre~erably pos ;ioned over the container, in electrical isolation from it, as in the em~adl~ent of Figs. 5-6 described below. ~owe~er, the made filter may als~ be in close mechanical and electrical contact with the container, or may be inte~ral with it (as in a pouc~ type o~ con-struction, also described belcw, with reference to Fig.23). When the aperture array is fabricated from rigid foil, a container or pan for holding the food to be heated may be constructed ~rom the same foil, using similar techniques to thase e~ployed in the manu~acture of "wrinkle-wall" or "smacthwall'' pans.
Dielectric material is used to maintain the spatial relationship between the island and aperture arrays.
Suitable dielectric material (typified by such plastics as polypropylene, polyester, or polycar~onate resins) shcws g~od resistanc2 to dielectric breakdown, has low dielectric losses, and ~aintains its strength properties at the service temperatures impased by the heating o~
the focd.
Each island is generally centered on each aper-ture, but may be either coplanar with the aperture, cr (as hereinafter further explained, for example with reference to Figs. 3-4 and 8-10) displaced vertically, s~ as to be approximately plane-parallel with the aper-ture. When the island array is coplanar with the aper-ture array, the area cf each island is constrained to be less than that of the corresponding aperture. However, when the island and aperture arrays are vertically displaced tas, for example, in Figs. 3-4), the islands may be of greater or lesser area than the corresponding apertures.
One example of an arrangement for use of the mode-~iltering structure of Figs. 1 and 2 in conjunction with a microwave heating container is illustrated in Figs. 5 and 6, which show a microwave heating container having a gene~ally rect~n~ular, upwardly opening tray 10, with a bcttom 11 and side walls 12, fabricated of metal (e.g.
stiff, formed aluminum foil), for receiving and holding a body of fo~dstuff 1~ to be heated. A molded plastic (dielectric material) lid 16, transparent to mic.owave energy and havin~ a downwardly ext~n~ing portion 18 and a flat top or sheet pcrtion 20, ccvers the upward opening of the tray, the downwardly extending portion seatin~ on the tray rim. Typically, the upper surface of the contained foodstuff is spaced below the top of the lid.
The mote filter 22, as described with reference to Figs. 1 and 2 (but here shown as having a 4 x 4 array of apertures and islands) is mounted on the upwardly facing flat surface of the lid top 20. Thus, the electrically conductive plate 24 (e.g., of hcuseh~ld-gauge aluminum foil) is bonded to the lid top surface, extP~ g sub-stantially cver the entire lid in a hcrizontal plane, though the plate is electrically isclated from the metallic tray 10 ~y the downwardly eXt~n~i n~ portion 18 of the dielectric material lid. The islands 30 are liXewise bonded to the lid top surface. The arrangement of apertures and islands is sy~metrical with respect to the rectangular lid top and thus with respe~t to the container as viewed in a horizontal plane. Thus a 4 x 4 array ~f sixteen spaced, uniforcly and symmetrically distri~uted rectangular annular gaps 32 is provided in the lid top, constituting essentially the only micro-wave-transmissive areas or windows in the entire lid top, which is otherwise covered by the conductive plate 22.
Fig. 7 ,illustrates a madified for~ of container in which the tray lOa, liXe the lid, is for~ed of micro-wave-transparent material rather than metal, and in which a second mode-filterins structure 122a (which may be identical to, and in register with, the abave-de-scribed mode filter 22) is mounted on the downwardly-facing flat bottom surface of the microwave-transparent tray lOa. Both the plate lZ~a and islands 130a of the structure 122a may be constituted of household-gauge 13395~

al~min~l~ foil bonded to the tray battom surface. The plate 12~a defines an array af apertures 126a, the per~pheries of which in cooperation with the per~pher-ies a~ the islands 13aa define an array of gaps 132a e~ual in size and nu~ber to, and respectiYely in'regis-ter with, the gaps 32 of the upper ~ode filter 22.
Also, in Fig. 7, the con~in~ bady of ~oadst~
14a is sel~-sustaining in shape and smaller than the internal di~ensions of the tray, so that it is spac~
inwardly away frc~ the side walls of the tray. Sinca the cantainer tray is microwave-transparent, the body ~4a acts as a dielectric resanator, in determini ng t~e f~n~ tal mades a~ the systeu. Stated mare precisely, in the system of Fig. 7 the overall resonant boundaries are deter~ined both by the bcdy of foodstuff and by the mode-filtering structures, but pawer absarpticn ~s ccnfined to the focd crass-section. If the bady 14a ~illed the c~ntain~r out to the side walls of the tray, sa that the tray side walls defined the gecmetry cf the bcdy, still the ef~ect of the microwa~e-transparent tray side walls in detP~ini~ the resonant boundaries would he simply the conse~uence of the effect of the tray side walls Ln defining the food bcdy seometry, in contrast to the situation that obtains when the tray is electrically ccnductive (microwave-reflective) and constitutes a ca~ity resonator.
~ efer~ing now to Figs. 3, 4 and 8-10, vertical dis~lac~ment of the island and aperture arrays may he abtained by locating each array at opposite faces of a dielectric sheet or, alte-nati~ely, by locating the islands on dielectric protrusions (which may be filled cr unfilled). Dielectric protrusions may be obtained in the ther~oformin5 of plastic film, for example.
Figs. 3 and 4 show a rectangular flat plastic micr~wave-transparent sheet 20 Oe the type desc~i~ed - 15 - 13 39 ~i ~ 0 a~ave with re~erenc~ to Figs. l and 2 (e.g. the flat top of a microwave heating cont~ r lid 16 as shawn in Fi~.
5), but bearin~ a mcde filter constituted af a conduc-tive plata 34 (defining a 5 x 4 array of twenty rect-angular apertures 36 separated by strips 38) maunted an the dawnwardly facing horizontal planar majar surface of the sheet 20, and a 5 x 4 array of twenty rectanqu-lar conductive islands 40 maunted on the oppasite (i.e.
upwardly facing) horiz~ntal planar major sur~ace cf the sheet 20 in register, respectively, with the apertures 36. In this mcde ~ilter, the apertures 36 and islands 40 are spaced apart vertically ~y the thicXness of the sheet 20, and the rectangular annular ~ap 42 defined between each island 40 and the periphery af its assaci-ated aperture 36 is provided by virtue af the vertical spacing, since (as shawn) the islands 40 are larger than the apertures 36, though confor~ing thereto in peripher-al configuration.
Alternatively, as Fig. 8 illustrates, the top 20a of a plastic lid 16a (atherwise similar to lid 16 of Fig. S) may be molded with a multiplicity of hollow vertical protrusions 43 (one for each island 40) to increase the vertical spacing between the islands 40 and the apertures 36 of the plates 34. Each protrusian 43 pro~ects upwardly from the upper horizontal surface of the lid top 20a, and itself has a generally rectangu-lar, horizontal flat top surface, on which is mounted one of the islands 40. As in Figs. 3 and 4, the aper-ture-defining plate 34 is mounted on the lower (dawn-wardly facing~ hcrizontal surface of the lid top, and the apertures i6 are d~sp~sed in reqister with the protrusicns 43, bein~ thus a!so in register with the islands 4a. Again as in Fig. 4, the gaps (here desig-nated ~2a) ~etween the islands and the peripheries of their associated apertures are prav~ded by the vertic~l .
spacing between the islands 40 and plate 34, since the islands 40 are larger than the apertures 36. In top plan view, the structure of Fig. 8 (liXe that of Fig. 4) is as shown in Fiq. 3.
~ igs. 9 and lO illustrate further embadiments a~
mcde ~ilters having vertical spacing between apertures and islands. In the structures of these latter figures, the conductive plate 54 defines an array of apertures 56 which are larger in area than the conductive islands 60, so that the arransement of apertures and islands, in plan view, correspands to Fi~. 1. Each aperture and its associated island define an annular gap 62, which sap results both from the vertical spacing ~etween apertures and islands and from the fact that the islands are smaller in area than (though conforming in shape and orientation to) the apertures.
~ ore particularly, Fig. 9 shows a plastic lid 16b havin~ a top 20b for~ed with a multiplicity of solid (rather than hollow) molded protrusions 63, i.e., one for each island 60, projectin~ upwardly from its upper horizontal surface, but otherwise similar to the above-described lid 16. Each protrusion has a flat horizontal top surfaca cn which one of the islands 60 is mounted.
The plate 54 is mounted on the main upper horizontal surface of the lid top 20b, in such position that the protrusions 63 respectively project upwardly through the apertures 56.
Fig. 10 shows a plastic lid 16c with a top 20c havinq a planar horizontal upper surface and a multi-plicity of hollow protrusicns 6S (one for each island 60) p.ojectin~ dawnwa~dly frcm its lower s~rSace. Each protrusion 65 has a flat, downwardly facing horizontal lower surface on which is maunted one of the islands 60, while the aperture-defining plate 54 is mounted on the upper surface of the top 2~c with the apertu_es 56 in - 17 - 1 3 3 9 5q o .

re~ister with the protrusions 65. The latter protru-sions may be so dLmensioned that, when the lid 16c is placed on a tray 10, the islands 60 are substantially in contact with the top surface of the contained body 14 o~
foadstuff.
It will be seen that in all the embodiments of Figs. 3, 4 and 8-10, the aperture-defining conductive plate (34 or 54) and the conductive islands (40 or 60) are respectively disposed in parallel, but vertically spaced, horizontal planes. In all of these embadiments, and (except where otherwise n~ted) in those that follow, bath the plate and the island or islands may convenient-ly be ~abricated of aluminum foil and mounted on a lid or other container wall of microwave-transparent dielec-tric material such as one of the plastics mentioned a~ove.
In the mcde ~ilters of the invention, the islands and apertures may assume a number of geometries, among ~hich are the following:
(a) palygonal (including polyganal with rounded apices3, e.g., triangular, rectangular, pentagonal, hexagonal, etc. Fig. 14 shows a conductive plate 74 defining a hexagonal aperture 76 in which is dispased a smaller hexaganal conductive island 80 providing a hexagonal annular gap 82.
(b) round or elliptical (including epitrochoidal, multifoil, ,and siuilar variants). Fig. 15 shows a conductive plate 84 defining a circular aperture 86 in which is disposed a smaller circular conductive island 9o, ccncentric with t~e periphery of aperture 86, such that a circular annular gap 92 is defined t~erebetween:
Fig. 16 shcws a conductive plate 94 defining an array of generally elliptical apertures 96 within each of which is disposed a smaller but conf~rmal conductive island 100 to define, with the aperture periphery, a generally 1339~40 elliptical gap 102.
(c) confor~al (nat n~cPss~ily de~inable in ter~s of simple geometric shapes), having a geometric resem-blance to the shape of the food and/or container, and being intPn~e~ to promote the propasation of higher mcdes ~ithin the food. Fig. 13 shows a multi-co~part-ment container 140 in which each co~rtment is treated separately. The container has a series of metallic walls (not shown) which for~ compart~ents directly under reqians 150, 152, 154 and 156 in a lid 158. The lid is made o~ a microwave dielectric material and is basically transparent to microwave energy. Each compa,rtment has a corrPcF~in~ top surface area in lid lsa and each top surface area has an approxi~ately confornal plate o~
metallic foil. Such conformal plates are shown in Fig.
13 at 160, 162, 164 and 166. The area of each confor~al plate is substantially equal to the lid top surface area on which it is mounted. Each confor~al plate has a confor~al csntral aperture (170, 172, 174, and 176, respectively) within which is disposed a smaller but conformal metal foil island (180, 182, 184, and 186, respectively) definins, with the associated aperture periphery, an annular gap (190, 192, 194, and 196, respectively). Each gap is dimensioned so as to provide the proper cocking energy and distribution to the food-stuff located in the compart~ent in questian. For example, ga~ 190 is large with respect to region 150.
an the other hand, the foodstuff in region 156 requires a d~fferent distribution of heating and so gap 196 is appropriately di~ensioned.
(d) nonconformal and/or nonun form in gap width.
In the abovedescribed e~bodiments, a substantially unifor~ gap width has been shown. ~owever, the gap width may be nonuniform, as illustrated for ex2mple in Fig. 17, where a rectanqular aperture 26~ and a rectan-1339~40 ,, - 19 -gular island 3~a dispcsed therein have different aspect ratias so that the width of the short sides 32a' o~ the rectangular gap 32a between t~eu is greater than the width of the long sides 32a~ of the gap. Again, in Fig.
18, elliptical aperture 96a and elliptical island lO~a pasitioned therewithin differ in configuration so that the gap 102a between them is of variable width. The geometry of the island may be nQnco~ormal to the aper-ture periphery, as in Fis. 19, where a multilobed island 30b is dispased within a rectangular aperture Z6~ to define a variable-width gap 32b; in Fig. 2a, where ~oth the island 30c and the aperture 26c are nonconfor~al but once more define a variable-width gap 32c; and in Fig.
21, where a trifoliate island 9Oa is disposed within circular aperture 86a to define a variable-width gap 92a.
(e) with apertured islands, as shown in Fiq.:22, where a ~ultilobed island 3Od is p~ositioned in a rectan-gular aperture 26d to define therewith a gap 32d af varia~le width (similar to the arrangement shown in Fig.
1~), but the island itself also has a central aperture 27d.
The ~arious configurations illustrated in Figs. 13-22, as will be understood, are merel~ exemplary of the di~erse arransements (with unifor~ or nonunifor~ gaps, and geometrically conformal or nonconformal island-aperture pairs) that may be employed in the structures of the present invention. Also, while for convenience only a single island-aperture pair is shown in most of these figures, it will be understoad that an array co~pris~..g a ~ultipl city of such pairs may be provided ir. a complete mode-filtering structure, and that the pairs of such an array may (as hereinafter further discussed) be identical or nonidentical to each other deFendent on the heatins eCfect desired and the particu--- ZO . -lar conditions of use.
Far a focd article and~or ccntainer of rectangularcross-section, the island and aperture geometry wilL
typically or commonly also be rectangular. F~r an article and/or container of cylindrical shape, the preferred island and aperture geometry will typically zr co~m~nly be based on a cylindrical coardinate system, i.e., divided into ~calls" whase position is defined by radial and angular (harmonic) nodes. A system of the latter type is shawn in Fig. 11, which is a top plan view of a cylindrical cont~;n~r havinq a plastic lid 16d with a planar circular tap surfaca on which are mcunted a con~ctive plate 204 defining five or six identical segment-shaped apeL~Les 206 distributed in a radially symmetrical arrangement, and five or six con-for~ally shaped but smaller conductive islands 210 respectively pcsitisned in register with the apertures to define, with the aperture peripheries, five or six annular gaps 212, together with a central circular aperture 205 and island 207 defining a circular sap 209.
In the mode filters o~ the described embs~ nts of the invention, the mini~u~ separation between apertures is dictated by the heating distributicn desired in the foad, by the mechanical ruggedness required by the application, and the amcunt of ohmic heating occurring in the metal defining the aperture array. In aperture a.rays constructed from foil of household gauge and havins r~ctangular apertures, the width of foil between the apertures (e.g., the width of the strips 23 in Figs.
1-2) will tvpically be 5 mm or sreater.
~ eating distributions cver the plane of a mode f.lter comprised of a multiplicity of islands and aper-tures may be ~odified by varying differentially, over the cross-section of the structure, the island and/o~
aperture si~e, and/or the vertical displacement of the 1339~40 islands in relation to the apertures. For example, in the 3 x 3 array of apertures ~6 and associated islands 3a sho~n in Fig. 12, in a mode-~iltering structure other~ise of the general type shown in Figs. 1-2 and 5-6, the ~e.~ l one o~ these apertures 26e, to~ether with its ass~ciated island 30e, is made larger than the others, to control in a desired manner the heatins in the central region of an adjacent ~ody of foodstuff.
The size of this central aperture and island correspand to a fa~orable higher mode in the foadstuf~.
To confor~ better with the shape of food articles, the overall shape o~ a mode filter may ~e curved or corrugated, for example, rather than planar. Figs. 2S
and 26 show curved plastic container lids having mode filters in accor~ance with the invention. In Fiq. 25, the upper surface of the top 20e of lid 16e has a smooth continucus c~nvex curvature. An aperture-defining conductive plate 214 (generally similar to the plate 24 o~ Fi~. 1) is mounted thereon, with the conductive islands 220 (generally sLmilar to islands 30 of Fig. 1) also disposed on the sa~e li~ top surface. This curved mode filter c~rresponds to an arrangement (as shown, e.g., in Figs . 1-2 ) wherein the conductive plate and islands lie in a co~mon plane, and is embraced within the definition of a mcde filter having coplanar plate and islands. In Fig. 26, the top 20f of the lid 16f has an overall ~pwardly convex curvature and is formed with a plurality of radially extending upward protrusions 223 each having an upper surface curved concentrically with the overall top cur~ature. A conductive plate 224, mcunted on the lower surface of the lid top 20f, defines ar. ar.ay of apertures 226 respecti~ely in register with the protrusions 223; a correspandinq array of conductive islands 230 are mounted on the upper surfaces of the protrusions. The curved mcde filter of Fiq. 22 thus - 22 1339590 "' .
.

correspands to arrangements (as shown, e.g., in Figs. 3-4 and 8-lO) wherein the plate and islands are respec-tively dispased in spaced parallel planes, and is em-bracsd within the definition of parallel-plane plat~
arrangements.
Further in accordance with the invention, and as discussed above with referenc~ to Fig. 7, a plurality of mode filters may be provided at different walls or surfaces of the same microwave heating cont~iner, e.g.
for si~ultaneaus treatment o~ multiple f~cd surfaces.
When used at the upper and lower sur~aces of a body o~
~o,odstuff in a container, the mcde-filtering structures employed may be two distinct, electrically isclated mcde filters, or two mode filters ha~ing aperture arrays constructed from the same metallic sheet. When two electrically isolated mcde filters are used, the remain-der of the package or container is formed from dielec-tric material, so that the overall package may be con-sidered by the consumer a "composite" rather than "foil"
container. Electrically isolated mode filters m2y als~
be used at the upper and lower surfaces of a container havin~ metallic sidewalls.
Fig. Z4 shows a microwave heating container embody-in~ the invention and including both top and bottom mode filters, between which is disposed the body of focdstuff to be heated. This container may be of the familiar "clamshell" type, viz. a typically thermoforned foamed plastic package having an upper portion 231 and a lower portion 233 joined by an integral hinge or folding reg~on (not shcwn) formed along one side, and arranged to close positively or latch (by suitable and e.g.
conventional means, also not shown, formed along their edge portions), the walls of the package being somewhat deformable. A mode-filtering structure of the type shown in Figs. 1-2 (including aperture-defininq plate 2~

13~9~0 and islands 30) i ~aunted on the flat top of the pack-age upper partion 231. Another similar made-filterin~
structure Z34, maunted on the flat b~ttom of the lower partion 233, defines an array of apertures 236 (which, in this embadiment, are identical in shape, size, an~
arrangement to, and are in register with, the apertures 26 of the top mode filter 22) and also includes a like plurality of aluminum foil islands 240, each defining with the periphery of its associated aperture a rectan-gular annular gap 242. These gaps 242 are equal in size and nu~ber to, and respectively in register with, ~he gaps 3Z of the top made filter 22.
As an alternative, an electrically isolated mode filter in or on a container lid may be used with a metallic container tray which incorporates the aperture array of a se~ond mode filter. As a further alterna-tive, one mode filter ~ay be in close me~h~ica} and electrical contact with a container incorporating an aperture array af a second made filter in its base, cr may be integral wit~ it (as in a pauch type of construc-tisn). When twa ~ode filters having aperture arrays ccnstructed from the same sheet are used, this sheet may be folded in a U-shape to enclose the foad article to be heated, as shown in frag~entary view in Fig. 23, which illustrates a U-bent aluminum foil/plastic laminate sheet 243 ha~ing a plurality of rectangular apertures 246 for~ed in the foil and a liXe plurality of smaller but conformal foil is~ands 250 supported on the plastic of the laminate within the apertures to define therewith rectangular annular gaps 252 of uniform width. By ~irtue of the U-bend 253 of the sheet 243, first and second arrays o~ the gap-defining apertures 246 and islands 250 are respectively disposed on opposite sides of a contained bady (not shown) of foodstuff, so that these two arrays in effect constitute two ~ode filters - 24 - 13 39 5 ~ o acting at opposite surfaces of the foodstuff body. The edges of the sheet 243 may be suitably sealed together to form a pouch within which the body of foodstuff to be heated is enclosed.
Because microwave oven heating characteristics tend to be uneven in the vertical direction (owing to coupling effects caused by the presence of a glass tray or ceramic oven floor), different upper and lower mode-filter designs may be incorporated in the same container, i.e. to compensate for such vertical unevenness of heating characteristics. Compensation may be obtained by variation of relative island and aperture areas and/or of the vertical displacements of the island and aperture arrays.
While the foregoing embodiments have been chosen as illustrative of constructions which may be used with two mode filters, mode-filtering structures may also be used three-dimensionally, with mode filters located at all of the surfaces of a food.
The nature and principles of operation of the mode-filter containers of the invention may now be explained.
In the described mode filter structures, as in the higher-order-mode-generating means of the aforementioned U.S.
patent No. 4,866,234, the boundaries of each island or aperture define a set of modes with corresponding cross-sections. However, while an island array permits the entry of "lower" (or more fundamental) modes through strip-lines and slot-lines defined by the combination of islands, the entry of t~e "lower" modes is impeded by an aperture array. The aperture array may thus be perceived as analogous to a series of waveguide (or cavity) openings, each of which would effectively cut off or attenuate the lower modes.
It is useful to explain features of operation or function of a mode filter as herein contemplated, by -25- 13~9540 analogy to a complete container with the boundaries of each mode filter aperture considered analogous to metallic container walls, and each associated mode filter island considered analogous to a higher-mode-generating metallic plate. In a mode filter wherein the islands are vertically displaced over the aperture array (relative to a 5 body of food to be heated), the mode filter islands "feed" the aperture array so as to increase the amount of power (at the corresponding higher mode) available to the food over that which would enter the unmodified aperture array. It should be noted that in the absence of an island array, the use of apertures is regarded in the art as providing moderation (or reducing the amount of power available), such that an aperture array 10 with small openings would be regarded essentially as a "shield".
A distinction exists between the vertical displacements (between the island and aperture arrays) which are possible with the mode filters of the present invention, over those obtaining between a higher-order-mode generating plate and metallic container walls of the containers of the last-mentioned patent. In the latter containers, 15 there will seldom be occasion for the metallic plates to be positioned below the plane determined by the rim of the metallic container, and it would be clearly impractical for the plate to be immersed beneath the surface of the food. Contrastingly, since the ap~l lw e array of a mode filter as herein contemplated can be separated by an air gap from the food, the lower bound of island array vertical displacement relative to the 20 aperture array is determined by the food surface.

1339~5~0 Nevertheless, pursuing the aforementioned analogy, it is apparent that by differentially varying relative island and aperture size and/or island vertical displacement, food heating distributions may be varied over the mode filter cross-section.
Control of vertical heating gradients stems from the following considerations:
(a) Absorption/attenuation becomes particularly pronounced when the induced mode is cut off (i.e. when the condition of evanescent propagation obtains), this being the principal feature of the present invention.
(b) When a food contains layers with distinct dielectric properties, control of the mode structure can give rise to free propagation in a layer with a relatively high dielectric constant and cut off (steep attenuation/absor~tion) in a low dielectric constant layer.
(c) Thus, when a layer Of pastry or batter/breading with a relatively low dielectric constant overlies a food of higher dielectric constant, intense heating may be selectively obtained in the surEace layer. Thus, mode-filtering is a valuable tool in promoting browning or crispening effects, while minimizing undesirable overcoo~ing of a good bulk.
(d) When the mode structure is fixed, as by metal wall boundary conditions, in the horizontal plane, the absorption coefficient of the food is determined by the mode cross-sectional dimensions.
te) That is, for fixed food dielectric constant, and conductivity and dielectric losses, the absorption coefficient in the vertical axis increases with decreasing mode dimensions.
(f) By determining the mode dimensions, control is thus exerted over vertical heating gradients.

133~540 Figs. 34-36 illustrate graphically the vertical absorption profile of nicrowave energy, in a bady a~
~oadstuff adjacent a made filter gap for conditicns ranging from abave cut off (Fig. 34) to below cut of~
(Fig. 36), where the bady is sufficiently thic~ and/or absarptive so that the effects of reflection and/or propagation at oppasite surfaces of the bady can be ignored for purpases of the present analysis. Stated in general, it is the dimensi~n of the individual mcde ~ilter gap (or open gap segment, in the bridged-gap structures described below with reference to Fig. 36~
that determines whether a made is in cut off for a food bady o~ a particular dielectric constant, at a given wa~elen~th (typic~lly 2.45 G~z) of microwave energy.
Figs. 34-36 may be explained by reference to a body of foadstuff pasitioned ad3acent a planar harizontal gap- or aperture-defining electrically conductive plate, wherein the z axis is the axis of propagation into the food bady (i.e., z=0 is the surface of the bady adjacent the plate, and the distance along z in these graphs is penetration depth vertically into the bady).
In the graphs, ¦ E¦ 2 ( the squared magnitude of the elec-tric ~ield intensities, in the vectorial sansa) is plotted against z, t~e intercept of the curves with the ¦E¦2 axis b(,eing the squared magnitude,of a reference cr surfacs intensity. Owinq to the dependence of pawer abscrption (heating intensity) on ¦E¦t, the curves in these graphs indicate the steepness of a~sorp-tion/at~enuation (in the vertical direction into the focd) for the various conditions represented, showing that the steepness of the absorption/attenuation profile is much greater below cut of~ than above cut off.

- 28 - 13 39 ~ 40 .. -, ..

¦E¦ Z is propartLonal to e ~Z, where ~ is de~lned ~y t~e relation a ~ ~ 2~ k2) ~ ~ t (~2~ _ kZ) 2 ~, 2 Z 2 and 2~ being frequency;
magnetic per~eability (typically, ~r ~ 1 for nonmagnetic ~aterials);
4~ x 10 7 joule (s~c)2/tc~ulomb)2-meter;
'r'o ~ dielectric constant, ~r bein~ the relati~e dielectric co~ ant and ~c ~eing the free-space (elec~ric) per~it~ivity, cO - 8.8541878 x 10-12 (coulo~b)2j~aule-meter;
~ - conductiYity.

E~ propagatian is gcverned by an ~Yp~n~ntial law whcse argument includes bath the real component (+/-) and a complex c~mpanent (+/-) ~, de~ined by the relation ~2 ~ 2~ 2 ) ~ ~ 2J~ _ JC2 ) 2 + ~2~2 which gives rise to a nearly periodic variation energy absarption wit~ depth Or penetration. The cur~es shawn in the graphs ignare ~. For foads which are thick - or highly absorpti~e, ~ may be neglected. Thus, the cur~es should be understoad as s~cothed representations af the actual values involved.
It wlll ~e noted that the expressions for ~2 and ~2 allow 2 and ~ to assume pcsitive or ne~atlve signs. The chaice af a ne~ative sign of ~ in the propcrtionality deter~ining ¦E¦ reflects the absorption of energy and concomitant decrease of ¦E¦ with penetration. The existence of a companent with a positive 3 ~er~ indi-cates either ~eflectlan at, ar the entry of power from, an opposing surfaca. The ~uasi-periodic variation due to +~ follows from Euler's formula z - e~ = cos ~z ~ ~ sin ~z where j = (~ . Also to be noted is the relationship of ~ a~d ~ to the combined propagation constant p in the vertical axis, viz. p = 3 ~
- The f~c ~yaca value ~f 'r is unity. In foads, ~r is largely deter~ined by food moisture content or water actlvity, so that the value of 'r for high-moisture foods will nearly approach that of water, for which (at a frequency of 2.45 GHz) ~r varles from abaut 80 at O C
to abaut 55 at lOO C, the value for ice being approxi-mately 4. For low-density, low-moisture-content foad components s~ch as partially precooked batters or coat-ings, the value ~f ~r is a~out 5, varying by equilibra-tion of their m~isture contents with adjacent high-water-activity foads.
- For any given mode of propaqation of microwave energy, the condition for cut off is that k2 (defined as the separation constant for the equations gaverning the comronents directed in the plane of the plate) be equal to or greater than ~2~c. From the well-known relatians c = (~c~) ~ and c = ~Of, where c is the speed of light and~O is the free-space wavelength, it follows that ~2~ = 4~Zcr/~O2 when ~ = 1. Thus, the condition for cut off (k2 2 ~2~c) can be expressed as k2 4~2/~Zeff~ where the effective wavelength ~eff = ~J'r~
For f = 2.45 GXz, ~O = 12.24 c~. When cut off occurs, the magnitude of the ter~ Q (governing the penetration - of m~crowave energy into the food) increases substan-tially.

1~39540 The valuQ of k2 is dep~A~nt on the geometry and di~ensians of the gap or apertur~ as well as on the mode under consideration. In the simple case of a rectangu-lar aperture havins horizontal dimensions ~x~ Ly~ for the t~,n~ mode, ~2 = ~2~(m2/ ~2) ~ (n2/ ~ 2 and the condition for cut off is ~ ~ tm /I~C ) + (n2/r,y2) 1 ~ 4~r2/~2e~-Thus, for example, for the ~0,1] or ~1,01 mode, the condition for cut off is that the relevant dimension (i.e., ~ or ~) be e~ual to or less than ~eff/2~
Again, in the case of a circular geometry, in which for the tm~nl uade ~2 = j2m n/ro2 where jm n is the nth zero of the mth order Bessel function and rO is the radius of the aperture opening, the condition for c~tof~ in the ~0,1~ mcde is that rO be e~ual to-or less than 0.3827~eff. In summary, critical dimensions for cut off for exemplary aperture ~e~metries znd modes are as follows:
Geometry , Mode Critical Dimension Square (L= ~=Ly) ~0,1], tl,O] L-= ~eff/2 .. [1,1] L ~eff/2 Rectansular (~=~ ~) [1,1] ~ = ~eff(l+q2)~/2q Circular [0,1] rO = 0 3827~eff .- [ 1,1] rO = ~ ~ 6098~eff The ter~ k2 is easily deter~ined in rectan~ular and circular systems (tables of the zeros of Bessel func-- 31 - 1339~40 ....

tions are given in G.N. Watson, A Treatise on the TheorY
of Bessel Functions, Cam~ridge Univ. Press, 1~22). The analysis is more complex for other gap/aperture geome-tries (e.g. ellipses), but the general yru~aition holds that cut of~ of a given mode occurs when the relevant horizontal dimension of the gap or aperture is e~ual to or less than a value deter~ined by the gap/aperture geometry, the mode in question, and the dielectric constant of the food body or body portion o~
concern. Thus, where the o~jective is to achieve brcwn-ing and crispening by provision ~f a condition below cut off, with resultant steepness of food heating profile, it is feasible to do so by appropriate dimensioning o~
the mode filter gaps or apertures, viz. by keeping such dimensioning below the ~ r value for cut off.
Applying these considerations to the design of mode filters to achieve browning and crispening, it is ob-se~ved that open, wide apertures are ineffective for this purpose, since large square or circular apertures will have low field intensities across them and should therefore fail to produce desired browning and crispen-ing. By introducin5 islands in such apertures, higher har~onics result, and more intense fields may be expect-ed across the narrowed gaps.
Evidently, narrow slots give the desired heatin~
effects. Slot length will be < ~eff/2~ For segmented slots the désired seqment length will approximate to ~ef~/2~ Curved slot length should likewise approximate to ~efc~2 In the case of a round aperture with a small q2p hetween island and plate, the circumference should be nearly (or less than) ~eff. Larger gaps will allow resonance in the radial dimension. Similarly, it is ex-pected that the line inteqral of gap lenqth for narrow, uninterrupted rounded shapes will approach or be less th~n ~e~

In general, the width of a gap (in the island-aperture pairs or arrays) should be at least about 1 mm, to avoid excessively high field intensities. The length of the gap wil~ usually be at least abcut 5 mm.
Stated with reference both to embo~iments of the invention employing island-aperture (gap) pairs or arrays and to those employing annuli (further described below), the following general principles governing critical (cut-off) dimensions may ~e set forth:
~ imensions of narrow gaps ar annuli: for gaps or annuli defined by a smooth curve lacking prono~lnced cusps or apicec and encircling a closed area, cl~t off of the lawest order mode will occur when the line integral of the curve is less than one effective wavelength (~ef~) If the ends of a smooth, open curve are not closely spaced, cut-~ff will correspond to a curve line inte~ral of ~e~/2~ A closed curve with apices or cusps will be expected to have cut-off dimensions correspond-ing both ~o its circumference (one ef~fective wavelength) and to its segments (each being ~eff/2)~ For an odd num~er of equal segments, however, destructive interfer-ence may cause cancellation of the modes correspondin~
to them. An open cur~e with cusps or ~pices will simi-larly have its entire length as one cut-off dimension (~eff/2)/ and may also support higher order modes with cut-off dimensions defined as the distance bounded by t-~o such apices or cusps (each segment being ~eff/2)~
Wide gaps or annuli: As with their narrow counter-parts, wide gaps or annuli will support resonances over their lengths. However, they will also allow two-dimen-sional resonances, generally characterized by larger cut-off dimensions. ~hus, in decreasing critical dimen-sions, cut-off will first occur for two-dimensional resonances, and be followed by cut-off in resonances determined by gap or annul~- lensths. By selecting _ 33 _ 1339S~O

dimensions which suppart rPs~n~nCPs deter~ined by gap or annular lengths, while providing cut-of~ of two-dimen-sional resonances, heatins cf the bul~ of the absar~er may be balanced against heating of its surfaces.
In przctice, since at and adjacent the foot sur~aco some af the field will be in air, the wavelength will have a slightly greater value than ~eff as defined abave. In deter~ini~ cut-off dimensians for island-aperture ga~s or annuli, a lcwer ~ound is provided ~y the ~ul~ wavelength, taXen as the free-space wavelength ~0, ~Lvided by the square roat of the absor~er relati~e dielectric constant, here denoted as ~r(m) If these structures were embedded well within the absorber bulk, this lower bound would accurately determine cut-off dimensions for the gaps or annuli. However, the coexistence of fields within the air surrounding an absorber causes wavelengths used in determining cut-off dimensions at the absor~er surface ~the locus of interest fQr browning and crispenins effects) to be su~stantially larger than ~J 'r(m) -A useful approximation for deter~inin~ the effec-tive dielectric constant 'eff at the surface of a di-electric material is that suggestPd by S.B. Cohn, IEEE
Trans. Microwave Theor~ and Techni~ues, MTT 17(10), 76~
(1969), viz. the arithmetic average of the relative dielec~ric constant ~r(m) of the dielectric material and the relative dielectric constant ~r(s) cf free space overlvins its su--ace. Since the dielectric constant of free s~ace assumes a value of cO, the relative dielec-tric constant 'r(s) ~ust be unity. ~hus, the approximat-ed effect ~e wavelength ~eff for purpcses of determining cut-off dimensions for gaps or annuli at the surface of a focd or other load to ~e heated Is given by ~eff AJ~ r(l~) )/2] ~

r 1 3 3 !~ ~ i O

Referring, then, by way of exa~ple, to the d~mensions given above for the structure shown in Fig. 1 (a 5 x 4 array of rectangular apertures each 2.2 x 1.9 c~ and .enclosing an island 1.8 x 1.4 cm, such that the maximum gap width is 2.5 mm), the "narrow gap or annulus" con-siderations set forth above establish that the critical ncions for cut cff are a peri~eter, or sum of gap length and width, equal to ~ef~ or either length or width e~ual to ~eff/2~ ~ith the ~arious gap lengths based on aperture (rather than island) dimensions, we obtain:
~eff (1 ~ ~r(~))/2 ~r(m) (c~) cut-of~ _ lower bound at cut-aff 3.8 10.4 19.8 4.1 8.9 16.8 4.4 7.7 14.5 8.2 2.2 3.5 For a focd product ha~ing a batter or breaded coating with a dielectric constant of less than about 14, propa-gation in the coatin5 will be in cut-off for all but the hypathetical mode correspanding to the perimeter dimen-sion of the gap; propagation will not be in cut off in the underlying food bul~, however, because of its sub-stantially greater dielectric constant.
For circu~ar gaps or annuli, the critical dimen-sions are a diameter equal to ~eff/~
The control of horizontal plane heating distribu-tions ar.d of heating gradients in the '~ve-ticall~ axis is inc~eased, w~.en the entry cf radiation through ather food surfaces is suppressed. This suppression may be obtained by the selection of overall mode-filter dimen-sions and separation, by the shape or contour of the mode-filter edges (as by introducing well known "choke"
structures), and/or by the introduction o~ netal walls 133g54~

(which may be integral with the mode filter(s), and which may also incorporate mode filters).
Operation of the mode filters of this invention is typified by the following:
Considering first a single-mode filter array, i.e. at a single surface, modification of heating distributions in the horizontal plane of a container and/or food is generally obtained by positioning the island array over the aperture array, and by positioning the resulting structure over a metallic or composite container. The design principles used to obtain a particular heating pattern are similar to those used in the containers described in the aforementioned U.S. patent No. 4,866,234, except that there is less need (in the present invention) to compensate for the entry of "lower" modes.
When used with the crispening containers described in the aforementioned published European application under No. 246,041, the island array of a mode filter in accordance with the present invention may be vertically displaced above or below the aperture array. In tllis configuration, crispening may be obtained simultaneously at both the upper and lower surfaces of the food.
A particularly efficacious configuration is that in which the islands are in contact with the food, but are displaced beneath the aperture array. When used for browning or crispening, a mode-filter will generally use island and aperture dimensions on the order of less than 2 cm on a side.
Examples of the just discussed embodiments of the invention, provided on the floors or bottoms of microwave heating container trays in association with stepped structures or protrusions formed therein, are shown in Figs. 27 and 28. In Fig. 27, a dielectric-material (e.g., molded plastic) container ~ottom 301 is formed 1339~0 with one or mcre upward protrusians 3~3 having a planar upper horizontal surface spaced above the horizontal upper surface of the bottom. An aperture-defining conducti~e plate 304 is mounted on the latter surface, defining at least one aperture 306, throuqh which pro-trusicn 303 pro~ects; a conductive island 310 is mounted on the upper surface of the protrusion, to define (with the aperture) an annular gap of uniforu width, thus constituting a mode filter in accordance with the present invention. In Fi~. 23, a dielectric-material container bottom 311 is for~ed with one or more downward protrusions 313 having a planar lower horizontal sur~ace spaced below the horizontal lower surface of the bottom;
aperture-defining conductive plate 314 is mounted on the latter surface, defining an aperture 316-through which protrusion 313 projects downwardly, while a conductive island 320 is mounted on the lower surface of the pro-trusion 313, again so as to define with the aperture periphery a uniform-width annular gap. Each of these mcde filters of Figs. 27 and 28, as will be understood, may include an array of apertures, islands and protru-sions, only one beinq shown in each case for simplicity of illustration.
~ ode filter structures arranged for simultaneous treat~ent of multiple surfaces are of considerable interest for the browning or crispening of battered and breaded foods such as fish sticks, fried chicken, etc.
In these arrangements, similarly to the containers of Fi as. 7, 23 and 24, one or more food articles are placed between two mode-filtering structures. The island and aperture dimensions are chosen so as to intensify heat-ing at the f5ad coating. Two types of browning or crispeninq may be obtained:
(A) "Uniform": The island arrays are close to, or in cont~ct with the food surfaces, and the aperture 1339~40 arrays are either coplanar, or displaced "~ertically"
away from the food. This configuration may be used to give nearly uniform, intensified heating of the surfac-es. When (as shown in Figs. 29 and 30) the dielectric b~ttom 331 supporting the aperture-defining plate 334 and islands 340 is formed with inwardly projecting protn1sions 333, the resulting channels 335 between the islands improve venting and drainage from the fo~d during its microwave heatins.
(B) "Grilling": The aperture arrays are relati~e-ly close to the food surfaces. The pattern of brown-ing/crispening which results roughly corresponds to the metal areas of the aperture array. When the mode-filter islands are carried on outwardly projecting protrusions, the wells so formed improve venting, and allow for the collection of drainage from the food.
These and related configurations offer many advan-tages over sa-called "susceptor" packages:
ta) Because heating is induced in the food rather than in the packaqe itself, lower temperature materials may be used. A benefit of l~wer temperatures is the re~uction of pyrolytic by-product generation.
(b) The control of heating distributions offered over the horizontal plane of the ncde-filter-ing s.ructures allows more uniform heating and~or browning and crispening ef.ects to be obtained.
(c) The relatively hiSh impedance presented by the structures provides mcre even distribution of heating over multiple food items. By varia-tion of mode-filter desisn, selective heating may also be provided. ~lso, the attainment of desired results is less dependent on the particular oven used.

13395~o .,.

(d) Heating and/or browning and crispening effects can be "balanced" between the upper and lower fo~d surfaces, by variation of mode-filter design.
(e) The ~verall shape of the mode-filtering struc-tures can ~e modified to ~etter conform with the product to be treated.
(~ Drainage and venting can be accommodated as an integral feature of mcde-filter design. When suppcr~ing protrusions are generated by ther-moformLng, a mcre flexible pac~age results, - which is better able to confor~ to surface irreqularities of the f~od.
(g) The heat-resisting and hea~-distributing prop-erties of the metal surfaces which may be used to contact the food minimize damage to the package resulting from localized "hot" re-gions, and reduce the hazard of contamination of the focd by products generated through the heating o~ the container.
(h) Because the mode-filtering structures can ~e supported on a plastic dielectric, a variety of c~ntainer or packase shapes can be cffered, owing to the versatility of plastic for~-ins/fabricating methods.
The mode filters described above are a subset of a --- much broader se~, wi~ich is conceptually lin~ed also to the conductive indented structures of the last-mentioned European application. This much broader set may be characterized in the following features:
(1) A conductive area is made electrically distinct from surrour.ding or adjacent conductive areas. Modes corresponding to this distinct area are induced in a proximate foodstuff (or absorbing material). Modes not 133~S~O

necessarily the same as those induced by this area but corresponding to the surrounding or adjacent conductive area are also induced in the foodstuff. All of these modes will be higher modes than those fundamental to the combination of the foodstuff and container. They may therefore be used to modify heating distributions within the food and/or to induce browning or crispening effects.
(2) The conductive area may be made distinct (following (1)) in several ways, which may be used singly or in combination, and which include the following:
(a) The conductive area may be separated from the surrounding or adjacent areas by an air-gap or dielectric-filled gap.
(b) The area may be conductively connected to the surrounding or adjacent areas, being raised or lowered in relation to the plane defined by these surrounding or adjacent areas, but with the vertical separation providing some measure of electrical distinctness (i.e. vertical phase relationship). This connection may be at one or more sides of a polygonal area, so that when all the sides are connected, the structures described in Canadian patent no. 1,279,902 issued February 5, 1991 result.
(c) Electrical distinctness of such a conductively connected area may also be obtained by establishing an impedance (in a stripline/slotline sense) different in the areas from that of the connecting means, as by varying the width of this connecting means.
Different impedances may also be obtained through proximity of the area or connecting means to food or another dielectric substance.

1339~0 (3) One or a plurality of such combinations of a conductive area and surrounding or adjacent conductive areas may be used as described above. These combinations need not be of similar design, but may be varied in size or in the choice and/or dimensions of the separating gap or conductively connecting means.
In an illustrative example, mode filters were prepared from foil sheets which effectively incorporated a mode filter as herein contemplated in a structure as described in the aforementioned Canadian patent serial no. 1,279,902. These mode filters were intended for the crispening of breaded and coated fish fillets. The foil areas contacting the fillets were of the same size and disposed in the same positions as the "islands" of mode filters previously used for the same purpose. However, the areas of contact were electrically integral with the foil sheets, such that two opposite sides of these rectangular areas were connected with the sheet, and upwardly displaced from it (i.e., towards the fillets).
The other opposite sides were not connected, so that air gaps or slots existed at these sides. Crispening of the fish fillets was fully comparable to that obtained with the "island" constructions. While crispening can also be obtained, when the contacting areas are, in effect, folded tabs (joined to the foil sheets), caution must be exercised in the design of these structures to prevent arcing or localized scorching of surfaces of the food article. When a food is placed between two of the structures, the slots of the structures need not be in register.
Following from the number of island/aperture shapes possible, it is apparent that there exists an even larger number of combinations for which one or more sides of the polygonal "islands" are connected to the "aperture array." It should be mentioned that these 1339~S40 ,. .
structures may also be viewed as patterns af slots, such that the slots define tabs or other shapes, and may even define structures resembling slot/strip meander lines.
Sincs a single slot prc~ s a field ~Yir~lm at its middle (and thus, localized heating in the same region), it is desirable that the slots be configured so as either t~ give a desired pattern of heating, or even heating. While the structures defined by the slots may have apices or be angular in nature, rounded or convq-luted shapes may also be used.
Further examples of structures in accordance with the in~ention, e~odying some of the features just discussed, are shown in Figs. 31-33. In Fig. 31, a metallic plate 3S0 is far~ed with a plurality of spaced-apart rectangular projections 352 each having a flat top 354 lyin~ in a plane spaced from and parallel to the major surfaces of the plate. ~pposed side walls 356 of each pr~jection 3S2, integral with the projection and plate, connect the top 354 to the plate on two sides.
On the other two sides of the top 354 there is an apen gap pcrtion 358 between the top and the plate. In this structure, each conducti~e "island" is the flat top 354 of a projection, its periphery consisting of bends 360 and gap top edges 362. Each "aperture" has a periphery defined by bends 364 and gap battom edges 366. Walls 356 constitute conductive bridges spanning the gap between aperture and island. The open gap portions 358 provide dielectric isolation between aperture and island while the vertical displacement between top 354 and plate 350 due to phasing or elect-ical distance effects.
The st-ucture of Fig. 31 is formed from a single sheet af metal ~y slitting and drawing to form the projections 352. In the modified structure of Fig. 32, als~ formed from a single metallic plate 350a, the plate partions 368 intermediate adjacent projections 35'~ are 133~40 bent out af the plate major surface planes to an extent equal and opposite to the bending of the projections, sa that drawing of the metal is not required.
Fig. 33 illustrates a planar mode filtering struc-ture in which a metallic (conductive) plate 370 defining a rectanqular aperture 312, and a metallic (conductive) island 374 of rectangular configuration, smaller than and disposed within the aperture, are connected by conductive bridge portions 376 spanning the gap 378 defined between t~e island and aperture peripheries.
The plate, island and brid~es are formed integrally from a single metal sheet (e.g. an aluminum foil sheet of suita~le gauge) by cutting out from the sheet opposed C-shaped portions 380 of the gap 378. These portions ~80 are open (microwave-transparent) portions or segments of the gap. A mode filter thus constituted provides ef-fects comparable to those of mode filters in which there is complete isolation between island and aperture pe-riphery, as in the structures of Figs. 1-30 descri~ed above. A mode-filtering structure in accordance with the invention may ha~e one such mode filter, or an array cf these bridge-type mode filters, arranged for example in the same manner as the rectansular mode filters of Fis. 1.
The arrangement of Fig. 33 is merely exemplary of bridging arrangements by which islands are made integral with their associated aperture-defining conductive plates by spaced-apart conductive bridges spannin~ the anr.ular gaps bet-Jeen aperture peripheries and islands.
suc~ arran~ements afford important advantases from a manufacturing standpoint, in that 2 co~plete mode-fil-tering assembly of apertures and islands can be formed integrally in a single sheet of aluminum foil or the li~e and mounted as a unit on a microwave-transparent ccntainer lid or other supportin~ surface. In these 1339~40 . , structures, the open gap portions or segments (380 in Fig. 33) are dimensioned to provide sharp attenuation in the vertical direction so as to achieve browning or crispenin~ of the surface of the body of foodstuff being heated.

Fig. 37 shows a device in the for~ of a thin sheet 410 of microwave-transparent material on which there is located an array of rectangular annuli 411 of al~l~;nl~
or other metallic foil. Each annulus 411 defines an aperture 412 that remains microwave-transparent, as dc the spaces 413 and 414 between the annuli.
The sheet 410 can be used in association with a st~n~rd food container 415, and may be placed therein beneath a food article (not shown) or above such arti-cle, depending upon which surface of the food article is ta be sub~ected to an increased temperature for browning and/or crispening. Alternatively, if ~oth the top and bottom surfaces are to ~e subjected to an increased temperature, twc such sheets can be employed in the container 415, one below and one above the food article.
Each sheet 410 may be flexible so as to be able to conform to an irregularly shaped food article. For example, it may be made of polypropylene, polyester, polycar~onate or other low loss material that will be substantially transparent to microwave energy.
Alternatively, the sheet 410 can be more rigid, i.e. made of a low loss plastlc foam or cardboard-like material. As a further alternative, i~ may ~e made a~ a ceram~c or slass, provided that such material is sub-stantially transparent to the microwave energy.
A sheet 410 can be embodied in the container 41S as a part thereof, e.g. as the battom or as a lid, or as both. ~lternatively, the sheet ~lO c n be ~ separate 1339~40 element that is employed by the user in conjunction with a container. For example, the ~ser can place a st~n~d foad container (with a microwave-transparent bottom) on top of a sheet 410 in a microwave oven, or can plac~ a sheet 410 on top of the food article after remcving the conventional container lid.
Mcreover, a sheet 410 can be used directly with a food article without need for a container at all. For example, a pizza can be heated by simply placing it on a sheet 410 in the microwave oven, provided the sheet 410 is suf~iciently spaced above the oven ~loor to avoid arcing.
All these various possibilities are, however, subject to the requirement that the function of the sheet 410 (described in more detail below) is such that it shauld normally be located close to the food sur~ace requiring enhanced heating in order to achieve the maYi~l~ performance, although desirahle effects can be achieved with some gap between the food and the sheet.
The thicXness of the metal film for~ing the metàl-lic ann~li 411 will be sufficient to prevent it func-tionins as a susceptor, such metal film being virtually entirely reflective of the microwave energy and absorb-ing ne~ligible amounts of such energy. When using aluminum foil for the annuli, its thickness will prefer-ably be about 6 or 7 microns, since this is a convenient rolling thickness for aluminum. However, from the viewcoint of remaining microwave-reflective and not acting as a susceptor, a thickness of as lit'le as abcut 0.2 microns (as obtained by sputterins) might be used.
This is in contrast to a thic~ness of about 0.01 microns which would absorb mic-owave energy and become heated.
8efore describin5 the function of the metallic annuli 411, it will be con~enient to refer to alterna-tive shapes that these annuli c~n take. Fiq. t3 shows square annuli 420; Fig. 39 shows circular annuli 421;
Fig. 40 shows triangular annuli 422 and Fig. 41 shows hexagonal annuli 423. Moreover, the shape of the aperture defined by the annulus need not necessarily conform to the outer shape of the annulus. For example, a circular aperture in a square annulus can be used. Mixtures of these different shapes in a given array are possible, as well as modifications in the arrangement of the array and variations in the sizes of the different shapes in a given array. For example, alternate rows of the square annuli 420 in Fig. 38 can be staggered, to cause the microwave-transparent material between the annuli to trace out tortuous paths and avoiding long straight paths. Moreover, it is to be understood that the shapes of the annuli may only approximate the geometric shapes mentioned, and that normally the sharp corners that have been shown in the drawings for simplicity will be avoided by rounding to reduce the risk of arcing, and, as indicated above, the annuli can tolerate some measure of interruption while still effectively defining an aperture.
For discussion of the function of these annuli, it will be convenient to begin with the simple example of the square shape shown in Fig. 38, showing dimensions Di, Do and Db that respectively designate the inside distance of each annulus, i.e. the aperture width, the outside distance or the external width of each annulus, and the distance between adjacent annuli(assuming a symmetrically spaced array).
The function of the annuli is to set up a condition in which the aperture in each annulus causes the modes of microwave energy that propagate through the apertures to be in cut-off for air and for substances containing substantial quantities of air, e.g. batter, bread crumbs, pastry, etc., of which the surface layer of the food article will likely be composed, but preferably not to be in cut-off for the main portion of the food article inwardly of its surface layer.

For example, the wavelength in air of the microwave energy at the standard frequency of 2.45 GHz is approximately 12.24 cm, whereas in the food bulk (which will normally be composed mainly of water which has a relative dielectric constant of 5 the order of 80), the wavelength will be in a range from about 1.3 cm (pure water) to about 2.0 cm, depending on the proportion of water in the food. It is to be understood that these values and those given below are necess~rily approximate and can vary quite widely with the nature of the food or other article being heated. If the surface layer is of a substance different from the main portion of the food article, the 10 wavelength in such surface layer will normally be somewhere in between that of air and that of the main portion of the article. The value of relative dielectric constant ~r for such a layer will vary (owing, as mentioned above, to equilibration of a relatively low initial surface layer water activity with that of the underlying food); an exemplary low-end value of ~r for coatings (such as batters and the like) subject to these 15 considerations is 5. More broadly, an illuskative (but non-limiting) range of ~r for a wide range of surface layers is 1.5 - 16, for which the corresponding range of wavelengths (at 2.45 GHz) is 10.0 - 3.0 cm. For example, a crumb coating or puff pastry crust, which includes a large number of air pockets, can typically have an overall relative dieleckic constant that will result in a wavelength of the order of 8.0 -20 10.0 cm. A more dense coating, e.g. a batter, on the other hand, can typically producea wavelength more of the order of about 3.0 - 5.0 cm, although the wavelength may vary beyond this range depending on the exact nature of the coating. It follows that the dimensions of the annuli can be tailored to specific foods and coatings (surface layers) once their approximate relative dielectric 13395~0 constants are known, ar by trial and error, in order to arranse that the apertures, i.e. the width dimension Di, should be such that same of ~he ma~es of microwave energy that propagate through the apertures will be below c~t-off, i.e. co~monly referred to as "in" cut-off, in the surface layer (and in air), but ab~ve ("not in"~ cut-off in the main p~rtion of the food itself. It will be appreciate~ that in order to achieve the in cut-off condition for the ~1,0~ and ~0,1] modes the dimen-sion Di in the case of a rectangular structure must be smaller than half the wavelength in the substance con-cerned. ~ence, to ~abulate these numerical consider-atLons, the half wa~elengths will be bulk food 0.65 - 1.0 cm faod surface coating 1.0 - 3.0 cm air 6.0 cm Under these conditions, a gcod choice for the ~alue of Di will be in the range of 10 - 16 mm, preferably about 12 - 14 mm, because this value should achieve a situation where the dominant ~odes of microwave energy that propagate through the apertures are in cut-off for the surface coati~g (and air) while not in cut-off for the bulk of the food. On the ot~er hand, if it is not important ln a particular situation for the fundamental modes not to ~e in cut-off in the bulk of the focd, the lower end of t~is range can be extended down, e.g. to 5 or 6 mm. By the sa~e token, if the surface coating of the foad has a relatively low dielectric constant, the uppe~ end o f this range can be extended up, e.g. to abo~t 20 - 25 mm.
It is important to reiterate that the numerical values given above are only examples and can be ~odifie~
as needed to suit specific conditions, and in particular the specific nature of the food to be heated.

1~39540 When the annuli are not square, e.g. cne of the shapes sho~n in Figs. 37, 39, 40, or 41, the effective width dimension to be considered from the viewpcint o~
making the aperture small enough to ensure cut-off in the s~rface layer (i.e., equivalent to the d;r?ncion Di) will be the greater internal length in the case of a rectangular annulus (Fig. 37), the internal diameter in the- case of a circular annulus (Fig. 39), the height of the internal triangle in the case of a triangular annu-lus (Fig. 40), and the distance between a pair of oppc-site inside faces in the case of the hexagonal annulus (Fig. 41).
Moreover, the "smaller than half the wavelength"
criterion is strictly true only for s~uare or rectansu-lar apertures. For circular apertures it becomes more complicated (for example, for the TE01 mcde the cut-off wavelength ~co = ~D/2.4048, where D is the diameter of the aperture), and even more complicated for other geometries. However, to gain a general condition for cut-off dimensions, suffice to say that the largest dimension of the aperture correspcnds to approximately l~alf a wavelength, and more exact dimensions can be determined by routine testing.
The condition of cut-off is illustrated diagrammatically in Fig. 42, which shows energy E entering the sheet 410.
In this drawing, the sizes of tne waves shown are intended 1339~0 .

to represent their respecti~e amplitudes rather than their spatial locations. The enerqy E paCse~ through an aperture 412 in one of the annuli 411. First it encounters an air gap 425, where there is attenuatio~
per unit distance travelled (because the energy is in cut-off). Then the remaining energy E' enters a surface layer 426 where it is still in cut-off. Finally the r~ining energy E~ enters the main portion 427 cf the ~oad article, where it is no longer in cut-off and hence there is much less attenuation per unit distance due only to absorption.
The air gap 425 bet~een the structure and the focd is kept as short as possible, because the ~i~eld decays ev~n~cc~ntly in air, and the ob~ective is that the majority of the energy should be absorbed in the surface layer 426.
As shown in Fig. 42, the enerqy E" that does remain to be ~hCorh~ by the main portion 427 of the focd article will heat the same more uniformly in the depth direction of propasation, which is desirable, because the main portion of the food article will normally have a greater depth dimension than its surface layer.
The overall result is thus increased heating per unit ~olume in the surface layer 426 relative to the heating per unit volume in the main portion 427 and hence the attainment by the sllrface layer of a relative-ly high temperature (with a consequent browning or crispening effect) and the more uniform absorption o~
heat (at a lower temperature) by the main portion sa that the inner parts of this main portion, which are relatively remote from the surfacs layer, are not en-tirely unheated.

1339~5~0 - so -Taking the example of the Fig. 38 array with a value of Di = 10 - 14 mm, a convenient value for Do would be about 20 - 25 mm, and that for Db about 4 - 5 mm, with a m;nirl~ of about 3 mm. If the value of Db is made too small, there is a danger of arcing. If Db is made too large, the microwave energy will tend to be propagated through the spaces 413 and 414 instead of through the apertures 412. Assuming that the relative dielectric constant is within the exemplary range o~
values (1.5 - 16) mentioned above, as long as Db is na greater than about 6 mm, these spaces will also be in cut-off for air and the surface layer. On the other hand, the fact that these spaces 413, 414 are elongate may permit some of the energy to propagate through them.
If this effect is found to be disadvantageous, it can be reduced by staggering the annuli to create more tortuous paths between the annuli as shown in Figs. 39 and 41.
It has also been found that good results are obtained from the device when the annuli are interconnected with each other (as shown, for example, in broken lines at 430 in Fig. 38) by similar microwave-reflective, sub-stantially non-absorptive material. Such a layout of interconnected annuli enables the whole array to be stamped out in a single operation from a sheet of alumi-num foil and mounted as a unit on the substrate 410.

1339~0 Another way of viewing the effect of the arrays of annuli is to consider them as generators of higher order modes of microwave energy.
The embodiments with continuous, substantially straight open lines of microwave-transparent material (Figures 37, 38 and 40) allow more lower order modes to propagate and hence tend to achieve more bulk heating (which may be desired in some cases, depending on the nature, especially the water content, of the food article). This effect can be reduced by avoiding such open lines, as in Figures 39 and 41, or by staggering the rows of annuli in Figures 37, 38 or 40.
Experiment l A first experiment was carried out in a square container with side walls and a lid of aluminum, and a bottom of lO mil microwave-transparent polycarbonate, so that all the energy would enter the container through its bottom. The dimensions of the container were llOmm x llOmm x 27mm. To compare the invention with the prior art, two different square arrays "A" and "B" were used. In array "A" (prior art) each annulus was completely filled in, i.e. it became an island with no aperture, and in array "B" (according to the invention) there were apertures as in Figs. 37 and 38. In both cases Do = 20mm and Db = 5mm.
The value of Di was Array Di in mm A o Each array had nine bodies (islands in the case of array "A" and annuli in the case of array "B") arranged in a square, non-staggered layout as in Figure 38.
Both tests were carried out under otherwise identical conditions, namely with a uniform load of 315g of Cream of Wheat* made by Nabisco Co. and with * Trade Mark - 52 - 1 3 3 9 5 ~ 0 heating on ~ull pawer in a Sanyo, Cuisine-~aste~ 70~-watt microwave oven for three minutes. As shown in Fig.
4~, temperat~re probes were p~s5ed through rigid plastic tubing into the center cf the load L which completely filled the container, pro~e "X" being at cr very near to the bottom, pro~e ~yl~ at three ~uarter af the depth of the load and probe ~Zt~ at half the depth of the lcad.
The tPmr~ratures measured are shown diagram~tical-ly in Figs. 44A and 44B respectively, and it will be noted that the difference after three minutes between curve "X" (carresponding to pro~e "X") and curves "y"
and "Z" (corresponding respectively to pro~es "y- and l~zn~ reached about 26-C in Fig. 44B in constrast to about 5 C in Fig. 44A. Als~, the absalute value of the temperature of cur~e "X" was significantly higher. The S-C advantage of curve X over curve "y" in Fig. 44A is attributable to the normal attenuation of the micr~wa~e energy as it passes through the load, but is considered insufficient to pr~duce the desired browning or crispen-in~
It will be appreciated that, since the load was a uniform mass af Cream of Wheat cereal, the l~ad had a surface layer that did not differ significantly in nature tand hence in relative dielectric constant) from its main partion. ~owever, the experiment nevertheless demcnstrated the significantly increased surface tem-peratures that can be achieved with an array according to the present invention, even in the absence of a differ-ence of dielectric constant between the surface layer and the main portion of the load. When such a difference in relative dielectric constant is also present, as in Experiment 2, the temperature difference between the surface layer and the main portion of the food is expected to be even more pronounced.

* Trade Marks 133~40 Experiment 2 A second experiment was conducted using different food articles, each having a different type of surface layer requiring browning or crispening, while varying the shapes of the annuli and hence the apertures.
For example, a container of frozen, battered and crumb-coated fish (haddock) was heated first using the hexagonal annuli and then using the square annuli. It was found that, when using the square annuli, it was sometimes best to use a different aperture dimension on the top surface from that used on the bottom.
This fish article had a flat bottom surface and rounded top and sides, and weighed approximately 190 g. It was placed in a microwave-transparent container, the base of which was fitted with an array of 28 (4x7) square annuli of dimensions Do = 20 mm and Di = 10 mm. A similar structure was placed over the top of the article, i.e. 28 (4x7) square annuli, but with dimensions Do = 20 mm, Di = 13 mm.
The assembly was heated for 4-1/2 minutes on full power in the same 700-watt oven. The result was a product in which the fish itself was uniformly heated to an appropriate temperature for serving, but not overcooked, while the surface appropriately crispened.
While the theory postulated above, namely that the improved surface heating that the above experiments have - demonstrated to be obtainable follows principally from the fact that some of the modes of microwave energy that propagate through the apertures are in cut-off in the surface layer, is the best explanation currently known to applicants, it is desired to point out that other factors may be at work in a system as complex as that involved when microwave energy propagates in confined spaces. For example, the improved surface heating that has been observed may result from a combination of effects, including not only the size of the aperture in each annulus but also the width of the microwave-reflective material forming the annuli and the spacing between annuli.

1339,540 It is believed that the most important consideration to bear in mind is that substantially improved practical results have been obtained using the structures disclosed herein, and that this fact is independent of the theory put forward concerning the mechanism involved in achieving such improvements.
It is to be understood that the invention is not limited to the features and embodiments hereinabove specifically set forth, but may be carried out in other ways without departure from the scope of the claims.

1339~40 SUPPLEMENTARY DISCLOSURE

The drawings accompanying the supplementary disclosure include:
Fig. 38A which is a fragmentary variation of Fig. 38;
and~
Figs. 45- ~ which are diagrams serving to illustrate Experiment 3 described below.
Fig. 38A shows square annuli 420a interrupted at 420b.
Any of the shapes shown in Figs. 39, 40 and 41 can also have interruptions in the annuli, analagous to those of Fig. 38A, and such interruptions need not necessarily be two in number, but may be a single interruption or more than two interruptions.
The embodiments of the invention so far described and illustrated have taken the form of an array of metallic structures on a microwave transparent sheet. However, instead of forming the apertures necessary to achieve cut-off by means of shapes formed of thin reflective, metallic shapes or configurations, the invention can also be practiced by defining the apertures by means of shapes or configurations of a material that differs from the microwave transparent sheet in some other electromagnetic property, such as conductivity, lossiness, dielectric constant, spatial thickness, a stepwise discontinuity or a magnetic property, as explained in the published European applications referred to above.
Experiment 3 This experiment was conducted in a 750 watt Gerling Oven model GL701(MPS 229-10)*. The container was square with dimensions of length 88 mm, width 88 mm and height 30 mm, and was made of brass to ensure that all the microwave energy entered the load from the top.

* Trade Marks 1339~40 A first load used was purified agar in fine granular form dissolved in hot water to provide a gel density of 1.03 g/mQ (sold as "Bacto-Agarn* by Difco Laboratories, Detroit, Michigan, U.S.A.) First runs on full power for 20 seconds with an unmodified container, i.e. no lid, and with different depths of load, showed in all instances the usual lateral disuniformity of heating, i.e. a cold center resulting from the dominant influence of the fundamental modes.
Corresponding runs on full power for 20 seconds with a mode-filtering array as shown in Figs. 37 and 38 extending across the top of the load in contact with the load surface exhibited a more uniform heat distribution across the surface of the load, including significantly more heating in the central area.
The temperature measurements were taken by means of an AGA THERMOVISION Infrared Camera Model 780* and processed with a VIEWSCAN LTD. Scan Converter 700* and Viewsoft*
Software.
Variations in the heating patterns were observed for different depths of load, i.e. for a depth of 6-7 mm (the theoretically minimum absorption depth) and for a depth of 10-11 mm (the theoretically maximum absorption depth). The effect of depth on energy absorption is the subject of Canadian patent application Serial No. 590,860 filed February 13, 1989 (U.S. patent application Serial No.
359,589 filed June 1, 1989~. It was found that, while there were differences in the heating effect with different depths of load, at all depths the tests conducted with a mode-filtering array in accordance with the present invention exhibited more uniform lateral uniformity of heating effect than those tests without such an array.

Trade Marks _ 57 _ 1339~40 In order to observe the heating d istribution in the vertical direction, the experiment employed a LUXTRON 750*
Fluoroptic Thermometry System using a pair of probes. One probe was positioned 2 mm below the sample surface and the other 5 mm below the sample surface. Both were in the center of the sample in the length and width directions.
The first probe effectively measured the "surface"
temperature. These dimensions were maintained regardless of the depth of the load, which was either 6 mm or 10 mm.
Measurement of the "surface" temperature by means of a probe that was actually 2 mm below the surface was required by the finite dimensions of the probe itself and in order to minimise the surface cooling effect.
The loads used were pastry (Gainborough Easi-dough*) rolled to a uniform depth of either 6 mm or 10 mm.
First runs were conducted in the same brass container with no array on top of the load. With full power the surface to bulk temperature differential at the end of 120 seconds was approximately 20~C for a load of 6 mm depth and approximately 10~C for a load of 10 mm depth.
Effective crispening was not achieved.
Similar runs were conducted with various arrays in contact with the load.
The array used (Fig. 45), which is basically similar in structure to Fig. 1, was separated into two parts, namely an array of islands 428 (Fig. 46) and an array of apertures 429 (Fig. 47). Three samples were tested under identical conditions, one with the island array (Fig. 46) alone, a second with the aperture array (Fig. 47) alone, and a third with these two arrays combined to provide the composite array of Fig. 45. It was found that neither of the single arrays when used individually was effective.
However the combination produced a mode-filtering array that provided uniformity of heating across the surface of * Trade Mark 13395~0 the pastry and an intensification of heat at the surface, i.e. a non-uniformity of heating in the vertical direction, sufficient to achieve satisfactory browning across the entire surface.
As measured by the probes the surface to bulk temperature differentials were approximately 45~C and 38~C
for the 6 mm and 10 mm deep samples, respectively.
A further run was conducted using a pastry load of lO mm depth and a mode-filtering array as shown in Fig. 48 having metal "annuli" 431 of such a shape as to define cruciform apertures 432, these annuli being arrayed on a sheet 433 of microwave-transparent material. The differ-ence between the surface and bulk temperatures was already approximately 35~C after 20 seconds heating at full power and remained at about this value as heating progressed.
The array of Fig. 48 was tested in order to demonstrate that the interior shape of the annulus, i.e. the aperture, in this case cruciform, need not necessarily conform to the outer shape of the annulus, in this case square.

Claims (30)

1. A method of enhancing the heating of a surface of an article to be heated by microwave energy, comprising the step of directing said energy through a plurality of microwave-transparent apertures defined by annuli of microwave-reflective, substantially non-absorptive material and into the surface layer and thence into a main portion of the article wherein said microwave energy enters into said surface layer in the form of cut-off propagation to directly heat said surface layer without first converting such microwave energy into heat.
2. A method according to claim 1, wherein the surface layer has a lower dielectric constant than the main portion and said microwave energy is not in the form of cut-off propagation in the main portion, whereby to cause absorption of energy in the surface layer per unit distance into the article to be greater than absorption of energy per unit distance into the main portion and hence raise the surface layer to a temperature higher than that of the main portion.
3. A method according to claim 1 wherein each of said apertures has a width dimension from 5 to 25 mm.
4. A method according to claim 1, further comprising the step of generating higher order modes of microwave energy in the article to improve the uniformity of heating of the article in lateral directions transverse to a direction of propagation of the energy through the surface layer.
5. A mode-filtering device for enhancing the heating of a surface of an article to be heated by microwave energy and having a surface layer having a dielectric constant, comprising a sheet of microwave-transparent material including a plurality of microwave-transparent apertures defined by annuli of microwave-reflective, substantially non-absorptive material and for transmission of microwave energy at a frequency into the article to be heated by the microwave energy, wherein said sheet is located adjacent to the surface layer and said apertures have dimensions so that microwave energy enters through the apertures in the form of cut-off propagation into said surface layer to directly heat said surface layer without first converting such microwave energy into heat.
6. A device according to claim 5, the apertures have dimensions so that the microwave energy in the form of cut-off propagation propagated through the apertures is not absorbed in a main portion of the article located beneath the surface layer and having a higher dielectric constant than the surface layer.
7. A device according to claim 5, wherein said annuli are arranged in an array.
8. A device according to claim 7, wherein microwave-transparent material between said annuli traces out tortuous paths.
9. A device according to claim 7, wherein the annuli in said array are interconnected with each other by microwave-reflective, substantially non-absorptive material.
10. A device according to claim 5, wherein said annuli each has a shape and said shape is selected from the group consisting of rectangular, substantially square, substantially circular, substantially triangular, substantially hexagonal and combinations of at least two of such shapes.
11. A device according to claim 5, for use with a food article to be heated by microwave energy at a frequency of 2.45 GHz, wherein said apertures each have a transverse dimension in the range of 5 to 25 mm.
12. A device according to claim 5, wherein said annuli have an outer width of 10 mm to 16 mm.
13. A device according to claim 5, for use with an article the surface layer of which has a relatively low dielectric constant, wherein said annuli have an outer width of 20 mm to 25 mm.
14. A device according to claim 7, wherein said array provides a spacing between annuli of from 3 mm to 6 mm.
15. A device according to claim 5, further including an electrically conductive plate located on said sheet of microwave-transparent material, said plate defining at least one said aperture having a closed outer periphery, and at least one electrically conductive island disposed substantially in register with said aperture to define a microwave energy transmissive gap between the outer periphery of the island and the outer periphery of the aperture for generating in the article to be heated at least one microwave energy mode of a higher order than a fundamental mode in said article.
16. A device according to claim 15, wherein said gap is continuously open.
17. A device according to claim 15, wherein said gap is bridged at spaced intervals by electrically conductive material spanning the gap between said plate and said island.
18. A device according to claim 15, wherein said island has an aperture.
19. A device according to claim 15, wherein said plate and said island are disposed in coplanar relation to each other.
20. A device according to claim 15, wherein said plate and said island are respectively disposed in parallel planes spaced apart in a direction transverse to said planes.
21. A device according to claim 20, wherein said island is smaller in area than said aperture.
22. A device according to claim 20, wherein said island is at least equal in area to said aperture.
23. A device according to claim 15, wherein said plate defines a plurality of said apertures distributed over its area in spaced relation to each other, with a plurality of said islands disposed in register with respective apertures to provide an array of annular gaps distributed over the area of said plate.
24. A device according to claim 15, wherein the device forms a first wall portion of a container for said article.
25. A device according to claim 24, further comprising a second said device forming a further wall portion of the container opposed to the first wall portion.
26. A device according to claim 24, wherein said container comprises an upwardly opening tray for holding said article and a lid for covering the upward opening of the tray, said device being disposed on said lid with the conductive plate of the device extending over substantially the entire area of said lid.
27. A device according to claim 5, wherein said plurality of apertures are positioned on said sheet of microwave-transparent material and have an electromagnetic property different from that of the sheet.
28. A combination comprising: an article to be heated by microwave energy, said article having a surface layer and a dielectric constant, a container in which said article is mounted, and a mode-filtering device incorporated in at least one wall of the container for enhancing the microwave energy heating of the article, said at least one wall being at least one of a bottom and a lid of said container, said device comprising a sheet of microwave-transparent material including a plurality of microwave-transparent apertures defined by annuli of microwave-reflective, substantially nonabsorptive material and for transmission of microwave energy at a frequency into said article, wherein said sheet is located adjacent to the surface layer and said apertures have dimensions so that microwave energy enters through the apertures in the form of cut-off propagation into said surface layer to directly heat said surface layer without first converting such microwave energy into heat.
29. A device according to claim 27, wherein said electromagnetic property is selected from conductivity, lossiness, dielectric constant, spatial thickness, a stepwise discontinuity and a magnetic property.
30. A device according to any one of claims 5 to 14, wherein at least one of said annuli has at least one interruption therein.
CA000590564A 1989-02-09 1989-02-09 Methods and devices used in the microwave heating of foods and other materials Expired - Fee Related CA1339540C (en)

Priority Applications (11)

Application Number Priority Date Filing Date Title
CA000590564A CA1339540C (en) 1989-02-09 1989-02-09 Methods and devices used in the microwave heating of foods and other materials
ZA90446A ZA90446B (en) 1989-02-09 1990-01-22 Microwave heating by means of a modified energy field including higher order modes
DE69014331T DE69014331T2 (en) 1989-02-09 1990-01-31 Methods and devices for use in microwave heating of food and other materials.
AT90300997T ATE114598T1 (en) 1989-02-09 1990-01-31 METHODS AND DEVICES FOR APPLICATION IN MICROWAVE HEATING OF FOOD AND OTHER MATERIALS.
EP90300997A EP0382399B1 (en) 1989-02-09 1990-01-31 Methods and devices used in the microwave heating of foods and other materials
NO90900546A NO900546L (en) 1989-02-09 1990-02-05 MICROWAVE HEATING OF FOODS AND OTHER MATERIALS.
BR909000574A BR9000574A (en) 1989-02-09 1990-02-08 PROCESS OF INTENSIFYING THE HEATING OF A SURFACE LAYER OF AN ARTICLE BEING HEATED BY MICROWAVE ENERGY AND APPLIANCE FOR PROCESSING THE PROCESS
AU49171/90A AU628918B2 (en) 1989-02-09 1990-02-08 Microwave heating by means of a modified energy field including higher order modes
FI900648A FI900648A0 (en) 1989-02-09 1990-02-09 FOERFARANDEN OCH ANORDNINGAR FOER MIKROVAOGSUPPVAERMNING AV MAT OCH ANDRA AEMNEN.
JP2031351A JP3049071B2 (en) 1989-02-09 1990-02-09 Microwave heating method and apparatus for food etc.
US08/015,311 US5519195A (en) 1989-02-09 1993-02-09 Methods and devices used in the microwave heating of foods and other materials

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AU628918B2 (en) 1992-09-24
JP3049071B2 (en) 2000-06-05

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