CA1211738A - Method and apparatus for the decomposition of hazardous materials and the like - Google Patents
Method and apparatus for the decomposition of hazardous materials and the likeInfo
- Publication number
- CA1211738A CA1211738A CA000485768A CA485768A CA1211738A CA 1211738 A CA1211738 A CA 1211738A CA 000485768 A CA000485768 A CA 000485768A CA 485768 A CA485768 A CA 485768A CA 1211738 A CA1211738 A CA 1211738A
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- chamber
- hazardous material
- arc
- compartment
- molten bath
- Prior art date
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Abstract
ABSTRACT
An apparatus for the decomposition of hazardous material utilizing a DC
arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the edit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the exit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal tbereof through the exhaust means.
An apparatus for the decomposition of hazardous material utilizing a DC
arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the edit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the exit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal tbereof through the exhaust means.
Description
~Z~73~3 MET~OD AND APP~R~TUS FOR THE DECOMPOSITION
OF H~Z~RDOUS MATERIALS AND THE LIKE
... . . .
This applieation is a division of eo-pendiny patent applieation serial number 429,593 ~iled June 2, 1983.
B k~round of the Invention The present invention relates generally to a ;method and apparatus for ~he decomposition of hazardous materials, such as polychlorobiphenyls (PCBs) and th like, and, more particularly, to such a method and appara~us for the pyrolysis of PCBs and other such hazardous materials utilizing a D.C. arc in a sealed electric arc furnace.
Description of the Prior Art Polychlorobiphenyl materials (PCBs) have been used ex~ensively in the past in electrical equipment such as transform~rs and capacicors, due in a large part to their flame retardant characteristic, high temperature stability, inertness to biodegradation and excellent dielectric properties. Other uses in mining equipment, hydraulic systems and heat transfer systems were prompted by chese same properties.
In the nineteen sixties it was discovered that PCBs were highly toxic snd the environmental impact of PCB contamination received a great deal of coverage in the public press. The fact that PCBs were found to be c~rcinogenic in mice and are extremely stnble has resulced in the enactment of legislstion severely restrictillg the manufacturing, processing ~3nd sale of PCBs. The storage nnd disposal of existing PCBs and matcriAls concailling PCBs has nlso been the subject of le~;isl.l~ioll, as well as reg~ cion by goverllmelltnl a~;el~cie~, sllcll a~ ch~ Irl~iroll~ncnCal l'rotectioll A~ency.
Th~ exceptional chemical stability which makes PCBs useful ~s a dielectric fluid and heat transfer agent also makes it extremely difficult to destroy.
Four basic techniques have been previously S developed for PCB disposal: landfill; chemic~l destruction; biological destruction; and incineration/pyroylsis.
The simplest and lowest cost technique used for disposal of PCBs has been by landfill. However, at the present time there is only a relatively small number of landfill sites which have obtained the requisite permits from the Environmental Protection Agency and ot~er government agencies for receiving and disposing of PCBs. In the present era of increasing public awareness and with the existing regulatory struct~lre, it is unlikely that a significant number of new landfill sites will be approved for disposal of PCBs.
In addition, the existing ~overnmental regulations only permit the disposal of solid materials contaminated by PCBs at landfill sites (liquid PCBs must be incinerated), thereby necessitating the prior draining, flushing and stora~e of all liquid PCBs. Thus, it is clear that the disposal of PCBs utilizing landfill sites is not a viable final solution to the PCB
disposal problem.
Various chemicsl treatment processes have reportedly been successfully used for the destruction of small quantities of PCBs in the lnboratory. One such technique involves the treatment of PCBs with alkaline 2-propanol solution followed by exposing the resulting material to ultraviolet light for a predetermined period of time. Another such chemical treatment technique involves t~le atepwise removal of ~2~738 electrons from the aromatic ring sys~em of the PCBs, followed by hydrolysis, solvolysis, oxida~ive coupling and dimerization utilizing high anodic potentials in acetonitrile.
While the above-described chemical treatment process, as well as other chemical treatment processes, have achieved some success in the decomposition of PCBs, the techniques have only been employed in connection with very small quant.ities of PCBs. These chemical treatment processes would be cumbersome and extremely expensive to employ in connection with the decomposition of large quantities of PCBs. In ad:dition, some of the chemical treatment processes have resulted in the generation of haæardous by-products, which require additional special handling and destruction.
Although PCBs are generally thought to be extremely resistant to biological or enzyme attnck, recent studies have shown that some PCBs are degradable . 20 by certain strains of bacteria and soil fungus. One such technique involves the use of acromasacter (two species) pseudomonas sp, acinetrobacter sp strain y42+33, and acinecobacter sp strain P6 ~o oxidatively degrade PCBs to chlorobenzoic acids. A second technique as described in U.S. Patent No. 3,779,866 employs strains of caldosporium cladosporicides, candidelipoly~ice, nocardia globerola, nocardia rubra and/or saccharomyces cerevisiae to totally destroy PCBs.
Again, while the above~described and other biological techniques have nchieved some success in the destruction of Pcss in limited quantities, none of these biological tcchlliques have offered a solution to ~he disposal of large ~uantities of PCBs in an environmentally sound manner at n reasonable cost.
In regard to incineration of PCBs, it has been found that PCBs have high thermal stability and generally require combustion telnperatures on the order of 1600C for total destruction. Although numerous prior art attempts have been made to develop a method or system for the incineration of PCBs utilizing different variations of conventional combustion techniques, the prior art methods and processes for the most part have been unsuccessu] primarily due to the extreme difficulty involved in maintaining the required 1~00C temperature. The failure to maintain the requisite temperature generally results in an incomplete destruction of the PCBs and may result in the generation of even more toxic by-product materials, such as hexachlorobenzene or polychlorinated dibenzo~urans. In addition, the prior art i~ineration/pyroloysis methods were primarily used for the destruction of liquid PCBs due to difficulties in employing such methods in connection with solids.
Furthermore, the prior art techniques resulted in the ~eneration of large volumes of gas which had to be collected and scrubbed to remove various impurities 2S therefrom.
The present invention was developed to overcome various problems associated with a number of prior art destruction processes. More specifically, the present invention comprises a method and apparatus for the destruction of PCBs and other hazardous materials u~ilizing a totally sealed system, which includes a high current DC arc for maintaining a temperature considerflbly in excess of 1600C ~nd for providin~
~Z~L738 bond-breaking ultraviolet and other radiation. The use of the DC arc nssures that the original PCBs are decomposed into relatively harmless gaseous components and that no dangerous intermediate chemicals remain in the exhaust gas. The system of the present invention is capable of effective decomposition of both solid and liquid PCBs and, due to the lack of oxygen or other atmospheric gases present in the sealed system, the need for excessive containment and scrubbing equipment for the exhaust gases is effectively reduced.
Summary of the Invention Briefly stated, the present invention provides an apparatus for the decomposition of hazardous mat0rial utilizing a DC arc, comprising:
. a gas-tight ch~mber including a sump which contains a molten bath;
inlet means for introducing the ha%ardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having Q closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the exit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the exit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintainin~ a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gnses from the chamber, whereby the gaseous product passes in the 73~
proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
In another aspect, the invention provides an apparatus for the decomposition of haæardous material utilizing a DC arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a sealable passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, and puncturin~ means within the passage for puncturing containers with hazardous material therein;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the ha~ardous mater;al;
exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the ~aseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust meQns.
srief Description of the Drawin~s The foregoing summary, as well as the following detailed description of a preferred embodiment and ~Z~73~3 several alterna~e embodiments of the present invention, will be better understood when read in conjunction with the appended drawings, in which:
Fig. 1 is a schematic elevational view, partially in section, of a preferred embodiment of an appartaus for the decomposition of ha~ardous material in accordance with the present invention;
Fig. 2 is a schematic elevational view, partially in section, of an alternate embodiment of the apparatus of Fig. l;
Fig. 3 is a fragmentary schematic sectional view showing a variation of a portion of the apparatus of Fig~ 2;
Fig. 4 ;s a fragmentary schematic sectional view showing a different variation of the apparatus of Fig.
OF H~Z~RDOUS MATERIALS AND THE LIKE
... . . .
This applieation is a division of eo-pendiny patent applieation serial number 429,593 ~iled June 2, 1983.
B k~round of the Invention The present invention relates generally to a ;method and apparatus for ~he decomposition of hazardous materials, such as polychlorobiphenyls (PCBs) and th like, and, more particularly, to such a method and appara~us for the pyrolysis of PCBs and other such hazardous materials utilizing a D.C. arc in a sealed electric arc furnace.
Description of the Prior Art Polychlorobiphenyl materials (PCBs) have been used ex~ensively in the past in electrical equipment such as transform~rs and capacicors, due in a large part to their flame retardant characteristic, high temperature stability, inertness to biodegradation and excellent dielectric properties. Other uses in mining equipment, hydraulic systems and heat transfer systems were prompted by chese same properties.
In the nineteen sixties it was discovered that PCBs were highly toxic snd the environmental impact of PCB contamination received a great deal of coverage in the public press. The fact that PCBs were found to be c~rcinogenic in mice and are extremely stnble has resulced in the enactment of legislstion severely restrictillg the manufacturing, processing ~3nd sale of PCBs. The storage nnd disposal of existing PCBs and matcriAls concailling PCBs has nlso been the subject of le~;isl.l~ioll, as well as reg~ cion by goverllmelltnl a~;el~cie~, sllcll a~ ch~ Irl~iroll~ncnCal l'rotectioll A~ency.
Th~ exceptional chemical stability which makes PCBs useful ~s a dielectric fluid and heat transfer agent also makes it extremely difficult to destroy.
Four basic techniques have been previously S developed for PCB disposal: landfill; chemic~l destruction; biological destruction; and incineration/pyroylsis.
The simplest and lowest cost technique used for disposal of PCBs has been by landfill. However, at the present time there is only a relatively small number of landfill sites which have obtained the requisite permits from the Environmental Protection Agency and ot~er government agencies for receiving and disposing of PCBs. In the present era of increasing public awareness and with the existing regulatory struct~lre, it is unlikely that a significant number of new landfill sites will be approved for disposal of PCBs.
In addition, the existing ~overnmental regulations only permit the disposal of solid materials contaminated by PCBs at landfill sites (liquid PCBs must be incinerated), thereby necessitating the prior draining, flushing and stora~e of all liquid PCBs. Thus, it is clear that the disposal of PCBs utilizing landfill sites is not a viable final solution to the PCB
disposal problem.
Various chemicsl treatment processes have reportedly been successfully used for the destruction of small quantities of PCBs in the lnboratory. One such technique involves the treatment of PCBs with alkaline 2-propanol solution followed by exposing the resulting material to ultraviolet light for a predetermined period of time. Another such chemical treatment technique involves t~le atepwise removal of ~2~738 electrons from the aromatic ring sys~em of the PCBs, followed by hydrolysis, solvolysis, oxida~ive coupling and dimerization utilizing high anodic potentials in acetonitrile.
While the above-described chemical treatment process, as well as other chemical treatment processes, have achieved some success in the decomposition of PCBs, the techniques have only been employed in connection with very small quant.ities of PCBs. These chemical treatment processes would be cumbersome and extremely expensive to employ in connection with the decomposition of large quantities of PCBs. In ad:dition, some of the chemical treatment processes have resulted in the generation of haæardous by-products, which require additional special handling and destruction.
Although PCBs are generally thought to be extremely resistant to biological or enzyme attnck, recent studies have shown that some PCBs are degradable . 20 by certain strains of bacteria and soil fungus. One such technique involves the use of acromasacter (two species) pseudomonas sp, acinetrobacter sp strain y42+33, and acinecobacter sp strain P6 ~o oxidatively degrade PCBs to chlorobenzoic acids. A second technique as described in U.S. Patent No. 3,779,866 employs strains of caldosporium cladosporicides, candidelipoly~ice, nocardia globerola, nocardia rubra and/or saccharomyces cerevisiae to totally destroy PCBs.
Again, while the above~described and other biological techniques have nchieved some success in the destruction of Pcss in limited quantities, none of these biological tcchlliques have offered a solution to ~he disposal of large ~uantities of PCBs in an environmentally sound manner at n reasonable cost.
In regard to incineration of PCBs, it has been found that PCBs have high thermal stability and generally require combustion telnperatures on the order of 1600C for total destruction. Although numerous prior art attempts have been made to develop a method or system for the incineration of PCBs utilizing different variations of conventional combustion techniques, the prior art methods and processes for the most part have been unsuccessu] primarily due to the extreme difficulty involved in maintaining the required 1~00C temperature. The failure to maintain the requisite temperature generally results in an incomplete destruction of the PCBs and may result in the generation of even more toxic by-product materials, such as hexachlorobenzene or polychlorinated dibenzo~urans. In addition, the prior art i~ineration/pyroloysis methods were primarily used for the destruction of liquid PCBs due to difficulties in employing such methods in connection with solids.
Furthermore, the prior art techniques resulted in the ~eneration of large volumes of gas which had to be collected and scrubbed to remove various impurities 2S therefrom.
The present invention was developed to overcome various problems associated with a number of prior art destruction processes. More specifically, the present invention comprises a method and apparatus for the destruction of PCBs and other hazardous materials u~ilizing a totally sealed system, which includes a high current DC arc for maintaining a temperature considerflbly in excess of 1600C ~nd for providin~
~Z~L738 bond-breaking ultraviolet and other radiation. The use of the DC arc nssures that the original PCBs are decomposed into relatively harmless gaseous components and that no dangerous intermediate chemicals remain in the exhaust gas. The system of the present invention is capable of effective decomposition of both solid and liquid PCBs and, due to the lack of oxygen or other atmospheric gases present in the sealed system, the need for excessive containment and scrubbing equipment for the exhaust gases is effectively reduced.
Summary of the Invention Briefly stated, the present invention provides an apparatus for the decomposition of hazardous mat0rial utilizing a DC arc, comprising:
. a gas-tight ch~mber including a sump which contains a molten bath;
inlet means for introducing the ha%ardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having Q closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the exit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the exit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintainin~ a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gnses from the chamber, whereby the gaseous product passes in the 73~
proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
In another aspect, the invention provides an apparatus for the decomposition of haæardous material utilizing a DC arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a sealable passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, and puncturin~ means within the passage for puncturing containers with hazardous material therein;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the ha~ardous mater;al;
exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the ~aseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust meQns.
srief Description of the Drawin~s The foregoing summary, as well as the following detailed description of a preferred embodiment and ~Z~73~3 several alterna~e embodiments of the present invention, will be better understood when read in conjunction with the appended drawings, in which:
Fig. 1 is a schematic elevational view, partially in section, of a preferred embodiment of an appartaus for the decomposition of ha~ardous material in accordance with the present invention;
Fig. 2 is a schematic elevational view, partially in section, of an alternate embodiment of the apparatus of Fig. l;
Fig. 3 is a fragmentary schematic sectional view showing a variation of a portion of the apparatus of Fig~ 2;
Fig. 4 ;s a fragmentary schematic sectional view showing a different variation of the apparatus of Fig.
2; and Fig. 5 is a schematic view of a pressure relief system employed in connection with the apparatus of Fi~s. 1 or 2.
Description of the Preferred and Alternate Embodiments Referring to Fig. 1, there is shown a schematic view of an apparatus or pyrolytic furnace indicated generally as 10, for the decomposition of liquid, solid or gaseous hazardous materials or any combination thereof, such as polychlorobiphenyls (PCBs)~ PCB
contaminated liquids and solids and the like, into innocuous gases by pyrolysis employing a D.C. arc. It ha-s been found that by subjecting PCBs and PCB
contaminated liquids and solids to a two-step process in which they are initially exposed to a high cemperature (such as in a molten bath) to promote ~L2~'738 initial decomposition into a gaseous product and then eXposing the gaseous product to a high current, high temperature D.C. arc, the resulting gaseous product produced comprises C0, C02, H2, CH4 and HCl.
The furnace 10 compr;ses, in this embodimen~, a generally cylindrical housing 12 having an outer con~ainmen~ shell 14, which may be comprised of steel or any o~her similar electrically conductive structural material, and an inner refractory lining 16, which may be comprised of any suitable known electrically conductive furnace lining material, Çor example, graphite. Because of the high temperatures and pressures involved in the decomposition process conducted within the furnace 10, the outer shell 14 and/or ~he inner lining 16 must be capable o~
withstanding an interior pressure of five atmosphere and may be cooled in any conventional manner, for example, by circulating cooling ~luid (s~lch as water) through fluid passages (not shown) which may be embedded within or adjacent to the outer shell 14 and/or the inne~ lining 16.
Due to the hazardous nature of the PCBs and other materials which are to be decomposed within the furnsce 10, it is important that the ~urnace 10 be carefully constructed ~o maintain a completely gas-tight chamber 18 within which the decomposition takes place.
Suitable seals (not shown) are employed where required to main~ain the chamber 18 in a gas-tight condition.
I~ this Inanner, leakage of unreacted or partially decomposed toxic gases into the a~mosphere can be avoided. In addition, in the gas-tight chamber, the presence of oxy~en in the furnace 10 can be avoided to thereby provide a reducing environment wllich per;nits ., the use of unconventional lining material ~such as graphite which would quickly deteriorate from burning in the presence of oxygen) for the furnace 10.
The lower portion of the furnace 10 forms an S annular sump 20 within the chamber 18. The sump 20 has maintained therein a molten bath 22 comprised of metals, salts or any other suitable material which, in its molten state, is a good electrical conductor. The molten bath 22 serves to promote the initial decomposition or volitization of the PCBs and other hazardous materials, which may be introduced into the furnace 10, into a gaseous product which is liberated i~to the chamber 18 above the molten bath 22. In addition, the molten bath 22 serves to melt or decompose any other organic or inorganic materials which may be introduced into the furnace and remain in the molten bath. Such organic or inorganic materials may include, for example~ the metal, plastic or cellulose packaging materials which were employed to contain the PCBs. It is considered necessary to destroy such container materials since, due to their `prior contact with the PCBs, they are also considered to be hazardous.
As will here;nafter be described in more detail, the temperature of the molten bath 22 is maintained at a level commensurate with the volitization temperature of che particular hazardous material being decomposed.
For example, when PCBs are being decomposed, the temperature level of the molten bath may be on the order of 1500C, which is lower than the temperature for complete destruction of PCBs in the prior art, but lower temperatures are possible in the present system ~Z~17313 due to the use of the arc which significantly aids the destruction process.
The furnace 10 includes inlet means, shown generally as 24, for charging or introducing the S hazardous material from the outside of the housing 12 into the chamber 18. The inlet means 24 comprises a plurality of individual charging ports positioned at various locations around the circumference of the housing 12. By po~itioning the charging ports around the circumference of the housing 12, the PCBs or other hazardous material may be immersed into different areas of the molten bath 22 (perhaps sequentially) ~o thereby prevent excessive localized cooling of the molten bath 22 which may occur if only a single charging port is employed. The charging ports must be capable of introducing PCBs or other hazardous material into the r~ chamber 18 while maintaining a generally gas-tight system. In this manner, the furnace 10 has the capability of operating batch (one charge of hazardous material at a time) or operating continuously (continuous addition of hazardous material).
In the present embodiment, two differPnt types of charging ports 26 and 28 are shown and will hereinafter be described in some detail. Furnace 10 may include one or more of each type of the chargin~ ports 26 and 28 or may include one type of charging port or ports.
Charging ports 26 and 28, which each comprise a two stage air-lock arran~ement, are but two examples of the ty~es of charging ports which may be employed for introducing ha~ardous material into the chamber 18.
Therefore, it should be appreciated that the present invention is not limited to the specific type or combination of charging ports disclosed bu~ could employed any other suitable type or combination of inlet means which allows for introduction of hazardous material into the furnace 10 while effectively S maintaining the chamber 18 in a gas-tight condition to prevent the escape of any toxic or otherwise hazardous gas.
Charging port 26 is particularly suited for introducing, for exa~ple, capacitors designated 29 into the furnace 10. Capacitors 29 of the type shown may comprise ceramic, cellulose plastic metal and some form of generally sealed metalic outer container which enclose (sometimes under pressure) liquid PCBs as a dielectric element. Both the PCBs within ~he container and the container itself must be disposed of as hazardous materials. The charging port 26 comprises a :; sealed (gas-tigh~) generally tubular passage 30 having an entry port 32 on a first or outer end and an exit pQr~ 34 on the second or inner end. The sealed passage 30 further includes a closable parcition means 36 positioned approximatley halfway between the entry port 32 and ~he exit port 34 to divide the sealed passage into a first outer compartment 38 adjacent to the entry port 32 and a s~cond inner compartment 40 adjacent to the exit port 34. Each of the ports 32 and 34 and partition 36 are adapted to open and close independently of each other and to provide tight seals when closed, so that the charging port 26 has the c~`pability of continuously charging or introducing material into the furnace 10 while continuing to maintain the gas-tight condition of the chamber 18.
In the operation of the inlet device 26, the ports 32 and 34 and partition 36 are initially closed as sbown. The entry port 32 is then opened and capacitor 29, or other solid or liquid hazardous material to be decomposed or destroyed, is admitted or inserted into the first compartment 38 as shown. The entry port 32 is then closed and the first compartment 38 is evacuated (employing any known suitable means) to prevent the introduction of oxygen into the chamber 18.
Thereafter, the partition 36 is opened and the capa~itor 29 is passed from the first compartment 38 into the second compartment 40. In the embodiment shown on Figo 1, the tubular passage 30 slopes slightly downwardly so that the capacitor 29 may sîmply s~ide or roll downwardly from the first co~partment 38 through ~he partition 36 ~o the second compartment 40.
Alternatively, any other suitable means could be employed for moving the capacitor 29 from ~he first compartment 38 to the second compartment 40, such as a push rod (not shown) or a conveyor belt (not shown).
~ Once the capacitor 29 is positioned within the second compartment 40, the partition 36 is again closed and the first compartment 38 is evacuated to prevent the escape (to the atmosphere) of any toxic gas when the entry port 32 is opened again. The exit port 34 ~s then opened and the capacitor 29 passes from the second compartment 40 along the downwardly sloping passage 30 and into the molten bath 22~ As previously mentioned, any other suitable means may be employed for moving the capacitor 29 from the second compartment 40 into the molten bath 22.
While in some cases it is desirable to have entire capacitors inserted directly into the molten bath 22 as described above, in other cases this is not an acceptable procedure. secause of the size and construction of some capacitors, and particularly large p~essure sealed capacitors, the immersion of the er.tire capacitor directly into the molten bath 22 would result in R build-up in pressure within the capacitor and 5 eventually a violent or uncontrolled explosion which may result in potential damage to the furnace. In order to alleviate the potential explosion hazard, the second compartment 40 may include suitable means 42, for example the multi-pronged "iron maiden" shown in 10 Figo 1, for puncturing and/or crushing the capacitor 29 in order to prevent the formation of excessive pressure. In addition, by puncturing or crushing the capacitor 29 in this manner, the liquid PCBs within the capacitor 29 are permitted to drain from the capacitor 15 container.
The lower end of the second compartment 40 g includes an opening into a conduit means or drain pipe 44 which communicates with the interior of the chamber 18 as shown. The drain pipe 44 receives liquid PCBs 20 from the punctured or crushed capacitor 29 and allows liquid PCBs to flow into the molten bath 22. The liquid PCBs may be preheated utilizing waste heat from the furnace 10 (not shown) prior to their entering ~he molten bath 22. A suitable valve means 46, which may 25 be provided by any suitable known control valve, may be installed within the drain pipe 44 in order to restrict and control the flow of liquid PCBs into the molten bath 22. In addition, the liquid PCBs may be pr~essurized, atomized and sprayed (not shown) against 30 the surface of the molten bath 22 to provide more intimate contact between the PCBs and the molten bath and to avoid localized cooling of the bath.
As discusscd briefly above, each of the compartments 38 and 40 of tlle charging por~ 26 also ~ -13-includes a suitable evacuation system (not shown) for removing any ~ses which may enter ei~her compartment from the chamber 18 or from the a~mosphere. The evacuated gas from the compartments 38 and 40 is preferably recycled back into the chamber 18 by any suitable means (not shown) to provide for the processing of any hazardous gas which may be present.
Such an evacuation system may be of any suitable known type and need not be described in detail for a complete understanding of the present invention.
Charging port 28 is similar to charging port 26, in that, it comprises a generally tubular sealed (gas-tight) passage 48 having an entry port 50, an exit port 52 and a partition means S4 to divide the passage 48 into a first outer compartmen~ 56 and a second inner compartment 58. Both of the compartments 56 and 58 include an evacuation system (not shown) for the purposes described in connection wi~h charging port 26.
}lowever, unlike charging port 26, the second compartment 58 of charging port 28 includes a conventional motor driven screw conveyor or auger 60.
The screw conveyor 60 transports the PCBs and the PCB
containers received within compartment 58 to the exit port 52 and for the reasons as stated above, punctures or c~ushes the capacitors or containers.
The second compartment 58 of the inlet device 28 also includes a conduit means or drain pipe 62 for conveying the li~uid PCBs from punctured capacitors (not shown) within the second compartment 58 to the molten bath 22. However, unlilce the prèviously discussed arrangemcnt of drain pipe 44, drain pipe 62 empties directly into the molten bath 22 below the surface tllereof. ~ ~suit~ble pump 64 is employed to provide cnough plcssurc to "bubblc" thc liquid PCBs ~Z1~38 directly into the molten bath 22 as well as to control the flow rate of liq~id PCBs into the bath.
As discussed above, the immersion of the PCBs into the high temperature molten bath 22 results in the S decomposition of the PCBs into gases which remain within the chamber 18 above the molten bath 22. As the gases come into contact with the high temperature upper surface of the molten bath 22, the chemical bonds are further broken. By controlling the quantity of PCBs which are immersed into the molten bath 22 (i.e., through the use of valve 46 and pump 64), the quantity of the gases subsequently released into the chamber 18 and thus, the gas pressure within the chamber 18, may be controlled. The housing 12 should be strong enough lS to withstand a gas pressure of five atmospheres within the chamber 18 with no uncontrolled leakage of gas to the atmosphere.
The furnace 10 also includes electrode means, generally designated 66, for maintaining a direct current (DC) electric arc within the chamber 18. The electrode means 66 comprises in part an elongated tubular electrode 68 movably mounted to the furnace cover 70. The electrode 68 is moved vertically with respect to the molten bath 22 for the purpose of establishing and maintaining ~he desired elec~rical arc (shown generally as 72) extending from the arcing tip 82 to the molten bath 22. Any suitable means may be employed for the vertical movement of the electrode 68.
For example, a rack 74 may be fixed to the electrode and a suitable pair of motor-driven pinions 76 may be employed to engage the electrode rack 74 for movement thereof in either vertical direction.
.
73~
The furnace 10 also includes exhaust means, generally designated 78, for the removal o gases from the gas-tight chamber 18. In the present embodiment, the exhaust means 78 comprises the hollow interior of the tubular electrode 68 which communicates with a suitable exhaust conduit 80 extending throu~h the furnace cover 70 to atmosphere. ~oweYer, it should be appreciated that any other suitable exhaust means (other than the hollow inter;or of the tubular electrode 68) could be employed for the removal of gases from the chamber 18. The only requirement for the exhaust means 78 is that its entrance be loca~ed proximate to the ~rcing tip 82 of the electrode 68, so that all of the gases within the chamber 18 must pass near or through the arc 72 before being exhausted from the furnace 10.
The exhaust gas removed from the furnace lO may be received snd stor~d in suitable containers (not shown) f~r testing and analysis. If the analyzed gas is found to be clean enough to comply with existing regulations or standards, it may be exhausted directly to the atmosphere. If the analyzed gas is found to be of unacceptable quality, it may be further processed by a suitable device such as a bubble tank (not shown) or a scrubb~r (not shown). An exit gas afterburner (not shown) may also be employed. In the event that the exhaust gas from the furnace still contains toxic or other hazardous material, the gas may be recycled by any suitable means (not shown) back into the chamber l~
for further processing relative to the electric arc.
Suitable heat exchange means (not shown) may be provided to lower the temperature of the exhaust gases from the furnace and to rec1aim or recycle the recovered therma1 energy.
73~3 In order to provide a subs~antially continuous DC
arc within the chamber 18 be~ween the arcing tip 82 of the electrode 68 and the molten bath 22, the outer shell 14 of the furnace is connected to ground (not shown) and the electrode is connected to a suitable low voltage, solid state DC current supply (not shown).
Preferably, the DC current supply is so poled that the electrode 68 is negative with respect to the outer shell 1~. The conductive inner lining 16 ~nd the conductive molten bath 22 are also maintained at ground potential. Thus, the electrode 68 constitutes the negative terminal and the molten bath 22 constitutes the positive terminal of a DC load circuit. As shown, the two terminsls (the electrode 68 and the molten bath 22) are spaced apart in operation to provide between them an arc gap of a predetermined distance in which .~ the arc 72 exists when the circuit is energized. A
current regulator (not shown) m~y be provided to maintain a substantially constant predetermined arc level as required for the desired decomposition of the hazardous material being processed. Arc voltage sensing equipment (not shown) rnay also be employed to compare the arc voltage with a preset reference for comparison and arc length control. A DC choke coil (not shown) may also be connected in series with the DC
arc current path in order to prevent arc extinction due to any sudden rise in arc vol~age, any sudden cooling of the arc due to endothermic chemical reactions, or to tr.ansient gas pressures which occur during PCB
decomposition.
The arc 72 provides the primary heat to initially melt and thereafter maintain the material within the sump in the molten state. The arc 72 also serves as a source o~ radiation, or example, ultraviolet radiation, which assists in bresking the bonds of the PCBs. In addition, the extreme high temperature of the arc (10,000C or higher) assures that the gases and any previously non-decomposed material passing through or S near the arc toward the exhaust means 78 ~re completely decomposed into the above-described generally innocuous gaseous elements.
In order to further insure that the gases from the chamber 18 obeain maximum exposure to the arc for complete decomposition, the furnace 10 also includes means, generally designated 84, for rapidly and uniformly moving the arc 72 in a predetermined path around the surface of the arcing tip 82 of the el~ctrode 68. The rapid rotation of the arc 72 around the arcing tip 82 also provides a more uniform distribution of heat to the molten bath 22 and processing in the chamber 18 which tends to preserve the inner lining 16. The rotating arc also puts pressure on the molten bath material where the arc hits the molten bath 22, this together with the high temperature of the arc causes the material to boil and form an indentation in molten bath material. The rotation of the arc around the arcing tip 82 may be so fast that the indentation may not be refilled, and high temperature boiling materiAl is spewed out in the vicini~y of the indentation. The gases passing proximate the arc are contacted by the heat and the super heated bath material to aid in decomposition.
In the present embodiment, the means for moving the arc around the surfsce of the arcing tip 82 of the tubular electrode 68 comprises magnetic me~ns in the form of an annular electromagnetic coil 86 positioned within the housing 12 beneath the arcing ~ip 82. The eleccroma~entic coil 86 is connected to a ~suit~ble DC
73i~
voltage source (not shown) to generate a ma~netic field having flux lines (not shown) extending generally perpendicular to the arc 72. In this manner, well-known magnetohydrodynamics principles are employed S to move the arc 72 around the surface of the arcing tip 82. The rate of movement of the arc around the arcing tip 82 is controlled by controlling the location of the electromagnetic coil 86 and the intensity and orientacion of the magnetic field generated by the coil 86. The magne~ic field also serves to stir the molten bath 22 to provide more complete mixing of the molten bath ma~erial and the hazardous materials which are being decomposed. In this manner, the upper su~face of t~e mol~en bath 22 is kept in condition to receive and react with newly introduced hazardous material.
As hazardous material and the various inorganic (metallic) containers ~ssociated therewith are added to the furnace 10, the level of the molten bath 22 tends to rise. In order to maintain the molten bath 22 at a p~edetermined depth commensurate with the size of the chamber, the length of the arc and other such factors, it is necessary to provide a means for removing some of the material from the molten bath 22 while still continuing the decomposition of the hazardous material.
In the present embodiment, the means for maintaining the molten bath at the desired prede~ermined depth comprises a generally cylindrical container 88 positioned beoeath the center of the furnace housing 12. ~n annular weir 90 is provided to establish the predetermined depth of the molten bath. Whenever the depth of the molten bath exceeds the height of the weir 90~ molten material flows over the weir 90, through a conduit rncans or drain pipe 92 and into the cylindrical ` ~Z1~738 ,9 container 88. The conduit means 92 and the cylindrical container 88 are provided with suitable sealing mesns (not shown) in order to maintain the chamber 18 in the gas-tight condition.
The cylindrical container 88 is removably attached to the furnace housing 12. In this manner, material flowing from the molten bath 22 over the weir 90 may be collected in the cylindrical container 88 until the cylindrical container is filled. The cylindrical container may then be removed from the furnace housing 12 and the material collected therein may be suitably emptied and/or disposed of in a conventional manner.
In order to ensure that the chamber 18 remains ga3-tight during the period of time when the cylindrical container 88 is removed for emptying, a suitable sealing apparatus 94 is provided to close off the conduit means g2. A suitable evacuation system (not shown) may also be provided to remove any gases which may have accumulated within the cylindrical co~tainer 88. The gases removed from the cylindrical container 88 are recycled back into the chamber 18. By first sealing off the conduit means 92 with the sealing apparatus 94 and then employing the evacuation system to remove gases accumulated in the cylindrical container 88, the container 88 may be removed for emptying without affecting the continued operation of the furnace 10. Once the empty contaîner is replaced, the sealing apparatus 94 is again opened and molten material may again flow through the conduit means 92 for collection in the container 88.
Alternatively, excess material may be removed from the molten bath 22 by means of a standard tap or drain (shown in phantom as 96). However, in order to utilize ~Z1~38 such a tap or drain 96, it is first preferable to halt the normal operation of the furnace 10. Material removed through ~he tap 94 may be suitably disposed of in any conventional manner.
As a variation of the above-described embodiment, the gases from the chamber 18 may be exhausted through the conduit means 92, into the cylindrical container 88 and out of an alternate exhaust conduit (shown in phantom as 81). In this manner, the gases may react with the material within the container 88 for further processing.
Referring now to Fig. 2, there is shown an apparatus or furnace 110 for the decomposition of h~zardous material which is substantially the same as the furnace 10 of Fig. 1. In connection with the description of Fig. 2, the same numbers will be used for the same components bu~ with the addition of 100 thereto. Viewing Fig. 2, it can be seen that the furnace 110 comprises a generally cylindrical housing 1~2 which defines a gas-tight, generally cylindrical ~hamber 118. Within the chamber 118 is a molten bath 122 of metal, salt or any other suitable conductive material. A generally tubular electrode 168 is similarly movably actached to the furnace cover 170.
As in the furnace shown in Fig. 1 J the center of the tubular electrode 168 comprises an exhaust means 178 which further includes an exhaust conduit 180 to permit che removal of gases from the chamber 118 to the outside of the furnace 110. The furnace 110 further includes suitable inlet means (not shown in Fig. 2) for introducing hazardous material into the chnmber 118 in che same manner as was shown and described in conneccion with Fig. 1.
73~
The primary difference between the furnace 10 of F~g. 1 and the furnace 110 of Fig. 2 is in the manner in which the excess material is removed from the molten bath. As shown on Fig. 2, a generally cylindrical container 188 is provided adjacent to one side of the furnace housing 112. The adjacent side wall of the furnace housing 112 includes an opening which forms a weir 190 to establish the depth level of the material within ~he molten bath 122. Any material rising above the level of the weir 190 flows through a conduit means 192 and into the container 188. The con~ainer 188 is remo~able from the conduit means 192 and both the container 188 and the condui~ means 192 are provided with suitable sealing means (not shown) to preserve the gas-tight integrity of the chamber 118. A suitable sealing apparatus 194 is provided to close off and seal the conduit means 192 when the container 188 has been removed for emptying. A suitable evacuation system 198 co~prising a sui~able pump 200 and a corresponding check valve 202 is provided to evacuate any gases which may accumulate in the container 188 prior to emptying the container. As shown, the gases removed from the container 188 are recycled back into the chamber 118 for further processing.
A further difference between the furnace 10 of Fig. 1 and the furnace 110 of Fig. 2 is in the loc~tion of the nnnular electromagnetic coil 186 which is employed to cause the rotation of the arc 172 around the arcing tip 182 of the tubul~r electrode 168. As shown, the electromagnetic coil 186 is located on the outside of the housing 112 beneath the electrode 168.
In order to insure that the housing ll2 does not interfere with the magnetic field generated by the . ~L2~738 external electromagnetic coil 186, the lower portion of ~he housing is comprised of non-magnetic material as shown. As in the embodiment of Fig. 1, the flux lines from the ma~netic field are perpendicular to the arc 172, thereby causirlg the arc to rotate around the surface of the arcing tip 182.
Fig. 3 shows a slight variation of the furnace of Fig~ 2, wherein the same numbers are used as appear in Fi~. 2 but with the addition of primes thereto. In Fig. 3, the conduit me~ns 192' for removing material from the molten bath 122' is positioned beneath the surface of the molten bath. The conduit 192' further includes a standard plumber's P-trap arrangement 104' to effectively prevent gases contained within the chamber 118' from entering the container 188'. A
sealing apparatus 144' is also provided to facilitate the emptying of the container 188' without any interruption of furnace operation.
Fig. 4 shows a different variation of the furnace of Fig. 2 in which a different means is provided for moving ehe arc 472 around the arcing electrode tip 482.
Referring to Fig. 4~ the same numbers are used as in Fig. 1 but with the addition of 400 thereto. In Fig.
4, instead of employing an electromagnetic coil, as was done in connection with the embodiment of Fig. 2, first generally cylindrical ferrous member 406 is positioned within the hollow interior of the tubular electrode 468 adjacent to the arcing tip 482.
Similarly, a tubular ferrous member 407 surrounds the tubular electrode 468 edjacent to ehe arcing eip 482.
Both of the ferrous members 406 and 407 may be cooled employing a suitable known cooling system (not shown) which uses a heat transfer fluid such as water (not -~ ~Z1~738 shown). The ferrous members 406 and 407 interact with the arc current to generate a magnetic field having flux lines (not shown) which extend generally perpendicular to the arc 472. In this manner, ~he arc S is made to rotate around the surface of the arcing tip 482 in the same manner as was discussed in detail in relation to the apparatus of Fig. 1.
~ eferring now to ~ig. S, there is shown a schematic representation of a pressure relief system ge~erally designated SOO which may be employed in connection with furnace 10 of the type described in Fig. 1 or any of the above-described alternative furnace embodiments. The pressure relief system comprises a sealed (gas-tight~ container or surge tank 502 located proximate to the furnace 10. A suitable first conduit means 504 extends between the furnace 10 and the sealed container 502 and provides communication between ~he interiors thereof. A pressure relief valve 506 is positioned within the first conduit means 504 to conerol and effectuate relief of the pressure within the furnace lO, if necessary. As described above, the furnace lO should be constructed to withstand an internal gas pressure of five atmosphere without leaking any gas therefrom. The pressure relief valve 506 should be designated to relieve the furnace pressure ~t a preset pressure point slightly less than the five atmosphere level.
Once the preset pressure point of the pressure relief valve 506 has been exceeded the excess gas from the furnace lO flows into the container 502 thereby lowering the pressure within the furnace. A second conduit means 508 and a suitable pump S10 are provided to return gas from the sealed contniner 502 to the ~2~1~38 furnace 10 for further processing when the pressure within the furnace has decreased to sn acceptable level.
From the foregoing description and the accompanying figures, it can be seen that the present invention provides a method and npparatus for the decomposition of PCBs and o~her hazardous material which is efficient, relatively easy to control and is very effective in operaeion. It will be recognized by those skilled in the art ~hat changes or modifications may be made to the above-described embodiments without departing from the broad inventive concepts of the invention. It is understood, therefore, that this invention is not limited to the particular embodiments described9 but it is intended to cover all changes and modifications which are within ehe scope and spirit of the invention as set forth in the appended claims.
Description of the Preferred and Alternate Embodiments Referring to Fig. 1, there is shown a schematic view of an apparatus or pyrolytic furnace indicated generally as 10, for the decomposition of liquid, solid or gaseous hazardous materials or any combination thereof, such as polychlorobiphenyls (PCBs)~ PCB
contaminated liquids and solids and the like, into innocuous gases by pyrolysis employing a D.C. arc. It ha-s been found that by subjecting PCBs and PCB
contaminated liquids and solids to a two-step process in which they are initially exposed to a high cemperature (such as in a molten bath) to promote ~L2~'738 initial decomposition into a gaseous product and then eXposing the gaseous product to a high current, high temperature D.C. arc, the resulting gaseous product produced comprises C0, C02, H2, CH4 and HCl.
The furnace 10 compr;ses, in this embodimen~, a generally cylindrical housing 12 having an outer con~ainmen~ shell 14, which may be comprised of steel or any o~her similar electrically conductive structural material, and an inner refractory lining 16, which may be comprised of any suitable known electrically conductive furnace lining material, Çor example, graphite. Because of the high temperatures and pressures involved in the decomposition process conducted within the furnace 10, the outer shell 14 and/or ~he inner lining 16 must be capable o~
withstanding an interior pressure of five atmosphere and may be cooled in any conventional manner, for example, by circulating cooling ~luid (s~lch as water) through fluid passages (not shown) which may be embedded within or adjacent to the outer shell 14 and/or the inne~ lining 16.
Due to the hazardous nature of the PCBs and other materials which are to be decomposed within the furnsce 10, it is important that the ~urnace 10 be carefully constructed ~o maintain a completely gas-tight chamber 18 within which the decomposition takes place.
Suitable seals (not shown) are employed where required to main~ain the chamber 18 in a gas-tight condition.
I~ this Inanner, leakage of unreacted or partially decomposed toxic gases into the a~mosphere can be avoided. In addition, in the gas-tight chamber, the presence of oxy~en in the furnace 10 can be avoided to thereby provide a reducing environment wllich per;nits ., the use of unconventional lining material ~such as graphite which would quickly deteriorate from burning in the presence of oxygen) for the furnace 10.
The lower portion of the furnace 10 forms an S annular sump 20 within the chamber 18. The sump 20 has maintained therein a molten bath 22 comprised of metals, salts or any other suitable material which, in its molten state, is a good electrical conductor. The molten bath 22 serves to promote the initial decomposition or volitization of the PCBs and other hazardous materials, which may be introduced into the furnace 10, into a gaseous product which is liberated i~to the chamber 18 above the molten bath 22. In addition, the molten bath 22 serves to melt or decompose any other organic or inorganic materials which may be introduced into the furnace and remain in the molten bath. Such organic or inorganic materials may include, for example~ the metal, plastic or cellulose packaging materials which were employed to contain the PCBs. It is considered necessary to destroy such container materials since, due to their `prior contact with the PCBs, they are also considered to be hazardous.
As will here;nafter be described in more detail, the temperature of the molten bath 22 is maintained at a level commensurate with the volitization temperature of che particular hazardous material being decomposed.
For example, when PCBs are being decomposed, the temperature level of the molten bath may be on the order of 1500C, which is lower than the temperature for complete destruction of PCBs in the prior art, but lower temperatures are possible in the present system ~Z~17313 due to the use of the arc which significantly aids the destruction process.
The furnace 10 includes inlet means, shown generally as 24, for charging or introducing the S hazardous material from the outside of the housing 12 into the chamber 18. The inlet means 24 comprises a plurality of individual charging ports positioned at various locations around the circumference of the housing 12. By po~itioning the charging ports around the circumference of the housing 12, the PCBs or other hazardous material may be immersed into different areas of the molten bath 22 (perhaps sequentially) ~o thereby prevent excessive localized cooling of the molten bath 22 which may occur if only a single charging port is employed. The charging ports must be capable of introducing PCBs or other hazardous material into the r~ chamber 18 while maintaining a generally gas-tight system. In this manner, the furnace 10 has the capability of operating batch (one charge of hazardous material at a time) or operating continuously (continuous addition of hazardous material).
In the present embodiment, two differPnt types of charging ports 26 and 28 are shown and will hereinafter be described in some detail. Furnace 10 may include one or more of each type of the chargin~ ports 26 and 28 or may include one type of charging port or ports.
Charging ports 26 and 28, which each comprise a two stage air-lock arran~ement, are but two examples of the ty~es of charging ports which may be employed for introducing ha~ardous material into the chamber 18.
Therefore, it should be appreciated that the present invention is not limited to the specific type or combination of charging ports disclosed bu~ could employed any other suitable type or combination of inlet means which allows for introduction of hazardous material into the furnace 10 while effectively S maintaining the chamber 18 in a gas-tight condition to prevent the escape of any toxic or otherwise hazardous gas.
Charging port 26 is particularly suited for introducing, for exa~ple, capacitors designated 29 into the furnace 10. Capacitors 29 of the type shown may comprise ceramic, cellulose plastic metal and some form of generally sealed metalic outer container which enclose (sometimes under pressure) liquid PCBs as a dielectric element. Both the PCBs within ~he container and the container itself must be disposed of as hazardous materials. The charging port 26 comprises a :; sealed (gas-tigh~) generally tubular passage 30 having an entry port 32 on a first or outer end and an exit pQr~ 34 on the second or inner end. The sealed passage 30 further includes a closable parcition means 36 positioned approximatley halfway between the entry port 32 and ~he exit port 34 to divide the sealed passage into a first outer compartment 38 adjacent to the entry port 32 and a s~cond inner compartment 40 adjacent to the exit port 34. Each of the ports 32 and 34 and partition 36 are adapted to open and close independently of each other and to provide tight seals when closed, so that the charging port 26 has the c~`pability of continuously charging or introducing material into the furnace 10 while continuing to maintain the gas-tight condition of the chamber 18.
In the operation of the inlet device 26, the ports 32 and 34 and partition 36 are initially closed as sbown. The entry port 32 is then opened and capacitor 29, or other solid or liquid hazardous material to be decomposed or destroyed, is admitted or inserted into the first compartment 38 as shown. The entry port 32 is then closed and the first compartment 38 is evacuated (employing any known suitable means) to prevent the introduction of oxygen into the chamber 18.
Thereafter, the partition 36 is opened and the capa~itor 29 is passed from the first compartment 38 into the second compartment 40. In the embodiment shown on Figo 1, the tubular passage 30 slopes slightly downwardly so that the capacitor 29 may sîmply s~ide or roll downwardly from the first co~partment 38 through ~he partition 36 ~o the second compartment 40.
Alternatively, any other suitable means could be employed for moving the capacitor 29 from ~he first compartment 38 to the second compartment 40, such as a push rod (not shown) or a conveyor belt (not shown).
~ Once the capacitor 29 is positioned within the second compartment 40, the partition 36 is again closed and the first compartment 38 is evacuated to prevent the escape (to the atmosphere) of any toxic gas when the entry port 32 is opened again. The exit port 34 ~s then opened and the capacitor 29 passes from the second compartment 40 along the downwardly sloping passage 30 and into the molten bath 22~ As previously mentioned, any other suitable means may be employed for moving the capacitor 29 from the second compartment 40 into the molten bath 22.
While in some cases it is desirable to have entire capacitors inserted directly into the molten bath 22 as described above, in other cases this is not an acceptable procedure. secause of the size and construction of some capacitors, and particularly large p~essure sealed capacitors, the immersion of the er.tire capacitor directly into the molten bath 22 would result in R build-up in pressure within the capacitor and 5 eventually a violent or uncontrolled explosion which may result in potential damage to the furnace. In order to alleviate the potential explosion hazard, the second compartment 40 may include suitable means 42, for example the multi-pronged "iron maiden" shown in 10 Figo 1, for puncturing and/or crushing the capacitor 29 in order to prevent the formation of excessive pressure. In addition, by puncturing or crushing the capacitor 29 in this manner, the liquid PCBs within the capacitor 29 are permitted to drain from the capacitor 15 container.
The lower end of the second compartment 40 g includes an opening into a conduit means or drain pipe 44 which communicates with the interior of the chamber 18 as shown. The drain pipe 44 receives liquid PCBs 20 from the punctured or crushed capacitor 29 and allows liquid PCBs to flow into the molten bath 22. The liquid PCBs may be preheated utilizing waste heat from the furnace 10 (not shown) prior to their entering ~he molten bath 22. A suitable valve means 46, which may 25 be provided by any suitable known control valve, may be installed within the drain pipe 44 in order to restrict and control the flow of liquid PCBs into the molten bath 22. In addition, the liquid PCBs may be pr~essurized, atomized and sprayed (not shown) against 30 the surface of the molten bath 22 to provide more intimate contact between the PCBs and the molten bath and to avoid localized cooling of the bath.
As discusscd briefly above, each of the compartments 38 and 40 of tlle charging por~ 26 also ~ -13-includes a suitable evacuation system (not shown) for removing any ~ses which may enter ei~her compartment from the chamber 18 or from the a~mosphere. The evacuated gas from the compartments 38 and 40 is preferably recycled back into the chamber 18 by any suitable means (not shown) to provide for the processing of any hazardous gas which may be present.
Such an evacuation system may be of any suitable known type and need not be described in detail for a complete understanding of the present invention.
Charging port 28 is similar to charging port 26, in that, it comprises a generally tubular sealed (gas-tight) passage 48 having an entry port 50, an exit port 52 and a partition means S4 to divide the passage 48 into a first outer compartmen~ 56 and a second inner compartment 58. Both of the compartments 56 and 58 include an evacuation system (not shown) for the purposes described in connection wi~h charging port 26.
}lowever, unlike charging port 26, the second compartment 58 of charging port 28 includes a conventional motor driven screw conveyor or auger 60.
The screw conveyor 60 transports the PCBs and the PCB
containers received within compartment 58 to the exit port 52 and for the reasons as stated above, punctures or c~ushes the capacitors or containers.
The second compartment 58 of the inlet device 28 also includes a conduit means or drain pipe 62 for conveying the li~uid PCBs from punctured capacitors (not shown) within the second compartment 58 to the molten bath 22. However, unlilce the prèviously discussed arrangemcnt of drain pipe 44, drain pipe 62 empties directly into the molten bath 22 below the surface tllereof. ~ ~suit~ble pump 64 is employed to provide cnough plcssurc to "bubblc" thc liquid PCBs ~Z1~38 directly into the molten bath 22 as well as to control the flow rate of liq~id PCBs into the bath.
As discussed above, the immersion of the PCBs into the high temperature molten bath 22 results in the S decomposition of the PCBs into gases which remain within the chamber 18 above the molten bath 22. As the gases come into contact with the high temperature upper surface of the molten bath 22, the chemical bonds are further broken. By controlling the quantity of PCBs which are immersed into the molten bath 22 (i.e., through the use of valve 46 and pump 64), the quantity of the gases subsequently released into the chamber 18 and thus, the gas pressure within the chamber 18, may be controlled. The housing 12 should be strong enough lS to withstand a gas pressure of five atmospheres within the chamber 18 with no uncontrolled leakage of gas to the atmosphere.
The furnace 10 also includes electrode means, generally designated 66, for maintaining a direct current (DC) electric arc within the chamber 18. The electrode means 66 comprises in part an elongated tubular electrode 68 movably mounted to the furnace cover 70. The electrode 68 is moved vertically with respect to the molten bath 22 for the purpose of establishing and maintaining ~he desired elec~rical arc (shown generally as 72) extending from the arcing tip 82 to the molten bath 22. Any suitable means may be employed for the vertical movement of the electrode 68.
For example, a rack 74 may be fixed to the electrode and a suitable pair of motor-driven pinions 76 may be employed to engage the electrode rack 74 for movement thereof in either vertical direction.
.
73~
The furnace 10 also includes exhaust means, generally designated 78, for the removal o gases from the gas-tight chamber 18. In the present embodiment, the exhaust means 78 comprises the hollow interior of the tubular electrode 68 which communicates with a suitable exhaust conduit 80 extending throu~h the furnace cover 70 to atmosphere. ~oweYer, it should be appreciated that any other suitable exhaust means (other than the hollow inter;or of the tubular electrode 68) could be employed for the removal of gases from the chamber 18. The only requirement for the exhaust means 78 is that its entrance be loca~ed proximate to the ~rcing tip 82 of the electrode 68, so that all of the gases within the chamber 18 must pass near or through the arc 72 before being exhausted from the furnace 10.
The exhaust gas removed from the furnace lO may be received snd stor~d in suitable containers (not shown) f~r testing and analysis. If the analyzed gas is found to be clean enough to comply with existing regulations or standards, it may be exhausted directly to the atmosphere. If the analyzed gas is found to be of unacceptable quality, it may be further processed by a suitable device such as a bubble tank (not shown) or a scrubb~r (not shown). An exit gas afterburner (not shown) may also be employed. In the event that the exhaust gas from the furnace still contains toxic or other hazardous material, the gas may be recycled by any suitable means (not shown) back into the chamber l~
for further processing relative to the electric arc.
Suitable heat exchange means (not shown) may be provided to lower the temperature of the exhaust gases from the furnace and to rec1aim or recycle the recovered therma1 energy.
73~3 In order to provide a subs~antially continuous DC
arc within the chamber 18 be~ween the arcing tip 82 of the electrode 68 and the molten bath 22, the outer shell 14 of the furnace is connected to ground (not shown) and the electrode is connected to a suitable low voltage, solid state DC current supply (not shown).
Preferably, the DC current supply is so poled that the electrode 68 is negative with respect to the outer shell 1~. The conductive inner lining 16 ~nd the conductive molten bath 22 are also maintained at ground potential. Thus, the electrode 68 constitutes the negative terminal and the molten bath 22 constitutes the positive terminal of a DC load circuit. As shown, the two terminsls (the electrode 68 and the molten bath 22) are spaced apart in operation to provide between them an arc gap of a predetermined distance in which .~ the arc 72 exists when the circuit is energized. A
current regulator (not shown) m~y be provided to maintain a substantially constant predetermined arc level as required for the desired decomposition of the hazardous material being processed. Arc voltage sensing equipment (not shown) rnay also be employed to compare the arc voltage with a preset reference for comparison and arc length control. A DC choke coil (not shown) may also be connected in series with the DC
arc current path in order to prevent arc extinction due to any sudden rise in arc vol~age, any sudden cooling of the arc due to endothermic chemical reactions, or to tr.ansient gas pressures which occur during PCB
decomposition.
The arc 72 provides the primary heat to initially melt and thereafter maintain the material within the sump in the molten state. The arc 72 also serves as a source o~ radiation, or example, ultraviolet radiation, which assists in bresking the bonds of the PCBs. In addition, the extreme high temperature of the arc (10,000C or higher) assures that the gases and any previously non-decomposed material passing through or S near the arc toward the exhaust means 78 ~re completely decomposed into the above-described generally innocuous gaseous elements.
In order to further insure that the gases from the chamber 18 obeain maximum exposure to the arc for complete decomposition, the furnace 10 also includes means, generally designated 84, for rapidly and uniformly moving the arc 72 in a predetermined path around the surface of the arcing tip 82 of the el~ctrode 68. The rapid rotation of the arc 72 around the arcing tip 82 also provides a more uniform distribution of heat to the molten bath 22 and processing in the chamber 18 which tends to preserve the inner lining 16. The rotating arc also puts pressure on the molten bath material where the arc hits the molten bath 22, this together with the high temperature of the arc causes the material to boil and form an indentation in molten bath material. The rotation of the arc around the arcing tip 82 may be so fast that the indentation may not be refilled, and high temperature boiling materiAl is spewed out in the vicini~y of the indentation. The gases passing proximate the arc are contacted by the heat and the super heated bath material to aid in decomposition.
In the present embodiment, the means for moving the arc around the surfsce of the arcing tip 82 of the tubular electrode 68 comprises magnetic me~ns in the form of an annular electromagnetic coil 86 positioned within the housing 12 beneath the arcing ~ip 82. The eleccroma~entic coil 86 is connected to a ~suit~ble DC
73i~
voltage source (not shown) to generate a ma~netic field having flux lines (not shown) extending generally perpendicular to the arc 72. In this manner, well-known magnetohydrodynamics principles are employed S to move the arc 72 around the surface of the arcing tip 82. The rate of movement of the arc around the arcing tip 82 is controlled by controlling the location of the electromagnetic coil 86 and the intensity and orientacion of the magnetic field generated by the coil 86. The magne~ic field also serves to stir the molten bath 22 to provide more complete mixing of the molten bath ma~erial and the hazardous materials which are being decomposed. In this manner, the upper su~face of t~e mol~en bath 22 is kept in condition to receive and react with newly introduced hazardous material.
As hazardous material and the various inorganic (metallic) containers ~ssociated therewith are added to the furnace 10, the level of the molten bath 22 tends to rise. In order to maintain the molten bath 22 at a p~edetermined depth commensurate with the size of the chamber, the length of the arc and other such factors, it is necessary to provide a means for removing some of the material from the molten bath 22 while still continuing the decomposition of the hazardous material.
In the present embodiment, the means for maintaining the molten bath at the desired prede~ermined depth comprises a generally cylindrical container 88 positioned beoeath the center of the furnace housing 12. ~n annular weir 90 is provided to establish the predetermined depth of the molten bath. Whenever the depth of the molten bath exceeds the height of the weir 90~ molten material flows over the weir 90, through a conduit rncans or drain pipe 92 and into the cylindrical ` ~Z1~738 ,9 container 88. The conduit means 92 and the cylindrical container 88 are provided with suitable sealing mesns (not shown) in order to maintain the chamber 18 in the gas-tight condition.
The cylindrical container 88 is removably attached to the furnace housing 12. In this manner, material flowing from the molten bath 22 over the weir 90 may be collected in the cylindrical container 88 until the cylindrical container is filled. The cylindrical container may then be removed from the furnace housing 12 and the material collected therein may be suitably emptied and/or disposed of in a conventional manner.
In order to ensure that the chamber 18 remains ga3-tight during the period of time when the cylindrical container 88 is removed for emptying, a suitable sealing apparatus 94 is provided to close off the conduit means g2. A suitable evacuation system (not shown) may also be provided to remove any gases which may have accumulated within the cylindrical co~tainer 88. The gases removed from the cylindrical container 88 are recycled back into the chamber 18. By first sealing off the conduit means 92 with the sealing apparatus 94 and then employing the evacuation system to remove gases accumulated in the cylindrical container 88, the container 88 may be removed for emptying without affecting the continued operation of the furnace 10. Once the empty contaîner is replaced, the sealing apparatus 94 is again opened and molten material may again flow through the conduit means 92 for collection in the container 88.
Alternatively, excess material may be removed from the molten bath 22 by means of a standard tap or drain (shown in phantom as 96). However, in order to utilize ~Z1~38 such a tap or drain 96, it is first preferable to halt the normal operation of the furnace 10. Material removed through ~he tap 94 may be suitably disposed of in any conventional manner.
As a variation of the above-described embodiment, the gases from the chamber 18 may be exhausted through the conduit means 92, into the cylindrical container 88 and out of an alternate exhaust conduit (shown in phantom as 81). In this manner, the gases may react with the material within the container 88 for further processing.
Referring now to Fig. 2, there is shown an apparatus or furnace 110 for the decomposition of h~zardous material which is substantially the same as the furnace 10 of Fig. 1. In connection with the description of Fig. 2, the same numbers will be used for the same components bu~ with the addition of 100 thereto. Viewing Fig. 2, it can be seen that the furnace 110 comprises a generally cylindrical housing 1~2 which defines a gas-tight, generally cylindrical ~hamber 118. Within the chamber 118 is a molten bath 122 of metal, salt or any other suitable conductive material. A generally tubular electrode 168 is similarly movably actached to the furnace cover 170.
As in the furnace shown in Fig. 1 J the center of the tubular electrode 168 comprises an exhaust means 178 which further includes an exhaust conduit 180 to permit che removal of gases from the chamber 118 to the outside of the furnace 110. The furnace 110 further includes suitable inlet means (not shown in Fig. 2) for introducing hazardous material into the chnmber 118 in che same manner as was shown and described in conneccion with Fig. 1.
73~
The primary difference between the furnace 10 of F~g. 1 and the furnace 110 of Fig. 2 is in the manner in which the excess material is removed from the molten bath. As shown on Fig. 2, a generally cylindrical container 188 is provided adjacent to one side of the furnace housing 112. The adjacent side wall of the furnace housing 112 includes an opening which forms a weir 190 to establish the depth level of the material within ~he molten bath 122. Any material rising above the level of the weir 190 flows through a conduit means 192 and into the container 188. The con~ainer 188 is remo~able from the conduit means 192 and both the container 188 and the condui~ means 192 are provided with suitable sealing means (not shown) to preserve the gas-tight integrity of the chamber 118. A suitable sealing apparatus 194 is provided to close off and seal the conduit means 192 when the container 188 has been removed for emptying. A suitable evacuation system 198 co~prising a sui~able pump 200 and a corresponding check valve 202 is provided to evacuate any gases which may accumulate in the container 188 prior to emptying the container. As shown, the gases removed from the container 188 are recycled back into the chamber 118 for further processing.
A further difference between the furnace 10 of Fig. 1 and the furnace 110 of Fig. 2 is in the loc~tion of the nnnular electromagnetic coil 186 which is employed to cause the rotation of the arc 172 around the arcing tip 182 of the tubul~r electrode 168. As shown, the electromagnetic coil 186 is located on the outside of the housing 112 beneath the electrode 168.
In order to insure that the housing ll2 does not interfere with the magnetic field generated by the . ~L2~738 external electromagnetic coil 186, the lower portion of ~he housing is comprised of non-magnetic material as shown. As in the embodiment of Fig. 1, the flux lines from the ma~netic field are perpendicular to the arc 172, thereby causirlg the arc to rotate around the surface of the arcing tip 182.
Fig. 3 shows a slight variation of the furnace of Fig~ 2, wherein the same numbers are used as appear in Fi~. 2 but with the addition of primes thereto. In Fig. 3, the conduit me~ns 192' for removing material from the molten bath 122' is positioned beneath the surface of the molten bath. The conduit 192' further includes a standard plumber's P-trap arrangement 104' to effectively prevent gases contained within the chamber 118' from entering the container 188'. A
sealing apparatus 144' is also provided to facilitate the emptying of the container 188' without any interruption of furnace operation.
Fig. 4 shows a different variation of the furnace of Fig. 2 in which a different means is provided for moving ehe arc 472 around the arcing electrode tip 482.
Referring to Fig. 4~ the same numbers are used as in Fig. 1 but with the addition of 400 thereto. In Fig.
4, instead of employing an electromagnetic coil, as was done in connection with the embodiment of Fig. 2, first generally cylindrical ferrous member 406 is positioned within the hollow interior of the tubular electrode 468 adjacent to the arcing tip 482.
Similarly, a tubular ferrous member 407 surrounds the tubular electrode 468 edjacent to ehe arcing eip 482.
Both of the ferrous members 406 and 407 may be cooled employing a suitable known cooling system (not shown) which uses a heat transfer fluid such as water (not -~ ~Z1~738 shown). The ferrous members 406 and 407 interact with the arc current to generate a magnetic field having flux lines (not shown) which extend generally perpendicular to the arc 472. In this manner, ~he arc S is made to rotate around the surface of the arcing tip 482 in the same manner as was discussed in detail in relation to the apparatus of Fig. 1.
~ eferring now to ~ig. S, there is shown a schematic representation of a pressure relief system ge~erally designated SOO which may be employed in connection with furnace 10 of the type described in Fig. 1 or any of the above-described alternative furnace embodiments. The pressure relief system comprises a sealed (gas-tight~ container or surge tank 502 located proximate to the furnace 10. A suitable first conduit means 504 extends between the furnace 10 and the sealed container 502 and provides communication between ~he interiors thereof. A pressure relief valve 506 is positioned within the first conduit means 504 to conerol and effectuate relief of the pressure within the furnace lO, if necessary. As described above, the furnace lO should be constructed to withstand an internal gas pressure of five atmosphere without leaking any gas therefrom. The pressure relief valve 506 should be designated to relieve the furnace pressure ~t a preset pressure point slightly less than the five atmosphere level.
Once the preset pressure point of the pressure relief valve 506 has been exceeded the excess gas from the furnace lO flows into the container 502 thereby lowering the pressure within the furnace. A second conduit means 508 and a suitable pump S10 are provided to return gas from the sealed contniner 502 to the ~2~1~38 furnace 10 for further processing when the pressure within the furnace has decreased to sn acceptable level.
From the foregoing description and the accompanying figures, it can be seen that the present invention provides a method and npparatus for the decomposition of PCBs and o~her hazardous material which is efficient, relatively easy to control and is very effective in operaeion. It will be recognized by those skilled in the art ~hat changes or modifications may be made to the above-described embodiments without departing from the broad inventive concepts of the invention. It is understood, therefore, that this invention is not limited to the particular embodiments described9 but it is intended to cover all changes and modifications which are within ehe scope and spirit of the invention as set forth in the appended claims.
Claims (8)
IS CLAIMED ARE DEFINED AS FOLLOWS:
1. An apparatus for the decomposition of hazardous material utilizing a DC arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the exit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the edit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a multi-sealed passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, the passage further including closable partition means between the entry port and the exit port for dividing the passage into a first compartment adjacent the entry port and a second compartment adjacent the exit port, the sealed passage operating such that hazardous material is introduced into the first compartment with the partition means closed, the hazardous material passing from the first compartment into the second compartment through the partition means with the entry port and the edit port closed, and the hazardous material passing from the second compartment into the chamber through the exit port with the partition means closed;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material; and exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
2. The apparatus as recited in claim 1 including means within the second compartment for puncturing containers with hazardous material therein to release hazardous material therefrom.
3. The apparatus as recited in claim 2 including conduit means communicating between the second compartment and the chamber for removing liquid hazardous material from the second compartment and introducing the liquid hazardous material into the chamber at a controlled rate.
4. The apparatus of claim 3 wherein the conduit means further includes valve means for controlling the flow of liquid hazardous material from the second compartment to the chamber.
5. The apparatus as recited in claim 1 further including screw conveyor means for moving hazardous material from the second compartment into the chamber.
6. An apparatus for the decomposition of hazardous material utilizing a DC arc, comprising:
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a sealable passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, and puncturing means within the passage for puncturing containers with hazardous material therein;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material;
exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
a gas-tight chamber including a sump which contains a molten bath;
inlet means for introducing the hazardous material into the chamber and the molten bath for initial decomposition of the hazardous material into a product within the molten bath and a gaseous product within the chamber, wherein the inlet means comprises a sealable passage having a closable entry port for access outside the chamber and a closable exit port providing communication inside the chamber, and puncturing means within the passage for puncturing containers with hazardous material therein;
electrode means for maintaining a DC arc within the chamber, the arc having a current level sufficient to promote the decomposition of the hazardous material;
exhaust means within the chamber proximate to the DC arc for the removal of gases from the chamber, whereby the gaseous product passes in the proximity of the arc for undergoing decomposition prior to removal thereof through the exhaust means.
7. The apparatus as recited in claim 6 including conduit means communicating between the sealable passage and the chamber for removing liquid hazardous material from the passage and introducing the liquid hazardous material into the chamber wherein said conduit means includes valve means for controlling and restricting the flow of liquid hazardous material from the passage into the chamber.
8. The apparatus as recited in claim 6 comprising screw conveyor means disposed within said passage for moving hazardous material through said passage into the chamber.
27.
27.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000485768A CA1211738A (en) | 1982-06-03 | 1985-06-27 | Method and apparatus for the decomposition of hazardous materials and the like |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/384,613 US4431612A (en) | 1982-06-03 | 1982-06-03 | Apparatus for the decomposition of hazardous materials and the like |
| US384,613 | 1982-06-03 | ||
| CA000429593A CA1209092A (en) | 1982-06-03 | 1983-06-02 | Method and apparatus for the decomposition of hazardous materials and the like |
| CA000485768A CA1211738A (en) | 1982-06-03 | 1985-06-27 | Method and apparatus for the decomposition of hazardous materials and the like |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000429593A Division CA1209092A (en) | 1982-06-03 | 1983-06-02 | Method and apparatus for the decomposition of hazardous materials and the like |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1211738A true CA1211738A (en) | 1986-09-23 |
Family
ID=25670050
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000485767A Expired CA1212355A (en) | 1982-06-03 | 1985-06-27 | Method and apparatus for the decomposition of hazardous materials and the like |
| CA000485768A Expired CA1211738A (en) | 1982-06-03 | 1985-06-27 | Method and apparatus for the decomposition of hazardous materials and the like |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000485767A Expired CA1212355A (en) | 1982-06-03 | 1985-06-27 | Method and apparatus for the decomposition of hazardous materials and the like |
Country Status (1)
| Country | Link |
|---|---|
| CA (2) | CA1212355A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114642096A (en) * | 2022-03-24 | 2022-06-21 | 生态环境部南京环境科学研究所 | Device and method for improving soil quality through closed straw burning |
-
1985
- 1985-06-27 CA CA000485767A patent/CA1212355A/en not_active Expired
- 1985-06-27 CA CA000485768A patent/CA1211738A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114642096A (en) * | 2022-03-24 | 2022-06-21 | 生态环境部南京环境科学研究所 | Device and method for improving soil quality through closed straw burning |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1212355A (en) | 1986-10-07 |
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