CA1162726A - Prevention of corrosion in aqueous systems - Google Patents

Prevention of corrosion in aqueous systems

Info

Publication number: CA1162726A
Authority: CA; Canada
Prior art keywords: phosphonate; triazole; acid; zinc salt; corrosion
Prior art date: 1981-03-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000387564A

Other languages

English (en)

French (fr)

Inventor

Stuart W. Longworth

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Suez WTS USA Inc

Original Assignee

Dearborn Chemicals Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-03-11

Filing date

1981-10-08

Publication date

1984-02-28

1981-10-08 Application filed by Dearborn Chemicals Ltd filed Critical Dearborn Chemicals Ltd

1984-02-28 Application granted granted Critical

1984-02-28 Publication of CA1162726A publication Critical patent/CA1162726A/en

Status Expired legal-status Critical Current

Links

238000005260 corrosion Methods 0.000 title claims abstract description 16
230000007797 corrosion Effects 0.000 title claims abstract description 16
230000002265 prevention Effects 0.000 title abstract description 4
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 22
150000003751 zinc Chemical class 0.000 claims description 16
229920000642 polymer Polymers 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 13
-1 ferrous metals Chemical class 0.000 claims description 12
238000000034 method Methods 0.000 claims description 11
150000003852 triazoles Chemical class 0.000 claims description 10
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical group [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical group OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 6
229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 6
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
150000003839 salts Chemical class 0.000 claims description 5
MVRGLMCHDCMPKD-UHFFFAOYSA-N 3-amino-1h-1,2,4-triazole-5-carboxylic acid Chemical compound NC1=NNC(C(O)=O)=N1 MVRGLMCHDCMPKD-UHFFFAOYSA-N 0.000 claims description 4
229920002125 Sokalan® Polymers 0.000 claims description 4
239000011592 zinc chloride Substances 0.000 claims description 4
235000005074 zinc chloride Nutrition 0.000 claims description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
229910002651 NO3 Inorganic materials 0.000 claims description 3
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
229910021653 sulphate ion Inorganic materials 0.000 claims description 3
230000002401 inhibitory effect Effects 0.000 abstract description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
229910052739 hydrogen Inorganic materials 0.000 description 10
239000001257 hydrogen Substances 0.000 description 10
125000000217 alkyl group Chemical group 0.000 description 7
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
239000011701 zinc Substances 0.000 description 4
229910001209 Low-carbon steel Inorganic materials 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
239000012964 benzotriazole Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
150000002431 hydrogen Chemical group 0.000 description 3
229920005610 lignin Polymers 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
239000010959 steel Substances 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
FMCUPJKTGNBGEC-UHFFFAOYSA-N 1,2,4-triazol-4-amine Chemical compound NN1C=NN=C1 FMCUPJKTGNBGEC-UHFFFAOYSA-N 0.000 description 1
RZMGZEJEAAVXRG-UHFFFAOYSA-N 1,2-dihydrotriazole-3-carboxylic acid Chemical compound N1NN(C=C1)C(=O)O RZMGZEJEAAVXRG-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
101001133936 Homo sapiens Prolyl 3-hydroxylase 2 Proteins 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
MISDVWGQNGVTPP-UHFFFAOYSA-N N1N=NC=C1.P(O)(O)=O Chemical compound N1N=NC=C1.P(O)(O)=O MISDVWGQNGVTPP-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
102100034015 Prolyl 3-hydroxylase 2 Human genes 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
YVPJCJLMRRTDMQ-UHFFFAOYSA-N ethyl diazoacetate Chemical compound CCOC(=O)C=[N+]=[N-] YVPJCJLMRRTDMQ-UHFFFAOYSA-N 0.000 description 1
238000009472 formulation Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical class C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
230000005764 inhibitory process Effects 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000009533 lab test Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
BDTOTMBOHYUNSQ-UHFFFAOYSA-N triazole-1-carboxylic acid Chemical compound OC(=O)N1C=CN=N1 BDTOTMBOHYUNSQ-UHFFFAOYSA-N 0.000 description 1
238000013022 venting Methods 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Preventing Corrosion Or Incrustation Of Metals (AREA)

CA000387564A 1981-03-11 1981-10-08 Prevention of corrosion in aqueous systems Expired CA1162726A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB81.07611		1981-03-11
GB8107611A GB2094776B (en)	1981-03-11	1981-03-11	Prevention of corrosion in aqueous systems

Publications (1)

Publication Number	Publication Date
CA1162726A true CA1162726A (en)	1984-02-28

Family

ID=10520306

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000387564A Expired CA1162726A (en)	1981-03-11	1981-10-08	Prevention of corrosion in aqueous systems

Country Status (8)

Country	Link
JP (1)	JPS57161072A (de)
CA (1)	CA1162726A (de)
DE (1)	DE3208119A1 (de)
ES (1)	ES8302795A1 (de)
FR (1)	FR2501709A1 (de)
GB (1)	GB2094776B (de)
IT (1)	IT1150645B (de)
SE (1)	SE8201509L (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3341152A1 (de) *	1983-11-14	1985-05-23	Henkel KGaA, 4000 Düsseldorf	Korrosionsinhibitoren fuer aluminium
DE3519522A1 (de) *	1985-05-31	1986-12-04	Henkel KGaA, 4000 Düsseldorf	Verwendung von 3-amino-5((omega)-hydroxyalkyl)-1,2,4-triazolen als korrosionsinhibitoren fuer buntmetalle in waessrigen systemen
DE3620025A1 (de) *	1986-06-13	1987-12-17	Henkel Kgaa	Verwendung von acylierten 3-amino-1,2,4-triazolen als korrosionsinhibitoren fuer buntmetalle
US5338347A (en) *	1992-09-11	1994-08-16	The Lubrizol Corporation	Corrosion inhibition composition
GB2331999B (en) *	1997-10-28	2003-01-22	Ibm	Copper preservative treatment

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1222133A (en) *	1968-05-25	1971-02-10	Geigy Uk Ltd	Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole
JPS4862634A (de) *	1971-12-04	1973-09-01
US3794603A (en) *	1972-01-17	1974-02-26	Sherwin Williams Co	Zn++-benzotriazole-h2so4 corrosioninhibitor
US3985503A (en) *	1975-03-17	1976-10-12	The Sherwin-Williams Company	Process for inhibiting metal corrosion
DE2934461A1 (de) *	1979-08-25	1981-03-26	Henkel KGaA, 40589 Düsseldorf	Korrosionsinhibitoren fuer buntmetalle

1981
- 1981-03-11 GB GB8107611A patent/GB2094776B/en not_active Expired
- 1981-10-08 CA CA000387564A patent/CA1162726A/en not_active Expired
1982
- 1982-03-06 DE DE19823208119 patent/DE3208119A1/de not_active Withdrawn
- 1982-03-09 ES ES510242A patent/ES8302795A1/es not_active Expired
- 1982-03-09 IT IT20056/82A patent/IT1150645B/it active
- 1982-03-10 FR FR8204049A patent/FR2501709A1/fr not_active Withdrawn
- 1982-03-10 JP JP57036718A patent/JPS57161072A/ja active Pending
- 1982-03-10 SE SE8201509A patent/SE8201509L/ not_active Application Discontinuation

Also Published As

Publication number	Publication date
FR2501709A1 (fr)	1982-09-17
ES510242A0 (es)	1983-01-16
SE8201509L (sv)	1982-09-12
ES8302795A1 (es)	1983-01-16
GB2094776B (en)	1984-05-16
DE3208119A1 (de)	1982-11-11
JPS57161072A (en)	1982-10-04
GB2094776A (en)	1982-09-22
IT8220056A0 (it)	1982-03-09
IT1150645B (it)	1986-12-17

Legal Events

Date	Code	Title	Description
2001-02-28	MKEX	Expiry

Publication	Publication Date	Title
US3935125A (en)	1976-01-27	Method and composition for inhibiting corrosion in aqueous systems
US3960576A (en)	1976-06-01	Silicate-based corrosion inhibitor
CA1205715A (en)	1986-06-10	Systems inhibited against corrosion and/or scale deposition
EP0544345B1 (de)	1996-08-14	Verhinderung von Korrosion und Ablagerungen
US4497713A (en)	1985-02-05	Method of inhibiting corrosion and deposition in aqueous systems
US5256332A (en)	1993-10-26	Method of inhibiting corrosion in aqueous systems
US4351796A (en)	1982-09-28	Method for scale control
US4557896A (en)	1985-12-10	Treatment of aqueous systems
US4317744A (en)	1982-03-02	Corrosion inhibitor
US4033896A (en)	1977-07-05	Method of corrosion inhibition and compositions therefor
KR20010101740A (ko)	2001-11-14	스케일 및(또는) 부식 억제 조성물
US4297237A (en)	1981-10-27	Polyphosphate and polymaleic anhydride combination for treating corrosion
EP1208248B1 (de)	2005-05-25	Verfahren zur korrsosionsinhibierung geeignet zur verwendung in trinkwasser
US4664884A (en)	1987-05-12	Corrosion inhibitor
EP0396243A1 (de)	1990-11-07	Korrosioninhibierung in wässrigen Systemen
AU597467B2 (en)	1990-05-31	Inhibiting corrosion of iron base metals
CA1162726A (en)	1984-02-28	Prevention of corrosion in aqueous systems
EP0538969A2 (de)	1993-04-28	Zusammensetzung und Verfahren zur Kesselstein- und Korrosionsinhibierung, unter Verwendung von Naphtylaminpolykarbonsäuren
CA1211624A (en)	1986-09-23	Treatment of aqueous systems
US4778655A (en)	1988-10-18	Treatment of aqueous systems
EP0225051B1 (de)	1992-02-19	Behandlung von wässrigen Systemen
US4401587A (en)	1983-08-30	Aminomethylphosphonic acid and polymaleic anhydride combinations for treating corrosion
CA2073660C (en)	2003-05-06	Substituted carboxymethoxysuccinic acid corrosion inhibitors
US4806310A (en)	1989-02-21	Corrosion inhibitor
KR100310168B1 (ko)	2001-12-17	부식및스케일형성을억제하기위한수처리제조성물및그를이용한수처리방법