CA1129331A - Gas recovery - Google Patents

Gas recovery

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Publication number
CA1129331A
CA1129331A CA334,031A CA334031A CA1129331A CA 1129331 A CA1129331 A CA 1129331A CA 334031 A CA334031 A CA 334031A CA 1129331 A CA1129331 A CA 1129331A
Authority
CA
Canada
Prior art keywords
gas
vessel
receiving vessel
sulphur hexafluoride
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA334,031A
Other languages
French (fr)
Inventor
Anthony D. Stokes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Sydney
Original Assignee
University of Sydney
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Sydney filed Critical University of Sydney
Priority to CA334,031A priority Critical patent/CA1129331A/en
Application granted granted Critical
Publication of CA1129331A publication Critical patent/CA1129331A/en
Expired legal-status Critical Current

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Abstract

ABSTRACT

A gas recovery method and apparatus for the recovery and storage of a gas from a gas enclosure or circuit particularly for the recovery of sulphur hexafluoride (SF6) from the arc chamber of a high voltage/current circuit breaker. A gas bottle is connected via quick connect coupling and a non-return valve to the gas circuit or en-closure. The gas bottle is immersed in a liquid nitrogen environment in a Dewar flask thereby generating a self pumping action as the sulphur hexafluoride liquifies (or solidifies) within the gas bottle due to the temperature of the liquid nitrogen (-196°C) being well below the phase change temperature of the sulphur hexafluoride over the range of encountered vapour pressures. When the gas has been recovered, it is stored in the gas bottle which is returned to ambient temperature by removal from the liquid nitrogen and/or by immersion in a heated bath. The gas bottle is reconnected to the gas circuit when recharging of the circuit with the recovered SF6 is required.

Description

3~

~3ACKGROUND OF T~[E INVENTION
This invention relates to gas recovery and is more specifically concerned with th~ recovery of gases from en-closures containing equipment which has to operate in a gas-eous environment other than air.
There are many areas of technology in which fairly large equipment is required to operate in an atmosphere of a particular gas. One such area is the electrical supply industry where, for example, electric circuit breakers are ~-often required to operate in an atmosphere of sulphur hexafluoride (SF6)gas.
Sulphur hexafluoride gas is relatively expensive and it is normally recovered and stored if equipment which normally works in the gas is to be serviced or repaired. As the equipment may be sited in remote areas, a portable assembly is used to recover the gas and to recharge the equipment with the gas after the equipment has been serviced or repaired. Such assembly comprises a large pump and a storage vessel normally mounted on a vehicle. The amount of gas to be recovered may be 200kg or more, and, as it is normally at pressures between 4 and perhaps 20 atmospheres in the enclosure, the pump used must have a high capacity and the assembly is therefore a cumbersome and expensive piece of equipment, which is used only intermittently.
SUMM~RY OF TEIE INVENTION
The present invention seeks to amend the need for high capacity pumps by providing a gas recovery apparatus comprising at least one vessel connectable to an enclosure or circuit from which a gas is to be recovered and means for holding the vessel at a temperature below that at which the gas is transformed from its vapour phase to a liquid or solid phase.
The apparatus of the invention has the advantage that the use of a high pressure pump is avoided altogether and the gas storage vessels are reduced in size, perhaps four-fold. The conversion of the recovered gas to its liquid 3~

phase produces a drop in pressure which induces its OWII
pumping action so that the gas can be rapidly withdrawn from the enclosure or circuit by way of a coupling and, when cold, stored at a pressure at or beneath atmospheric pressure.
The cooling arrangement conveniently comprises a bath of liquid nitrogen. The vessel may take the form of a stainless steel or aluminium cylinder mounted in the bath.
Liquid nitrogen has the advantage that air is not liquified when contained in vessels at temperatures just above the boiling point of the liquid nitrogen. The recovered gas may therefore be separated from air which may have con-taminated it through leakage, by applying a vacuum pump to the vessel after the gas has been solidified in the vessel.
The invention is particularly well-suited to recovering ; sulphur hexafluoride from electrical circuit hreakers and other such equipment. Sulphur hexafluoride is solid at the temperature of liquid nitrogen (-196C) and liquid nitrogen is readily available as a cheap safe, refrigerant. The apparatus can be stored at a maintenance depot for servicing a number of circuit breakers and temporarily transported any breaker which requires servicing.
According to the invention there is provided a gas recovery apparatus comprising at least one vessel connectable to an enclosure or circuit from which a gas is to be recovered such that the gas is enabled to flow from the enclosure or circuit into the vessel and means for holding the vessel at a temperature below that at which the gas is transformed ~; from its vapour phase to its liquid phase or to its solid phase thereby storing the gas in the vessel.
According to the invention there is further provided a method of recovering gas from an enclosure or circuit, the method comprising connecting to the closure or circuit a gas receiving vessel which is held at a temperature below that at which the gas is transformed from its vapour phase to its liquid phase or to its solid phase and storing the gas in the receiving vessel.

_ ~3 _ BRIEF DESCRIPTION OF THE DRAWINGS
The invention will now be described in more detail in a preferred embodiment, by way of example, with reference to the accompanying drawings, in which:-FIGURE 1 is a graph showing the vapour pressure ofsulphur hexafluoride as a function of its temperature.
FIGURE 2 is a schematic circuit diagram of apparatus for recovering sulphur hexafluoride from a circuit breaker, the diagram showing also the sulphur hexafluoride gas circuit for the breaker, and FIGURE 3 is a code chart which identifies the legends employed in Figure 2.
DESCRIPTION OF THE PREFERRED EMBODIMENT
As is shown in the curve of Figure 1, between a critical point 5 and a point 6, sulphur hexafluoride is either at a liquid phase or a gaseous phase dependent on its temperature and pressure. Between the points 6 and 7 sulphur he~afluoride exists either in its gaseous phase or its solid phase in accordance with the temperature and pressure. Point 8 on the curve of Figure 1 shows that at temperatures beneath -60C the sulphur hexafluoride exists in its solid state at atmospheric pressure.
It will be seen from the curve that at a temperature of -196C, which is the temperature of liquid nitrogen, sulphur hexafluoride exists in a solid phase unless its pressure is reduced below about 10 2-5 Torr. Bearing in mind that one Torr is equal to 1/760th of an atmosphere, this is almost a pure vacuum condition. As with most gases, the conversion of sulphur hexafluor~de from its gaseous to its solid phase is accompanied by a very great reduction in volume, exceeding 100:1 at one atmosphere pressure.
Referring now to the apparatus as shown schematically in Figure 2 and having the elements identified by the legends encoded in Figure 3:
Figure 2 shows, within the broken line 10 equipment associated with a gas-filled circuit breaker using sulphur 3~

hexafluoride gas. This equipment comprises an arc chamber 11 from which sulphur hexafluoride gas travels through a fast opening valve 12 to a dump tank 13. Typically, the gas is at a pressure of four atmospheres and the arc chamber and its surrounding enclosure together contain about 8 litres of gas, although this vaxies with design. Gas from the dump tank is cleaned by passage through filters 14 before being recycled back to the arc chamber with additional gas provided for topping-up purposes from a gas bot-tle 15.
The equipment also includes manual valves, one-way valves, meters, regulators and additional filters, as identified by the legend encoding of Figure 3. These elements form a normal part of most fluid circuits and are not therefore detailed herein.
The apparatus for recovering sulphur hexafluoride from the circuit shown in Figure 2 is contained within the broken outline 20. It comprises a dewar flask 21 containing a stainless steel vessel 22 connected by a valve 23 and a quick-connector coupling 24 to the gas circuit of the equipment and apparatus 10. The vessel 22 is carried at one end of a yoke 25 which carries at its other end a second similar vessel 26 also connected by a valve 27 and a quick-release coupling 28 to the gas circuit of the breaker. The yoke 25 can be raised and lowered by a double-acting piston 30 operating in a cylinder 31 in which the piston can rotate when raised.
The vessel 26 is partially immersed in a heated water tank 33 which contains a further vessel 34 containing sulphur hexafluoride and connected through a valve 35 which can be opened to provide a rapid pressure build up of sulphur hexafluoride gas to the circuit breaker enclosure as it by-passes the regulators which control the gas flow into the circuit from the vessel 26.
A pressure switch 40 and associated ~-part, 3-position ; hand operated valve controlling a compressed air supply is 3~

`used to provide compressed air as the working f1uid to the cylinder 31.
A large dewar flask of liquid nitrogen (not illustrated) may also be provided as a liquid nitrogen reservoir.
When the sulphur hexafluoride gas is to be recovered from the circuit breaker enclosure the vessel 22 is connected to the gas circuit by means of the quick connector couplings and operation of the non-return valve. The sulphur hexa-fluoride gas from the gas circuit of the breaker flows quickly into the stainless steel vessel 22 where it liquifies and quickly solidifies. A pumping rate of approximately 400 grms per square meter of cooled cylinder area is maintained provided the connecting pipe-work can deliver this quantity of gas. The gas in the circuit is rapidly converted into liquid and then ~lid sulphur hexafluoride in the cooled vessel 22. It is important that the neck of the vessel is not held at temperatures at which it could be choked by SF6 snow formation as it enters the vessel 22. Also the SF6 should preferably pass from a gaseous phase to a liquid phase in the vessel 22, before solidifying, so that it collects in the base of the vessel 22 and leaves the vessel walls free of any insulation caused by solid SF6 build up.
The pressure within the vessel falls to very low values and the consumption of nitrogen is approximately one litre per kg of sulphur hexafluoride gas recovered. Air which may have seeped into the gas circuit is not liquified at the temperature of liquid nitrogen, and can be evacuated by a vacuum pump normally provided but not shown.
When the sulphur hexafluoride has been recovered, valve 23 is closed and the circuit breaker enclosure can ~hen be opened up for maintenance or other work to be carried out.
When necessary work has been completed, the enclosure is evacuated by means of the vacuum pump 50 provided and the system is recharged with sulphur hexafluoride gas. This gas may be obtained by raising, turning and then lowering 3~

^the yoke 25 so that the vessel 22 is located in the heated bath 33 in the position previously occupied by vessel 26.
Vessel 22 thus becomes vessel 26, as shown in Figure 2, and as such it is heated to cause the previously recovered sulphur hexafluoride to be discharged into the gas circuit enclosed by the dotted line lO. Vessel 34 also may be used to recharge the gas circuit quickly, if required, as its connections by-pass the regulators.
The vessel 22 and 26 can be positionally interchanged after raising the piston, by rotating the yoke, as above described. Alternatively cylinder 22 can be used alone if heated by electric heaters when it is required to recharge the equipment with the previous recovered gas.
In such case the apparatus would comprise a single liquid nitrogen flask 21 containing an electrical heater and the vessel 22. Connections would allow the liquid nitrogen to be fed between the flask and a reservoir of liquid nitrogen. Control circuitry would enable the vessel 22 to be cooled when sulphur hexafluoride was to be recovered and heated when it was to be fed back into a breaker con-nected temporarily to the apparatus. The apparatus could be portably mounted.
From the above description it will be appreciated that the gas recovery apparatus of the invention is cheap to make, has low running costs, is very much more compact than currently available gas recovery apparatus, and is perhaps one quarter of the size. secause there are few moving parts, there is also a lesser risk of damage. Although care has to be taken when handling liquid nitrogen, it is a cheap commodity and requires no special precautions to be taken other than those associated with low temperature liquids and which are fairly well known at this time.
Although the invention has been above described in the context of removing hexafluoride gas from an electric circuit breaker, it is to be understood that this is only one ~2~3~

application of the invention and that it has broader sig-nificance. Thus, the invention may be applied to the recovery of any gas from any device, using the concept of holding the vessel which is used in recovery of the gas at a temperature beneath that at which the recovered gas is transformed from its vapour phase to a liquid or solid phase.
It has been found that the apparatus for carrying out the invention may be even more economically provided by using aluminium vessels instead of stainless steel vessels.
Aluminium vessels are commercially available and are cheaper than stainless steel vessels. Additionally, if the invention is being applied to the recovery of sulphur hexafluoride gas from a high voltage circuit breaker and the servicing time on the breaker is likely to be extensive, the liquid or solid phase gas stored in the vessel may be allowed to slowly return to room or ambient tempexature without the aid of the aforementioned heating bath. Under such cir-cumstances the natural heat transfer from the ambient ; to the liquified or solidified gas may be sufficient over the seryice time to bring the stored gas back to the ambient temperature and hence at appropriate pressure for that temperature.

Claims (15)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows.
1. A gas recovery apparatus for recovering sulphur hexafluoride gas from the switching chamber of a high volt-age circuit breaker, comprising, a first high pressure gas supply line interconnect-ing the switching chamber with a quick-connect gas coupling, a gas storage facility including at least one storage vessel having a closure valve connectable to the quick-connect gas coupling, cryogenic means to reduce the temperature of the gas storage facility below the phase transition temperatures of the sulphur hexafluoride gas in the range of pressures from the switching chamber pressure of the gas to substantially pure vacuum pressure under cryopumping conditions set up upon opening of the closure valve, said cryogenic means including a dewar flask containing liquid nitrogen at atmos-pheric pressure, means to ensure that said closure valve and the gas storage vessel inlet are both maintained at another tempera-ture above said phase transition temperatures, a heating station for heating the stored gas in the gas storage facility, means to effect recharging of the switching chamber with stored gas from the heated storage facility in the heating station via a second high pressure line, and means to interchange the gas storage facility between the cryogenic means and the heating station, said interchange means including a carrier for supporting a gas storage vessel and means actuable to lift the carrier there-by to raise the vessel from the cryogenic means or the heat-ing station and to generate movement of the carrier thereby to effect the interchange.
2. Gas recovery apparatus, as claimed in Claim 1, wherein the carrier is a yoke and there is provided a gas storage vessel at the opposite side of the yoke such that when one vessel is in the dewar flask the other is in the heat-ing station.
3. A gas recovery apparatus, as claimed in Claim 1, wherein the heating station comprises a heatable water bath into which the said interchange of the gas storage vessel or vessels may be effected, thereby to set up a rapid heat exchange relationship between the stored phase-changed gas and the water bath via the respective gas storage vessels to return the gas at least to ambient temp-erature.
4. A gas recovery apparatus, as claimed in Claim 1, wherein the heating station comprises an atmospheric ambient storage area in which the said inter-change of the gas storage vessel or vessels may be effected thereby to set up a slow heat exchange relationship between the store phase-changed gas and the atmospheric ambience via the respective gas storage vessel or vessels to return the gas to ambient temperature.
5. A gas recovery apparatus, as claimed in claim 1, wherein the vessel or vessels is or are constructed substan-tially of aluminium.
6. A gas recovery apparatus, as claimed in Claim 1, wherein contaminating gases which have not undergone a phase change from their gaseous state are removed from the gas storage vessel or vessels by vacuum pump means.
7. A gas recovery apparatus, as claimed in Claim 1, wherein the second gas supply line includes at least one regulator valve and wherein a further vessel containing gaseous sulphur hexafluoride to be delivered to the chamber is provided, said further vessel being connectable to the chamber in such a way as to by-pass the regular valve.
8. A gas recovery apparatus, as claimed in Claim 1, wherein the vessel or vessels is or are constructed substan-tially of aluminium or of a stainless steel.
9. A method of recovering gas from an enclosure or circuit, the method comprising connecting to the closure or circuit a gas receiving vessel which is held at a temperature below that at which the gas is transformed from its vapour phase to its liquid phase or to its solid phase and storing the gas in the receiving vessel.
10. A method of alternatively evacuating and replacing sulphur hexafluoride gas from and to the switching chamber of a high voltage circuit breaker comprising, cryogenically reducing the temperature of a receiving vessel below the phase transition temperature of sulphur hexafluoride gas, fluidly connecting the receiving vessel to the switching chamber so that the sulphur hexafluoride gas flows quickly into the receiving vessel where it liquifies and solidifies, closing off the receiving vessel from the switch-ing chamber to contain the sulphur hexafluoride within the receiving chamber, fluidly reconnecting the receiving vessel to the switching chamber, heating the receiving vessel to cause the sulphur hexafluoride to vaporize the flow into the switching chamber, and disconnecting the receiving vessel from the switch-ing chamber.
11. The method of claim 10, further comprising the step of, evacuating unliquified air from the receiving vessel subsequent to closing off the receiving vessel from the switching chamber.
12. The method of claim 10, wherein, cryogenically reducing the temperature of a receiving vessel comprises surrounding the receiving vessel with liquid nitrogen at atmospheric temperature.
13. The method of claim 12, wherein heating the recei-ving vessel comprises removing the receiving vessel from the liquid nitrogen and placing the receiving vessel into a heated bath.
14. The method of claim 10, wherein heating the receiving vessel comprises maintaining the receiving vessel in an atmospheric ambient storage area to produce a heat exchange relationship between the receiving vessel and the atmospheric ambient to return the sulphur hexafluoride to ambient temperature.
15. The method of claim 10, wherein heating the receiving vessel comprises electrically heating the receiv-ing vessel.
CA334,031A 1979-08-17 1979-08-17 Gas recovery Expired CA1129331A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA334,031A CA1129331A (en) 1979-08-17 1979-08-17 Gas recovery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA334,031A CA1129331A (en) 1979-08-17 1979-08-17 Gas recovery

Publications (1)

Publication Number Publication Date
CA1129331A true CA1129331A (en) 1982-08-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA334,031A Expired CA1129331A (en) 1979-08-17 1979-08-17 Gas recovery

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109516441A (en) * 2018-11-06 2019-03-26 国网浙江省电力有限公司检修分公司 A kind of recycling of sulfur hexafluoride, low temperature fluid injection bulking system and its working method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109516441A (en) * 2018-11-06 2019-03-26 国网浙江省电力有限公司检修分公司 A kind of recycling of sulfur hexafluoride, low temperature fluid injection bulking system and its working method
CN109516441B (en) * 2018-11-06 2024-05-10 国网浙江省电力有限公司检修分公司 Sulfur hexafluoride recovery and low-temperature liquid injection filling system and working method thereof

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