CA1117266A

CA1117266A - In-the-mold coating method

Info

Publication number: CA1117266A
Application number: CA000331938A
Authority: CA
Inventors: Sigurdur I. Arnason; Edward J. Kleese
Original assignee: General Tire and Rubber Co
Current assignee: Aerojet Rocketdyne Holdings Inc
Priority date: 1978-12-29
Filing date: 1979-07-17
Publication date: 1982-02-02
Also published as: FR2445208A1; ES485217A1; DE2933244C2; IT7924933A0; MX154089A; DE2933244A1; IT1122435B; AU4954979A; FR2445208B1

Abstract

ABSTRACT OF THE DISCLOSURE
A method and apparatus for forming a thermoset in-the-mold coating on a hot, cured glass fiber reinforced thermoset resin substrate by (1) separating the mold halves slightly while maintaining a seal with the shear edge, (2) injecting an in-the-mold coating resin in a stream which flows parallel from the injector onto a surface of the substrate, and (3) closing the mold and curing the coating under pressure. The separation of the mold halves is performed by the conventional mold ram.
Preferably the mold surface forming the coated surface of the substrate is roughened.

Description

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In-the-Mbld Coatin~ Method This invention relates to a method of forming an in-the-mold thermoset coating.
In-the-mold coating processes involve, first molding a base portion of the article in the cavity of a pair of relatively movable die members of a die molding set. The b æ e portion of the article is allowed to cure aEter which a skin forming coating material is injected onto the surface to be improved. Pressure is applied onto the die members so as to distribute the skin forming coating material substantially uniformly across the surface of the base portion and thereby substantially fill the porosity and any shrink portions on the surface. Ihe prior art is best set forth in U.S. Patents 4,076,780; 4,076,788 and 4,082,426, all assigned to General Motors and an article entitled, "The Mechanics for Molded Coating for Compression Molded Reinforced Plastic Parts" by Robert Ongena, 33rd Annual Technical Conference, 1978, Reinforced Plastics/Composites Institute, m e Society of the Plastics Industry, Inc., Section 14B, pages 1-7, and Modern Plastics, June 1976, pa~es 54-56 by William Todd.
The apparatus disclosed in the prior art consists of a pair of relatively movable die members, one of which is , . ~ . ~ . -~ :

movable towards the other through a hydraulic ram. When the die members are closed, a cavity is formed therebetween for molding an article in a desired configuration. Ohe of the die members is characterized in that a chamber is formed therein which communicates with the cavity and is adapted to receive a metered amount of liquid coating material in the form of a thermosetting resin which is subsequently used for coating one surface of the -molded article. The chamber is provided with a slidable piston or plunger which is movable through an appropriate actuator so as to displace the liquid coating material from the chamber into the cavity and onto one surface of the molded article without requiring the die members to be opened. The coating material is applied to the chamber by an injector device which has a bo~y portion, one end of which is formed with a nozzle that is located adjacent to the chamber. The nozzle is selectively movable into and out of sealing engagement with an inlet port formed in the associated die members and comm micating with the cham~er. When the base portion oE the article is first being molded in the cavity, the piston in the chamber is flush with the mold cavity and so positioned that both the chamber and the inlet port are closed from communication with the cavity. After the base portion of the article is hardened sufficiently to retain its shape, the piston is moved by the actuator to a second position exposing a predetermined volume of the chamber to the cavity.
Simultaneously, the injector device is moved into the inlet port and the liquid coating material is supplied to the chamber with ;
the hydraulic pressure on the ram being reliçved. With the nozzle of the injector positioned in the inlet port, the piston is moved by the actuator towards the cavity so as to force the coating material under pressure onto the surface to be coated.
The press ram is again actuated to cause the die members to move t~ard each other and apply pressure to the coating material and the pressure and . ~.

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temperature is maintained for a time sufficient for the coating material to set up sufficiently to allow opening of the die members and ejection of the coated molded article.
The prior art mold dies are maintained in a parallel configuration by hydraulic cylinders mounted on the bottom press plates pushing upward against the upper plate. The cylinders also part the dies for injection. A fifteen hundred ton ram forces the upper plates downward resulting in two hydraulics operating against each other. The apparatus of the prior art, through a significant advance in the art, is extremely complex involving a toggled nozzle which comes into contact with the mold, fills a reservoir then retracts, then th0 contents of the reservoir are injected into the mold.
The present invention eliminates the need for the toggle mechanism, the reservoir, the reservoir fluid ejector system and the prior art hydraulic leveling system.
Accordingly, the invention provides a method of forming a thermoset coating on a hot, cured glass fiber reinforced thermo-set resin substrate in a hot mold which is opened and closed by a ram controlled by a timer by:
- (a) placing an uncured resin containing glass fibers into the hot mold, the mold formed by the two dies having a shear edge;
~b) closing the mold to form and cure the resin containing the glass fibers, using the mold timer to control the cure time;
~c) separating one of the dies from the cured resin containing the glass fibers while still maintaining the mold in a sealed condition at the shear edge;

(d) injecting a thermosetting in-the-mold resin coating into the ~ .

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space between one mold die and the cured resin containing glass fibers; .`
(e) bringing the dies together to spread the coating over the ~i cured resin containing the glass fibers and to cure the .
in-the-mold resin coating, wherein the improvement comprises: ;
(f) injecting the in-the-mold resin in a stream which flows parallel from the injector onto the surface of the substrate from a cooled injector permanently attached to the mold; and (g) controlling the relative positioning of the dies solely by the ram of the mold.
The apparatus for carrying out the method of the present invention includes a water cooled valved injector nozzle which is permanently mounted in a hot die member. The injector nozzle injects directly into the mold cavity. A stream is injected parallel to a roughened substrate surface. The die forming the roughened surface has, in turn, a rough surface. Mechanical assists on the corners of the movable upper die need not be used to supplement the lifting force created by the hydraulic fluid used to open the mold. Conventional heel blocks are used to maintain the dies in a parallel configuration. In addition, appropriate controls need not be employed to synchronize with the opening of the mold or with the rate of flow of the coating mlterial into the cavity.

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: . . ' ,: i " . ' One way of carrying out the invention is described in detail below with reEerences to the drawings in which, Figure 1 is a view partially in section of a mold having `~
the valved injection nozzle mounted in the lower die thereof.
Figure la is a view partially in section of the valved injection nozzle.
Figure 2 is a view of the Teflon* baffel used in the injection nozzle of Figure 1.
Figure 3 is a figure of the dies showing pillow blocks.
Figure 4 is a top view of the bottom die showing a roughened surface.
Referring to the drawings, a conventional hydraulic press, not shown, supports a pair of relatively movable die members 2 and 4, the lower one, of which identified by reference numeral 2, is rigidly secured to the base while the upper die member 4 is fixedly connected with a plate member which, in turn is movable vertically through a double acting hydraulic ram mounted on the support member. The hydraulic ram serves to raise the upper die member 4 relative to the lower die member 2, and, although not shown, the upper die member 4 is guided during such movement through appropriate guide members. Thus, by actuating the hydraulic ram, the upper die member 2 can assume an open raised position or a lowered closed position as shown in Figure 1. hhen the die members 2 and 4 are closed, they form a cavity for ~-molding a plastic article under heat and pressure in a desired configuration. The die members 2 and 4 cannot only serve to mold a plastic article as seen ,' .... _ ~
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in Figure 1, but, in addition, the die member 2 incorporates parts and components to be described hereinaEter that provide a coating on ~ne surface oE the molded article. The coa~ng is in the form of a liquid skin forming thermosetting resin ~hich is injected against the surface being coated.
In order to deliver the liquid thermosetting resin coating material to the surface to be improved, the lower die member 2 has been designed so as to include a valved injector nozzle 6.
In this regard, the lower die member 2 is formed with a horizontally oriented cylindrical recess 8 in which valved injector nozzle 6 is permanently mounted. Valve pin 10 is connected to an actuator in the form of a double acting hydraulic piston 12 movable in cylinder 14. By directing pressurized fluid to one end or the other of the hydraulic cyliner 14, the piston 12 is movable between the fabric bumper 16 and fabric bumper 18.
Movement of the piston 12 to fabric bumper 18 opens injector valve 20. In the open position, thermosetting resin 22 flows througb material inlet 24, stainless steel barrel 26 through open valve 20 and into the mold cavity 28.
The injector device 6 is carried by the lower die member 2, and as seen in Figure 1, includes a cylindrical recess 8 having its end portion 30 threaded, which serves to securely mount the injector device to the lower die member 2 by threaded nozzle end 32. The outer sleeve member 34 is secured at its left-hand end ~-as seen in Figure 1 to an elon~ated inner barrel 26 through flange 34 at its right-hand end, the outer sleeve member 34 is attached to barrel 26 through the injector nozzle assembly 36.
The inner periphery surface of a portion of the sleeve member 34, together with the outer surface of barrel 26, form passages for cooling fluid to be directed from inlet 38 around the barrel 26 and then exhaust at outlet port 40. Teflon baffels 42 are positioned in the cooling passage to ;, :
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direct the flow~of cooling water to the cooling chaniber 43 of injector nozzle assembly 36. As seen in Figure 2, Teflon baffel ~;
42 has flat surfaces 44 and 45 which permits water to flow between the outer sleeve member 34 and the Teflon baffel 42 and enter the injector nozzle assembly 36. This barrel 26 fits through hole 46. Directing cooling of the water to the injector nozzle assembly 36 keeps the injector nozzle assembly cool enough that it does not cause the resin injected by the nozzle to cure, but warm enough so that it doesn't cool the part of the mold to 10 which it is attached and cause undercure of resin in that area.
The valved nozzle is opened and closed by air at 100 psi (689 KPa) or hydraulic fluid at 1,000 psi (6894 KPa) when hydraulic Eluid (including air) is directed via a port 48 in flange 34, to the chamber at the left-hand side of the piston member 12, the pin 10 is shifted towards the right allowing resin to be injected into the mold. On the other hand, when hydraulic fluid is directed via a port 50 in flange 52 to the chamber at the left side of piston member 12, the pin 10 of the injector device moves to the ri8ht closing the valve at 20 and pin 10, 20 completing the smooth surface on the inside of die 2.
Air is the preferred fluid as it eliminates the danger of contaminating the injector resin with hydraulic fluid. Ihe injector resin is maintained at 1,000 psi (6894 KPa) so that any leakage will be resin into the air chamber and not vice-versa.
The in-the-mold coating resin is fed into the valved injector at resin inlet 54, which is adapted to be connected through a conduit (not shown) to a source of pressure supplied ingredients which make up one or a two component thermosetting resin system. If a two component resin is used, a static mixer 30 such as that made by Kenics Corporation serves to mix the two liquid components of the thermosetting resin system prior to introduction through port 24.

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Other kncwn mixers can also be used. It should be apparent that when the pin 10 is moved toward the left, the nozzle will be ;~
opened and permit the thermosetting resin coating material to flow into the upper die member 2 if the pressure is great enough to overcome the pressure exerted by the press on the die. The lower die 2 has a roughened inner surface 3. This imparts a roughened surface to the substrate part. Flow of in-the-mold coating resin across the roughened surface causes a separation of resin and filler, leaving a resin-rich layer on the substrate surface. The resin-rich layer appears to aid adhesion. The indentations in the surface of the die can range from about 0.001mm to 0.01mm.
The apparatus described above operates as follows.
Initially the upper die memher 4 is raised relative to the lower die member 2 so as to expose the cavity portion within the lower die member. Slabs of sheet molding compound are then placed in the bottom of the lower die member 2 within the cavity at appropriate locations. Pin 10 is positioned to form a s oth inner surface with the inner surface of die 2 by pressurization of port 50. The mold is pressurized, driving the heated upper die member 4 downwardly into telescoping engagement with the fixed heated lower die member 2. As the upper die member 4 closes on the lower die member 2, the slabs of sheet molding compound are deformed under heat and pressure and flows to fill the mold cavity and any rib forming grooves therein so as to form a ribbed substrate and is identified by the reference numeral 28. The molding pressure generated by the ram of the mold is maintained on the upper die member 18 until the substrate 28 cures and hardens sufficiently to permit separation of the upper die member 4 without adversely affecting the substrate. Mbld timer No. 1 is set at 1/2 to 5 minutes to accomplish the initial cure.

During the cure cycle, sink marks are ususally formed above the ribs due to shrinkage occurring. Similarly, the surface of the substrate may also have other imperfections, such as porosity, line cracks, etc. Such defects in the outer surface of the substrate 28 are eliminated by providing a cosmetic coating to the surface to be improved. This coating is applied, according to this inventicn, during the final stages of curing of the substrate.
In applying the coating, the ram pressure of the mold initially is relieved on the upper die member 4 by operation of a timer T-2, which is set at about 1 to 4 seconds. This opens the mold 1/2 inch. Pressurized fluid is directed through port 48 to the left side of the piston member 12 while the other side of the piston member is vented via port 50. The degas timer T-3 of the mold is used to control both the movement of pin 10 and the mold -~
opening time. In-the-mold coating material is injected for about 1 to 15 seconds through material inlet port 24. When T-3 has timed out, the press comes back down to tonnage and is timed out by T-4 (about 1 to 15 minutes) to cure the coating.
Simultaneously with the press coming down, pin 10 is moved back to form part of the inner mold wall.
During the time that the pin 10 is retracted, the coating mate~ial flows into the cavity. ~he coatin~ material moves outwardly parallel to the surface of the substrate 28 hydraulically pressing the latter tightly against the upper die `
member 4 and tbereby preventing its dislodgement or unseating therefrom. Following the pressuri~ed supply of the coating material onto the lower surface of the substrate 28, the press is once agaîn activated so as to close the die members 2 and 4 and cause the coating material to be uniformly distributed on the surface to be coated. Heel , . ~ , . . .
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blocks 60 which mate with recesses 62 align the dies of the closing mold. Guide pins and mating recesses can also be used in conjunction with the heel block.
Specific examples for injecting the coating by using an injection nozzle which has a pin protruding through the opening in the nozzle will now be set forth. In the closed position the end of the pin forms a small portion of the inner mold surface.
In the open position, the pin is pulled back from the mold and from the opening in the nozzle allowing coating material to be injected into the mold. The pin is stabilized against rotation so that it will always form a smooth surface with the mold wall in the closed position. ~he nozzle is at a different temperature from the mold because it is water cooled.
Charge weights giving as much as .5mm of coating have been used, but an average of .07 to .lOmm of coating has generally been enough to give both opaci~y and complete coverage. Since the usual substrate part averages 2.5mm in thickness, a typical coating has required about .03 to .05gm of coating per gm of SMC
(sheet molding compound) used.
Simple coating charge placements, often a single pool or strip formed by high pressure injection usually have provided complete coverage.
Mold temperatures from 140 to 160C have given satisfactory coatings. A minimum cure time of 10 to 30 seconds at 150C has been used but slower cure rates have sometimes been required to prevent too rapid gelation resulting in incomplete coverage.
Higher molding pressures, as expected~ provide better , :.
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coverage of steeper, lower draft surfaces. However, the typical pressures needed to mold the base SMC part have also generally been adequate to give a complete coating. The principle aim of the in-the-mold coating has been to fill voids, reduce sinks and act as a replacement for the primer-sealer now commonly used by custom lders of SMC.
In-the-mold coated parts have passed the automotive tests normally used.
In the following examples as elsewhere in the specification and claims, all parts and percentages are by weight unless otherwise specified.
Example I
A 1973 Oldsmobile grill opening panel was molded using a standard Rchm & Haas unsaturated polyester based sheet molding compound using 68.95 KPa pressure (1,000 psi). The press used was manufactured by Erie Press in Erie, PA. Most of the presses made by the various manufacturers have automatic degas controls or they can be added.
The automatic degas cycle of the press was activated to control the sequence necessary for molding the parts, opening the mold to inject the in-the{nold coat and reclose on the proper pressure to coat the parts. Ihe parts were lded and were excellent in appearance. m ey were tested and passed all the tests run. m e coating, in some instances, was so thick that a cross-hatch adhesive could not be run. The one component in-the-mold coating was 2.2mm thick. The molding sequence was as follows.
All four timers on press were used. Timer No. l (T-l) is the precure timer and was set at 2-1/2 minutes to mold and cure the part. When the cure time has elapsed and the press comes off tonnage T-2 times the flow of oil to . . ~

111~2~3 return the ram (set at 1-11/12 seconds), this opens the mold to 1~.
In-the-mold coating material was then injected into the mold with the timer on the injector being the T-3 ti~.e, which, in this case, was set at 13 seconds. When T-3 has timed out, the press came back down and onto tonnage and was timed out by T-4 (60 seconds) to cure the coating.
This whole se~uence worked very well for molding and coating parts and the press repeated the same se~uence correctly every time except T-2 which appeared to result in a 3mm variation either way once in a while. This is understandable as break-away force needed can and will fluctuate with fluctuation in charge weight and charge placement when shears are as wide open as on this part.
With this set-up, precure pressure and cure pressure were different to hide sinks over bosses and ribs. Mold cure pressure was reduced to 78740 Kg/area of front end (100 tons/area front end) less than precure tonnage to reduce the tendenc~y for parts to crack.
An interface signal from T-2 is used to activate the injector and another signal from T-3 is used to shut it off.
This eliminates a need for a separate timer for the injector.
During injection a seal was maintained by the shear edge of the mold. The following in-the-mold coating composition was the one injected through a cooled injection nozzle positioned between the partng surfaces of the mold and injecting parallel to the parting surfaces.
The coating composition used had the following formulation.

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Z~fi :, Components Parts :

Vinyl ester resinl in styrene (believed to be 66% copolymer of acrylic acid and diglycidyl ether of bisphenol A :;~
in 44% styrene some trimethoxyphenol is present for cross-linking) 200 40% polyvinyl acetate, free of carboxyl groups, dissolved in 60% styrene 80 Styrene 40 Canadian talc 0.03mm average particle '`
length 200 Suzorite mica (phlogopite) 0.03mm average particle length 140 :
20 Tertiary butyl benzoate 6 .. .
Saturated solution of parabenzoquinone ~:
in styrene ~(inhibitor~ 0.6 ; Dialkyl phosphate 3 (mold release) 3.0 .

lDow XD 9013.02 2Union Carbide LP90 3Zelac NE trademark of duPont ~. :

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Tne following are the processing parameters and test results of Example I:
Mold temperature 295F
SM~ Cure Time 2 mins.
Coating Cure Time 1 min.
Coating Thickness 3 to 18 mils (18 mils on horizontal uniform) The parts are presently being evaluated in actual handling and use. ~b failures have been reported. ~;
Example II
Example I was repeated manufacturing test parts using a two component in-the-mold coating co~position. Ihe for~ulation is generally set forth in U.S. Patent 4,081,578. A proportioning pump was used. The pump has two large cylinders. The piston in each cylinder was driven by a com~on drive so that each piston ved exactly the same distance. Che cylinder contained one reative component and the other cylinder contained the other reactive component. The displacement of the two cylinders is more than sufficient for one in-the-mold coating. The output from the two cylinders was mixed in a static mixer (Kinex Mixer) and injected into the mold using the valved injector nozzle of the present invention. The cure time for the in-the-mold coating was one minute.
Other than the above recited differences, the same procedure was followed as that set forth in Example I.
m e preferred mold has a chrome or nickel-plated cavity.
The interior faces of the mold are preferably roghened by impingement with glass beads or sand-blasted priQr to chrome plating. The roughened surface causes a separation of the resin and filler of the in-the-mold coating giving - ~, . - , ;

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a resin-rich phase at the interface between the substrate and the in-the-mold coating.
Both the injector and the proportioning pump are available from the Tompkins-Johnson Co~, 2425 West Michigan Avenue, Jackson, Michigan 49202.
Various changes and modifications can be made in this construction without departing from the spirit of the invention.
Such changes and modifications are contemplated by the inventors and they do not wish to be limited except by the scope of the `
appended claim.

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Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. In a method of forming a thermoset coating on a hot, cured glass fiber reinforced thermoset resin substrate in a hot mold which is opened and closed by a ram controlled by a timer by:
(a) placing an uncured resin containing glass fibers into the hot mold, the mold formed by two dies having a shear edge;
(b) closing the mold to form and cure the resin containing the glass fibers, using the mold timer to control the cure time;
(c) separating one of the dies from the cured resin containing the glass fibers while still maintaining the mold in a sealed condition at the shear edge;
(d) injecting a thermosetting in-the-mold resin coating into the space be-tween one mold die and the cured resin containing glass fibers;
(e) bringing the dies together to spread the coating over the cured resin containing the glass fibers and to cure the in-the-mold resin coating, wherein the improvement comprises:
(f) injecting the in-the-mold resin in a stream which flows parallel from the injector onto the surface of the substrate from a cooled injector perm-anently attached to the mold; and (g) controlling the relative positioning of the dies solely by the ram of the mold.