CA1106125A - Method for molding hollow objects of thermoplastic resins and an apparatus for making the same - Google Patents

Method for molding hollow objects of thermoplastic resins and an apparatus for making the same

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Publication number
CA1106125A
CA1106125A CA223,298A CA223298A CA1106125A CA 1106125 A CA1106125 A CA 1106125A CA 223298 A CA223298 A CA 223298A CA 1106125 A CA1106125 A CA 1106125A
Authority
CA
Canada
Prior art keywords
parison
heating
heating means
auxiliary
axially extending
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA223,298A
Other languages
French (fr)
Inventor
Yokichi Miyara
Yasunori Sugita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kureha Corp
Mitsui Toatsu Chemicals Inc
Original Assignee
Kureha Corp
Mitsui Toatsu Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kureha Corp, Mitsui Toatsu Chemicals Inc filed Critical Kureha Corp
Priority to CA223,298A priority Critical patent/CA1106125A/en
Application granted granted Critical
Publication of CA1106125A publication Critical patent/CA1106125A/en
Expired legal-status Critical Current

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  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

ABSTRACT

A method for making plastic containers comprises the steps of heat-ing an axially extending area of a tubular parison to a temperature higher than that of the remaining axially extending portion prior to forming the container in a mold. Apparatus for accomplishing such heating includes a furnace provided with an endless conveyor and auxiliary heater along a certain portion of the path of the conveyor.

Description

~1~6~'~5 This invention relates to a method for molding hollow objects of thermoplastic resins and an apparatus for making such hollow objects, and more particularly, to a method and apparatus for molding hollow objects of thermoplastic resins wherein each of solid parisons is heated in a manner as to have proper temperature differences in the respective axial portions of the solid parison so that the resultant hollow object is suitably controlled in thickness in a lengthwise direction.
In general, methods of blow-molding thermoplastic resins can be broadly classified into three categories: cold parison molding, hot parison molding and cold sheet molding. Most hollow materials or objects are now produced by a cold or hot parison molding method using resin tubes ~so-called "parisons"). In this sense, this invention concerns a cold parison molding method or a biaxially stretching and blow-molding method (hereinafter referred to simply as stretch and blow molding) which comprises a parison producing step and a heating~ stretching and blowing step.
In the case where plastic containers which have a flat or irregular form in section, or the diameter and sectional area of which vary to a great degree in a lengthwise direction, are produced by a hot parison molding method, the thickness of the final, desired, moldings is made uniform by suit-ably controlling the thicknesses of portions of a molten parison. This O~
parison is~o~ttonded-by means of an extruder or is produced by the use of an injection molding machine, according to the shape of the ultimate moldings.
That is, upon the extrusion of a molten parison, a die or core which has an angle with respect to an extruding direction is moved vertically for changing the clearance between dies and cores to control or change the thicknesses of a molten parison in a lengthwise direction ~i.e., a parison-thickness control method). Furthermore, the control of thickness of a molten parison in the circumferential direction can be achieved by the use of a flat or deformed extrusion die or coreJ so that it is possible to produce a container which bo~
has greatly different diameters in the~Xoll portions thereof without unnec-*

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essarily incre&sing the weight of container, or to form a container, which is flat or deformed in section, with a uniform thickness in all portions of the container, or to make uniform the bottom thereof. In many instances the bottoms tend to be thin.
In a cold parison molding system which comprises a parison producing step and a blowing step, the two steps being independent each other, it is usual to produce parisons by continuously extruding cylindrical pipes, followed by cutting, so that it is almost impossible to change or control in a lengthwise direction the thickness of parison in accordance with the shape of an ultimate container product. Furthermore, the control of thickness in the circumferential direction does not prevail to such an extent as in the hot parison molding system since it is difficult to place a cut parison in correct position in a metal mold when the parison has a thickness which varies in the circumferential direction. A complicated apparatus is required.
Accordingly, where containers have irregular cross-sections are molded by a cold parison molding method without controlling the thickness of parison, extremely thin wall portions may be formed. To avoid this, it is necessary to increase the entire thickness of the staring parisons. This is undesirable as the ultimate containers disadvantageously increase in weight, resulting in increase in production costs and reduction in transparency of the containers.
Especially with a stretch and blow molding system wherein the blow molding temperature is low, a parison becomes poor in moldability. Accord-ingly, upon expansion by blowing, the thickness of portions of the parison not in contact with a metal mold at an initial stage of the expansion are made extremely thin in comparison with the remainder of the container, i.e. a small diameter body portion and/or neck portion. These portions include long span portions of a container with a flat or deformed section and a great diameter body portion and a bottom portion of a container which has different body diameters therein or which is formed by a wide range of expansion ratios.
The resultant containers have extremely non-iniform thickness distribution.

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1~61Z5 In accordance with one aspect of this invention, there is provided a method of forming biaxially oriented hollow articles having an irregular configuration with respect to a particular axis comprising:
a) introducing a tubular parison having a uniform wall thickness into a closed heating zone and conducting said parison in a predetermined path through said heating zone for a time sufficient to impart heat to elevate the temperature of the entire parison to a first orientation temperature within 1C temperature tolerance;
b) subjecting the entire circumference of an axially extending portion of said parison which corresponds to a portion of a biaxially oriented hollow article having a rotatably smaller expansion ratio than the remaining portion to the influence of an auxiliary source of heat within said closed heating zone during a concluding portion of said path to elevate said axially extend-ing portion only to a second temperature which is higher than that of the remainder of the parison by 1 to 5C;
c) removing said heated parison from said closed heating zone and axially stretching said heated parison;
d) placing said stretched and heated parison into a molding zone having an irregular circumferential configuration with respect to the longitudinal axis of said parison when disposed therein, said axially extending portion of the parison being disposed in axial alignment with a portion of the molding zone having a circumferential dimension which is less than the maximum circum-ferential dimension of the molding zone; and e) creating a pressure differential to expand said parison out into con-formity with said molding zone.
Another aspect of the invention provides apparatus for heating parisons comprising: (a) a furnace; (b) conveyor means including chain means for transporting tubular parisons along a circuitous path in said furnace; (c) said conveyor means including a series of support means for holding each of said parisons in positions for rotation about their respective central axes ,;~. ~ ' lZS

while being transported along said path; (d) said furnace also including auxiliary heating means disposed along a predetermined length of said circuitous path for heating an axially extending portion of a parison to a temperature different from that of the remainder of the parison, said auxiliary heating means comprising an elongated fixed source of heat disposed parallel to said predetermined length of said circuitous path with said chain means guided to move in one direction spaced horizontally from one side of said auxiliary heating means and in the opposite direction spaced horizontally from the other side of said heating means; ~e) and means for rotating a support means for a parison while exposed to said auxiliary heating means, including a shaft including a gear rotatably journaled on said chain means, and fixed sprocket means engaging with said gear along said predetermined path.
Thus the apparatus of this inveniton is characterized in that the auxiliary heating means is provided within the parison heating device, the parison being first uniformly heated by means of the parison heating furnace and thereafter the certain portions with respect to the axial direction of the parison being further heated by the auxiliary heating means while the parison is rotated for producing predetermined temperature differences in the parison which are uniform in the circumferential direction while varying with respect to each other in the axial direction. A known stretcher and a fluid-blowing means are provided for axially stretching the heated parison, followed by blowing thereinto a pressurized fluid or air mold.
The thermoplastic resins useful in the present invention are all thermoplastic resins capable of blow-molding by the cold parison molding -method. In particular these resins include high density polyethylene, low density polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride and the like~ These thermoplastic resins may be laminated with a thermoplastic resin of a different type.
This invention is very effective when applied to the production of ~ - .

11~ lZ5 containers whose body diamcter varies in a lengthwise direction, e.g. a con-tainer having a conical form or a container with a narrow body part. However, this invention is not limited to the production of containers with such speci-fic forms or shapes. It is also effective for the production of general cylindrical containers with the bottom being made strong and uniform in thick-ness. The heating source of the auxiliary heating means is not limited to a specific type but preferably may be a radiant heating means such as an infra-red heater, a silica tube heater, a far infrared heater, a hot air generator, a steam heating device and the like.
The heating source of the heating device which includes therein the auxiliary heating means is not limited to those of a specific type and may be - 4a -S

the same type of heating source used in the auxiliary heating means. In either case, the heating source is required to control the temperatures with-in 1 C.
Where the temperature difference in the axial direction of the parison attained by using the auxiliary heating means is smaller than 1 C, it is difficult to make uniform the thickness of a final product and the mainten-ance of such small temperature difference will be almost impossible. However, with the temperature difference in excess of 5 C, good molding products can not be obtained since the portions heated by the auxiliary heating means are expanded to an excessive extent and so-called "necking" will take place.
The heating device is required to be so designed as to vertically support parisons upon respective supporting pins and to be capable of circul-atingly feeding or conveying the parisons through the heating device. Further-more, when the parisons pass by the auxiliary heating means, it is necessary to permit the parisons to rotate together with the respective supporting pins so that the parisons are uniformly heated in a circumferential direction.
This invention will be particularly illustrated by the following detailed description and accompanying drawings, in which:
Figure 1 is a plan view of a preferred form of heating device embodying the present invention;
Figures 2 and 3 are vertical sectional views t~Xen along the lines A-A and B-B in Figure l;
Figure 4 is a plan view taXen along the line C-C in Figure 3;
Figure 5 is a front view of a hollow object obtained in accordance with the invention; and Figure 6 is a bottom view of the container of Figure 5.
~; Figure 1 is a plan view of a heating device and an auxiliary means embodying the present invention, in which indicated at 1 is the auxiliary heating means, at 2 a hot air port of the heating device, at 3 a parison conveying or feeding chain, at 4 and 4' axes for returning the conveying chain 3, at 5 a heating furnace and at 6 means for introducing a parison into the ,v _ 5 _ 11~;61~S

heating furnace 5;
Figures 2 and 3 are vertical sectional view taken along the lines A-A and B-B in Figure 1, respectively, in which views indicated at 7 is a parison supporting pin, at 8 a gear wheel for rotating the supporting pin 7, at 9 a parison, at 10 a fixed sprocket mating with the gear 8, at 11 a shaft supporting the pin 7 and at 12 a chain guide, Figure 4 is a plan view taken along the line C-C in Figure 3, Figure 5 is a front view of a container obtained in accordance with the present invention; and Figure 6 is a bottom view of the container of Figure 5.
Referring now to Figures 1, 2, 3 and 4, the chain 3 which carries the parison supporting pins 7 is endless and runs in the direction of the arrows shown in Figure 1. The heating furnace 5 is entirely uniformly heated up to a predetermined molding temperature T by hot air which is blown through the hot air ports 2. The parison 9 is put on the supporting pin 7 with the aid of the parison introducing means 6. The parison 9 is fed through the heat-ing device to heat it entirely and uniformly and comes to the position where it encounters the auxiliary heating means 2 on its next to last pass of the con-veyor means. The auxiliary heating means 1 is, for example, sets of three far infrared heaters which are set in position to heat the upper, middle and lower portions of the parisons, respectively, and which are ad~ustably mounted to be movable up and down in a vertical line. Moreover, the auxiliary heaters are respectively connected to voltage regulators to suitably control the quan-tity of heat. The parison 9 which is mounted on the supporting pin 7 is fed through the furnace in the direction of the arrows while allowing it to rotate at a constant rotational frequency by means of the gear 8 mating with fixed sprocket, during which certain portions of the rotating parison are further heated for a predetermined period of time by the auxiliary heating means. As a result, the upper, middle and lower portions or parts of the parison is uniformly heated in a circumferential direction up to temperatures of (T + tl) C, ~'~d~,``' ~1~61;~S

(T + t2) C and (T ~ t3) C, respectively. The thus heated parison is then fed to a subsequent blowing step or a stretching and blowing step to shape the same into a desired form.
EXAMPLE
Polypropylene having a density of 0.900 g/cc (at 20 C) and a melt index of 0.5 g/10 min (ASTM-D-1238-62T) was used as a raw material for pro-ducing by means of an extruder and a parison cutter each having an outer diameter of 22 mm, a thickness of 5 mm, an inner diameter o~ 12 mm and a length of 120 mm. The resultant parison was heated to 155 C (hereinafter referred to as T C) by the use of the heating device of Figure 1. The upper portion (i.e., A portion (expansion ratio 1.6) in Figure 5) of the parison was further heated by the far infrared heaters up to T + 4 C, the middle ; portion (i.e., B portion (expansion ratio 2.3) in Figure 5) up to T + 2 C, but the lower portion (i.e., C portion (expansion ratio 3.0) in Figure 5) - 6a -,~
~3 11~61Z5 was not supplementarily heated. The thus heated parison was withdrawn from the furnace and the ends of the parison were grasped by conventional apparatus for stretching the parison by about 2.5 times as long at a constant rate in the direction of a tube axis. The thus stretched parison was immediately placed in a metal mold having an internal configuration as shown in Figures 5 (front view) and 6 (bottom view), and a pressurized fluid, such as air, was blown into the parison to mold a container. The thickness distribution of the container which was obtained by the use of the auxiliary heating means in accordance with the present invention is shown in the Table below in com-10 parison with that of a container obtained as a result of conventional uniform heating. The measured points are indicated by numerals corresponding to those : of Figure 5.
'. -Measured Thickness (mm) point _ _ , ~ Container of invention Container of prior art Front Side Front Side ~0 ~; ~ ~ .

It wi.ll be apparent from the Table that the thickness distribution of the container of this invention is markedly uniform when compared with the ` 11~;6~;25 container which is obtained from the same kind of parison uniforrnly heated by a conventional manner.
As for the molding of containers of different shapes, the almost same results can be obtained by suitable control of heating intensity, heat-ing position and heating time. It should be noted that the above-described specific apparatus is intended to merely illustrate one preferred embodiment of the present invention. Various modifications may be made without depart-ing from the scope of this invention.

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Claims (7)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Method of forming biaxially oriented hollow articles having an ir-regular configuration with respect to a particular axis comprising:
a) introducing a tubular parison having a uniform wall thickness into a closed heating zone and conducting said parison in a predetermined path through said heating zone for a time sufficient to impart heat to elevate the tempera-ture of the entire parison to a first orientation temperature within 1°C temper-ature tolerance;
b) subjecting the entire circumference of an axially extending portion of said parison which corresponds to a portion of a biaxially oriented hollow article having a rotatably smaller expansion ratio than the remaining portion to the influence of an auxiliary source of heat within said closed heating zone during a concluding portion of said path to elevate said axially extending portion only to a second temperature which is higher than that of the re-mainder of the parison by 1 to 5°C;
c) removing said heated parison from said closed heating zone and axially stretching said heated parison;
d) placing said stretched and heated parison into a molding zone having an irregular circumferential configuration with respect to the longitudinal axis of said parison when disposed therein, said axially extending portion of the parison being disposed in axial alignment with a portion of the molding zone having a circumferential dimension which is less than the maximum circum-ferential dimension of the molding zone; and e) creating a pressure differential to expand said parison out into conformity with said molding zone.
2. Method of claim 1, in which said parison is cylindrical, and which includes the step of rotating said parison in proximity to said auxiliary source of heat during step (b).
3. Method of claim 2 wherein said thermoplastic is polypropylene, said first temperature is approximately 155°C and said second temperature is approxi-mately 159°C.
4. Apparatus for heating parisons comprising: (a) a furnace; (b) con-veyor means including chain means for transporting tubular parisons along a circuitous path in said furnace; (c) said conveyor means including a series of support means for holding each of said parisons in positions for rotation about their respective central axes while being transported along said path;
(d) said furnace also including auxiliary heating means disposed along a predetermined length of said circuitous path for heating an axially extending portion of a parison to a temperature different from that of the remainder of the parison, said auxiliary heating means comprising an elongated fixed source of heat disposed parallel to said predetermined length of said circuitous path with said chain means guided to move in one direction spaced horizontally from one side of said auxiliary heating means and in the opposite direction spaced horizontally from the other side of said heating means; (e) and means for rotating a support means for a parison while exposed to said auxiliary heating means, including a shaft including a gear rotatably journaled on said chain means, and fixed sprocket means engaging with said gear along said predetermined path.
5. An apparatus as defined in claim 4 wherein said auxiliary heating means includes means for heating at least two axially extending portions of the parison to temperatures different from each other and from that of the remainder of the parison.
6. An apparatus as defined in claim 4 wherein said auxiliary heating means includes at least two elongated heating means disposed in vertical superimposition.
7. An apparatus as defined in claim 6 wherein said auxiliary heating means comprises a source of infrared heat.
CA223,298A 1975-03-27 1975-03-27 Method for molding hollow objects of thermoplastic resins and an apparatus for making the same Expired CA1106125A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA223,298A CA1106125A (en) 1975-03-27 1975-03-27 Method for molding hollow objects of thermoplastic resins and an apparatus for making the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA223,298A CA1106125A (en) 1975-03-27 1975-03-27 Method for molding hollow objects of thermoplastic resins and an apparatus for making the same

Publications (1)

Publication Number Publication Date
CA1106125A true CA1106125A (en) 1981-08-04

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA223,298A Expired CA1106125A (en) 1975-03-27 1975-03-27 Method for molding hollow objects of thermoplastic resins and an apparatus for making the same

Country Status (1)

Country Link
CA (1) CA1106125A (en)

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