CA1085947A - lements photovoltaiques organigues multicouches - Google Patents

lements photovoltaiques organigues multicouches

Info

Publication number: CA1085947A
Authority: CA; Canada
Prior art keywords: layer; dye; photoconductive; phthalocyanine; layers
Prior art date: 1977-08-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA287,802A

Other languages

English (en)

Inventor

Ching W. Tang

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-08-02

Filing date

1977-09-29

Publication date

1980-09-16

1977-09-29 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1980-09-16 Application granted granted Critical

1980-09-16 Publication of CA1085947A publication Critical patent/CA1085947A/fr

Status Expired legal-status Critical Current

Links

238000013086 organic photovoltaic Methods 0.000 title abstract description 3
239000000203 mixture Substances 0.000 claims abstract description 31
150000001875 compounds Chemical class 0.000 claims abstract description 27
238000006243 chemical reaction Methods 0.000 claims abstract description 26
239000000463 material Substances 0.000 claims description 21
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 18
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 14
239000002184 metal Substances 0.000 claims description 14
125000004432 carbon atom Chemical group C* 0.000 claims description 13
125000000217 alkyl group Chemical group 0.000 claims description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
239000011669 selenium Substances 0.000 claims description 8
WVIICGIFSIBFOG-UHFFFAOYSA-N pyrylium Chemical compound C1=CC=[O+]C=C1 WVIICGIFSIBFOG-UHFFFAOYSA-N 0.000 claims description 6
229910052717 sulfur Inorganic materials 0.000 claims description 6
RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 5
229910052738 indium Inorganic materials 0.000 claims description 5
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
229910052711 selenium Inorganic materials 0.000 claims description 5
RJOLPPWIFYDSEI-UHFFFAOYSA-M 4-[(2,6-diphenylthiopyran-4-ylidene)methyl]-2,6-diphenylthiopyrylium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=C(C=2C=CC=CC=2)SC(C=2C=CC=CC=2)=CC1=CC(C=1)=CC(C=2C=CC=CC=2)=[S+]C=1C1=CC=CC=C1 RJOLPPWIFYDSEI-UHFFFAOYSA-M 0.000 claims description 4
125000002373 5 membered heterocyclic group Chemical group 0.000 claims description 4
125000004070 6 membered heterocyclic group Chemical group 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
150000001450 anions Chemical class 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
229910052759 nickel Inorganic materials 0.000 claims description 4
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 3
125000003545 alkoxy group Chemical group 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 3
125000004093 cyano group Chemical group *C#N 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
150000002367 halogens Chemical class 0.000 claims description 3
AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 3
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
239000011593 sulfur Chemical group 0.000 claims description 2
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 2
229910001887 tin oxide Inorganic materials 0.000 claims description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
239000000975 dye Substances 0.000 abstract description 65
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
239000011521 glass Substances 0.000 description 11
238000000034 method Methods 0.000 description 11
-1 methoxy, propoxy Chemical group 0.000 description 10
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 10
VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 10
239000002674 ointment Substances 0.000 description 8
230000003647 oxidation Effects 0.000 description 7
238000007254 oxidation reaction Methods 0.000 description 7
239000004065 semiconductor Substances 0.000 description 7
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
238000005286 illumination Methods 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000002904 solvent Substances 0.000 description 6
239000011248 coating agent Substances 0.000 description 4
238000000576 coating method Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
239000011133 lead Substances 0.000 description 4
102220029346 rs34541442 Human genes 0.000 description 4
102220012898 rs397516346 Human genes 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
239000010949 copper Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
150000004032 porphyrins Chemical class 0.000 description 3
229910052709 silver Inorganic materials 0.000 description 3
239000004332 silver Substances 0.000 description 3
238000004528 spin coating Methods 0.000 description 3
238000000859 sublimation Methods 0.000 description 3
230000008022 sublimation Effects 0.000 description 3
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
239000000370 acceptor Substances 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
238000010276 construction Methods 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000013078 crystal Substances 0.000 description 2
239000011737 fluorine Substances 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N isopropyl alcohol Natural products CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
230000031700 light absorption Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
238000005498 polishing Methods 0.000 description 2
230000005855 radiation Effects 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
238000012360 testing method Methods 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000011701 zinc Substances 0.000 description 2
YLGQLQSDQXOIBI-UHFFFAOYSA-N (29h,31h-phthalocyaninato(2-)-n29,n30,n31,n32)platinum Chemical compound [Pt+2].[N-]1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)[N-]3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 YLGQLQSDQXOIBI-UHFFFAOYSA-N 0.000 description 1
BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 1
BCUKECZYWCNORC-UHFFFAOYSA-M 4-[(2,6-diphenylpyran-4-ylidene)methyl]-2,6-diphenylpyrylium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=C(C=2C=CC=CC=2)OC(C=2C=CC=CC=2)=CC1=CC(C=1)=CC(C=2C=CC=CC=2)=[O+]C=1C1=CC=CC=C1 BCUKECZYWCNORC-UHFFFAOYSA-M 0.000 description 1
AFHSCVRRJSCCQY-UHFFFAOYSA-M 4-[(2,6-diphenylselenopyran-1-ium-4-yl)methylidene]-2,6-diphenylselenopyran;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=C(C=2C=CC=CC=2)[Se]C(C=2C=CC=CC=2)=CC1=CC(C=1)=CC(C=2C=CC=CC=2)=[se+]C=1C1=CC=CC=C1 AFHSCVRRJSCCQY-UHFFFAOYSA-M 0.000 description 1
QEFYDDIPVYUZHP-UHFFFAOYSA-M 4-[(2,6-diphenylselenopyran-1-ium-4-yl)methylidene]-2,6-diphenylthiopyran;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=C(C=2C=CC=CC=2)SC(C=2C=CC=CC=2)=CC1=CC(C=1)=CC(C=2C=CC=CC=2)=[se+]C=1C1=CC=CC=C1 QEFYDDIPVYUZHP-UHFFFAOYSA-M 0.000 description 1
JNUHUKNOWAWTQS-UHFFFAOYSA-M 4-[(2,6-diphenylthiopyran-4-ylidene)methyl]-2,6-diphenylpyrylium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=C(C=2C=CC=CC=2)SC(C=2C=CC=CC=2)=CC1=CC(C=1)=CC(C=2C=CC=CC=2)=[O+]C=1C1=CC=CC=C1 JNUHUKNOWAWTQS-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
DYSQEFBWRBAADQ-UHFFFAOYSA-M Cl(=O)(=O)(=O)[O-].C1(=CC=CC=C1)C=1C(=[S+]C=CC1)C1=CC=CC=C1 Chemical compound Cl(=O)(=O)(=O)[O-].C1(=CC=CC=C1)C=1C(=[S+]C=CC1)C1=CC=CC=C1 DYSQEFBWRBAADQ-UHFFFAOYSA-M 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
WPXOZDYAIYMJBU-UHFFFAOYSA-M [4-(2,6-diphenylthiopyran-4-ylidene)cyclohexa-2,5-dien-1-ylidene]-dimethylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=CC(=[N+](C)C)C=CC1=C1C=C(C=2C=CC=CC=2)SC(C=2C=CC=CC=2)=C1 WPXOZDYAIYMJBU-UHFFFAOYSA-M 0.000 description 1
FPSJLPNPRZYDHG-UHFFFAOYSA-M [4-(2,6-diphenylthiopyran-4-ylidene)cyclohexa-2,5-dien-1-ylidene]-dipropylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=CC(=[N+](CCC)CCC)C=CC1=C1C=C(C=2C=CC=CC=2)SC(C=2C=CC=CC=2)=C1 FPSJLPNPRZYDHG-UHFFFAOYSA-M 0.000 description 1
SDHCATSZXNNORZ-UHFFFAOYSA-M [4-[(2,6-diphenylthiopyran-4-ylidene)methyl]-6-ethoxythiopyran-2-ylidene]-ethyloxidanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CC[O+]=C1SC(OCC)=CC(C=C2C=C(SC(=C2)C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 SDHCATSZXNNORZ-UHFFFAOYSA-M 0.000 description 1
SLUCADRVPCDMEU-UHFFFAOYSA-M [4-[(2,6-diphenylthiopyran-4-ylidene)methyl]-6-methoxythiopyran-2-ylidene]-methyloxidanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C[O+]=C1SC(OC)=CC(C=C2C=C(SC(=C2)C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 SLUCADRVPCDMEU-UHFFFAOYSA-M 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
PVGJMICJSHYLON-UHFFFAOYSA-N benzo[f]chromen-4-ium Chemical class C1=CC=C2C3=CC=CC=C3C=CC2=[O+]1 PVGJMICJSHYLON-UHFFFAOYSA-N 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
JPBGLQJDCUZXEF-UHFFFAOYSA-N chromenylium Chemical class [O+]1=CC=CC2=CC=CC=C21 JPBGLQJDCUZXEF-UHFFFAOYSA-N 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000004020 conductor Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
239000002019 doping agent Substances 0.000 description 1
230000005611 electricity Effects 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
VNWHJJCHHGPAEO-UHFFFAOYSA-N fluoroboronic acid Chemical compound OB(O)F VNWHJJCHHGPAEO-UHFFFAOYSA-N 0.000 description 1
125000002541 furyl group Chemical group 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
238000003384 imaging method Methods 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
229940107698 malachite green Drugs 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000011368 organic material Substances 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
125000000714 pyrimidinyl group Chemical group 0.000 description 1
125000000168 pyrrolyl group Chemical group 0.000 description 1
NTQLADLBRQMNQJ-UHFFFAOYSA-M pyrylium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.C1=CC=[O+]C=C1 NTQLADLBRQMNQJ-UHFFFAOYSA-M 0.000 description 1
238000011160 research Methods 0.000 description 1
238000012552 review Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000009987 spinning Methods 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000001113 thiadiazolyl group Chemical group 0.000 description 1
125000000335 thiazolyl group Chemical group 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1
238000002834 transmittance Methods 0.000 description 1
238000007740 vapor deposition Methods 0.000 description 1
238000001429 visible spectrum Methods 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1

Classifications

- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/20—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/311—Phthalocyanine
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
- H10K85/621—Aromatic anhydride or imide compounds, e.g. perylene tetra-carboxylic dianhydride or perylene tetracarboxylic di-imide
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/649—Aromatic compounds comprising a hetero atom
- H10K85/652—Cyanine dyes
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells

Landscapes

Physics & Mathematics (AREA)
Electromagnetism (AREA)
Photovoltaic Devices (AREA)
Photoreceptors In Electrophotography (AREA)
Bipolar Transistors (AREA)

CA287,802A 1977-08-02 1977-09-29 lements photovoltaiques organigues multicouches Expired CA1085947A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US82111577A	1977-08-02	1977-08-02
US821,115		1977-08-02

Publications (1)

Publication Number	Publication Date
CA1085947A true CA1085947A (fr)	1980-09-16

Family

ID=25232560

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA287,802A Expired CA1085947A (fr)	1977-08-02	1977-09-29	lements photovoltaiques organigues multicouches

Country Status (5)

Country	Link
EP (1)	EP0000829B1 (fr)
JP (1)	JPS5427787A (fr)
AU (1)	AU521118B2 (fr)
CA (1)	CA1085947A (fr)
DE (1)	DE2861508D1 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2947797A1 (de) *	1979-11-28	1981-07-30	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung elektrisch leitfaehiger polyene und deren verwendung in der elektrotechnik und zur antistatischen ausruestung von kunststoffen
EP0047027A1 (fr) *	1980-08-22	1982-03-10	BBC Aktiengesellschaft Brown, Boveri & Cie.	Mélange de cristaux liquides
JPS5940647A (ja) *	1982-05-05	1984-03-06	カナデイアン・パテンツ・アンド・デイベロツプメント・リミテツド	感光性分子
US4717673A (en) *	1984-11-23	1988-01-05	Massachusetts Institute Of Technology	Microelectrochemical devices
JPS61200996A (ja) *	1985-03-04	1986-09-05	Agency Of Ind Science & Technol	有機導電体結晶の製造方法
JPH0719925B2 (ja) *	1985-03-05	1995-03-06	株式会社東芝	導電性薄膜
JPH02294257A (ja) *	1989-05-08	1990-12-05	Japan Servo Co Ltd	回転子
EP0966468B1 (fr) *	1997-03-05	2004-09-22	Ciba SC Holding AG	Perylenes derives d'ether couronne
US20070290195A1 (en) *	2005-08-22	2007-12-20	Stephen Forrest	Increased open-circuit-voltage organic photosensitive devices
JP2008135540A (ja) *	2006-11-28	2008-06-12	Sanyo Electric Co Ltd	有機光電変換素子
DE102009024956A1 (de) *	2009-06-05	2010-12-09	Technische Universität Dresden	Invertierte oder transparente organische Solarzelle oder Photodetektor mit verbesserter Absorption
DE102009051142B4 (de)	2009-06-05	2019-06-27	Heliatek Gmbh	Photoaktives Bauelement mit invertierter Schichtfolge und Verfahren zu seiner Herstellung
DE102009038633B4 (de)	2009-06-05	2019-07-04	Heliatek Gmbh	Photoaktives Bauelement mit organischen Doppel- bzw. Mehrfachmischschichten
WO2011015550A1 (fr)	2009-08-03	2011-02-10	Heliatek Gmbh	Système évaporateur pour des couches et composants organiques
DE102010028945A1 (de)	2009-10-29	2010-12-09	Heliatek Gmbh	Anwendungen für organische Photovoltaik
WO2011064330A1 (fr)	2009-11-27	2011-06-03	Heliatek Gmbh	Composant photoactif organique à système de couche(s) à cavité
ES2587082T3 (es)	2009-12-16	2016-10-20	Heliatek Gmbh	Elemento de construcción fotoactivo con capas orgánicas
DE102010007403A1 (de)	2010-02-09	2011-08-11	heliatek GmbH, 01139	Aufdampfparameter für organische Solarzellen
ES2857904T3 (es)	2010-05-04	2021-09-29	Heliatek Gmbh	Componente fotoactivo con capas orgánicas
DK2398056T3 (en)	2010-06-21	2016-05-30	Heliatek Gmbh	Organic solar cell with multiple transportlagsystemer
DE102012103448B4 (de)	2012-04-19	2018-01-04	Heliatek Gmbh	Verfahren zur Optimierung von in Reihe geschalteten, photoaktiven Bauelementen auf gekrümmten Oberflächen
CN104584252B (zh)	2012-07-02	2018-11-02	赫里亚泰克有限责任公司	用于光电构件的透明电极
DE102012105810B4 (de)	2012-07-02	2020-12-24	Heliatek Gmbh	Transparente Elektrode für optoelektronische Bauelemente
DE102012105809B4 (de)	2012-07-02	2017-12-07	Heliatek Gmbh	Organisches optoelektronisches Bauelement mit transparenter Gegenelektrode und transparenter Elektrodenvorrichtung
DE102012105812A1 (de)	2012-07-02	2014-01-02	Heliatek Gmbh	Elektrodenanordnung für optoelektronische Bauelemente
JP6995596B2 (ja) *	2017-12-08	2022-01-14	住友化学株式会社	光電変換素子

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3057947A (en) *	1959-10-01	1962-10-09	Calvin Melvin	Photoelectric cell using organic materials
US3403165A (en) *	1963-11-19	1968-09-24	American Cyanamid Co	Tetrathiotetracene ion-radical salts
US3379742A (en) *	1965-06-18	1968-04-23	American Cyanamid Co	Process for preparing transformed 1:1 complex of 1, 6-diaminopyrene-p-chloranil
US3814600A (en) *	1970-06-30	1974-06-04	Eastman Kodak Co	Electrophotographic element
JPS50942A (fr) *	1973-05-07	1975-01-08
NL7310500A (nl) *	1973-07-30	1975-02-03	Oce Van Der Grinten Nv	Elektrofotografisch, donor-acceptor complex bevattend reproduktie-element, beelddrager, werkwijze ter bereiding van een preparaat, genitreerde 11h-pyrido (2,1-b) chinazolin-11-on verbindingen alsmede een werkwijze ter bereiding daarvan.
DE2353639C2 (de) *	1973-10-26	1983-08-04	Hoechst Ag, 6230 Frankfurt	Elektrophotographisches Aufzeichnungsmaterial
GB1572181A (en) *	1975-08-18	1980-07-23	Ici Ltd	Device comprising a thin film of organic materila

1977
- 1977-09-29 CA CA287,802A patent/CA1085947A/fr not_active Expired
1978
- 1978-08-02 AU AU38543/78A patent/AU521118B2/en not_active Expired
- 1978-08-02 DE DE7878300233T patent/DE2861508D1/de not_active Expired
- 1978-08-02 EP EP78300233A patent/EP0000829B1/fr not_active Expired
- 1978-08-02 JP JP9373178A patent/JPS5427787A/ja active Granted

Also Published As

Publication number	Publication date
JPS624871B2 (fr)	1987-02-02
DE2861508D1 (en)	1982-02-25
EP0000829B1 (fr)	1982-01-06
JPS5427787A (en)	1979-03-02
AU521118B2 (en)	1982-03-18
AU3854378A (en)	1980-02-07
EP0000829A1 (fr)	1979-02-21

Legal Events

Date	Code	Title	Description
1997-09-16	MKEX	Expiry

Publication	Publication Date	Title
CA1085947A (fr)	1980-09-16	lements photovoltaiques organigues multicouches
US4164431A (en)	1979-08-14	Multilayer organic photovoltaic elements
US4281053A (en)	1981-07-28	Multilayer organic photovoltaic elements
Loveland et al.	1973	Photoconductivity and absorption in amorphous Si
CA1096022A (fr)	1981-02-17	Cellule photovoltaique
CA1089065A (fr)	1980-11-04	Pile photovoltaique
US6153824A (en)	2000-11-28	Photo-semiconductive electrode and photo-electic cell using the same
Whitlock et al.	1993	Investigations of materials and device structures for organic semiconductor solar cells
CA1086410A (fr)	1980-09-23	Elements photovoltaiques organiques
US4992109A (en)	1991-02-12	Photoelectric conversion element
Antohe	2000	Electrical and photoelectrical properties of the single-, and multilayer organic photovoltaic cells
JP3269247B2 (ja)	2002-03-25	有機太陽電池およびその製造方法
JPH01154571A (ja)	1989-06-16	光電変換素子
EP0000830B1 (fr)	1981-12-09	Elément transducteur photo-électrique
JPH01208873A (ja)	1989-08-22	光電変換素子
Meyer	1996	Solid state nanocrystalline titanium oxide photovoltaic cells
Di Marco et al.	2022	Organic Photoconductors and Photovoltaics
JPH01215069A (ja)	1989-08-29	光電変換素子
JP2516750B2 (ja)	1996-07-24	光電変換素子
JPH01154572A (ja)	1989-06-16	光電変換素子
JPS63120474A (ja)	1988-05-24	光電変換素子
JPH02153576A (ja)	1990-06-13	光電変換素子
Lan et al.	1998	A novel dual-layer dye photoreceptor
JPS61245583A (ja)	1986-10-31	光電変換素子
JPH01166575A (ja)	1989-06-30	光電変換素子