CA1041451A - System for handling the underflow from a primary separation vessel in the tar sand hot water process - Google Patents

System for handling the underflow from a primary separation vessel in the tar sand hot water process

Info

Publication number
CA1041451A
CA1041451A CA221,134A CA221134A CA1041451A CA 1041451 A CA1041451 A CA 1041451A CA 221134 A CA221134 A CA 221134A CA 1041451 A CA1041451 A CA 1041451A
Authority
CA
Canada
Prior art keywords
tailings
stream
primary
solids
pump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA221,134A
Other languages
French (fr)
Inventor
Stanley Mcquitty
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canada Minister of Energy Mines and Resources
Alberta Province Department of Energy and Natural Resources
Ontario Energy Corp
Gulf Canada Ltd
Canada Cities Service Ltd
Imperial Oil Ltd
Original Assignee
Canada Minister of Energy Mines and Resources
Alberta Province Department of Energy and Natural Resources
Ontario Energy Corp
Canada Cities Service Ltd
Gulf Oil Canada Ltd
Imperial Oil Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canada Minister of Energy Mines and Resources, Alberta Province Department of Energy and Natural Resources, Ontario Energy Corp, Canada Cities Service Ltd, Gulf Oil Canada Ltd, Imperial Oil Ltd filed Critical Canada Minister of Energy Mines and Resources
Priority to CA221,134A priority Critical patent/CA1041451A/en
Application granted granted Critical
Publication of CA1041451A publication Critical patent/CA1041451A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C10G1/047Hot water or cold water extraction processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

"SYSTEM FOR HANDLING THE UNDERFLOW
FROM A PRIMARY SEPARATION VESSEL
IN THE TAR SAND HOT WATER PROCESS"

ABSTRACT OF THE DISCLOSURE
For operating control and safety, a close-coupled pump is direct connected to the underflow of the primary separation vessel (PSV). The desired discharge density of the PSV is 70 - 80% solids in order to minimize bitumen losses. For a good pumping system, the pump discharge density should be less than 65% solids to avoid settling out of the solids in the downstream conduit. Therefore it is necessary to dilute the PSV underflow before it reaches the pump.
Secondary flotation tailings, a dilute stream containing a high proportion of fine solids, is used for this purpose.
The solids content of the PSV underflow is monitored by one of two alternative systems - a torque recorder on the PSV rake shaft or a density gauge on the PSV underflow conduit. The former is used when the PSV is being fed low fines tar sand -the latter when it is treating high fines tar sand. The density of the stream at the pump discharge is monitored to control the amount of secondary flotation tailings added.
By the use of the controlled-speed, close-coupled pump, a closed system for controlling underflow density is provided.
By using secondary tailings as the diluent, water requirements for the process are reduced and a pumpable mixture is provided from which the solids do not readily settle out.

Description

BACKGROUND OF THE INVENTION
This invention relat:es to the hot water process for extracting bitumen from tar sand. More particularly, it /
1 30 relates to a system for controlling the density or solids , j :~1 ''I .

~ , .
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1 ~ .::, ;
:~, ;'.

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content of the primary separation vessel (PSV) underflow and fluidizing it to render it pumpable and non~plugging.
A large proportion of the world's known hydrocarbon reserves exists in the form of tar sands. One large deposit of this material is found along the banks of the Athabasca River in Alberta. The tar sand exists in the ,. ...
~ form of water-wet grains of sand, sheathed in a film of bitumen.
:~ :. . .
~ In treating the tar sand to recover commercially useful -~
; products, it is first necessary to separate the bitumen from the water and sand.
, . . .
-~ The method commonly employed to extract the -~
i bitumen from the mined tar sand is known as the hot water '3,' process. In the first step of this process, tar sand, hot water and steam are fed into a rotating tumbler and mixed therein.
The hot water is supplied at a temperature of about 180F
and in amounts sufficient to supply a slurry containing about 20 - 25~ by weight water. The residence time within the -tumbler is typically four minutes and the exit temperature of the slurry is about 180F. While in the tumbler, the tar sand disintegrates and the bitumen particles are liberated from the i sand.
ii . :
¦ The t~bler product is passed through a screen to remove lumps and rocks and is then flooded with additional hot water to further disperse the sand and bitumen particles.
A typical flooded, aqueous, aerated slurry will have a composition of~7% bitumen, 43% water and 50% solids, and its temperature will be about 160F - 180F.
The ~looded slurry is then continuously fed ' `1-into a primary separation vessel. This vessel is conventionally 3Q a cylindrical settler having a conical bottom. In the vessel, most of the large sand particles (i.e. plus 200 mesh), .: :: , ~ fall to the bottom and leave through an outlet as a primary ~ ;
: ... .

:

~f~f~
tailings stream. Most of the bit~men particles, rise to ~` the top of the vessel and form primary bitumen ~roth. This froth overflows the vessel wall into a launder for removal.
A middlings stream, typically comprising about ~- 5 77~ water/ 21% solids and 2% bitumen, is continuously with-drawn from the intermediate zone of the primary vessel. The middlings stream is processed in a secondary recovery flotation -~ cell to produce secondary froth and a secondary tailings stream.
.. . .. .:
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:' 10 SUMMARY OF T~IE INVENTION
It is desirable to operate the primary separation , vessel so as to keep the underflow or tailings relatively dry.
fi This is done to reduce the loss of bitumen with this stream, ;f since bitumen loss increases as the water content of the primary tailings stream increases. In practice, the PSV
is operated to try to keep the primary tailings solids content ;f above about 65% by weight, preferably above 7~%. A typical ! primary tailings stream may comprise 30% waterl 69.3% solids -: ~ ,. :.
I and 0.7~ bitumen. The solids are mainly coarse in nature, ; ..........
as shown in Table I hereinbelow which provides an illus~rative -particle siæe analysis.
Due to the high coarse sand content, the primary tailings stream must be diluted to improve its pumpability and to reduce the possibility o the solids settling out and ~ 25 plugging the conduit carrying it to the tailings distribution - :
i~ ~ system.
f The secondary tailings stream is a good deal more dilute than the primary tailings stream and carries a large proportlon of fine clay and silt solids particles in it. A typical secondary tailings stream comprises 78.4% by ;~
f~
1~; ~ ~ ' ' - ` ' $ ~ - 3 -1 ' :

weight water, 21.1% solids and 0.5% bitumen. Table 1 shows an illustrative particle size analysis ~or this stxeam.

TABLE I
Size fraction Primary Secondary (microns?_ _ tailings tailings -~
.:
~ 5 0 - 5 2.6 11.
- 5 - 10 .2 10.7 10 ~ 20 1.5 10.4 20 - 3Q .8 ~.5 30 - 44 1.4 4.3 _ 44 6.6 ~1~6 44 - 74 3.2 10.5 ^:
~ 74 - 147 48.~ 46.0 ,~, ~ ~ 147 42.1 1.8 ;' ' .
In accordance with one aspect of this invention, Z the PSV is operated to produce a dry primary tailings stream.
At least part of the secondary tailings stream is combined therewith between the PSV outlet and the pump to produce a ~ ;
. single pumpable stream. As a result, the fine solids of the secondary tailings stream help to keep the coarse solids ~i 20 of the primary tailings stream in suspension and process water is conserved.
It is also desirable to provide a responsive and safe system for controlling the rate at which the primary tailings are withdrawn from the PSV. In this connection, a variable-speed close-coupled pump is direct connected to the PSV downcomer conduit and pumps the combined tailings through a line to the tailings distribution system. The speed of Z~ the pump is controlled to ensure that the solids content of the PSV tailings is maintained close to the desired level. ~;
In a preferred feature, the speed of the close-::

~` coupled pump ~s controlled responsive to the torque on the PSV rake shaft or to the density of the PSV tailings stream.
In the case where the PSV is operating on low ~ines tar sand ~eed, the torque-sensing system is used. With high fines tar sand ~eed, the density~sensing system is used.
Broadly stated, the invention comprises an improvement in the hot water process for recovering bitumen ~rom tar sand wherein aqueous tar sand slurry is fed to a primary separation vessel having a sand rake and tailings outlet and conduit to produce a primary bitumen froth stream, a relatively - dry primary tailings stream comprising coarse solids, and an :
aqueous middlings stream comprising fine solids and bitumen, said middlings stream being processed in a secondary recovery ~lotation cell to produce a secondary bitumen froth stream ~ ;
and a relatively Eluid secondary tailings stream comprising ,;. . :.
water containing fine solids. The improvement comprises the ~ ~
steps o~: pumping at least part of the secondary tailings -stream with a variable speed pump through a conduit which 3 joins the primary separation vessel outlet conduit and combining said secondary tailings with the primary tailings, said secondary tailings being supplied at a rate su~ficient to ., .:
I produce a stream o~ combined tailings which is pumpable;
and then pumping the combined tailings stream through a conduit with a variable-speed close-coupled pump to deliver it ;. h to a tailings distribution system, the speed o~ said close- -coupled pump being controllad to maintain the density of the primary tailings stream close to a pre-determined value.

DESCRIPTION OF T~E DRA~ING
The figure is a schematic ~iew o~ the no~el ~; 30 system.

- . :
:" .
.- :: .. . .
: ~- 5 ~

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~ DESCRIPTION OF PREFERRED EMBPDIMENT
- With re~erence to the Figure, tar sand slurry is introduced into a primary separation vessel 1 of conven-`~ tional designO In the vessel,floatàble bitumen in the slurry ` 5 rises to the surface of the vessel contents. Here this bitumen forms primary froth which is recovered in the launder 2.
A middlings stream is wikhdrawn through an ~; outlet 3 intermediate th~ ends of the vessel by a pump 4 and transferred through -the conduit 5 to a secondary separation vessel 6. The vessel 6 is a conventional flotation unit, wherein air is~supplied through an agitation shaft 7 to the agitator blades 8. The air becomes dispersed in the middlings ;~ in the form of fine bubbles and displaces the bitumen to the ::..
~;~ surface where it forms secondary froth. This froth is recovered in the launder 9.
,~ . .; Tailings streams are produced from the bottom outlets 10, 11 of the primary and secondary vessels 1, 6. ~-As previously stated, it is desirable to maintain the primary tailings solids content at about 70~ ~ however this is a ~; 20 stream which is difficult to pump and is subject to rapid ;;~
-~ settling out of solids. Therefore a portion of the secondary ~:1 ~ tailings, which are relatively dilute, is pumped by a variable-i speed pump 12 through a conduit 13 which connects with the downcomer conduit 14 of the primary separation vessel. The ~ 25 secondary tailings mix with the primary tailings to form a "'! dilute stream. The combined tailings stream is pumped by the variable-speed close~coupled pump 15 through the conduit ~,' 16 to a tailings distribution 17 for transfer to a settling pond.
1~30 A nuclear density gauge 18 establishes a ~ measure of the density of the combined tailings stream passing ~
'1 - ~ `
'-.': ' :
.,.~ .:

: . ~
.:, ; . , . .. .... .. " ... : .. . .

through the conduit 16, This continuous reading is trans-mi-tted to a controller on the secondary tailings pump 12 and the speed of the pump is varied to maintain the solids content i of the combined stream below 65% ~y weight, thereby ensuring pumpability and non-plugging of the conduits.
A second nuclear density guage 19 establishes a measure of the density of th~ primary tailings stream as it leaves the outlet 10. This continuous reading can be transmitted to a controller on the primary tailings pump 15 and the speed of the pump can be varied to maintain the density of the primary tailings stream close to a pre-determined value, i.e. that value corresponding to a solids content of about 70%. This method of monitoring the primary tailings solids content is particularly useful when high fines tar sand is being fed to the circuit.
l , .
In the event that low fines tar sand is being fed to the primary separation vessel, it is preferred to l establish a measure of the torque on the shaft 20 of the 1 , .. i . ,.. ;. ., l vessel rake 21. A rake torque recorder 22 can be used for .
this purpose and its signals transmitted to the controller j on the primary tailings pump 15. The speed of the pump 15 can thus be varied responsive to these signals to maintain the density of the primary tailings stream at the desired level.
The invention is characterized by several ~-advan~ages. The use of a close-coupled pump and closed conduit system ensures a responsive and safe operation. The use of the secondary tailings as a fluidizing agent for the primary tailings reduces the possibility of the contained solids settling out downstream. In addition, the water requirements ~ ;
of the process are less than would be the case if fresh water was used, as has been advocated in the prior art. Finally, the control systems used in conjunction with the pumps are particularly responsive.

Claims (5)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. In the hot water process for recovering bitumen from tar sand wherein aqueous, tar sand slurry is fed to a primary separation vessel having a sand rake and tailings outlet and conduit to produce a primary bitumen froth stream, a relatively dry primary tailings stream comprising coarse solids, and an aqueous middlings stream being processed in a secondary recovery flotation cell to produce a secondary bitumen froth stream and a relatively fluid secondary tailings stream comprising water containing fine solids, the improvement comprising the steps of:
pumping at least part of the secondary tailings stream with a variable speed pump through a conduit which joins the primary separation vessel outlet conduit and combining said stream with the primary tailings stream, said combined secondary tailings stream being supplied at a rate sufficient to produce a stream of combined tailings which is pumpable; and then pumping the combined tailings stream through a conduit with a variable-speed close-coupled pump to deliver it to a tailings distribution system, the speed of said close-coupled pump being controlled to maintain the density of the primary tailings stream close to a pre-determined value.
2. The process as set forth in claim 1 wherein:
the combined secondary tailings stream is supplied at a rate sufficient to produce a stream of combined tailings containing a maximum of 65% by weight solids.
3. The process as set forth in claim 2 comprising:

establishing a measure of the density of the combined tailings stream and controlling the speed of the secondary tailings pump relative thereto to maintain the solids content of the combined stream below about 65% by weight.
4. In combination:
primary separation vessel means for separating bitumen from an aqueous aerated tar sand slurry by flotation to produce and recover a primary bitumen froth stream, a middlings stream comprising water, fine solids and bitumen, and a primary tailings stream containing coarse solids, said vessel means having a tailings outlet at its base and a middlings outlet between its ends;
secondary recovery vessel means for separating bitumen from the middlings stream by aeration and flotation to produce and recover a secondary bitumen froth stream and a dilute aqueous secondary tailings stream containing fine solids, said secondary recovery vessel means having an inlet and a secondary tailings outlet;
means connecting the middlings outlet of the primary separation vessel with the inlet of the secondary recovery vessel for the transfer of the middlings stream therebetween;

first conduit means leading from the primary tailings outlet for the removal of the primary tailings stream;
second conduit means connecting the secondary tailings outlet with the first conduit means at a junction adjacent the primary tailings outlet for delivering at least part of the secondary tailings stream thereto to be combined with the primary tailings stream to form a pumpable mixture;
a first variable speed pump cooperating with the second conduit means to pump secondary tailings therethrough;
third conduit means connected with the outlet of the first conduit means for conveying the combined tailings stream to a distribution zone;
variable-speed close-coupled pump means cooperating with the first conduit means to pump the combined tailings stream through the third conduit; and means for controlling the speed of the close-coupled pump means to maintain the solids content of the primary tailings close to a pre-determined value.
5. The combination as set forth in claim comprising:
means for controlling the speed of the first pump responsive to the solids content of the combined tailings stream, whereby the rate at which secondary tailings is added to the primary tailings may be varied to maintain a pumpable combined tailings stream.
CA221,134A 1975-03-03 1975-03-03 System for handling the underflow from a primary separation vessel in the tar sand hot water process Expired CA1041451A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA221,134A CA1041451A (en) 1975-03-03 1975-03-03 System for handling the underflow from a primary separation vessel in the tar sand hot water process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA221,134A CA1041451A (en) 1975-03-03 1975-03-03 System for handling the underflow from a primary separation vessel in the tar sand hot water process

Publications (1)

Publication Number Publication Date
CA1041451A true CA1041451A (en) 1978-10-31

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Link
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
WO2014193605A1 (en) * 2013-05-28 2014-12-04 Flsmidth A/S Combined tailings disposal for minerals processes background of the invention

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7914670B2 (en) 2004-01-09 2011-03-29 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8685210B2 (en) 2004-01-09 2014-04-01 Suncor Energy Inc. Bituminous froth inline steam injection processing
WO2014193605A1 (en) * 2013-05-28 2014-12-04 Flsmidth A/S Combined tailings disposal for minerals processes background of the invention
US9687892B2 (en) 2013-05-28 2017-06-27 Flsmidh A/S Combined tailings disposal for minerals processes

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