BR9916426A - Composições semicristalinas de c3 etileno-propileno superior ramificado - Google Patents
Composições semicristalinas de c3 etileno-propileno superior ramificadoInfo
- Publication number
- BR9916426A BR9916426A BR9916426-4A BR9916426A BR9916426A BR 9916426 A BR9916426 A BR 9916426A BR 9916426 A BR9916426 A BR 9916426A BR 9916426 A BR9916426 A BR 9916426A
- Authority
- BR
- Brazil
- Prior art keywords
- propylene
- ethylene
- branched
- composition
- monomers
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Patente de Invenção:_<B>"COMPOSIçõES SEMICRISTALINAS DE C~ 3~ ETILENO-PROPILENO SUPERIOR RAMIFICADO"<D>. Composições de etileno-propileno ramificado as quais possuem resistência à fusão e espessamento ao casilhamento aperfeiçoados são proporcionadas. O índice médio g' de ramificação por peso com relação à região de maior peso molecular da composição de etileno-propileno é de menos do que 0,95. Adicionalmente, um novo processo é proporcionado para a produção eficiente de uma composição de etileno-propileno ramificado compreendendo: a) o contato de monómeros de propileno e monómeros de etileno em um reator em um solvente ou diluente de hidrocarboneto inerte e uma composição de catalisador compreendendo um ou mais compostos catalisadores de local único capazes da produção de um polímero de etileno-propileno em uma temperatura de cerca de 50°C a cerca de 180°C, em que a proporção, no reator, de monómeros de propileno e etileno para o solvente ou diluente de hidrocarboneto inerte é de menos do que 2,0 e, ainda, em que os monómeros de propileno e etileno e o solvente ou diluente de hidrocarboneto inerte compreendem não mais do que 90 por cento dos conteúdos totais do reator; e b) recuperação de uma composição de etileno-propileno ramificado, em que o índice de ramificação média por peso g' com relação à região de maior peso molecular da composição de etileno-propileno é de menos do que 0,95.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11322798P | 1998-12-21 | 1998-12-21 | |
PCT/US1999/029787 WO2000037514A1 (en) | 1998-12-21 | 1999-12-15 | Branched semi-crystalline ethylene-propylene compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9916426A true BR9916426A (pt) | 2001-09-04 |
Family
ID=22348278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9916426-4A BR9916426A (pt) | 1998-12-21 | 1999-12-15 | Composições semicristalinas de c3 etileno-propileno superior ramificado |
Country Status (11)
Country | Link |
---|---|
US (2) | US6573350B1 (pt) |
EP (1) | EP1141051B1 (pt) |
JP (1) | JP4860819B2 (pt) |
KR (1) | KR100653018B1 (pt) |
CN (1) | CN1234739C (pt) |
AT (1) | ATE384747T1 (pt) |
BR (1) | BR9916426A (pt) |
CA (1) | CA2356667A1 (pt) |
DE (1) | DE69938061D1 (pt) |
MX (1) | MXPA01006372A (pt) |
WO (1) | WO2000037514A1 (pt) |
Families Citing this family (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7807769B2 (en) | 2002-09-20 | 2010-10-05 | Exxonmobil Chemical Patents Inc. | Isotactic polypropylene produced from supercritical polymerization process |
CN101041701B (zh) | 2002-09-20 | 2013-02-27 | 埃克森美孚化学专利公司 | 包括丙烯的聚合物及其应用 |
US8618219B2 (en) | 2002-10-15 | 2013-12-31 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
US8653169B2 (en) | 2002-10-15 | 2014-02-18 | Exxonmobil Chemical Patents Inc. | Propylene copolymers for adhesive applications |
US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7700707B2 (en) * | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
AU2003304716A1 (en) | 2002-10-15 | 2005-11-25 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
AU2003277350A1 (en) | 2002-10-24 | 2004-05-13 | Exxonmobil Chemical Patents Inc. | Branched crystalline polypropylene |
EP1422250A1 (en) * | 2002-11-20 | 2004-05-26 | ATOFINA Research | Branched polypropylene |
US7666918B2 (en) | 2004-03-17 | 2010-02-23 | Dow Global Technologies, Inc. | Foams made from interpolymers of ethylene/α-olefins |
US7582716B2 (en) | 2004-03-17 | 2009-09-01 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack |
US7504347B2 (en) | 2004-03-17 | 2009-03-17 | Dow Global Technologies Inc. | Fibers made from copolymers of propylene/α-olefins |
US7863379B2 (en) | 2004-03-17 | 2011-01-04 | Dow Global Technologies Inc. | Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers |
US7795321B2 (en) | 2004-03-17 | 2010-09-14 | Dow Global Technologies Inc. | Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom |
US8273838B2 (en) | 2004-03-17 | 2012-09-25 | Dow Global Technologies Llc | Propylene/α-olefins block interpolymers |
US7671131B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom |
AR053693A1 (es) | 2004-03-17 | 2007-05-16 | Dow Global Technologies Inc | Composiciones de interpolimero de etileno/alfa-olefina multibloque adecuado para peliculas |
US7687442B2 (en) | 2004-03-17 | 2010-03-30 | Dow Global Technologies Inc. | Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils |
US7897689B2 (en) | 2004-03-17 | 2011-03-01 | Dow Global Technologies Inc. | Functionalized ethylene/α-olefin interpolymer compositions |
US7714071B2 (en) | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
US7524911B2 (en) | 2004-03-17 | 2009-04-28 | Dow Global Technologies Inc. | Adhesive and marking compositions made from interpolymers of ethylene/α-olefins |
US7579408B2 (en) | 2004-03-17 | 2009-08-25 | Dow Global Technologies Inc. | Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins |
US7803728B2 (en) | 2004-03-17 | 2010-09-28 | Dow Global Technologies Inc. | Fibers made from copolymers of ethylene/α-olefins |
US7741397B2 (en) | 2004-03-17 | 2010-06-22 | Dow Global Technologies, Inc. | Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof |
US7514517B2 (en) | 2004-03-17 | 2009-04-07 | Dow Global Technologies Inc. | Anti-blocking compositions comprising interpolymers of ethylene/α-olefins |
US7622529B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
JP5133050B2 (ja) | 2004-03-17 | 2013-01-30 | ダウ グローバル テクノロジーズ エルエルシー | エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物 |
US7355089B2 (en) | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7662881B2 (en) | 2004-03-17 | 2010-02-16 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
US7608668B2 (en) | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
US7622179B2 (en) | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof |
US7557147B2 (en) | 2004-03-17 | 2009-07-07 | Dow Global Technologies Inc. | Soft foams made from interpolymers of ethylene/alpha-olefins |
US7671106B2 (en) | 2004-03-17 | 2010-03-02 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
CN102936304B (zh) | 2004-03-24 | 2014-10-22 | 埃克森美孚化学专利公司 | 乙烯共聚体及其生产方法、含有乙烯共聚体的组合物和电装置 |
US7645829B2 (en) | 2004-04-15 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Plasticized functionalized propylene copolymer adhesive composition |
US7741420B2 (en) | 2004-07-14 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Polymer production at supercritical conditions |
GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
US7737061B2 (en) | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates |
US7786216B2 (en) | 2005-03-17 | 2010-08-31 | Dow Global Technologies Inc. | Oil based blends of interpolymers of ethylene/α-olefins |
JP5231987B2 (ja) | 2005-03-17 | 2013-07-10 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/α−オレフィン共重合体から製造される接着剤およびマーキング用組成物 |
US7910658B2 (en) | 2005-03-17 | 2011-03-22 | Dow Global Technologies Llc | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
US7737215B2 (en) | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
CA2601263A1 (en) | 2005-03-17 | 2006-10-26 | Dow Global Technologies Inc. | Cap liners, closures and gaskets from multi-block polymers |
US20060260031A1 (en) * | 2005-05-20 | 2006-11-23 | Conrad Joseph M Iii | Potty training device |
US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
US7928164B2 (en) | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
US7951872B2 (en) * | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
EP1896537B1 (en) | 2005-06-24 | 2017-10-11 | ExxonMobil Chemical Patents Inc. | Functionalized propylene copolymer adheside composition |
US7906587B2 (en) | 2005-09-16 | 2011-03-15 | Dow Global Technologies Llc | Polymer blends from interpolymer of ethylene/α olefin with improved compatibility |
US7695812B2 (en) | 2005-09-16 | 2010-04-13 | Dow Global Technologies, Inc. | Fibers made from copolymers of ethylene/α-olefins |
EP3216899B1 (en) | 2005-10-26 | 2021-03-24 | Dow Global Technologies LLC | A fiber comprising a low crystallinity polymer and a high crystallinity polymer |
US8153243B2 (en) | 2005-12-09 | 2012-04-10 | Dow Global Technologies Llc | Interpolymers suitable for multilayer films |
CA2630329A1 (en) | 2005-12-09 | 2007-06-14 | Dow Global Technologies Inc. | Processes of controlling molecular weight distribution in ethylene/alpha-olefin compositions |
US8143352B2 (en) | 2006-12-20 | 2012-03-27 | Exxonmobil Research And Engineering Company | Process for fluid phase in-line blending of polymers |
ATE424424T1 (de) * | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
US8080610B2 (en) | 2007-03-06 | 2011-12-20 | Exxonmobil Research And Engineering Company | Monomer recycle process for fluid phase in-line blending of polymers |
US7910637B2 (en) | 2007-09-13 | 2011-03-22 | Exxonmobil Research And Engineering Company | In-line blending of plasticizers with a base polymer |
WO2009035580A1 (en) | 2007-09-13 | 2009-03-19 | Exxonmobil Research And Engineering Company | In-line process for producing plasticized polymers and plasticized polymer blends |
EP2799235A1 (en) | 2007-10-22 | 2014-11-05 | Dow Global Technologies LLC | Multilayer films |
US7910679B2 (en) | 2007-12-20 | 2011-03-22 | Exxonmobil Research And Engineering Company | Bulk homogeneous polymerization process for ethylene propylene copolymers |
EP2231779B1 (en) | 2007-12-20 | 2012-06-06 | ExxonMobil Research and Engineering Company | In-line process to produce pellet-stable polyolefins |
CN101945940B (zh) | 2007-12-20 | 2014-04-09 | 埃克森美孚研究工程公司 | 聚丙烯乙烯-丙烯共聚物共混物和生产它的在线方法 |
DE102008005949A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
DE102008005945A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Polyolefinen mit syndiotaktischen Strukturelementen, Polyolefine und deren Verwendung |
US20110021713A1 (en) | 2008-03-13 | 2011-01-27 | Dow Global Technologies | Long chain branched (lcb), block or interconnected copolymers of ethylene in combination with one other polymer |
US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
US8399725B2 (en) * | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
US8283419B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
US8399586B2 (en) * | 2008-09-05 | 2013-03-19 | Exxonmobil Research And Engineering Company | Process for feeding ethylene to polymerization reactors |
DE102009027446A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
DE102009027447A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
DE102009027445A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
US20110054117A1 (en) * | 2009-08-27 | 2011-03-03 | Hall Gregory K | Polyolefin Adhesive Compositions and Method of Making Thereof |
US8455597B2 (en) * | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
BR112013033143A2 (pt) | 2011-06-27 | 2017-01-24 | Fuller H B Co | composição adesiva termofundida modificada por iniciador de radical livre incluindo polietileno funcionalizado e polímero de propileno-alfa-olefina |
CN103619976B (zh) | 2011-06-27 | 2016-05-04 | H.B.富勒公司 | 丙烯-α-烯烃聚合物、包含丙烯-α-烯烃聚合物的热熔粘合剂组合物以及包含其的制品 |
WO2013081742A1 (en) | 2011-12-02 | 2013-06-06 | Exxonmobil Chemical Patents Inc. | Multilayer film and method of making same |
US20140020165A1 (en) | 2012-07-20 | 2014-01-23 | For Kids By Parents, Inc. | Potty training device |
US9267060B2 (en) | 2013-02-15 | 2016-02-23 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
US9593235B2 (en) | 2013-02-15 | 2017-03-14 | H.B. Fuller Company | Reaction product of propylene polymer and wax, graft copolymers derived from polypropylene polymer and wax, hot melt adhesive compositions including the same, and methods of using and making the same |
US9376559B2 (en) * | 2013-11-22 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Reverse staged impact copolymers |
US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US9926396B2 (en) | 2015-10-23 | 2018-03-27 | Exxonmobil Chemical Patents Inc. | Production of polyolefins with internal unsaturation structures using a metallocene catalyst system |
CN106632781B (zh) * | 2015-10-29 | 2020-05-12 | 中国石油化工股份有限公司 | 具有支化结构的乙烯/丙烯共聚物的制备方法和该共聚物 |
US10882925B2 (en) | 2017-11-29 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Catalysts that produce polyethylene with broad, bimodal molecular weight distribution |
US10889663B2 (en) | 2017-11-29 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Asymmetric ANSA-metallocene catalyst compounds for producing polyolefins having a broad molecular weight distribution |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52141888A (en) | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
EP0190889B2 (en) | 1985-01-31 | 2000-07-05 | Montell North America Inc. | Polypropylene with free-end long chain branching, process for making it, and use thereof |
IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
WO1991017194A1 (en) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | UNSATURATED α-OLEFIN COPOLYMERS AND METHOD FOR PREPARATION THEREOF |
TW272985B (pt) * | 1992-09-11 | 1996-03-21 | Hoechst Ag | |
CA2145635A1 (en) * | 1992-09-29 | 1994-04-14 | Patrick Brant | Long chain branched polymers and a process to make long chain branched polymers |
US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
US5955557A (en) * | 1993-10-26 | 1999-09-21 | Idemitsu Kosan Co., Ltd. | Branched ethylenic macromonomer and its polymer |
CN1068015C (zh) * | 1994-05-24 | 2001-07-04 | 埃克森化学专利公司 | 改进的丙烯共聚物热密封树脂及其制品 |
US5766713A (en) * | 1995-06-14 | 1998-06-16 | Exxon Chemical Patents Inc. | Elastomeric vehicle hoses |
JP3486007B2 (ja) * | 1995-06-23 | 2004-01-13 | 三井化学株式会社 | シール用架橋ゴム成形体およびその製造方法 |
MX9800210A (es) | 1995-06-29 | 1998-04-30 | Dsm Nv | Copolimero elastomerico. |
JPH1072506A (ja) * | 1996-08-30 | 1998-03-17 | Mitsubishi Chem Corp | プロピレン重合用触媒およびプロピレン重合体の製造法 |
EP0855413B1 (en) * | 1997-01-23 | 2002-01-02 | JSR Corporation | Ethylene copolymer rubber composition |
DE19703478A1 (de) * | 1997-01-31 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung eines Matallocen-Katalysatorsystems |
US6303717B1 (en) * | 1997-02-05 | 2001-10-16 | The Penn State Research Foundation University Park Pa | Metal catalyzed synthesis of hyperbranched ethylene and/or α-olefin polymers |
JP4226088B2 (ja) * | 1997-06-06 | 2009-02-18 | 出光興産株式会社 | プロピレン系共重合体 |
TW482770B (en) * | 1997-08-15 | 2002-04-11 | Chisso Corp | Propylene/ethylene random copolymer, molding material, and molded article |
US6184327B1 (en) * | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
US6197910B1 (en) * | 1997-12-10 | 2001-03-06 | Exxon Chemical Patents, Inc. | Propylene polymers incorporating macromers |
-
1999
- 1999-12-15 KR KR1020017007820A patent/KR100653018B1/ko active IP Right Grant
- 1999-12-15 CN CNB998157996A patent/CN1234739C/zh not_active Expired - Lifetime
- 1999-12-15 US US09/461,797 patent/US6573350B1/en not_active Expired - Lifetime
- 1999-12-15 DE DE69938061T patent/DE69938061D1/de not_active Expired - Lifetime
- 1999-12-15 JP JP2000589583A patent/JP4860819B2/ja not_active Expired - Lifetime
- 1999-12-15 MX MXPA01006372A patent/MXPA01006372A/es not_active Application Discontinuation
- 1999-12-15 CA CA002356667A patent/CA2356667A1/en not_active Abandoned
- 1999-12-15 AT AT99966280T patent/ATE384747T1/de not_active IP Right Cessation
- 1999-12-15 WO PCT/US1999/029787 patent/WO2000037514A1/en active IP Right Grant
- 1999-12-15 EP EP99966280A patent/EP1141051B1/en not_active Expired - Lifetime
- 1999-12-15 BR BR9916426-4A patent/BR9916426A/pt not_active Application Discontinuation
-
2002
- 2002-10-23 US US10/278,666 patent/US6569965B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1141051A1 (en) | 2001-10-10 |
US6573350B1 (en) | 2003-06-03 |
CN1234739C (zh) | 2006-01-04 |
WO2000037514A1 (en) | 2000-06-29 |
JP2002533485A (ja) | 2002-10-08 |
KR100653018B1 (ko) | 2006-11-30 |
CA2356667A1 (en) | 2000-06-29 |
MXPA01006372A (es) | 2002-06-04 |
DE69938061D1 (de) | 2008-03-13 |
CN1361795A (zh) | 2002-07-31 |
US20030060583A1 (en) | 2003-03-27 |
US6569965B2 (en) | 2003-05-27 |
EP1141051B1 (en) | 2008-01-23 |
KR20010081088A (ko) | 2001-08-25 |
JP4860819B2 (ja) | 2012-01-25 |
ATE384747T1 (de) | 2008-02-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BR9916426A (pt) | Composições semicristalinas de c3 etileno-propileno superior ramificado | |
WO2000012572A8 (en) | Branched polypropylene compositions | |
US6723829B1 (en) | Heterophasic copolymers | |
CA2018666C (en) | Polypropylene resin compositions of high syndiotacticity and preparation process thereof | |
EP0381495B1 (en) | Method of production of polyethylene | |
NO944525L (no) | Fremgangsmåte for fremstilling av olefinpolymerer og polymerprodukter fremstilt ved fremgangsmåten | |
KR930023381A (ko) | 용융상태에서 개선된 가공성을 갖는 결정성 프로필렌 중합체 및 그의 제조방법 | |
RU2001117824A (ru) | Блоксополимеры на основе винилциклогексана | |
NO161803C (no) | Fremgangsmaate ved fremstilling av en blanding av propylen- og etylenpolymerer ved totrinns polymerisering. | |
WO2004046214A3 (en) | Multiple catalyst system for olefin polymerization and polymers produced therefrom | |
RU2002105010A (ru) | Композиции на основе пропиленового полимера, обладающие улучшенной ударопрочностью и отличными оптическими свойствами | |
JP7094603B2 (ja) | ブロック共重合体組成物 | |
EP0067525A2 (en) | A method for making a thermoplastic elastomer | |
ATE263786T1 (de) | Verfahren zur kontinuierlichen herstellung von polyisobuten | |
AU2240999A (en) | Improved olefin polymerization process | |
RU2005100044A (ru) | Эластичные композиции на основе сополимера пропилена, имеющие высокую степень прозрачности | |
DE69521434D1 (de) | Elastisches lineares polyethylenniedriger dichte | |
JP2854886B2 (ja) | プロピレンとブテンの共重合体 | |
EP1361232A3 (en) | Polypropylene polymers incorporating macromers | |
KR970707174A (ko) | 말단에 관능기를 갖는 폴리올레핀 제조 방법 | |
US3378607A (en) | Production of solid copolymers | |
EA199900505A2 (ru) | Смешанные титано-ванадиевые катализаторы для полимеризации олефинов в растворе и способ их получения (варианты) | |
JP2891489B2 (ja) | シンジオタクチックポリプロピレン共重合体 | |
JPS5518428A (en) | Preparation of prolylene-ethylene block copolymer | |
EP1489112A3 (en) | Polymerisation process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PRESENTE PEDIDO DE PATENTE COMO INVENCAO - DE ACORDO COM O ART 8O DA LPI. |