BR9907741A - Nitrile derivatives and their use as pesticides - Google Patents
Nitrile derivatives and their use as pesticidesInfo
- Publication number
- BR9907741A BR9907741A BR9907741-8A BR9907741A BR9907741A BR 9907741 A BR9907741 A BR 9907741A BR 9907741 A BR9907741 A BR 9907741A BR 9907741 A BR9907741 A BR 9907741A
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl
- halogen
- independently
- alkoxy
- pesticides
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/63—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
- C07C255/65—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms
- C07C255/66—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms having cyano groups and nitrogen atoms being part of hydrazine or hydrazone groups bound to the same carbon skeleton
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
- C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
- C07C311/16—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the sulfonamide groups bound to hydrogen atoms or to an acyclic carbon atom
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C317/32—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/31—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
- C07C323/33—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring
- C07C323/35—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group
- C07C323/36—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton having at least one of the nitrogen atoms bound to a carbon atom of the same non-condensed six-membered aromatic ring the thio group being a sulfide group the sulfur atom of the sulfide group being further bound to an acyclic carbon atom
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
- C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D271/08—1,2,5-Oxadiazoles; Hydrogenated 1,2,5-oxadiazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
- C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
- C07D275/03—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/70—Nitro radicals
- C07D307/71—Nitro radicals attached in position 5
- C07D307/72—Nitro radicals attached in position 5 with hydrocarbon radicals, substituted by nitrogen-containing radicals, attached in position 2
- C07D307/74—Nitro radicals attached in position 5 with hydrocarbon radicals, substituted by nitrogen-containing radicals, attached in position 2 by hydrazino or hydrazono or such substituted radicals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/42—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms with nitro or nitroso radicals directly attached to ring carbon atoms
- C07D333/44—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms with nitro or nitroso radicals directly attached to ring carbon atoms attached in position 5
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Thiazole And Isothizaole Compounds (AREA)
Abstract
Patente de Invenção: <B>"DERIVADOS NITRILA E SEU USO COMO PESTICIDAS"<D>. Compostos de fórmula onde A~ 1~ e A~ 2~ cada representa independentemente um do outro um radical arila ou heteroarila; e A~ 1~onde apropriado está substituído com substituinte (R~ 3a~)~ n1~ e A~ 2~ onde apropriado com substituinte (R~ 3b~)~ n2~; n~ 1~ e n~ 2~ são independentemente um do outro 0,1,2,3,ou 4; e ou R~ 3a~ e R~ 3b~independentemente um do outro são por exemplo, halogênio, C~ 1-6~ alquila, C~ 2-4~ alquinila, halogeno C~ 1-6~ alquila, halogeno C~ 2-4~ alquinila, C~ 1-6~ alcóxi, halogeno C~ 1-6~ alcóxi, C~ 2-6~ alquenilóxi, C~ 2-6~ alquinilóxi ou halogeno C~ 2-6~ alquenilóxi; e R~ 2~ é R~ 2a~; R~ 2a~ é por exemplo, C~ 1-6~ alquil-NR~ 11~R~ 12~, -COC~ 9-20~ alquila, C~ 1-6~ alquil-O-C~ 1-6~ alquil-O-C~ 1-6~alquila ou -CH~ 2~O(C=O)C~ 1-6~alquila; ou , pelo menos um dos radicais R~ 3a~ ou R~ 3b~ é -CR~ 5~=CR~ 5~R~ 14~, -NR~ 11~R~ 12~, -C(=O)CN, -C(=O)C(=O)O-C~ 1-6~alquila, -CR~ 7~=NOR~ 10~ ou um anel heteroarila de cinco ou seis membros ligado por um átomo de carbono; R~ 2~ é R~ 2a~ ou R~ 2b~, onde R~ 2a~ é como definido anteriormente; R~ 2b~ é por exemplo hidrogênio, -OH, C~ 1-6~ alquila ou C~ 1-6~alcóxi; R~ 14~ é, por exemplo, hidrogênio, halogênio, C~ 1-6~ alquila ou halogeno C~ 1-6~ alquila; X é O ou S; p é 0,1 ou 2; R~ 5~ é independentemente H ou C~ 1-8~ alquila; R~ 6~ é, por exemplo, independentemente H, C~ 1-8~ alquila ou C~ 3-6~ ciclo alquila; R~ 7~ é, por exemplo, H, C~ 1-8~ alquila, C~ 2-8~alquenila ou halogeno C~ 1-8~ alquila; R~ 8~ é, por exemplo, C~ 1-8~ alquila, C~ 1-8~ alquila, C~ 1-8~ alquenila ou halogeno C~ 1-8~alquila; R~ 9~ é C~ 1-6~ alquila, halogeno C~ 1-4~alquila ou arila; R~ 10~ é H, C~ 1-6~alquila , C~ 3-6~ciclo alquila, fenila ou benzila; R~ 11~ e R~ 12~ são, independentemente um do outro, H, C~ 1-6~ alquila ou fenila; e onde aplicável os possíveis isómeros E/Z, misturas de isómeros E/ZZ e/ou seus tautómeros, em forma livre ou em forma agroquimicamente aceitável, podem ser usados como ingredientes ativos agroquímicos e podem ser preparados em uma maneira conhecida.Invention Patent: <B> "NITRILLA DERIVATIVES AND THEIR USE AS PESTICIDES" <D>. Compounds of formula where A ~ 1 ~ and A ~ 2 ~ each independently represent an aryl or heteroaryl radical; and A ~ 1 ~ where appropriate is substituted with substituent (R ~ 3a ~) ~ n1 ~ and A ~ 2 ~ where appropriate with substituent (R ~ 3b ~) ~ n2 ~; n ~ 1 ~ and n ~ 2 ~ are independently of each other 0,1,2,3, or 4; and or R ~ 3a ~ and R ~ 3b ~ independently of one another are, for example, halogen, C ~ 1-6 ~ alkyl, C ~ 2-4 ~ alkynyl, C ~ 1-6 ~ alkyl, C ~ 2 halogen -4 ~ alkynyl, C ~ 1-6 ~ alkoxy, C ~ 1-6 ~ alkoxy, C ~ 2-6 ~ alkenyloxy, C ~ 2-6 ~ alkynyloxy or C ~ 2-6 ~ alkenyloxy; and R ~ 2 ~ is R ~ 2a ~; R ~ 2a ~ is for example, C ~ 1-6 ~ alkyl-NR ~ 11 ~ R ~ 12 ~, -COC ~ 9-20 ~ alkyl, C ~ 1-6 ~ alkyl-OC ~ 1-6 ~ alkyl- OC ~ 1-6 ~ alkyl or -CH ~ 2 ~ O (C = O) C ~ 1-6 ~ alkyl; or, at least one of the radicals R ~ 3a ~ or R ~ 3b ~ is -CR ~ 5 ~ = CR ~ 5 ~ R ~ 14 ~, -NR ~ 11 ~ R ~ 12 ~, -C (= O) CN, -C (= O) C (= O) OC ~ 1-6 ~ alkyl, -CR ~ 7 ~ = NOR ~ 10 ~ or a five or six membered heteroaryl ring attached by a carbon atom; R ~ 2 ~ is R ~ 2a ~ or R ~ 2b ~, where R ~ 2a ~ is as previously defined; R ~ 2b ~ is for example hydrogen, -OH, C ~ 1-6 ~ alkyl or C ~ 1-6 ~ alkoxy; R ~ 14 ~ is, for example, hydrogen, halogen, C ~ 1-6 ~ alkyl or C ~ 1-6 ~ alkyl halogen; X is O or S; p is 0.1 or 2; R ~ 5 ~ is independently H or C ~ 1-8 ~ alkyl; R ~ 6 ~ is, for example, independently H, C ~ 1-8 ~ alkyl or C ~ 3-6 ~ cycloalkyl; R ~ 7 ~ is, for example, H, C ~ 1-8 ~ alkyl, C ~ 2-8 ~ alkenyl or halogen C ~ 1-8 ~ alkyl; R ~ 8 ~ is, for example, C ~ 1-8 ~ alkyl, C ~ 1-8 ~ alkyl, C ~ 1-8 ~ alkenyl or C ~ 1-8 ~ alkyl halogen; R ~ 9 ~ is C ~ 1-6 ~ alkyl, C ~ 1-4 ~ alkyl or aryl halogen; R ~ 10 ~ is H, C ~ 1-6 ~ alkyl, C ~ 3-6 ~ cycloalkyl, phenyl or benzyl; R ~ 11 ~ and R ~ 12 ~ are, independently of one another, H, C ~ 1-6 ~ alkyl or phenyl; and where applicable the possible E / Z isomers, mixtures of E / ZZ isomers and / or their tautomers, in free form or in agrochemical acceptable form, can be used as agrochemical active ingredients and can be prepared in a known manner.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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CH14998 | 1998-01-22 | ||
CH96398 | 1998-04-29 | ||
PCT/EP1999/000363 WO1999037603A1 (en) | 1998-01-22 | 1999-01-20 | Organic nitrile derivatives and their use as pesticides |
Publications (1)
Publication Number | Publication Date |
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BR9907741A true BR9907741A (en) | 2000-10-17 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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BR9907741-8A BR9907741A (en) | 1998-01-22 | 1999-01-20 | Nitrile derivatives and their use as pesticides |
Country Status (9)
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EP (1) | EP1049663A1 (en) |
JP (1) | JP2002501038A (en) |
KR (1) | KR20010034302A (en) |
CN (1) | CN1288459A (en) |
AU (1) | AU744872B2 (en) |
BR (1) | BR9907741A (en) |
CA (1) | CA2316835A1 (en) |
TW (1) | TW436475B (en) |
WO (1) | WO1999037603A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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AU2002212696A1 (en) * | 2000-11-02 | 2002-05-15 | Nippon Soda Co., Ltd. | Organic compound having cyano group and insecticides/miticides |
DE10353205A1 (en) * | 2003-11-13 | 2005-06-16 | Aventis Pharma Deutschland Gmbh | Ortho-substituted pentafluorosulfurane-benzenes, processes for their preparation and their use as valuable synthesis intermediates |
TW201029997A (en) * | 2008-12-23 | 2010-08-16 | Basf Se | Imine compounds for combating invertebrate pests |
CA2878815A1 (en) | 2012-07-10 | 2014-01-16 | Dana-Farber Cancer Institue, Inc. | Anti-proliferative compounds and uses thereof |
CN103224470A (en) * | 2013-05-17 | 2013-07-31 | 南京农业大学 | Preparation method and application of quinoxaline-6-phenylhydrazone derivants |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
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NZ241574A (en) * | 1991-02-22 | 1993-08-26 | Ishihara Sangyo Kaisha | Substituted phenyl derivatives of hydrazone and pesticidal compositions |
TW268881B (en) * | 1992-07-07 | 1996-01-21 | Ciba Geigy Ag | |
US6306798B1 (en) * | 1996-07-24 | 2001-10-23 | Syngenta Crop Protection, Inc. | Compounds for controlling insects and representatives of the order acarina |
-
1999
- 1999-01-20 CN CN99802323A patent/CN1288459A/en active Pending
- 1999-01-20 WO PCT/EP1999/000363 patent/WO1999037603A1/en not_active Application Discontinuation
- 1999-01-20 JP JP2000528528A patent/JP2002501038A/en active Pending
- 1999-01-20 CA CA002316835A patent/CA2316835A1/en not_active Abandoned
- 1999-01-20 AU AU27181/99A patent/AU744872B2/en not_active Ceased
- 1999-01-20 EP EP99907393A patent/EP1049663A1/en not_active Withdrawn
- 1999-01-20 KR KR1020007008020A patent/KR20010034302A/en not_active Application Discontinuation
- 1999-01-20 BR BR9907741-8A patent/BR9907741A/en not_active IP Right Cessation
- 1999-01-22 TW TW088100972A patent/TW436475B/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
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TW436475B (en) | 2001-05-28 |
EP1049663A1 (en) | 2000-11-08 |
JP2002501038A (en) | 2002-01-15 |
AU744872B2 (en) | 2002-03-07 |
WO1999037603A1 (en) | 1999-07-29 |
AU2718199A (en) | 1999-08-09 |
CA2316835A1 (en) | 1999-07-29 |
KR20010034302A (en) | 2001-04-25 |
CN1288459A (en) | 2001-03-21 |
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