BR9804658A - Catalisador de complexo de metal de monociclopentadienila não ligado e processo para a produção de poliolefinas. - Google Patents

Catalisador de complexo de metal de monociclopentadienila não ligado e processo para a produção de poliolefinas.

Info

Publication number
BR9804658A
BR9804658A BR9804658-6A BR9804658A BR9804658A BR 9804658 A BR9804658 A BR 9804658A BR 9804658 A BR9804658 A BR 9804658A BR 9804658 A BR9804658 A BR 9804658A
Authority
BR
Brazil
Prior art keywords
polyolefins
production
catalyst
unalloyed
complex catalyst
Prior art date
Application number
BR9804658-6A
Other languages
English (en)
Inventor
Eric Paul Wasserman
Xinlai Bai
Elizabeth Clair Fox
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of BR9804658A publication Critical patent/BR9804658A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"CATALISADOR DE COMPLEXO DE METAL DE MONOCICLOPENTADIENILA NãO LIGADO E PROCESSO PARA A PRODUçãO DE POLIOLEFINAS". Trata-se de um catalisador que contém um percursor de metal de transição que tem a fórmula (C~ 5~R^ 1^~ 5~)MX~ 3~, um álcool, um fenol de massa substituído, um aluminoxano, e opcionalmente um material de suporte ou secagem por aspersão. Também é apresentado um processo de polimerização que emprega a composição do catalisador, um polímero produzido com o uso do catalisador e um cabo produzido a partir dele.
BR9804658-6A 1997-12-09 1998-11-17 Catalisador de complexo de metal de monociclopentadienila não ligado e processo para a produção de poliolefinas. BR9804658A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/987,753 US5962362A (en) 1997-12-09 1997-12-09 Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production

Publications (1)

Publication Number Publication Date
BR9804658A true BR9804658A (pt) 1999-12-14

Family

ID=25533528

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9804658-6A BR9804658A (pt) 1997-12-09 1998-11-17 Catalisador de complexo de metal de monociclopentadienila não ligado e processo para a produção de poliolefinas.

Country Status (5)

Country Link
US (2) US5962362A (pt)
EP (1) EP0922711A1 (pt)
JP (1) JPH11236407A (pt)
KR (1) KR19990062879A (pt)
BR (1) BR9804658A (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6127302A (en) * 1997-12-09 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US5962362A (en) * 1997-12-09 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production
US6153550A (en) * 1997-12-18 2000-11-28 Mobile Oil Corporation Olefin polymerization catalyst based on metallocene complexes and perfluorinated oligoaryl derivatives of aluminates
US6291387B1 (en) * 1998-03-20 2001-09-18 Penn State Research Foundation Transition metal-free olefin polymerization catalyst
US6489416B2 (en) 1998-03-20 2002-12-03 The Penn State Research Foundation Process for synthesizing linear polymers of ethylene and alpha-olefins
CN1419570A (zh) * 1998-07-29 2003-05-21 联合碳化化学品及塑料技术公司 具有改善的改性甲基铝氧烷容限的未桥连单环戊二烯基金属络合物催化剂
EP0989139A1 (en) * 1998-09-25 2000-03-29 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst for olefin polymerization by reacting with particulate solids with functional groups
US6340771B1 (en) * 1999-12-22 2002-01-22 Nova Chemicals (International) S. A. “Sweet” MAO
EP1383810A2 (en) * 2001-03-27 2004-01-28 Union Carbide Chemicals & Plastics Technology Corporation Gas phase process for polymers with group 4 metal complex catalyst addition
EP1406761B1 (en) * 2001-06-20 2016-11-02 ExxonMobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
JP2004530772A (ja) * 2001-06-21 2004-10-07 ハバシット アクチエンゲゼルシャフト エチレン−α−オレフィンコポリマーを用いたモノリシック・ベルト
US6982306B2 (en) * 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
EP1963379A2 (en) * 2005-12-21 2008-09-03 Albermarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
ATE441931T1 (de) * 2006-07-10 2009-09-15 Borealis Tech Oy Kabelschicht auf der basis von polypropylen mit hoher elektrischer ausfall-spannungsfestigkeit
US7884165B2 (en) 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
JP2012046560A (ja) * 2010-08-24 2012-03-08 Yokohama Rubber Co Ltd:The 熱可塑性樹脂組成物およびそれを用いた空気入りタイヤ
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
JP6887238B2 (ja) * 2016-11-15 2021-06-16 国立大学法人広島大学 フェノール変性修飾メチルアルミノキサン含有組成物
JP7175692B2 (ja) * 2018-03-26 2022-11-21 三井化学株式会社 オレフィン重合用触媒、およびオレフィン重合体の製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304588A (en) * 1989-09-28 1994-04-19 Union Carbide Chemicals & Plastics Technology Corporation Core-shell resin particle
US4994534A (en) * 1989-09-28 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Process for producing sticky polymers
JPH08231622A (ja) * 1994-12-28 1996-09-10 Idemitsu Kosan Co Ltd オレフィン重合用触媒及びそれを用いたオレフィン系重合体の製造方法
JP3572339B2 (ja) * 1995-01-26 2004-09-29 東ソー株式会社 オレフィン重合体製造用触媒、その製造方法及びそれを用いたオレフィン重合体の製造方法
TW403916B (en) * 1995-03-30 2000-09-01 Union Carbide Chem Plastic Tree resistant cable
US5831109A (en) * 1995-12-22 1998-11-03 Akzo Nobel Nv Polyalkylaluminoxane compositions formed by non-hydrolytic means
US5908903A (en) * 1995-12-27 1999-06-01 Basf Aktiengesellschaft Metallocene catalyst systems containing lewis bases
JP3537248B2 (ja) * 1996-01-24 2004-06-14 出光興産株式会社 オレフィン重合用触媒及びそれを用いたオレフィン系重合体の製造方法
US5962362A (en) * 1997-12-09 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Unbridged monocyclopentadienyl metal complex catalyst and a process for polyolefin production

Also Published As

Publication number Publication date
US6258904B1 (en) 2001-07-10
US5962362A (en) 1999-10-05
JPH11236407A (ja) 1999-08-31
KR19990062879A (ko) 1999-07-26
EP0922711A1 (en) 1999-06-16

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements