BR9801712A - Processo de polimerização em solução de alta temperatura. - Google Patents
Processo de polimerização em solução de alta temperatura.Info
- Publication number
- BR9801712A BR9801712A BR9801712-8A BR9801712A BR9801712A BR 9801712 A BR9801712 A BR 9801712A BR 9801712 A BR9801712 A BR 9801712A BR 9801712 A BR9801712 A BR 9801712A
- Authority
- BR
- Brazil
- Prior art keywords
- ligand
- high temperature
- polymerization process
- temperature solution
- molecular weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Seasonings (AREA)
- Polymerisation Methods In General (AREA)
- Advance Control (AREA)
- Executing Machine-Instructions (AREA)
- Formation Of Various Coating Films On Cathode Ray Tubes And Lamps (AREA)
Abstract
"PROCESSO DE POLIMERIZAçãO EM SOLUçãO DE ALTA TEMPERATURA". A invenção é um processo em solução para a preparação de copolímeros de etileno de alto peso molecular, compreedendo o contato de monómeros de olefina com um sistema catalisador, a uma temperatura de polimerização de ou acima de 80°C, com um sistema catalisador compreendendo um composto de metal do Grupo 4 não ligado em ponte, tendo um ligante de monociclopentadienila, um ligante de fosfinimina e pelo menos um ligante reativo de ativação não negativo. O processo pode ser praticado a uma temperatura de reação de pelo menos 80°C, para obter polímero de alto peso molecular numérico médio.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002206944A CA2206944C (en) | 1997-05-30 | 1997-05-30 | High temperature solution polymerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9801712A true BR9801712A (pt) | 1999-11-23 |
Family
ID=4160816
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9801712-8A BR9801712A (pt) | 1997-05-30 | 1998-05-27 | Processo de polimerização em solução de alta temperatura. |
Country Status (13)
Country | Link |
---|---|
US (2) | US6063879A (pt) |
EP (1) | EP0881233B1 (pt) |
JP (1) | JP4253367B2 (pt) |
CN (2) | CN1106413C (pt) |
AT (1) | ATE229986T1 (pt) |
AU (1) | AU727947B2 (pt) |
BR (1) | BR9801712A (pt) |
CA (1) | CA2206944C (pt) |
DE (1) | DE69810190T2 (pt) |
ES (1) | ES2189092T3 (pt) |
FI (1) | FI120626B (pt) |
NO (1) | NO319603B1 (pt) |
RU (1) | RU2203905C2 (pt) |
Families Citing this family (81)
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CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
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CA2347410C (en) * | 2001-05-11 | 2009-09-08 | Nova Chemicals Corporation | Solution polymerization process catalyzed by a phosphinimine catalyst |
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US6921734B2 (en) * | 2002-04-10 | 2005-07-26 | China Petroleum & Chemical Corporation | Titanocene complexes and its catalyst for preparing syndiotactic polystyrene |
EP1380601B1 (en) * | 2002-07-12 | 2005-05-25 | Saudi Basic Industries Corporation | Supported Ziegler - metallocene catalyst composition and process for olefin polymerization and olefin copolymerization with alpha olefins using novel catalyst systems |
US6740724B2 (en) * | 2002-09-20 | 2004-05-25 | Nova Chemicals (International) S. A. | Ethylene styrene copolymer with isolated styrene |
CA2411183C (en) * | 2002-11-05 | 2011-06-14 | Nova Chemicals Corporation | Heterogeneous/homogeneous copolymer |
EP1641847A2 (en) | 2003-07-09 | 2006-04-05 | DSM IP Assets B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene |
EP1506974A1 (en) | 2003-08-04 | 2005-02-16 | DSM IP Assets B.V. | Process for the preparation of a metalloorganic compound comprising at least one imine ligand |
US7547751B2 (en) | 2003-08-04 | 2009-06-16 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
WO2005014601A2 (en) * | 2003-08-04 | 2005-02-17 | Dsm Ip Assets B.V. | Process for the preparation of a polyolefin |
DE10350786A1 (de) * | 2003-10-29 | 2005-06-02 | Röhm GmbH & Co. KG | Mischungen zur Herstellung von Reaktivschmelzklebstoffen sowie daraus erhältliche Reaktivschmelzklebstoffe |
US7309741B2 (en) * | 2004-06-01 | 2007-12-18 | Nova Chemicals (International) S.A. | Polyolefin blends and pipe |
US20060189769A1 (en) * | 2005-02-22 | 2006-08-24 | Nova Chemicals (International) S.A. | Broad/bimodal resins with controlled comonomer distribution |
EP2359930A1 (en) * | 2005-12-16 | 2011-08-24 | Dow Global Technologies LLC | A polymer prepared in the presence of metal complexes bearing a polydentate heteroatom ligand |
CA2625385A1 (en) * | 2007-04-04 | 2008-10-04 | Nova Chemicals Corporation | Produce packaging |
CA2629576C (en) * | 2008-04-21 | 2016-01-05 | Nova Chemicals Corporation | Closures for bottles |
CA2695552C (en) * | 2010-03-04 | 2017-01-03 | Nova Chemicals Corporation | Process for preparing low molecular weight wax |
CA2724943A1 (en) | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
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CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
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WO2016135590A1 (en) | 2015-02-24 | 2016-09-01 | Nova Chemicals (International) S.A. | Bottle cap |
CA2891693C (en) | 2015-05-21 | 2022-01-11 | Nova Chemicals Corporation | Controlling the placement of comonomer in an ethylene copolymer |
CA2892552C (en) | 2015-05-26 | 2022-02-15 | Victoria Ker | Process for polymerization in a fluidized bed reactor |
CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
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CA2914353C (en) | 2015-12-10 | 2023-01-24 | Nova Chemicals Corp. | Hot fill process with closures made from high density polyethylene compositions |
CA2914354C (en) | 2015-12-10 | 2022-11-08 | Nova Chemicals Corp. | Hot fill process with closures made frm bimodal polyethylene compositions |
TW201800424A (zh) | 2016-02-18 | 2018-01-01 | 努發化工(國際)公司 | 溶液聚合法 |
US9783664B1 (en) | 2016-06-01 | 2017-10-10 | Nova Chemicals (International) S.A. | Hinged component comprising polyethylene composition |
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CA3152079A1 (en) | 2019-10-16 | 2021-04-22 | Nova Chemicals Corporation | Use of recycled polyethylene in closures for bottles |
BR112022014022A2 (pt) | 2020-01-17 | 2022-10-11 | Nova Chem Int Sa | Composições de copolímero de polietileno e artigos com propriedades de barreira |
CA3176143A1 (en) | 2020-04-21 | 2021-10-28 | Nova Chemicals Corporation | Cyclopentadienyl/adamantyl phosphinimine zirconium and hafnium complexes |
EP4139371A1 (en) | 2020-04-21 | 2023-03-01 | Nova Chemicals (International) S.A. | Cyclopentadienyl/adamantyl phosphinimine titanium complexes |
WO2023120668A1 (ja) * | 2021-12-23 | 2023-06-29 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法及び触媒組成物 |
CA3221979A1 (en) | 2022-03-22 | 2023-10-05 | Nova Chemicals Corporation | Organometallic complex, olefin polymerization catalyst system and polymerization process |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5264405A (en) * | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
IT1227054B (it) * | 1988-09-09 | 1991-03-14 | Enichem Anic Spa | Componente di catalizzatore per laproduzione di poliolefine ad altissimo peso molecolare. |
CA2210131C (en) * | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
-
1997
- 1997-05-30 CA CA002206944A patent/CA2206944C/en not_active Expired - Lifetime
- 1997-10-29 US US08/960,489 patent/US6063879A/en not_active Expired - Lifetime
-
1998
- 1998-04-30 AU AU63731/98A patent/AU727947B2/en not_active Expired
- 1998-05-14 FI FI981073A patent/FI120626B/fi active IP Right Grant
- 1998-05-27 BR BR9801712-8A patent/BR9801712A/pt not_active IP Right Cessation
- 1998-05-29 CN CN98109368A patent/CN1106413C/zh not_active Expired - Lifetime
- 1998-05-29 JP JP15024698A patent/JP4253367B2/ja not_active Expired - Lifetime
- 1998-05-29 NO NO19982460A patent/NO319603B1/no not_active IP Right Cessation
- 1998-05-29 RU RU98110189/04A patent/RU2203905C2/ru active
- 1998-05-29 CN CNB021228523A patent/CN1181102C/zh not_active Expired - Lifetime
- 1998-06-01 DE DE69810190T patent/DE69810190T2/de not_active Expired - Lifetime
- 1998-06-01 EP EP98304313A patent/EP0881233B1/en not_active Expired - Lifetime
- 1998-06-01 AT AT98304313T patent/ATE229986T1/de active
- 1998-06-01 ES ES98304313T patent/ES2189092T3/es not_active Expired - Lifetime
-
2000
- 2000-02-25 US US09/513,681 patent/US6342463B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6342463B1 (en) | 2002-01-29 |
CA2206944C (en) | 2006-08-29 |
CA2206944A1 (en) | 1998-11-30 |
US6063879A (en) | 2000-05-16 |
JPH10338706A (ja) | 1998-12-22 |
FI981073A (fi) | 1998-12-01 |
JP4253367B2 (ja) | 2009-04-08 |
EP0881233B1 (en) | 2002-12-18 |
CN1106413C (zh) | 2003-04-23 |
FI120626B (fi) | 2009-12-31 |
FI981073A0 (fi) | 1998-05-14 |
DE69810190D1 (de) | 2003-01-30 |
ES2189092T3 (es) | 2003-07-01 |
AU6373198A (en) | 1998-12-03 |
CN1201042A (zh) | 1998-12-09 |
AU727947B2 (en) | 2001-01-04 |
CN1181102C (zh) | 2004-12-22 |
NO319603B1 (no) | 2005-08-29 |
ATE229986T1 (de) | 2003-01-15 |
CN1438251A (zh) | 2003-08-27 |
RU2203905C2 (ru) | 2003-05-10 |
NO982460L (no) | 1998-12-01 |
NO982460D0 (no) | 1998-05-29 |
DE69810190T2 (de) | 2003-09-11 |
EP0881233A1 (en) | 1998-12-02 |
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Free format text: PATENTE EXTINTA EM 27.05.2018 |