BR112019008046A2 - um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro - Google Patents
um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferroInfo
- Publication number
- BR112019008046A2 BR112019008046A2 BR112019008046A BR112019008046A BR112019008046A2 BR 112019008046 A2 BR112019008046 A2 BR 112019008046A2 BR 112019008046 A BR112019008046 A BR 112019008046A BR 112019008046 A BR112019008046 A BR 112019008046A BR 112019008046 A2 BR112019008046 A2 BR 112019008046A2
- Authority
- BR
- Brazil
- Prior art keywords
- nitrogen oxides
- gas
- zeolite catalyst
- exchange zeolite
- removing nitrogen
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title abstract 4
- 239000007789 gas Substances 0.000 title abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052742 iron Inorganic materials 0.000 title abstract 2
- 239000010457 zeolite Substances 0.000 title abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8631—Processes characterised by a specific device
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/869—Multiple step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8696—Controlling the catalytic process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/402—Dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
Abstract
a presente invenção se refere a um método para remoção de óxidos de nitrogênio nox a partir de uma corrente gasosa. em concordância com a presente invenção, referido método compreende as etapas de passagem da corrente gasosa através de um leito catalítico de de-nox com zeólito de troca de ferro como um catalisador, com a adição de amônia como um agente de redução, em que a relação molar de nh3 sobre nox é maior do que 1,33.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15191816.6A EP3162427A1 (en) | 2015-10-28 | 2015-10-28 | A method and apparatus for removing nox and n2o from a gas |
PCT/EP2016/076152 WO2017072332A1 (en) | 2015-10-28 | 2016-10-28 | A METHOD AND APPARATUS FOR REMOVING NOx AND N2O FROM A GAS |
EP17168721.3A EP3315188A1 (en) | 2016-10-28 | 2017-04-28 | A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst |
PCT/EP2017/074368 WO2018077554A1 (en) | 2016-10-28 | 2017-09-26 | A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112019008046A2 true BR112019008046A2 (pt) | 2019-07-02 |
Family
ID=54427562
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018008653A BR112018008653A2 (pt) | 2015-10-28 | 2016-10-28 | método e aparelho para remover nox e n2o de um gás |
BR112019008046A BR112019008046A2 (pt) | 2015-10-28 | 2017-09-26 | um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018008653A BR112018008653A2 (pt) | 2015-10-28 | 2016-10-28 | método e aparelho para remover nox e n2o de um gás |
Country Status (11)
Country | Link |
---|---|
US (1) | US11325069B2 (pt) |
EP (2) | EP3162427A1 (pt) |
CN (2) | CN108136329B (pt) |
AU (2) | AU2016347643B2 (pt) |
BR (2) | BR112018008653A2 (pt) |
CA (2) | CA3000915C (pt) |
CL (1) | CL2018001131A1 (pt) |
MY (2) | MY176370A (pt) |
RU (1) | RU2712609C2 (pt) |
SA (1) | SA519401611B1 (pt) |
WO (1) | WO2017072332A1 (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2746371C2 (ru) * | 2016-09-23 | 2021-04-12 | Касале Са | Каталитический химический реактор аксиально-радиального потока с двумя слоями катализатора |
EP3532189B1 (en) | 2016-10-28 | 2024-05-15 | Casale SA | A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst |
BR112020005604A2 (pt) | 2017-11-30 | 2020-09-29 | Casale Sa | processo para a produção de ácido nítrico com redução terciária de n2o e nox |
EP3689441A1 (en) * | 2019-02-01 | 2020-08-05 | Casale Sa | Process for removing nitrogen oxides from a gas |
EP3741449A1 (en) * | 2019-05-21 | 2020-11-25 | Haldor Topsøe A/S | A process for the removal of dinitrogen oxide in process off-gas |
CN111644048B (zh) * | 2019-09-09 | 2022-01-21 | 上海浦景化工技术股份有限公司 | 脱除尾气中氮氧化物、亚硝酸烷基酯气体的工艺方法 |
Family Cites Families (40)
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US3467492A (en) | 1964-11-06 | 1969-09-16 | Chemical Construction Corp | Elimination of nitrogen oxides from gas streams |
US4081511A (en) | 1975-03-21 | 1978-03-28 | Didier Engineering Gmbh | Process for removing nitric oxides from processing exhaust gases |
US4049777A (en) | 1976-05-20 | 1977-09-20 | Didier Engineering Gmbh | Method of waste gas treatment |
GB2162830B (en) | 1984-08-10 | 1988-08-10 | Babcock Hitachi Kk | Ammonia reduction-denitration process and apparatus therefor |
US4571329A (en) * | 1984-08-13 | 1986-02-18 | Babcock-Hitachi Kabushiki Kaisha | Ammonia reduction-denitration process and apparatus therefor |
DE3532209A1 (de) | 1985-09-10 | 1987-03-12 | Didier Eng | Verfahren zur selektiven katalytischen reduktion von stickoxiden |
DE4440833A1 (de) | 1994-11-15 | 1996-02-08 | Bayerische Motoren Werke Ag | Katalysator-Anordnung zur Reduktion von Stickoxiden in sauerstoffhaltigen Abgasen einer Brennkraftmaschine, insbesondere Dieselmotor |
TW410170B (en) | 1996-07-08 | 2000-11-01 | Boc Group Inc | Removal of nitrogen oxides from gas streams |
US20040179986A1 (en) * | 1998-09-09 | 2004-09-16 | Porzellanwerk Kloster Veilsdorf Gmbh | Ceramic catalyst for the selective decomposition of N2O and method for making same |
DE19859003A1 (de) | 1998-12-21 | 2000-06-29 | Bosch Gmbh Robert | Abgasreinigung zum Reduzieren von Stickoxiden aus sauerstoffhaltigen Abgasen einer Brennkraftmaschine |
US6182443B1 (en) | 1999-02-09 | 2001-02-06 | Ford Global Technologies, Inc. | Method for converting exhaust gases from a diesel engine using nitrogen oxide absorbent |
FR2789911B1 (fr) | 1999-02-18 | 2001-05-04 | Grande Paroisse Sa | Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent |
US6182553B1 (en) | 1999-03-22 | 2001-02-06 | The United States Of America As Represented By The Secretary Of The Navy | Boat deployed explosive net assembly |
DE10001539B4 (de) * | 2000-01-14 | 2006-01-19 | Uhde Gmbh | Verfahren zur Beseitigung von NOx und N2O |
DE10001541B4 (de) * | 2000-01-14 | 2005-04-28 | Uhde Gmbh | Verfahren zur Beseitigung von NOx und N¶2¶O aus dem Restgas der Salpetersäureproduktion |
DE10020100A1 (de) * | 2000-04-22 | 2001-10-31 | Dmc2 Degussa Metals Catalysts | Verfahren und Katalysator zur Reduktion von Stickoxiden |
NL1017245C2 (nl) | 2001-01-31 | 2002-08-01 | Stichting Energie | Werkwijze voor het gelijktijdig verwijderen van stikstofoxiden en lachgas uit een stikstofoxiden en lachgas bevattende gasstroom. |
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DE102010003765A1 (de) * | 2010-04-08 | 2011-10-13 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Photovoltaik-Moduls mit rückseitenkontaktierten Halbleiterzellen |
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EP2844372B1 (de) | 2012-06-27 | 2016-06-29 | Siemens Aktiengesellschaft | Abgasreinigungsvorrichtung und verfahren zur reduktion von stickoxiden aus einem abgas einer fossil befeuerten kraftwerksanlage |
US8834823B2 (en) * | 2012-08-09 | 2014-09-16 | Exxonmobil Research And Engineering Company | Catalytic reduction of NOx with high activity catalysts |
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-
2015
- 2015-10-28 EP EP15191816.6A patent/EP3162427A1/en not_active Withdrawn
-
2016
- 2016-10-28 BR BR112018008653A patent/BR112018008653A2/pt active Search and Examination
- 2016-10-28 RU RU2018118804A patent/RU2712609C2/ru active
- 2016-10-28 AU AU2016347643A patent/AU2016347643B2/en active Active
- 2016-10-28 US US15/765,395 patent/US11325069B2/en active Active
- 2016-10-28 CA CA3000915A patent/CA3000915C/en active Active
- 2016-10-28 EP EP16788521.9A patent/EP3368194B1/en active Active
- 2016-10-28 CN CN201680059727.4A patent/CN108136329B/zh active Active
- 2016-10-28 WO PCT/EP2016/076152 patent/WO2017072332A1/en active Application Filing
- 2016-10-28 MY MYPI2018701396A patent/MY176370A/en unknown
-
2017
- 2017-09-26 CA CA3039301A patent/CA3039301C/en active Active
- 2017-09-26 MY MYPI2019002348A patent/MY196674A/en unknown
- 2017-09-26 AU AU2017349650A patent/AU2017349650B2/en active Active
- 2017-09-26 CN CN201780065577.2A patent/CN109862956A/zh active Pending
- 2017-09-26 BR BR112019008046A patent/BR112019008046A2/pt active Search and Examination
-
2018
- 2018-04-27 CL CL2018001131A patent/CL2018001131A1/es unknown
-
2019
- 2019-04-18 SA SA519401611A patent/SA519401611B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
EP3368194A1 (en) | 2018-09-05 |
US11325069B2 (en) | 2022-05-10 |
RU2018118804A3 (pt) | 2019-11-29 |
RU2712609C2 (ru) | 2020-01-29 |
EP3368194B1 (en) | 2019-08-14 |
CA3000915C (en) | 2023-04-04 |
SA519401611B1 (ar) | 2023-06-04 |
AU2017349650A1 (en) | 2019-05-02 |
CN108136329B (zh) | 2021-09-10 |
CN108136329A (zh) | 2018-06-08 |
CA3039301A1 (en) | 2018-05-03 |
BR112018008653A2 (pt) | 2018-10-30 |
US20180280873A1 (en) | 2018-10-04 |
MY196674A (en) | 2023-04-29 |
RU2018118804A (ru) | 2019-11-29 |
MY176370A (en) | 2020-08-04 |
CA3039301C (en) | 2023-10-17 |
WO2017072332A1 (en) | 2017-05-04 |
CN109862956A (zh) | 2019-06-07 |
AU2017349650B2 (en) | 2023-04-13 |
CA3000915A1 (en) | 2017-05-04 |
EP3162427A1 (en) | 2017-05-03 |
AU2016347643B2 (en) | 2021-11-04 |
AU2016347643A1 (en) | 2018-04-12 |
CL2018001131A1 (es) | 2018-08-10 |
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