BR112019008046A2 - um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro - Google Patents

um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro

Info

Publication number
BR112019008046A2
BR112019008046A2 BR112019008046A BR112019008046A BR112019008046A2 BR 112019008046 A2 BR112019008046 A2 BR 112019008046A2 BR 112019008046 A BR112019008046 A BR 112019008046A BR 112019008046 A BR112019008046 A BR 112019008046A BR 112019008046 A2 BR112019008046 A2 BR 112019008046A2
Authority
BR
Brazil
Prior art keywords
nitrogen oxides
gas
zeolite catalyst
exchange zeolite
removing nitrogen
Prior art date
Application number
BR112019008046A
Other languages
English (en)
Inventor
François Granger Jean
Original Assignee
Casale Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=54427562&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112019008046(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from EP17168721.3A external-priority patent/EP3315188A1/en
Application filed by Casale Sa filed Critical Casale Sa
Priority claimed from PCT/EP2017/074368 external-priority patent/WO2018077554A1/en
Publication of BR112019008046A2 publication Critical patent/BR112019008046A2/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/869Multiple step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8696Controlling the catalytic process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20723Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/402Dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/10Capture or disposal of greenhouse gases of nitrous oxide (N2O)

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
  • Treating Waste Gases (AREA)

Abstract

a presente invenção se refere a um método para remoção de óxidos de nitrogênio nox a partir de uma corrente gasosa. em concordância com a presente invenção, referido método compreende as etapas de passagem da corrente gasosa através de um leito catalítico de de-nox com zeólito de troca de ferro como um catalisador, com a adição de amônia como um agente de redução, em que a relação molar de nh3 sobre nox é maior do que 1,33.
BR112019008046A 2015-10-28 2017-09-26 um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro BR112019008046A2 (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP15191816.6A EP3162427A1 (en) 2015-10-28 2015-10-28 A method and apparatus for removing nox and n2o from a gas
PCT/EP2016/076152 WO2017072332A1 (en) 2015-10-28 2016-10-28 A METHOD AND APPARATUS FOR REMOVING NOx AND N2O FROM A GAS
EP17168721.3A EP3315188A1 (en) 2016-10-28 2017-04-28 A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst
PCT/EP2017/074368 WO2018077554A1 (en) 2016-10-28 2017-09-26 A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst

Publications (1)

Publication Number Publication Date
BR112019008046A2 true BR112019008046A2 (pt) 2019-07-02

Family

ID=54427562

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112018008653A BR112018008653A2 (pt) 2015-10-28 2016-10-28 método e aparelho para remover nox e n2o de um gás
BR112019008046A BR112019008046A2 (pt) 2015-10-28 2017-09-26 um método para remoção de óxidos de nitrogênio a partir de um gás utilizando um catalisador de zeólito de troca de ferro

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR112018008653A BR112018008653A2 (pt) 2015-10-28 2016-10-28 método e aparelho para remover nox e n2o de um gás

Country Status (11)

Country Link
US (1) US11325069B2 (pt)
EP (2) EP3162427A1 (pt)
CN (2) CN108136329B (pt)
AU (2) AU2016347643B2 (pt)
BR (2) BR112018008653A2 (pt)
CA (2) CA3000915C (pt)
CL (1) CL2018001131A1 (pt)
MY (2) MY176370A (pt)
RU (1) RU2712609C2 (pt)
SA (1) SA519401611B1 (pt)
WO (1) WO2017072332A1 (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2746371C2 (ru) * 2016-09-23 2021-04-12 Касале Са Каталитический химический реактор аксиально-радиального потока с двумя слоями катализатора
EP3532189B1 (en) 2016-10-28 2024-05-15 Casale SA A method for removing nitrogen oxides from a gas using an iron exchanged zeolite catalyst
BR112020005604A2 (pt) 2017-11-30 2020-09-29 Casale Sa processo para a produção de ácido nítrico com redução terciária de n2o e nox
EP3689441A1 (en) * 2019-02-01 2020-08-05 Casale Sa Process for removing nitrogen oxides from a gas
EP3741449A1 (en) * 2019-05-21 2020-11-25 Haldor Topsøe A/S A process for the removal of dinitrogen oxide in process off-gas
CN111644048B (zh) * 2019-09-09 2022-01-21 上海浦景化工技术股份有限公司 脱除尾气中氮氧化物、亚硝酸烷基酯气体的工艺方法

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Also Published As

Publication number Publication date
EP3368194A1 (en) 2018-09-05
US11325069B2 (en) 2022-05-10
RU2018118804A3 (pt) 2019-11-29
RU2712609C2 (ru) 2020-01-29
EP3368194B1 (en) 2019-08-14
CA3000915C (en) 2023-04-04
SA519401611B1 (ar) 2023-06-04
AU2017349650A1 (en) 2019-05-02
CN108136329B (zh) 2021-09-10
CN108136329A (zh) 2018-06-08
CA3039301A1 (en) 2018-05-03
BR112018008653A2 (pt) 2018-10-30
US20180280873A1 (en) 2018-10-04
MY196674A (en) 2023-04-29
RU2018118804A (ru) 2019-11-29
MY176370A (en) 2020-08-04
CA3039301C (en) 2023-10-17
WO2017072332A1 (en) 2017-05-04
CN109862956A (zh) 2019-06-07
AU2017349650B2 (en) 2023-04-13
CA3000915A1 (en) 2017-05-04
EP3162427A1 (en) 2017-05-03
AU2016347643B2 (en) 2021-11-04
AU2016347643A1 (en) 2018-04-12
CL2018001131A1 (es) 2018-08-10

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