BR112018004265A2 - composições e métodos para oligomerização seletiva de olefinas compreendendo estruturas metal-orgânicas - Google Patents
composições e métodos para oligomerização seletiva de olefinas compreendendo estruturas metal-orgânicasInfo
- Publication number
- BR112018004265A2 BR112018004265A2 BR112018004265A BR112018004265A BR112018004265A2 BR 112018004265 A2 BR112018004265 A2 BR 112018004265A2 BR 112018004265 A BR112018004265 A BR 112018004265A BR 112018004265 A BR112018004265 A BR 112018004265A BR 112018004265 A2 BR112018004265 A2 BR 112018004265A2
- Authority
- BR
- Brazil
- Prior art keywords
- metal
- compositions
- methods
- organic structures
- olefin oligomerization
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/26—Zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Lubricants (AREA)
Abstract
a presente invenção refere-se às composições e aos méto-dos para oligomerização seletiva de olefinas (por exemplo, etileno) compreendendo estruturas metal-orgânicas (mofs). em algumas mo-dalidades, uma mof compreende uma pluralidade de íons metálicos, cada um coordenado com no mínimo um ligante compreendendo no mínimo dois grupamentos aromáticos n-heterocíclicos insaturados arranjados em torno de um núcleo orgânico.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562218003P | 2015-09-14 | 2015-09-14 | |
US201662306028P | 2016-03-09 | 2016-03-09 | |
PCT/US2016/051646 WO2017048787A1 (en) | 2015-09-14 | 2016-09-14 | Compositions and methods for selective oligomerization comprising metal organic frameworks |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112018004265A2 true BR112018004265A2 (pt) | 2018-10-09 |
Family
ID=58289860
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018004265A BR112018004265A2 (pt) | 2015-09-14 | 2016-09-14 | composições e métodos para oligomerização seletiva de olefinas compreendendo estruturas metal-orgânicas |
Country Status (4)
Country | Link |
---|---|
US (1) | US10493441B2 (pt) |
CN (1) | CN108025286A (pt) |
BR (1) | BR112018004265A2 (pt) |
WO (1) | WO2017048787A1 (pt) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015171791A1 (en) | 2014-05-06 | 2015-11-12 | Massachusetts Institute Of Technology | Compositions and methods comprising conductive metal organic frameworks and uses thereof |
WO2017048795A1 (en) | 2015-09-14 | 2017-03-23 | Massachusetts Institute Of Technology | Compositions and methods for olefin polymerization comprising metal organic frameworks |
EP3463655A4 (en) | 2016-05-27 | 2020-05-06 | Massachusetts Institute Of Technology | COMPOSITIONS COMPRISING ORGANIC METAL STRUCTURES FOR THE ABSORPTION OF COMPOUNDS AND RELATED METHODS |
US11179708B2 (en) | 2016-10-04 | 2021-11-23 | Massachusetts Institute Of Technology | Compositions and methods for selective carbonylation of heterocyclic compounds |
CN109225338B (zh) * | 2018-09-14 | 2020-05-08 | 中国石油大学(北京) | 一种可循环使用的液相乙烯选择性二聚非均相催化剂及其制备方法 |
EP3947396A1 (en) * | 2019-04-01 | 2022-02-09 | ExxonMobil Research and Engineering Company | Metal-organic framework materials comprising a diimine scaffold and methods for production thereof |
US20220401936A1 (en) | 2019-09-09 | 2022-12-22 | King Abdullah University Of Science And Technology | Mof catalysts for oligomerization of olefins |
WO2021067251A1 (en) * | 2019-09-30 | 2021-04-08 | Massachusetts Institute Of Technology | Metal-organic frameworks for supercapacitor electrodes |
CN113372389B (zh) * | 2021-06-29 | 2023-03-03 | 万华化学集团股份有限公司 | 一种膦-氮配体及其制备方法和乙烯齐聚三元催化剂体系与应用 |
EP4197634A1 (en) | 2021-12-17 | 2023-06-21 | Metafuels AG | Method for converting unsaturated light hydrocarbons to unsaturated heavy hydrocarbons, metal organic framework composition to be used as catalyst, and method or preparing a metal organic framework |
WO2023128775A1 (en) * | 2021-12-29 | 2023-07-06 | Qatar Foundation For Education, Science And Community Development | High performance phosphinamine complex supported metal-organic framework for ethylene dimerization |
CN117106116B (zh) * | 2023-10-25 | 2024-02-13 | 传化智联股份有限公司 | 含有Nd和Al元素的MFU-4l催化剂及其制备和在制备聚丁二烯中的应用 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5112974A (en) | 1985-01-18 | 1992-05-12 | The Trustees Of Columbia University In The City Of New York | Mixed ligand complexes and uses thereof as binding agents to DNA |
US6989044B2 (en) | 1999-12-10 | 2006-01-24 | Praxair Technology, Inc. | Intermolecularly bound transition element complexes for oxygen-selective adsorption |
US6893564B2 (en) | 2002-05-30 | 2005-05-17 | Basf Aktiengesellschaft | Shaped bodies containing metal-organic frameworks |
US7215473B2 (en) | 2002-08-17 | 2007-05-08 | 3M Innovative Properties Company | Enhanced heat mirror films |
MX2007012388A (es) | 2005-04-07 | 2008-03-11 | Univ Michigan | Adsorcion elevada de gas en una estructura metal-organica microporosa con sitios de metal abiertos. |
GB0514478D0 (en) | 2005-07-14 | 2005-08-17 | Birkeland Innovasjon As | Compounds |
DE102005037893A1 (de) | 2005-08-10 | 2007-02-15 | Süd-Chemie AG | Verfahren zur Herstellung hochaktiver Metall/Metalloxid-Katalysatoren |
DE102005039654A1 (de) | 2005-08-22 | 2007-03-01 | Basf Ag | Mesoporöses metallorganisches Gerüstmaterial |
US7324029B2 (en) | 2006-01-26 | 2008-01-29 | Emerson Process Management | Capacitance-to-digital interface circuit for differential pressure sensor |
EP2155390B1 (de) | 2007-04-24 | 2012-10-17 | Basf Se | Metallorganische gerüstmaterialien mit hexagonal-trigonaler struktur basierend auf aluminium, eisen oder chrom, sowie einer dicarbonsäure |
RU2478602C2 (ru) | 2007-07-10 | 2013-04-10 | Басф Се | Способ отделения неразветвленных углеводородов от их разветвленных изомеров |
FR2931707B1 (fr) | 2008-05-30 | 2011-05-20 | Inst Francais Du Petrole | Systeme catalytique d'oligomerisation d'olefines a base de complexes organometalliques et de solide poreux. |
CA2742549C (en) | 2008-11-10 | 2017-07-04 | Institut National De La Recherche Scientifique | Catalyst precursors, catalysts and methods of producing same |
SG175132A1 (en) | 2009-04-08 | 2011-11-28 | Novomer Inc | Process for beta-lactone production |
US8197579B2 (en) | 2009-06-19 | 2012-06-12 | Empire Technology Development Llc | Gas storage and release using piezoelectric materials |
AU2010351979B2 (en) | 2010-04-30 | 2014-11-20 | Commonwealth Scientific And Industrial Research Organisation | Crystallisation facilitators for the synthesis of metal organic frameworks |
US9102609B2 (en) | 2010-07-20 | 2015-08-11 | The Regents Of The University Of California | Functionalization of organic molecules using metal-organic frameworks (MOFS) as catalysts |
US8835343B2 (en) * | 2010-09-27 | 2014-09-16 | Uchicago Argonne, Llc | Non-platinum group metal electrocatalysts using metal organic framework materials and method of preparation |
US8697191B2 (en) | 2010-12-07 | 2014-04-15 | Basf Se | Process for coating a support surface with a porous metal-organic framework |
WO2012138750A2 (en) | 2011-04-04 | 2012-10-11 | Massachusetts Institute Of Technology | Methods for electrochemically induced cathodic deposition of crystalline metal-organic frameworks |
FR2979836B1 (fr) * | 2011-09-08 | 2014-08-08 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de nickel et procede d'oligomerisation des olefines utilisant ladite composition |
US9272262B2 (en) | 2011-12-16 | 2016-03-01 | King Abdullah University of Science and Technology (KAUST) | Materials for gas capture, methods of making materials for gas capture, and methods of capturing gas |
GB201205365D0 (en) | 2012-03-27 | 2012-05-09 | Univ Nottingham | Frameworks |
WO2014182648A1 (en) | 2013-05-06 | 2014-11-13 | Massachusetts Institute Of Technolgy | Compositions and methods comprising porous metal organic framewroks and related uses |
US20170081345A1 (en) | 2014-03-18 | 2017-03-23 | The Regents Of The University Of California | Metal-organic frameworks characterized by having a large number of adsorption sites per unit volume |
WO2015171791A1 (en) | 2014-05-06 | 2015-11-12 | Massachusetts Institute Of Technology | Compositions and methods comprising conductive metal organic frameworks and uses thereof |
CN104001476B (zh) | 2014-05-07 | 2016-05-04 | 华南理工大学 | 一种氨气改性吸附材料及其制备方法与应用 |
WO2017048795A1 (en) | 2015-09-14 | 2017-03-23 | Massachusetts Institute Of Technology | Compositions and methods for olefin polymerization comprising metal organic frameworks |
EP3463655A4 (en) | 2016-05-27 | 2020-05-06 | Massachusetts Institute Of Technology | COMPOSITIONS COMPRISING ORGANIC METAL STRUCTURES FOR THE ABSORPTION OF COMPOUNDS AND RELATED METHODS |
US11179708B2 (en) | 2016-10-04 | 2021-11-23 | Massachusetts Institute Of Technology | Compositions and methods for selective carbonylation of heterocyclic compounds |
-
2016
- 2016-09-14 BR BR112018004265A patent/BR112018004265A2/pt not_active Application Discontinuation
- 2016-09-14 CN CN201680052674.3A patent/CN108025286A/zh active Pending
- 2016-09-14 US US15/760,104 patent/US10493441B2/en active Active
- 2016-09-14 WO PCT/US2016/051646 patent/WO2017048787A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2017048787A1 (en) | 2017-03-23 |
US10493441B2 (en) | 2019-12-03 |
US20180250664A1 (en) | 2018-09-06 |
CN108025286A (zh) | 2018-05-11 |
WO2017048787A8 (en) | 2017-04-20 |
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