BR112017015799A2 - cobalt-based fisher-tropsch synthesis catalyst and method of preparation and use thereof - Google Patents
cobalt-based fisher-tropsch synthesis catalyst and method of preparation and use thereofInfo
- Publication number
- BR112017015799A2 BR112017015799A2 BR112017015799A BR112017015799A BR112017015799A2 BR 112017015799 A2 BR112017015799 A2 BR 112017015799A2 BR 112017015799 A BR112017015799 A BR 112017015799A BR 112017015799 A BR112017015799 A BR 112017015799A BR 112017015799 A2 BR112017015799 A2 BR 112017015799A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- al2so3
- preparing
- tropsch synthesis
- cobalt
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- 229910017052 cobalt Inorganic materials 0.000 title abstract 2
- 239000010941 cobalt Substances 0.000 title abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000009792 diffusion process Methods 0.000 abstract 1
- 239000002923 metal particle Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
são descritos um catalisador de síntese fischer-tropsch à base de cobalto e método de preparo e uso do mesmo. o catalisador é constituído por um componente ativo co e um veículo composto de al2so3-sio2 aerogel, em que na base da quantidade total do catalisador, o teor de co é de 2-10% em peso, e o conteúdo do composto de al2so3-sio2 aerogel é de 90-98%; a área de superfície específica de 250-750 m²/g; tamanho médio de poro de 9-28.6 nm; e um volume de poros de 2,75-4,23 ml/g. o método de preparo do catalisador compreende: (1) preparar uma solução de al2so3; (2) preparar uma solução de sio2; e (3) preparar um composto co/al2so3-sio2 aerogel. o catalisador tem uma grande área de superfície específica e um grande tamanho de poro devido a um sistema de poros tridimensional; os componentes ativos são homogeneamente dispersos nos poros, o que não só evita a aglomeração de partículas de metal, mas também facilita a difusão dos reagentes e produtos de tal modo que o catalisador pode ser aplicado muito bem para a síntese de fischer-tropsch.A cobalt-based fischer-tropsch synthesis catalyst and method of preparation and use thereof are described. the catalyst consists of an active component co and a carrier compound of al2so3-sio2 airgel, wherein on the basis of the total amount of the catalyst the content of co is 2-10% by weight, and the content of the compound of al2so3- sio2 airgel is 90-98%; the specific surface area of 250-750 m² / g; average pore size 9-28.6 nm; and a pore volume of 2.75-4.23 ml / g. The method of preparing the catalyst comprises: (1) preparing an al2so3 solution; (2) preparing a sodium 2 solution; and (3) preparing an airborne co / al2so3-sodium2 compound. the catalyst has a large specific surface area and large pore size due to a three dimensional pore system; The active components are homogeneously dispersed in the pores, which not only prevents the agglomeration of metal particles, but also facilitates the diffusion of reagents and products such that the catalyst can be applied very well for fischer-tropsch synthesis.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510035042.3A CN104624192B (en) | 2015-01-23 | 2015-01-23 | Cobalt-based fischer-tropsch synthesis catalyst and preparation method and application |
| PCT/CN2016/071563 WO2016116055A1 (en) | 2015-01-23 | 2016-01-21 | Cobalt-based fischer-tropsch synthesis catalyst and preparation method and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112017015799A2 true BR112017015799A2 (en) | 2018-03-27 |
Family
ID=53203715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112017015799A BR112017015799A2 (en) | 2015-01-23 | 2016-01-21 | cobalt-based fisher-tropsch synthesis catalyst and method of preparation and use thereof |
Country Status (6)
| Country | Link |
|---|---|
| CN (1) | CN104624192B (en) |
| AU (2) | AU2016208857A1 (en) |
| BR (1) | BR112017015799A2 (en) |
| CA (1) | CA2974446A1 (en) |
| RU (1) | RU2661897C1 (en) |
| WO (1) | WO2016116055A1 (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104624192B (en) * | 2015-01-23 | 2017-04-12 | 武汉凯迪工程技术研究总院有限公司 | Cobalt-based fischer-tropsch synthesis catalyst and preparation method and application |
| CN105170153A (en) * | 2015-09-02 | 2015-12-23 | 浙江工业大学 | SiO2 aerogel supported Co-based catalyst and application thereof |
| FR3044004B1 (en) * | 2015-11-23 | 2017-12-15 | Ifp Energies Now | PROCESS FOR SYNTHESIZING HYDROCARBONS FROM SYNTHESIS GAS IN THE PRESENCE OF A CATALYST BASED ON COBALT TRAPS IN A MESOPOROUS OXIDE MATRIX OBTAINED FROM AT LEAST ONE COLLOIDAL PRECURSOR |
| FR3044005B1 (en) * | 2015-11-23 | 2017-12-15 | Ifp Energies Now | PROCESS FOR SYNTHESIZING HYDROCARBONS FROM SYNTHESIS GAS IN THE PRESENCE OF A CATALYST BASED ON COBALT TRAPS IN A MESOPOROUS OXIDE MATRIX AND OBTAINED FROM AT LEAST ONE MONOMERIC PRECURSOR |
| CN107185463B (en) * | 2017-06-26 | 2019-10-18 | 浙江工业大学 | A kind of SiO2-Al2O3The synthetic method of mixed oxide aerogel material |
| CN108435179B (en) * | 2018-05-04 | 2020-11-20 | 山东师范大学 | Preparation method of double-activity monatomic ammonia synthesis catalyst |
| CN110330899A (en) * | 2019-06-27 | 2019-10-15 | 浙江森井科技股份有限公司 | A kind of adhesive and preparation method thereof for photocatalyst |
| CN112705203B (en) * | 2019-10-24 | 2024-04-26 | 国家能源投资集团有限责任公司 | Composite oxide material and cobalt-based catalyst, and preparation methods and applications thereof |
| CN112973694A (en) * | 2019-12-12 | 2021-06-18 | 中国科学院大连化学物理研究所 | Aluminum element promoted disordered mesoporous silica-supported cobalt-based catalyst and preparation and application thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4717708A (en) * | 1983-12-27 | 1988-01-05 | Stauffer Chemical Company | Inorganic oxide aerogels and their preparation |
| CN1057321C (en) * | 1996-05-31 | 2000-10-11 | 中国科学院山西煤炭化学研究所 | Catalyst for preparing heavy hydrocarbon from synthesized gas and preparation method |
| US6235677B1 (en) * | 1998-08-20 | 2001-05-22 | Conoco Inc. | Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids |
| JP4429063B2 (en) * | 2003-04-07 | 2010-03-10 | 新日本製鐵株式会社 | Catalyst for producing hydrocarbon from synthesis gas, method for producing the catalyst, and method for producing hydrocarbon |
| FR2879478B1 (en) * | 2004-12-17 | 2007-10-26 | Inst Francais Du Petrole | COBALT CATALYST FOR THE FISHER-TROPSCH SYNTHESIS |
| CN101890373B (en) * | 2009-05-19 | 2012-06-27 | 中国石油化工股份有限公司 | Silica-alumina composite carrier and method for preparing same |
| CN102233282B (en) * | 2010-04-30 | 2013-06-26 | 中国石油化工股份有限公司 | Fischer-Tropsch synthesis catalyst taking silicon oxide-aluminum oxide as carrier and application thereof |
| CN104624192B (en) * | 2015-01-23 | 2017-04-12 | 武汉凯迪工程技术研究总院有限公司 | Cobalt-based fischer-tropsch synthesis catalyst and preparation method and application |
-
2015
- 2015-01-23 CN CN201510035042.3A patent/CN104624192B/en active Active
-
2016
- 2016-01-21 CA CA2974446A patent/CA2974446A1/en not_active Abandoned
- 2016-01-21 BR BR112017015799A patent/BR112017015799A2/en not_active Application Discontinuation
- 2016-01-21 RU RU2017129692A patent/RU2661897C1/en not_active IP Right Cessation
- 2016-01-21 AU AU2016208857A patent/AU2016208857A1/en not_active Abandoned
- 2016-01-21 WO PCT/CN2016/071563 patent/WO2016116055A1/en active Application Filing
-
2018
- 2018-12-18 AU AU2018282301A patent/AU2018282301A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2974446A1 (en) | 2016-07-28 |
| RU2661897C1 (en) | 2018-07-23 |
| AU2016208857A1 (en) | 2017-09-07 |
| CN104624192A (en) | 2015-05-20 |
| CN104624192B (en) | 2017-04-12 |
| WO2016116055A1 (en) | 2016-07-28 |
| AU2018282301A1 (en) | 2019-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
| B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |