BR112014012128A2 - vehicle for ethylene oxide catalysts - Google Patents

vehicle for ethylene oxide catalysts

Info

Publication number
BR112014012128A2
BR112014012128A2 BR112014012128A BR112014012128A BR112014012128A2 BR 112014012128 A2 BR112014012128 A2 BR 112014012128A2 BR 112014012128 A BR112014012128 A BR 112014012128A BR 112014012128 A BR112014012128 A BR 112014012128A BR 112014012128 A2 BR112014012128 A2 BR 112014012128A2
Authority
BR
Brazil
Prior art keywords
vehicle
ethylene oxide
oxide catalysts
catalyst
ethylene
Prior art date
Application number
BR112014012128A
Other languages
Portuguese (pt)
Other versions
BR112014012128A8 (en
Inventor
Rokicki Andrzej
Pak Serguei
kawabata Shuji
Ohashi Takayuki
Original Assignee
Scient Design Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scient Design Co filed Critical Scient Design Co
Publication of BR112014012128A2 publication Critical patent/BR112014012128A2/en
Publication of BR112014012128A8 publication Critical patent/BR112014012128A8/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/657—Pore diameter larger than 1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

resumo “veículo para catalisadores de óxido de etileno” um veículo melhorado para um catalisador de epoxidação de etileno é for-necido. o veículo inclui um componente de alumina contendo uma primeira porção de partículas de alumina tendo um tamanho de partícula primário médio de, ou maior do que, 2 µm e até 6 µm, e uma segunda porção de partículas de alumina tendo um tamanho de partícula menor do que 2 µm. um catalisador melhorado contendo o veículo descrito acima, bem como um processo melhorado para a epoxidação de etileno usando o catalisador é da mesma forma fornecido.summary "vehicle for ethylene oxide catalysts" an improved vehicle for an ethylene epoxidation catalyst is provided. the carrier includes an alumina component containing a first portion of alumina particles having an average primary particle size of or greater than 2 µm and up to 6 µm, and a second portion of alumina particles having a smaller particle size than 2 µm. an improved catalyst containing the vehicle described above, as well as an improved process for the epoxidation of ethylene using the catalyst is likewise provided.

BR112014012128A 2011-11-21 2011-11-21 vehicle for ethylene oxide catalysts BR112014012128A8 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2011/061660 WO2013077839A1 (en) 2011-11-21 2011-11-21 Carrier for ethylene oxide catalysts

Publications (2)

Publication Number Publication Date
BR112014012128A2 true BR112014012128A2 (en) 2017-06-13
BR112014012128A8 BR112014012128A8 (en) 2017-06-20

Family

ID=48470152

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014012128A BR112014012128A8 (en) 2011-11-21 2011-11-21 vehicle for ethylene oxide catalysts

Country Status (8)

Country Link
EP (1) EP2782669A4 (en)
JP (1) JP6454891B2 (en)
KR (1) KR20140104446A (en)
CN (1) CN104066504B (en)
BR (1) BR112014012128A8 (en)
CA (1) CA2856021A1 (en)
RU (1) RU2014125231A (en)
WO (1) WO2013077839A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
EP3341123B1 (en) 2015-08-28 2019-10-30 Lyondell Chemical Technology, L.P. Epoxidation catalysts
CN111655368A (en) 2018-02-07 2020-09-11 巴斯夫欧洲公司 Method for preparing silver impregnation solution
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP4271513A1 (en) * 2020-12-29 2023-11-08 Saint-Gobain Ceramics & Plastics, Inc. Ceramic article and methods of making the same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
WO1997046317A1 (en) * 1996-06-05 1997-12-11 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst and process
WO2003072246A2 (en) * 2002-02-25 2003-09-04 Shell Internationale Research Maatschappij B.V. Supported silver catalyst and an epoxidation process using the catalyst
RU2007108491A (en) * 2004-08-12 2008-09-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) METHOD FOR PREPARATION OF FORMED CATALYST, CATALYST AND APPLICATION OF SUCH CATALYST
EP1890807B1 (en) * 2005-06-07 2019-04-03 Shell International Research Maatschappij B.V. A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
KR101072239B1 (en) * 2005-06-07 2011-10-12 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 A catalyst carrier
MX2009004622A (en) * 2006-11-01 2009-05-15 Dow Global Technologies Inc Shaped porous bodies of alpha-alumina and methods for the preparation thereof.
US7714152B2 (en) * 2007-08-30 2010-05-11 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Carrier for olefin oxide catalyst
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
CN101850243B (en) * 2009-04-02 2012-07-04 中国石油化工股份有限公司 Carrier of silver catalyst for producing ethylene oxide, preparation method thereof, silver catalyst prepared by using same and application thereof in producing ethylene oxide
CN102145306B (en) * 2010-02-05 2013-05-01 中国石油化工股份有限公司 Method for adjusting properties of alumina carrier by selecting hydrated alumina with different grain size, carrier obtained by method and application
US8883678B2 (en) * 2010-06-04 2014-11-11 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
JP2014125497A (en) * 2012-12-25 2014-07-07 Mitsubishi Chemicals Corp Fluorescent resin composition and method for manufacturing the same, wavelength conversion member obtained by molding the fluorescent resin composition, and semiconductor light emission device possessing the wavelength conversion member

Also Published As

Publication number Publication date
EP2782669A1 (en) 2014-10-01
JP6454891B2 (en) 2019-01-23
CN104066504A (en) 2014-09-24
JP2015504361A (en) 2015-02-12
BR112014012128A8 (en) 2017-06-20
KR20140104446A (en) 2014-08-28
CN104066504B (en) 2017-10-10
RU2014125231A (en) 2015-12-27
WO2013077839A1 (en) 2013-05-30
EP2782669A4 (en) 2015-11-04
CA2856021A1 (en) 2013-05-30

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL

B350 Update of information on the portal [chapter 15.35 patent gazette]