BR112012021962A2 - método de reforma de gás de gasificação - Google Patents

método de reforma de gás de gasificação

Info

Publication number
BR112012021962A2
BR112012021962A2 BR112012021962A BR112012021962A BR112012021962A2 BR 112012021962 A2 BR112012021962 A2 BR 112012021962A2 BR 112012021962 A BR112012021962 A BR 112012021962A BR 112012021962 A BR112012021962 A BR 112012021962A BR 112012021962 A2 BR112012021962 A2 BR 112012021962A2
Authority
BR
Brazil
Prior art keywords
catalyst
metal catalyst
gasification gas
reforming
present
Prior art date
Application number
BR112012021962A
Other languages
English (en)
Other versions
BR112012021962B1 (pt
Inventor
Esa Kurkela
Ilkka Hiltunen
Pekka Simell
Original Assignee
Neste Oil Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Neste Oil Oyj filed Critical Neste Oil Oyj
Publication of BR112012021962A2 publication Critical patent/BR112012021962A2/pt
Publication of BR112012021962B1 publication Critical patent/BR112012021962B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/482—Gasifiers with stationary fluidised bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)

Abstract

método de reforma de gás de gasificação. a presente invenção refere-se a um método de reforma de um gás de gaseificação, de forma a decompor as impurezas compreendidas no mesmo e um novo uso de um catalisador de metal nobre pré-reforma de gás de gasificação. no presente método, o gás é mantido em contato com um catalisador de metal na presença de um agente de oxidação. de acordo com a presente invenção, a reforma é realizada em vários estágios, caso no qual pelo menos em um dos primeiros estágios, um catalisador de metal nobre é usado e, em um segundo estágio o qual segue o primeiro estágio, o catalisador usado é um catalisador de metal. o uso de um catalisador de metal nobre reduz o risco de desativação dos catalisadores de metal, e assim, aumenta a vida operacional do catalisador.
BR112012021962A 2010-03-03 2011-03-03 método de reforma de gás de gasificação BR112012021962B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20105201A FI123686B (fi) 2010-03-03 2010-03-03 Menetelmä kaasutuskaasun reformoimiseksi
PCT/FI2011/050181 WO2011107661A1 (en) 2010-03-03 2011-03-03 Method of reforming gasification gas

Publications (2)

Publication Number Publication Date
BR112012021962A2 true BR112012021962A2 (pt) 2016-06-07
BR112012021962B1 BR112012021962B1 (pt) 2018-09-25

Family

ID=42074320

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012021962A BR112012021962B1 (pt) 2010-03-03 2011-03-03 método de reforma de gás de gasificação

Country Status (9)

Country Link
US (1) US8936658B2 (pt)
EP (1) EP2542654B1 (pt)
CN (1) CN102812110B (pt)
BR (1) BR112012021962B1 (pt)
CA (1) CA2787672C (pt)
EA (1) EA025607B1 (pt)
ES (1) ES2625783T3 (pt)
FI (1) FI123686B (pt)
WO (1) WO2011107661A1 (pt)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI123686B (fi) 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi
ES2641640T3 (es) 2011-02-08 2017-11-10 Neste Oyj Método de lavado de gas en dos etapas
US20120291351A1 (en) * 2011-05-16 2012-11-22 Lawrence Bool Reforming methane and higher hydrocarbons in syngas streams
EP2530136B1 (en) 2011-05-30 2020-04-01 Neste Oyj Method of producing a hydrocarbon composition
EP2564918B1 (en) 2011-08-31 2018-03-07 Neste Oyj A two-stage gas washing method applying sulfide precipitation and alkaline absorption
ES2710851T3 (es) * 2011-09-02 2019-04-29 Neste Oyj Método para reformar gas de gasificación
CN104017610B (zh) * 2014-05-29 2015-12-02 中国天辰工程有限公司 一种高温条件下降解褐煤气化合成气中酚类的方法
JP6596888B2 (ja) * 2015-04-02 2019-10-30 株式会社Ｉｈｉ タール改質装置
US10584052B2 (en) * 2017-01-27 2020-03-10 American Air Liquide, Inc. Enhanced waste heat recovery using a pre-reformer combined with oxygen and fuel pre-heating for combustion
US20190113223A1 (en) * 2017-10-18 2019-04-18 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude METHOD FOR MINIMIZING NOx EMISSIONS DURING POX BASED SYNGAS PLANT STARTUP
SI25770A (sl) * 2019-01-07 2020-07-31 Teos Perne Postopek uplinjanja trdnih materialov z vsebnostjo ogljika, s poudarjeno koncentracijo katranov in njihovo katalitsko pretvorbo v ogljikov monoksid in vodik
CA3156317A1 (en) * 2019-10-08 2021-04-15 Teknologian Tutkimuskeskus Vtt Oy METHOD AND APPARATUS FOR REMOVING IMPURITIES FROM CARBONATING GAS AND USE
CN110846090A (zh) * 2019-12-09 2020-02-28 中城绿建科技有限公司 裂解气化装置

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
US3388074A (en) * 1963-12-26 1968-06-11 Catalysts & Chem Inc Two-stage steam reforming with rapid warm-up in first stage by means of a promoted catalyst
US4005996A (en) * 1975-09-04 1977-02-01 El Paso Natural Gas Company Methanation process for the production of an alternate fuel for natural gas
FI110691B (fi) * 2001-06-21 2003-03-14 Valtion Teknillinen Menetelmä kaasutuskaasun puhdistamiseksi
US7753973B2 (en) 2002-06-27 2010-07-13 Galloway Terry R Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions
EP1445235B1 (en) * 2003-02-05 2012-03-07 Haldor Topsoe A/S Process for treatment of synthesis gas
US20050095183A1 (en) 2003-11-05 2005-05-05 Biomass Energy Solutions, Inc. Process and apparatus for biomass gasification
MY151832A (en) * 2004-06-28 2014-07-14 Osaka Gas Co Ltd Reformed gas production method and reformed gas production apparatus
FI118647B (fi) 2006-04-10 2008-01-31 Valtion Teknillinen Menetelmä tervamaisia epäpuhtauksia sisältävän kaasun reformoimiseksi
DE102008021081A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verfahren zur katalytischen Verringerung des Teergehalts in Gasen aus Vergasungsprozessen unter Verwendung eines Katalysators auf Edelmetallbasis
DE102008021084A1 (de) 2008-04-28 2009-10-29 Süd-Chemie AG Verwendung eines Katalysators auf Edelmetallbasis zur Verringerung des Teergehalts in Gasen aus Vergasungsprozessen
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Also Published As

Publication number Publication date
CA2787672A1 (en) 2011-09-09
EA025607B1 (ru) 2017-01-30
FI20105201A0 (fi) 2010-03-03
CA2787672C (en) 2018-09-18
US20130047511A1 (en) 2013-02-28
CN102812110A (zh) 2012-12-05
EA201290812A1 (ru) 2013-03-29
US8936658B2 (en) 2015-01-20
BR112012021962B1 (pt) 2018-09-25
EP2542654A4 (en) 2014-12-03
CN102812110B (zh) 2015-04-22
WO2011107661A1 (en) 2011-09-09
ES2625783T3 (es) 2017-07-20
FI20105201A (fi) 2011-09-04
EP2542654A1 (en) 2013-01-09
FI123686B (fi) 2013-09-30
EP2542654B1 (en) 2017-04-19

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 03/03/2011, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: NESTE OYJ (FI)

B25L Entry of change of name and/or headquarter and transfer of application, patent and certificate of addition of invention: publication cancelled

Owner name: NESTE OIL OYJ (FI)

Free format text: ANULADA A PUBLICACAO CODIGO 25.1 NA RPI NO 2511 DE 19/02/2019 POR TER SIDO INDEVIDA.

B25D Requested change of name of applicant approved

Owner name: NESTE OYJ (FI)