BR112012014485A2 - processo contínuo para a carbonilação de etileno em uma fase líquida - Google Patents
processo contínuo para a carbonilação de etileno em uma fase líquidaInfo
- Publication number
- BR112012014485A2 BR112012014485A2 BR112012014485A BR112012014485A BR112012014485A2 BR 112012014485 A2 BR112012014485 A2 BR 112012014485A2 BR 112012014485 A BR112012014485 A BR 112012014485A BR 112012014485 A BR112012014485 A BR 112012014485A BR 112012014485 A2 BR112012014485 A2 BR 112012014485A2
- Authority
- BR
- Brazil
- Prior art keywords
- ethylene
- liquid phase
- carbonylation
- continuous process
- gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
''processo contínuo para a carbonilação de etileno em uma fase líquida''. um processo contínuo para carbonilação de etileno em uma fase líquida usando monóxido de carbono, um co-reagente e um sistema de catalisador adequado é descrito. o processo compreende as etapas de: (i) formar uma fase líquida que compreende o co-reagente e um sistema de catalisador adequado obtenível combinando-se: (a) um metal/composto do grupo viii; (b) um ligante da fórmula geral (i) e c) opcionalmente, uma fonte de ânions; em que q^1^ é opcionalmente fósforo; (ii) formar uma fase gasosa em contato com a fase líquida fornecendo-se pelo menos uma corrente de alimentação de entrada de gás de etileno e uma corrente de alimentação de entrada de gás de monóxido de carbono em que a razão molar de etileno: co que entra na fase líquida a partir das correntes de alimentação de entrada é maior do que 2:1; (iii) reagir etileno com monóxido de carbono na presença do co-reagente, e do sistema de catalisador adequado na fase líquida; em que a razão molar de etileno; gás co na fase gasosa está entre 20:1 e 1000:1 ou em que a razão molar de etileno: co na fase líquida é maior do que 10:1.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0921875.1A GB0921875D0 (en) | 2009-12-15 | 2009-12-15 | A continuous process for the carbonylation of ethylene |
| GB0921875.1 | 2009-12-15 | ||
| PCT/GB2010/052095 WO2011073655A1 (en) | 2009-12-15 | 2010-12-15 | A continuous process for the carbonylation of ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012014485A2 true BR112012014485A2 (pt) | 2016-08-16 |
| BR112012014485B1 BR112012014485B1 (pt) | 2018-12-18 |
Family
ID=41667108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012014485-5A BR112012014485B1 (pt) | 2009-12-15 | 2010-12-15 | processo contínuo para a carbonilação de etileno em uma fase líquida |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US8785678B2 (pt) |
| EP (1) | EP2513031B1 (pt) |
| JP (1) | JP5826764B2 (pt) |
| KR (1) | KR101814054B1 (pt) |
| CN (1) | CN102741213B (pt) |
| AU (1) | AU2010332503B2 (pt) |
| BR (1) | BR112012014485B1 (pt) |
| CA (1) | CA2783663C (pt) |
| EA (1) | EA021605B1 (pt) |
| ES (1) | ES2701014T3 (pt) |
| GB (1) | GB0921875D0 (pt) |
| MX (1) | MX2012006716A (pt) |
| MY (1) | MY161937A (pt) |
| SG (1) | SG181519A1 (pt) |
| TW (1) | TWI506017B (pt) |
| WO (1) | WO2011073655A1 (pt) |
| ZA (1) | ZA201204315B (pt) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201122054D0 (en) | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
| AU2013207783B2 (en) | 2012-01-13 | 2017-07-13 | Lummus Technology Llc | Process for providing C2 hydrocarbons via oxidative coupling of methane and for separating hydrocarbon compounds |
| US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
| AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| CA2924806C (en) | 2013-09-30 | 2021-10-19 | Dow Global Technologies Llc | Gas phase production of alkyl alkanoate |
| US10047020B2 (en) | 2013-11-27 | 2018-08-14 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| WO2015105911A1 (en) | 2014-01-08 | 2015-07-16 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
| US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
| US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
| US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
| US9328297B1 (en) * | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| EP3786138A1 (en) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative coupling of methane |
| US9944573B2 (en) | 2016-04-13 | 2018-04-17 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
| EP3554672A4 (en) | 2016-12-19 | 2020-08-12 | Siluria Technologies, Inc. | PROCEDURES AND SYSTEMS FOR CHEMICAL DEPOSITION |
| WO2018217924A1 (en) | 2017-05-23 | 2018-11-29 | Siluria Technologies, Inc. | Integration of oxidative coupling of methane processes |
| EP3649097A4 (en) | 2017-07-07 | 2021-03-24 | Lummus Technology LLC | SYSTEMS AND PROCESSES FOR THE OXIDATIVE COUPLING OF METHANE |
| CN110586102B (zh) * | 2019-08-21 | 2022-09-27 | 中山大学 | 一种类杂原子催化剂的制备方法 |
| CN114409541A (zh) * | 2020-10-28 | 2022-04-29 | 上海浦景化工技术股份有限公司 | 一种乙烯羰基化制丙酸酯类的*** |
| CN116099455B (zh) * | 2023-04-12 | 2023-07-07 | 西南化工研究设计院有限公司 | 一种基于多釜串联的羰基化反应***及方法 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0055875B1 (en) | 1981-01-06 | 1986-08-20 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of olefins |
| CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
| GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
| GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
| KR880007426A (ko) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
| GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
| US5158921A (en) | 1989-03-03 | 1992-10-27 | Shell Oil Company | Carbonylation catalyst and process |
| GB8917579D0 (en) * | 1989-08-01 | 1989-09-13 | Shell Int Research | Preparation of alkyl propionates |
| CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
| CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
| ES2088082T3 (es) | 1991-01-15 | 1996-08-01 | Shell Int Research | Carbonilacion de olefinas. |
| DE69204691T2 (de) | 1991-01-15 | 1996-04-11 | Shell Int Research | Verfahren zur Karbonylierung von Olefin. |
| DE69200122T2 (de) | 1991-02-15 | 1994-09-29 | Shell Int Research | Katalytisches System für die Carbonylierung. |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| US6156934A (en) | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
| US6706912B2 (en) | 2000-03-14 | 2004-03-16 | Shell Oil Company | Process for the carbonylation of ethylenically unsaturated compounds |
| DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
| DE10228293A1 (de) | 2001-07-28 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Dialkylketonen |
| JP4801321B2 (ja) | 2002-02-19 | 2011-10-26 | ルーサイト インターナショナル ユーケー リミテッド | エチレン性不飽和化合物のカルボニル化方法とその触媒 |
| KR100924521B1 (ko) | 2002-09-12 | 2009-11-02 | 루싸이트 인터내셔날 유케이 리미티드 | 촉매 시스템 |
| WO2004103948A1 (en) | 2003-05-22 | 2004-12-02 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of a conjugated diene |
| GB0403592D0 (en) | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
| JP2007524700A (ja) | 2004-02-26 | 2007-08-30 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エチレン的に又はアセチレン的に不飽和である化合物のカルボニル化のための方法 |
| GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
-
2009
- 2009-12-15 GB GBGB0921875.1A patent/GB0921875D0/en not_active Ceased
-
2010
- 2010-12-15 WO PCT/GB2010/052095 patent/WO2011073655A1/en active Application Filing
- 2010-12-15 KR KR1020127018433A patent/KR101814054B1/ko active IP Right Grant
- 2010-12-15 MX MX2012006716A patent/MX2012006716A/es active IP Right Grant
- 2010-12-15 US US13/515,585 patent/US8785678B2/en active Active
- 2010-12-15 TW TW099144093A patent/TWI506017B/zh active
- 2010-12-15 CA CA2783663A patent/CA2783663C/en active Active
- 2010-12-15 BR BR112012014485-5A patent/BR112012014485B1/pt active IP Right Grant
- 2010-12-15 JP JP2012543907A patent/JP5826764B2/ja active Active
- 2010-12-15 MY MYPI2012002648A patent/MY161937A/en unknown
- 2010-12-15 ES ES10795449T patent/ES2701014T3/es active Active
- 2010-12-15 EP EP10795449.7A patent/EP2513031B1/en active Active
- 2010-12-15 SG SG2012041273A patent/SG181519A1/en unknown
- 2010-12-15 EA EA201290507A patent/EA021605B1/ru not_active IP Right Cessation
- 2010-12-15 AU AU2010332503A patent/AU2010332503B2/en not_active Ceased
- 2010-12-15 CN CN201080062999.2A patent/CN102741213B/zh active Active
-
2012
- 2012-06-12 ZA ZA2012/04315A patent/ZA201204315B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012014485B1 (pt) | 2018-12-18 |
| CN102741213A (zh) | 2012-10-17 |
| CA2783663A1 (en) | 2011-06-23 |
| EA021605B1 (ru) | 2015-07-30 |
| SG181519A1 (en) | 2012-07-30 |
| US20120277474A1 (en) | 2012-11-01 |
| MY161937A (en) | 2017-05-15 |
| CN102741213B (zh) | 2015-05-27 |
| EP2513031A1 (en) | 2012-10-24 |
| ZA201204315B (en) | 2013-01-31 |
| TWI506017B (zh) | 2015-11-01 |
| AU2010332503A1 (en) | 2012-07-19 |
| WO2011073655A1 (en) | 2011-06-23 |
| US8785678B2 (en) | 2014-07-22 |
| AU2010332503B2 (en) | 2014-11-20 |
| EA201290507A1 (ru) | 2013-01-30 |
| ES2701014T3 (es) | 2019-02-20 |
| KR20120107494A (ko) | 2012-10-02 |
| GB0921875D0 (en) | 2010-01-27 |
| TW201136889A (en) | 2011-11-01 |
| MX2012006716A (es) | 2012-11-29 |
| JP2013513654A (ja) | 2013-04-22 |
| CA2783663C (en) | 2019-01-08 |
| JP5826764B2 (ja) | 2015-12-02 |
| KR101814054B1 (ko) | 2018-01-02 |
| EP2513031B1 (en) | 2018-08-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/12/2010, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25D | Requested change of name of applicant approved |
Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB) |
|
| B25I | Requirement for requested change of headquarter |
Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB) Free format text: A FIM DE ATENDER A ALTERACAO DE ENDERECO REQUERIDA ATRAVES DA PETICAO NO 870210025388 DE 17/03/2021, E NECESSARIO APRESENTAR MAIS UMA GUIA DE RECOLHIMENTO, CODIGO 248, VISTO QUE FORAM DUAS ALTERACOES DE SEDE. ALEM DISSO, E PRECISO APRESENTAR A GUIA DE CUMPRIMENTO DE EXIGENCIA. |
|
| B25L | Entry of change of name and/or headquarter and transfer of application, patent and certificate of addition of invention: publication cancelled |
Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB) Free format text: ANULADA A PUBLICACAO CODIGO 25.9 NA RPI NO 2645 DE 14/09/2021 POR TER SIDO INDEVIDA. |
|
| B25G | Requested change of headquarter approved |
Owner name: MITSUBISHI CHEMICAL UK LIMITED (GB) |