BR0311438A - Solid, heterogeneous particulate catalyst composition - Google Patents

Solid, heterogeneous particulate catalyst composition

Info

Publication number
BR0311438A
BR0311438A BR0311438-4A BR0311438A BR0311438A BR 0311438 A BR0311438 A BR 0311438A BR 0311438 A BR0311438 A BR 0311438A BR 0311438 A BR0311438 A BR 0311438A
Authority
BR
Brazil
Prior art keywords
solid
catalyst composition
heterogeneous
group
particulate catalyst
Prior art date
Application number
BR0311438-4A
Other languages
Portuguese (pt)
Inventor
Jessica A Cook
Ann Marie Schoeb-Wolters
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BR0311438A publication Critical patent/BR0311438A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"COMPOSIçãO CATALISADORA SóLIDA, HETEROGêNEA, EM PARTìCULAS". A presente invenção refere-se a uma composição catalisadora, secada por atomização, heterogênea, em partículas, sólida, para a polimerização de monómeros polimerizáveis de adição compreendendo a) um composto de metaloceno de Grupo 4; b) um complexo sólido de metal de Grupo 4 - haleto de magnésio compreendendo porções de pelo menos magnésio, um metal de transição de Grupo 4, e um haleto; c) carga inerte, finamente dividida, e d) um aglutinante opcional capaz de ligar componentes a) e b) e/ou c) em um aglomerado heterogêneo, em partículas, sem adversamente afetar as propriedades catalíticas deste; e um método para a fabricação desta compreendendo formar uma mistura da composição acima em um diluente líquido e secar por atomização a mesma para remover diluente."SOLID, Heterogeneous CATALYST COMPOSITION IN PARTICULES". The present invention relates to a solid, heterogeneous, particulate, spray-dried catalyst composition for the polymerization of addition polymerizable monomers comprising a) a Group 4 metallocene compound; b) a solid Group 4 - magnesium halide metal complex comprising portions of at least magnesium, a Group 4 transition metal, and a halide; c) finely divided inert filler; and d) an optional binder capable of binding components a) and b) and / or c) into a heterogeneous particulate agglomerate without adversely affecting its catalytic properties; and a method of manufacturing it comprising forming a mixture of the above composition in a liquid diluent and spray drying it to remove diluent.

BR0311438-4A 2002-06-03 2003-05-22 Solid, heterogeneous particulate catalyst composition BR0311438A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38579602P 2002-06-03 2002-06-03
PCT/US2003/016266 WO2003102037A1 (en) 2002-06-03 2003-05-22 Solid, particulated, spray dried, heterogenous catalyst composition

Publications (1)

Publication Number Publication Date
BR0311438A true BR0311438A (en) 2005-03-22

Family

ID=29712212

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0311438-4A BR0311438A (en) 2002-06-03 2003-05-22 Solid, heterogeneous particulate catalyst composition

Country Status (7)

Country Link
EP (1) EP1509552A1 (en)
JP (1) JP2005526175A (en)
CN (1) CN1284805C (en)
AU (1) AU2003233649B2 (en)
BR (1) BR0311438A (en)
CA (1) CA2482640A1 (en)
WO (1) WO2003102037A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100471882C (en) 2003-11-20 2009-03-25 联合碳化化学及塑料技术有限责任公司 Spray-dried, mixed metal ziegler catalyst compositions
US20050182210A1 (en) * 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
US7973112B2 (en) 2004-02-17 2011-07-05 Univation Technologies, Llc De-foaming spray dried catalyst slurries
CN102492062B (en) * 2011-11-11 2014-03-26 上海立得催化剂有限公司 Preparation method for self-forming vinyl polymerization catalyst granules
US8653208B2 (en) * 2012-05-18 2014-02-18 Union Carbide Chemicals & Plastics Technology Llc Process for preparing catalysts and catalysts made thereby
KR102135226B1 (en) * 2013-01-14 2020-07-20 유니베이션 테크놀로지즈, 엘엘씨 Methods for preparing catalyst systems with increased productivity
US11008412B2 (en) * 2016-09-29 2021-05-18 Dow Global Technologies Llc Method of polymerizing an olefin
CN110267994A (en) 2016-12-22 2019-09-20 埃克森美孚化学专利公司 The olefin Polymerization catalyst compositions of spray drying and the polymerization for using it
BR112020018781A2 (en) 2018-03-26 2020-10-13 Dow Global Technologies Llc spray dried zirconocene catalyst system
KR20240017932A (en) * 2021-06-10 2024-02-08 다우 글로벌 테크놀로지스 엘엘씨 Catalyst compositions with modified activity and their manufacturing processes

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290745A (en) * 1992-08-10 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
US5648310A (en) * 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
CA2142669C (en) * 1994-02-17 1999-11-23 Eric Paul Wasserman Spray dried metallocene catalyst composition for use in polyolefin manufacture
ES2150529T3 (en) * 1994-04-07 2000-12-01 Bp Chem Int Ltd POLYMERIZATION PROCEDURE.
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
JP4553986B2 (en) * 1996-06-21 2010-09-29 ダブリュー・アール・グレース・アンド・カンパニー−コーン Frangible spray-dried agglomerated carrier, process for producing such carrier and olefin polymerization catalyst supported thereon
US6313061B1 (en) * 1998-12-22 2001-11-06 W. R. Grace & Co.-Conn. Method of making frangible spray dried agglomerated supports and olefin polymerization catalysts supported thereon
EP1335792A1 (en) * 2000-10-24 2003-08-20 MERCK PATENT GmbH Catalyst support, production and use thereof in the polymerization of olefins
BR0116461A (en) * 2000-12-04 2003-09-23 Univation Tech Llc Polymerization Process
CN101062959A (en) * 2001-11-30 2007-10-31 尤尼威蒂恩技术有限责任公司 Method of making mixed ziegler-natta/metallocece catalysts

Also Published As

Publication number Publication date
CN1284805C (en) 2006-11-15
AU2003233649A1 (en) 2003-12-19
CN1653093A (en) 2005-08-10
EP1509552A1 (en) 2005-03-02
CA2482640A1 (en) 2003-12-11
JP2005526175A (en) 2005-09-02
WO2003102037A1 (en) 2003-12-11
AU2003233649B2 (en) 2006-04-13

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