BR0208592A - Aparelho para um processo fischer-tropsch e processo para remover o enxofre de um gás de sìntese em um reator fischer-tropsch - Google Patents
Aparelho para um processo fischer-tropsch e processo para remover o enxofre de um gás de sìntese em um reator fischer-tropschInfo
- Publication number
- BR0208592A BR0208592A BR0208592-5A BR0208592A BR0208592A BR 0208592 A BR0208592 A BR 0208592A BR 0208592 A BR0208592 A BR 0208592A BR 0208592 A BR0208592 A BR 0208592A
- Authority
- BR
- Brazil
- Prior art keywords
- fischer
- sulfur
- tropsch
- reactor
- ppbp
- Prior art date
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 10
- 229910052717 sulfur Inorganic materials 0.000 title abstract 10
- 239000011593 sulfur Substances 0.000 title abstract 10
- 238000000034 method Methods 0.000 title abstract 5
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000003463 adsorbent Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00654—Controlling the process by measures relating to the particulate material
- B01J2208/00707—Fouling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"APARELHO PAPA UM PROCESSO FISCHER-TROPSCH E PROCESSO PARA REMOVER O ENXOFRE DE UM GáS DE SìNTESE EM UM REATOR FISCHER-TROPSCH". Os métodos para remover enxofre de syngas em um reator Fischer-Tropsch e reatores que incluem meios para remover enxofre de syngas são divulgados. Metais reativos ao enxofre podem ser usados na unidade Fischer-Tropsch para separar o enxofre. Por exemplo, a unidade Fischer-Tropsch pode funcionar em estágios, usando-se um catalisador de sacrifício em um primeiro estágio para adsorver o enxofre. O reator de Fischer-Tropsch pode incluir defletores internos que separam o reator em zonas, com um catalisador de sacrifício em uma ou mais das zonas, que pode ser facilmente separado e regenerado ou substituído. Os adsorventes de enxofre podem ser colocados nos canos do gás de entrada. Uma porção do catalisador de Fischer-Tropsch pode ser convertida e permanecer perto da entrada de gás onde esta adsorve e seq³estra o enxofre. Estas formas de realização podem ser combinadas de qualquer maneira adequada para diminuir a concentração de enxofre na alimentação do syngas. A alimentação de syngas resultante, preferivelmente tem uma concentração de enxofre menor do que 50 ppbp, mais preferivelmente menor do que 15 ppbp e mais preferivelmente menor do que 1 ppbp.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/842,673 US6682711B2 (en) | 2001-04-27 | 2001-04-27 | Protection of Fischer-Tropsch catalysts from traces of sulfur |
PCT/US2002/009673 WO2002087743A1 (en) | 2001-04-27 | 2002-03-29 | Protection of fischer-tropsch catalysts from traces of sulfur |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0208592A true BR0208592A (pt) | 2004-03-23 |
Family
ID=25287959
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0208592-5A BR0208592A (pt) | 2001-04-27 | 2002-03-29 | Aparelho para um processo fischer-tropsch e processo para remover o enxofre de um gás de sìntese em um reator fischer-tropsch |
Country Status (8)
Country | Link |
---|---|
US (2) | US6682711B2 (pt) |
JP (1) | JP4434588B2 (pt) |
AU (1) | AU783424B2 (pt) |
BR (1) | BR0208592A (pt) |
GB (1) | GB2379620B (pt) |
NL (1) | NL1020496C2 (pt) |
WO (1) | WO2002087743A1 (pt) |
ZA (1) | ZA200202852B (pt) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6962683B2 (en) * | 2002-07-15 | 2005-11-08 | Research Triangle Institute | Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases |
US7892511B2 (en) * | 2004-07-02 | 2011-02-22 | Kellogg Brown & Root Llc | Pseudoisothermal ammonia process |
US20060149423A1 (en) * | 2004-11-10 | 2006-07-06 | Barnicki Scott D | Method for satisfying variable power demand |
US8455556B2 (en) | 2006-07-14 | 2013-06-04 | Shell Oil Company | Fischer-Tropsch catalyst |
WO2009118372A1 (en) * | 2008-03-28 | 2009-10-01 | Shell Internationale Research Maatschappij B.V. | Process for regenerating a catalyst |
US8518357B2 (en) * | 2008-05-05 | 2013-08-27 | The Trustees Of Columbia University In The City Of New York | Systems and methods for sequestering sulfur |
GB201000971D0 (en) * | 2010-01-21 | 2010-03-10 | Johnson Matthey Plc | Process for the convertion of synthesis gas |
GB201000993D0 (en) | 2010-01-22 | 2010-03-10 | Johnson Matthey Plc | Catalyst support |
GB2546929B (en) * | 2010-09-13 | 2018-04-04 | Lummus Technology Inc | Low temperature sulfur tolerant and sulfur removal with concomitant synthesis gas conditioning |
US8685146B2 (en) | 2012-05-01 | 2014-04-01 | Uop Llc | Processes and apparatuses for preparing liquified natural gas |
FI127086B (en) * | 2013-10-10 | 2017-11-15 | Teknologian Tutkimuskeskus Vtt Oy | Process and apparatus for producing a hydrocarbon fraction and hydrocarbon fraction and its use |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2450500A (en) * | 1945-09-05 | 1948-10-05 | Phillips Petroleum Co | Synthesis of hydrocarbons |
US4088735A (en) | 1974-07-10 | 1978-05-09 | Metallgesellschaft Aktiengesellschaft | Process for purifying gases from the gasification of fossil fuels |
US3941820A (en) | 1975-01-09 | 1976-03-02 | Continental Oil Company | Predominantly aliphatic hydrocarbon materials from carbonaceous solids |
FR2460990A1 (fr) | 1979-07-09 | 1981-01-30 | Inst Francais Du Petrole | Procede et appareil de conversion catalytique d'hydrocarbures |
DK144530C (da) * | 1979-12-18 | 1982-09-06 | Topsoee H A S | Fremgangsmaade til fremstilling af en gasblanding med hoejt indhold af metan |
US4539334A (en) | 1983-11-14 | 1985-09-03 | The Dow Chemical Company | Selective poisoning of Fischer-Tropsch catalysts |
US4831060A (en) * | 1984-07-30 | 1989-05-16 | The Dow Chemical Company | Mixed alcohols production from syngas |
US4624968A (en) | 1985-12-30 | 1986-11-25 | Exxon Research And Engineering Company | Multi-stage Fischer-Tropsch process |
US5621155A (en) | 1986-05-08 | 1997-04-15 | Rentech, Inc. | Process for the production of hydrocarbons |
US4857559A (en) | 1987-10-23 | 1989-08-15 | Gas-To-Oil, Inc. | Process for production of hydrocarbons |
US5182248A (en) | 1991-05-10 | 1993-01-26 | Exxon Research And Engineering Company | High porosity, high surface area isomerization catalyst |
CA2105940C (en) | 1992-10-05 | 2001-12-25 | Robert M. Koros | Bubble column, tube side slurry process and apparatus |
US5260239A (en) | 1992-12-18 | 1993-11-09 | Exxon Research & Engineering Company | External catalyst rejuvenation system for the hydrocarbon synthesis process |
EP0958237B1 (en) | 1996-04-23 | 2002-06-26 | ExxonMobil Research and Engineering Company | Process for removal of hydrogen cyanide from synthesis gas |
IT1283774B1 (it) | 1996-08-07 | 1998-04-30 | Agip Petroli | Processo di fischer-tropsch con reattore a colonna a bolle multistadio |
US5928980A (en) | 1997-02-06 | 1999-07-27 | Research Triangle Institute | Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts |
CA2294456C (en) | 1997-06-24 | 2009-04-28 | Process Dynamics, Inc. | Two phase hydroprocessing |
US5882614A (en) | 1998-01-23 | 1999-03-16 | Exxon Research And Engineering Company | Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes |
US6566411B2 (en) | 2001-02-20 | 2003-05-20 | Chevron U.S.A. Inc. | Removing sulfur from hydroprocessed fischer-tropsch products |
-
2001
- 2001-04-27 US US09/842,673 patent/US6682711B2/en not_active Expired - Lifetime
-
2002
- 2002-03-29 WO PCT/US2002/009673 patent/WO2002087743A1/en active Application Filing
- 2002-03-29 BR BR0208592-5A patent/BR0208592A/pt not_active Application Discontinuation
- 2002-03-29 JP JP2002585077A patent/JP4434588B2/ja not_active Expired - Fee Related
- 2002-04-08 AU AU32985/02A patent/AU783424B2/en not_active Ceased
- 2002-04-11 ZA ZA200202852A patent/ZA200202852B/xx unknown
- 2002-04-26 GB GB0209629A patent/GB2379620B/en not_active Expired - Fee Related
- 2002-04-26 NL NL1020496A patent/NL1020496C2/nl not_active IP Right Cessation
-
2003
- 2003-09-23 US US10/667,443 patent/US20040126296A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JP2004530747A (ja) | 2004-10-07 |
JP4434588B2 (ja) | 2010-03-17 |
GB0209629D0 (en) | 2002-06-05 |
GB2379620B (en) | 2003-09-17 |
NL1020496C2 (nl) | 2002-11-12 |
WO2002087743A1 (en) | 2002-11-07 |
ZA200202852B (en) | 2002-11-22 |
US6682711B2 (en) | 2004-01-27 |
AU783424B2 (en) | 2005-10-27 |
US20020187094A1 (en) | 2002-12-12 |
GB2379620A (en) | 2003-03-19 |
AU3298502A (en) | 2002-10-31 |
US20040126296A1 (en) | 2004-07-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
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