BE511152A - - Google Patents

Info

Publication number

BE511152A

BE511152A BE511152DA BE511152A BE 511152 A BE511152 A BE 511152A BE 511152D A BE511152D A BE 511152DA BE 511152 A BE511152 A BE 511152A

Authority

BE

Belgium

Prior art keywords

water

cobalt

gas

sep

compounds

Prior art date

Links

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• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 46
• 239000007789 gas Substances 0.000 claims description 44
• 125000004043 oxo group Chemical group O=* 0.000 claims description 23
• 230000015572 biosynthetic process Effects 0.000 claims description 16
• 239000003054 catalyst Substances 0.000 claims description 16
• 238000006243 chemical reaction Methods 0.000 claims description 16
• 238000003786 synthesis reaction Methods 0.000 claims description 15
• 230000002194 synthesizing Effects 0.000 claims description 15
• 239000000203 mixture Substances 0.000 claims description 13
• WHWBTOCNUBAGRL-UHFFFAOYSA-N cobalt;formaldehyde Chemical group [Co].O=C WHWBTOCNUBAGRL-UHFFFAOYSA-N 0.000 claims description 11
• 239000007864 aqueous solution Substances 0.000 claims description 8
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
• 239000010941 cobalt Substances 0.000 claims description 7
• 229910052803 cobalt Inorganic materials 0.000 claims description 7
• 238000002360 preparation method Methods 0.000 claims description 7
• 150000001869 cobalt compounds Chemical class 0.000 claims description 6
• XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
• 150000001299 aldehydes Chemical class 0.000 claims description 5
• 239000007900 aqueous suspension Substances 0.000 claims description 3
• 229910052742 iron Inorganic materials 0.000 claims description 3
• 238000000034 method Methods 0.000 claims description 3
• 239000007858 starting material Substances 0.000 claims description 3
• UMYVESYOFCWRIW-UHFFFAOYSA-N cobalt;methanone Chemical class O=C=[Co] UMYVESYOFCWRIW-UHFFFAOYSA-N 0.000 claims description 2
• 150000002894 organic compounds Chemical class 0.000 claims description 2
• 229920000642 polymer Polymers 0.000 claims description 2
• 238000006555 catalytic reaction Methods 0.000 claims 1
• 229920001098 polystyrene-block-poly(ethylene/propylene) Polymers 0.000 description 54
• 239000000243 solution Substances 0.000 description 10
• -1 cobalt carbon compounds Chemical class 0.000 description 9
• 229910000831 Steel Inorganic materials 0.000 description 7
• 239000011630 iodine Substances 0.000 description 7
• PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 7
• 229910052740 iodine Inorganic materials 0.000 description 7
• 239000010959 steel Substances 0.000 description 7
• 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 6
• 150000001336 alkenes Chemical class 0.000 description 5
• 239000000919 ceramic Substances 0.000 description 5
• 229910052751 metal Inorganic materials 0.000 description 5
• 239000002184 metal Substances 0.000 description 5
• 239000000725 suspension Substances 0.000 description 4
• 239000008346 aqueous phase Substances 0.000 description 3
• 239000007795 chemical reaction product Substances 0.000 description 3
• 229910021446 cobalt carbonate Inorganic materials 0.000 description 3
• 150000002430 hydrocarbons Chemical class 0.000 description 3
• 239000000047 product Substances 0.000 description 3
• 238000003756 stirring Methods 0.000 description 3
• 239000004215 Carbon black (E152) Substances 0.000 description 2
• KTVIXTQDYHMGHF-UHFFFAOYSA-L Cobalt(II) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
• 238000010521 absorption reaction Methods 0.000 description 2
• 238000007792 addition Methods 0.000 description 2
• UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
• 229910002091 carbon monoxide Inorganic materials 0.000 description 2
• 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
• 229940044175 cobalt sulfate Drugs 0.000 description 2
• 229910000361 cobalt sulfate Inorganic materials 0.000 description 2
• ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 2
• AVWLPUQJODERGA-UHFFFAOYSA-L cobalt(2+);diiodide Chemical compound [Co+2].[I-].[I-] AVWLPUQJODERGA-UHFFFAOYSA-L 0.000 description 2
• 238000001816 cooling Methods 0.000 description 2
• 150000002148 esters Chemical class 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
• 150000002739 metals Chemical class 0.000 description 2
• 239000003921 oil Substances 0.000 description 2
• 239000012188 paraffin wax Substances 0.000 description 2
• BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
• 229910052709 silver Inorganic materials 0.000 description 2
• 239000004332 silver Substances 0.000 description 2
• 230000001131 transforming Effects 0.000 description 2
• KSMVZQYAVGTKIV-UHFFFAOYSA-N Decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 description 1
• 240000007817 Olea europaea Species 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
• 150000001728 carbonyl compounds Chemical class 0.000 description 1
• 230000003197 catalytic Effects 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 238000000576 coating method Methods 0.000 description 1
• PJQDFOMVKDFESH-UHFFFAOYSA-N cobalt(2+);N-(9H-fluoren-2-yl)-N-oxidoacetamide Chemical class [Co+2].C1=CC=C2C3=CC=C(N([O-])C(=O)C)C=C3CC2=C1.C1=CC=C2C3=CC=C(N([O-])C(=O)C)C=C3CC2=C1 PJQDFOMVKDFESH-UHFFFAOYSA-N 0.000 description 1
• MEYVLGVRTYSQHI-UHFFFAOYSA-L cobalt(2+);sulfate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Co+2].[O-]S([O-])(=O)=O MEYVLGVRTYSQHI-UHFFFAOYSA-L 0.000 description 1
• 239000011889 copper foil Substances 0.000 description 1
• 239000012043 crude product Substances 0.000 description 1
• ZSKCOFJBFXSEDP-UHFFFAOYSA-N formaldehyde;molecular hydrogen Chemical compound [H][H].O=C ZSKCOFJBFXSEDP-UHFFFAOYSA-N 0.000 description 1
• 238000005755 formation reaction Methods 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 239000002245 particle Substances 0.000 description 1
• 238000006116 polymerization reaction Methods 0.000 description 1
• 244000144977 poultry Species 0.000 description 1
• 238000000746 purification Methods 0.000 description 1