AU645557B2 - Gas detection by infrared absorption - Google Patents
Gas detection by infrared absorption Download PDFInfo
- Publication number
- AU645557B2 AU645557B2 AU76122/91A AU7612291A AU645557B2 AU 645557 B2 AU645557 B2 AU 645557B2 AU 76122/91 A AU76122/91 A AU 76122/91A AU 7612291 A AU7612291 A AU 7612291A AU 645557 B2 AU645557 B2 AU 645557B2
- Authority
- AU
- Australia
- Prior art keywords
- signal
- representative
- output signal
- radiation
- infrared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000001514 detection method Methods 0.000 title description 7
- 238000010521 absorption reaction Methods 0.000 title description 5
- 230000005855 radiation Effects 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 12
- 238000005070 sampling Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 27
- 239000002360 explosive Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000004308 accommodation Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/10—Photometry, e.g. photographic exposure meter by comparison with reference light or electric value provisionally void
- G01J1/16—Photometry, e.g. photographic exposure meter by comparison with reference light or electric value provisionally void using electric radiation detectors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
- G01N21/3504—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/42—Photometry, e.g. photographic exposure meter using electric radiation detectors
- G01J2001/4242—Modulated light, e.g. for synchronizing source and detector circuit
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Description
3 .64 555 7 COMMONWEALTH OF AUSTRALIA PATENTS ACT 1952 Form COMPLETE SPECIFICATION
(ORIGINAL)
FOR OFFICE USE Short Title: Int Cl: Application Number: PK0010 Lodged: 7 May 1990 a S Complete Specification-Lodged: Accepted: Lapsed: Published: S Priority: Related Art: B *TO BE COMPLETED BY APPLICANT Name of Applicant: THE UNIVERSITY OF SYDNEY Address of Applicant: Parramatta Road, New South Wales 2006, Australia
A
Actual Inventor: Stephen Walter SIMPSON e Address for Service: GRIFFITH HACK CO 71 YORK STREET SYDNEY NSW 2000 Complete Specification for the invention entitled: GAS DETECTION BY INFRARED ABSORPTION The following statement is a full description of this invention, including the best method of performing it known to me/us:- GH&CO REF: 04828-PR RW/SMcL 5279A/SMcL 2 This invention relates to a method of and apparatus for detecting the presence of an infrared absorbing gas within an atmosphere containing the gas. The invention has particular application to the detection of a combustible gas in air and the invention is hereinafter described in such context.
However, it is to be understood that the invention does have broader application, to the detection of the presence per se of any infrared absorbing gas, for example an explosive or toxic gas, in an atmosphere containing or consisting of any other gas.
A procedure which currently is employed for determining the presence of an explosive gas involves passing a beam of infrared radiation through a sample chamber and detecting the level of absorption of the radiation within the chamber. An output signal is derived which provides a measure of the infrared radiation which impinges on detector, with an increase in the level of the output signal indicating a reduction in the level of infrared absorbing gas in the Schamber. A filter is normally located between the radiation .0 source and the detector to selectively pass an infrared frequency which, by its absorption, is indicative of the presence of a gas of interest.
In order to accommodate the existence of background radiation, which normally increases with increasing ambient :25 temperature, the beam is modulated and an adjustment is made o to compensate for the level of background radiation. In one 0 known prior art system this is achieved by switching an Sinfrared source on and off, measuring the level of radiation 0 which is incident on the detector during an ON period, measuring the level of incident radiation during an OFF period and subtracting a signal which is representative of the second level measurement from that which is representative of the first level measurement. Any steady background infrared radiation will make the same contribution to both signals and will be cancelled when the two signals are subtracted.
A problem which is known to exist in the above described S:04828PR -3prior art system is that false readings are obtained when the background radiation level varies with time. If the background radiation changes between the OFF period and the ON period measurements of incident radiation, a false reading will be obtained when the signals that are representative of the two levels are subtracted one from the other. Given that gas detection may be required in hazardous environments, such as on oil rigs and in petrochemical plants, it is important that fast responses be obtained to indicate accurately the existence of any explosive gas mixtures and that false indications be minimised.
The present invention seeks to provide a system which makes accommodation for changes in the level of background radiation.
Broadly defined, the invention seeks to provide a method of detecting for the presence of an infrared absorbing gas within an atmosphere and which comprises beaming infrared radiation through a chamber containing the atmosphere, modulating the radiation by cyclically switching a source of radiation on and off, detecting the level of radiation that impinges on an infrared detector within the chamber, and generating an output signal representative of the detected level. The invention is characterised in that, during predetermined periods corresponding to on-off cycles of the :25 radiation source, the output signal from the detector is sampled and: a first signal component which is representative of the amplitude of a first extremum of the output signal is stored, a second signal component which is representative of the amplitude of a second, succeeding, extremum of the output signal is stored, the first signal component is subtracted from the second signal component to produce a first difference signal component, the second signal component is subtracted from a third signal component which is representative of the S:04828PR Ii 4 amplitude of a third, succeeding, extremum of the output signal to produce a second difference signal component.
the first difference signal is amplified by a factor which is proportional to the time period between the second and third extrema of the output signal, the second difference signal is amplified by a factor which is proportional to the time period between the first and second extrema of the output signal, and the two amplified difference signals are subtracted to produce an output which is representative of the level of infrared radiation attributable to the radiation source.
The first, second and third extrema result from switching of the source from one state to the other, although, depending upon the nature of the detector, the '.35 extrema need not necessarily correspond in time with switching of the source. Also, again depending upon the nature of the detector, it may be necessary to distinguish between primary extrema which reflect the source switching and secondary (less significant) extrema that may exist as a result of oscillations in the output signal.
The first extremum of the output signal may comprise a minimum signal value resulting from source switch-off prior .3 to the commencement of an ON-OFF period. Then, the second extremum will comprise a succeeding peak signal value resulting from switching-on the source, and the third extremum will comprise a succeeding minimum signal value resulting from the next occurring source switch-off during the same ON-OFF period.
However, the first, second and third extremum may 0 alternatively comprise peak, minimum and peak signal levels respectively during any one ON-OFF-ON sequence.
When the first extremum of the output signal comprises a minimum signal value, the first difference signal component will be amplified by a value derived as a function of (tgff and the second difference signal will then be amplified by a value derived as a function of (T (toff where (tof is the numerical value of P04828PR/SMcL the time difference between the peak value of the output signal and the next succeeding minimum value in any one cycle, and where T is the numerical value of the time period of one complete cycle of the output signal.
The infrared source is preferably switched in a manner to provide an ON period which is shorter than the OFF period.
The output signal from the detector may be sampled during each succeeding ON-OFF cycle, so that a very rapid indication of the presence of an infrared-absorbing gas will be obtained. Alternatively, sampling may be effected during ON-OFF cycles that are spaced-apart in time, for example every sixty seconds.
The output resulting from subtraction of the two amplified difference signals may be employed simply to provide indication of the presence per se of infrared absorbing gas within the chamber. However, a filter may be located between the infrared source and the detector in order that selective Indication may be obtained as to the S composition of the absorbing gas present within the chamber.
Moreover, the magnitude of the output signal may be measured to provide indication as to the proportion of infrared absorbing gas within the atmosphere containing the absorbing gas.
The invention may also be defined as providing an :25 apparatus for detecting the presence of an infrared absorbing gas within an atmosphere and which comprises a chamber for receiving a sample of the atmosphere, a source of infrared radiation, means for cyclically switching the source on and Soff, a detector for sensing the presence of incident infrared radiation and providing an output signal representative of the level of incident radiation, and circuitry for processing the output signal from the detector. The processing circuitry preferably includes two sample and hold circuits which are arranged to produce the above defined first an second difference signals and further includes means subtracting the outputs from the two sample and hoed circuits.
S:04828PR 6 The invention will be more fully understood from the following description of a preferred embodiment of a gas presence detector, the description being provided with reference to the accompanying drawings in which: Figure 1 shows a diagrammatic representation of the complete detector, Figure 2 shows a series of graphs which are representative of infrared radiation and detection signals, and Figure 3 shows a schematic diagram of circuitry which is employed in processing the detection signal.
As illustrated, the detector comprises a chamber which is constructed to admit an atmospheric gas which is to be tested or monitored for the possible inclusion of an explosive gas. An infrared generator/radiator 11 is located 94006: at one end of the chamber and is connected to associated electrical circuitry 12. The radiator may comprise a conventional incandescent lamp which is, powered from a main supply, and the circuitry 12 provides for electronically controlled switching modulation) of the lamp output.
Each switched cycle of the lamp may occupy 1.5 seconds, with a 0.5 second on period followed by a 1.0 second off period.
0 o Graph 2A shows an idealised switching waveform and graph 2B shows a representative waveform of the infrared radiation envelope, this indicating the delay in build-up of the 0000 infrared level following switch-on and the delayed decay in radiation following switch-off. The mark-space ratio of the on-off switching or modulation of the infrared source may be 00. 0 different from that indicated (for example the ratio may be 0o 1:1) but, due to incandescent lamps having an emissions rise time which is more rapid than the decay time, it is desirable in the interest of greater efficiency that the on time be shorter than the off time.
An infrared detector 13 is located at the opposite end of the chamber frc,,l the lamp 11 and it provides an output signal which is representative of the level of infrared radiation which impinges on the detector. The detector 13 P04828PR/SMcL 7 may comprise a simple thermopile detector, which would normally provide an output signal which follows the incident radiation waveform, or a pyroelectric detector. In the latter case the detector will produce a more complicated response to incident radiation and the time intervals of signal sampling will need to be adjusted accordingly.
A filter 13a may be located between the lamp 11 and the detector 13 and be employed to selectively pass an infrared frequency or range of frequencies which, by absorption, is indicative of the presence of a particular gas or class of gases.
The detector 13 functions to detect infrared radiation from the lamp 11 and, also, background radiation from external sources. A steady state background will cause a dc shift in the level of the radiation from the lamp 11 and the detector output signal will then follow the waveform shown in 0 graph 2B. Then, if the background were to remain substantially constant, relatively simple signal processing -00 might be employed to subtract the effect of the dc shift from the detected waveform. However if, as is more likely, the background radiation changes with time, as indicated by the detector output signal waveform shown in graph 2C, known prior art forms of signal processing cannot by employed to provide an output signal which is representative of the •:025 radiation which falls incident on the detector due solely to 0 radiation from the lamp 11.
For completeness of this description, it is mentioned 0" 0that any recorded rise or fall in the level of radiation °0 which impinges on the detector 13 (and which originates from the lamp 11) should be attributable to a reduction or increase respectively in the level of infrared absorbing gas within the chamber 10. It is important therefore that rapid compensation be made for any change in the background radiation, so that the output from the detector does provide a true indication of the presence of an absorbing gas.
A signal processing circuit 14 which is shown in greater detail in Figure 3 is employed to accommodate background P04828PR/SMcL 8 radiation which changes with time but, before proceeding to a description of the circuitry, it is appropriate to provide a brief description of the mathematical operations which are performed by the circuitry.
In referring to graph C in Figure 2, a measure of the peak extremum S. of the detector output signal is derived at time this resulting from excitation of the lamp 11.
Also, a measure of the minimum extremum Som of the detector output signal is derived at the earlier time tor,, and a measure of a (different level) minimum extremum Sog is derived at the later time instant tor The shape of the detector output signal will depend both on the source 11 and on the type of detector 13 that is used. For some types of detectors, for example pyroelectric detectors, the peak and minimum values in the output waveform will not necessarily coincide in time with the switching of the source, and it is to be understood that the time instant to,, etc may apply only to the detector output waveform and not to the switching intervals of the lamp 11.
Employing the above terms, the level of radiation incident on the detector can be expressed mathematically as being proportional to: (tofr tn)Sorf TS. (T-(tor t.))Sorn.
Thus, a signal which is proportional to this expression is produced by the detector 13 for each lamp switching cycle, where T is the duration (tf of one complete cycle.
The above expression can be rewritten as: (T (toM ton))0 2 (ton t.)01 where the term 02 corresponds with (Sof So) and the term 01 corresponds with Som This expression is used for controlling the processing circuitry which is shown in Figure 3.
As shown in Figure 3, the output signal from the detector 13 is fed to an input amplifier and filter Also, although not shown, the input circuit may include provision for static temperature compensation, with provision P04828PR/SMcL 9 thus being made for changing the gain in the amplifier 15 as a function of temperature.
The conditioned detector output signal is then applied to two sample and hold circuits 17 and 18. In respect of each complete cycle of the detector output signal, the first sample and hold circuit 17 stores the minimum value So,, of the signal at time to, and subtracts it from the following peak value Sm of the signal at time The second circuit 18 stores the peak value S, of the signal, also at time and then subtracts it from the following minimum signal value S.o at time ty,.
Amplifiers 19 and 20 in the respective sample and hold circuits 17 and 18 increase the amplitude of the difference signals which are derived from the respective sample and hold 5 circuits. Amplifier 19 is set to provide a gain corresponding numerically proportionately) to the time
S
period (torn and the amplifier 20 has its gain set to a numerical value corresponding to a time period T -(tor e" The outputs from the two sample and hold circuit 17 and 18 are then applied to a following subtractor/filter circuit 21 where the signal corresponding to the expression (torn (So. Sou) is subtracted from the signal ,o corresponding to the expression (T (tor tm)) (S S.) As hereinbefore mentioned, this signal provides a measure of the infrared radiation incident on the detector 13 due solely to radiation emitted by the lamp 11. Thus, the output signal from the subtracting circuit 21 is representative of the amount of infrared absorbing gas within the chamber
Q
"0 The output from the subtractor circuit 21 is applied as an input signal to a following alarm or metering apparatus 22 which, depending on the requirements of the system, may provide indication of the presence, level or composition of infrared absorbing gas within the chamber P04828PR/SMcL
Claims (9)
- 2. The method as claimed in claim 1 wherein the output signal is sampled during each of the periods that correspond to the on-off cycles of the radiation source. S:04828PR 11
- 3. The method as claimed in claim 1 or claim 2 wherein the source of radiation is switched on for a period which is shorter tha-i the off period.
- 4. The method as claimed in any ie of claims 1 to 3 wherein the output which is representative of the level of infrared radiation directed to means for indicating the presence of the gas within the atmosphere. The method as claimed in any one of claims 1 to 3 wherein the output which is representative of the level of infrared radiation is directed to means for determining the proportion of infrared absorbing gas within the gas contained by the chamber.
- 6. The method as claimed in any one of the preceding e" claims wherein the radiation from the source is directed to 4 the detector by way of a filter which is selected to pass a band of infrared frequencies which is characteristically absorbed by a gas whose presence is to be detected.
- 7. The method as claimed in any one of claims 1 to 6 wherein the first signal component is representative of the amplitude of a first minimum value of the output signal in a predetermined period, the second signal component is representative of the amplitude of a succeeding maximum value 4 9 *0 of the output signal in the predetermined period and the third signal component is representative of the amplitude of a succeeding second minimum value of the output signal in the predetermined period.
- 8. The method as claimed in any one of claims 1 to 6 wherein the first signal component is representative of the amplitude of a first peak value of the output signal in a predetermined period, the second signal component is representative of the amplitude of a succeeding minimum value of the output signal in the predetermined period and the third signal component is representative of the amplitude of a second peak value of the output signal in the predetermined period. P04828PR/SMcL 12
- 9. The method of detecting for the presence of an infrared absorbing gas within an atmosphere, substantially as hereinbefore described with reference to the accompanying drawings.
- 10. An apparatus for detecting the presence of an infrared absorbing gas within an atmosphere and which comprises a chamber for receiving a sample of the atmosphere, a source of infrared radiation, means for cyclically switching the source on and off, a detector for sensing the presence of incident infrared radiation and providing an output signal representative of the level of incident radiation, and processing circuitry for processing the output signal from the detector; characterised in that the processing circuitry includes means for sampling and deriving first, second and third signal components which are representative of the amplitude of first, second and third extrema respectively in predetermined periods corresponding to on-off cycles of the radiation source, means for subtracting the first signal component from the second signal component to produce a first difference signal, means for .subtracting the second signal component from the third signal component to produce a second difference signal, means for amplifying the first difference signal by a factor which is proportional to the time period between the second and third :25 extrema in the output signal, means for amplifying the second difference signal by a factor which is proportional to the time period between the first and second extrema of the output signal, and means for subtracting the two amplified difference signals to produce an output which is representative of the level of infrared radiation attributable to the radiation source. S:0482-PPR 13
- 11. The apparatus for detecting the presence of infrared absorbing gas within an atmosphere substantially as shown in the accompanying drawings and substantially as hereinbefore described with reference thereto. DATED this 16th day of November 1993 THE UNIVERSITY OF SYDNEY By its Patent Attorneys GRIFFITH HACK CO S.* C C. C. **C C C CC. *C.CC. S;O 428P 4/7 Q
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU76122/91A AU645557B2 (en) | 1990-05-07 | 1991-04-29 | Gas detection by infrared absorption |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPK001090 | 1990-05-07 | ||
AUPK0010 | 1990-05-07 | ||
AU76122/91A AU645557B2 (en) | 1990-05-07 | 1991-04-29 | Gas detection by infrared absorption |
Publications (2)
Publication Number | Publication Date |
---|---|
AU7612291A AU7612291A (en) | 1991-11-07 |
AU645557B2 true AU645557B2 (en) | 1994-01-20 |
Family
ID=25638147
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU76122/91A Ceased AU645557B2 (en) | 1990-05-07 | 1991-04-29 | Gas detection by infrared absorption |
Country Status (1)
Country | Link |
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AU (1) | AU645557B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5293210A (en) * | 1992-04-24 | 1994-03-08 | Becton, Dickinson And Company | Detection of bacteria in blood culture bottles by time-resolved light scattering and absorption measurement |
CA2092372C (en) * | 1992-04-24 | 2000-03-14 | Klaus W. Berndt | Methods and apparatus for detecting microorganisms in blood culture vials |
AU702148B2 (en) * | 1994-12-02 | 1999-02-18 | Austech Instruments Pty Limited | Gas detector |
AUPM982094A0 (en) * | 1994-12-02 | 1995-01-05 | Gas Tech Australia Pty Ltd | Gas detector |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4549080A (en) * | 1983-06-17 | 1985-10-22 | Infrared Industries, Inc. | Double-pass flue gas analyzer |
US4641973A (en) * | 1981-09-22 | 1987-02-10 | H. Maihak Ag | Method and apparatus for measurement of the concentration of a component of a mixture |
US4772790A (en) * | 1986-10-14 | 1988-09-20 | Teledyne Industries, Inc. | Non-dispersive optical gas analyzer |
-
1991
- 1991-04-29 AU AU76122/91A patent/AU645557B2/en not_active Ceased
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4641973A (en) * | 1981-09-22 | 1987-02-10 | H. Maihak Ag | Method and apparatus for measurement of the concentration of a component of a mixture |
US4549080A (en) * | 1983-06-17 | 1985-10-22 | Infrared Industries, Inc. | Double-pass flue gas analyzer |
US4772790A (en) * | 1986-10-14 | 1988-09-20 | Teledyne Industries, Inc. | Non-dispersive optical gas analyzer |
Also Published As
Publication number | Publication date |
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AU7612291A (en) | 1991-11-07 |
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