AU636796B2 - Absorbent article having an absorbent with a variable density in the z direction and a method of forming said article - Google Patents

Absorbent article having an absorbent with a variable density in the z direction and a method of forming said article Download PDF

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AU636796B2
AU636796B2 AU84622/91A AU8462291A AU636796B2 AU 636796 B2 AU636796 B2 AU 636796B2 AU 84622/91 A AU84622/91 A AU 84622/91A AU 8462291 A AU8462291 A AU 8462291A AU 636796 B2 AU636796 B2 AU 636796B2
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absorbent
absorbent article
thickness
density
liquid
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AU8462291A (en
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Michael Tod Morman
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Kimberly Clark Worldwide Inc
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Kimberly Clark Corp
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Priority claimed from US07/685,585 external-priority patent/US5611879A/en
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Assigned to KIMBERLY-CLARK WORLDWIDE, INC. reassignment KIMBERLY-CLARK WORLDWIDE, INC. Alteration of Name(s) in Register under S187 Assignors: KIMBERLY-CLARK CORPORATION
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  • Absorbent Articles And Supports Therefor (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)

Description

6367 99 S F Ref: 191489
AUSTRALIA
PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT 9* a a a a
ORIGINAL
a *r a Name and Address of Applicant: Actual Inventor(s): Address for Service: Invention Title: Kimberly-Clark Corporation 401 North Lake Street Neenah Wisconsin 54956 UNITED STATES OF AMERICA Michael Tod Morman Spruson Ferguson, Patent Attorneys Level 33 St Martins Tower, 31 Market Street Sydney, New South Wales, 2000, Australia Absorbent Article Having an Absorbent with a Variable Density in the Z Direction and a Method of Forming said Article The following statement is a full description of this invention, including the best method of performing it known to me/us:- 5845/3
PATENT
ABSORBENT ARTICLE HAVING AN ABSORBENT WITH A VARIABLE DENSITY IN THE Z DIRECTION AND A METHOD OF FORMING SAID ARTICLE Field of the Invention This invention relates to an absorbent article, such as a sanitary napkin, a diaper, training pants, an incontinent garment or a bedpad, having an absorbent with a variable density in the z direction. A method of forming the article is also disclosed.
Background of the Invention Absorbent pads such as sanitary napkins which utilize cellulosic fiber as their principal absorbent are well known.
S 15 Cellulosic fiber provides a relatively inexpensive source of S.absorbent material but suffers from distinct disadvantages when utilized alone as an absorbent layer. One of the main disadvantages is that when a layer of cellulosic fiber is wetted, it tends to memo collapse upon itself. This results in a saturated cellulosic fiber which is dense, compacted, and relatively hard and uncomfortable.
It has been proposed that sanitary napkins be formed of a material containing plastic fibers that allow fusing the absorbent to aid in shaping. Such a pad having aC-fold structure has been proposed in U.S. 4,576,596 issued to Jackson et al. The Jackson S 25 patent also teaches that an insert, such as a meltblown strip, may be *i incorporated into the interior of the sanitary napkin to aid in absorbing and holding body fluids. While such a sanitary napkin is i satisfactory, the thermoplastic-containing absorbent has properties that are a compromise between softness, stiffness, fluid transfer and fluid holding properties.
i •It is desirable that the absorbent material at the top of a feminine pad, adjacent to the wearer's body, be soft and cushiony.
The absorbent material should also be high in porosity, that is, it should have a low density to facilitate rapid fluid absorption and be capable of transferring the fluid rapidly away from the body. The absorbent material situated below the top absorbent should have good -1- C_ i I fluid holding properties and be capable of wicking the fluid throughout the pad. These desirable features are not present in the Jackson patent.
Other U.S. patents, such as 4,505,705; 4,475,913; 3,699,966 and 3,430,629, teach that the absorbent can be folded about itself without referring to the advantages of having a variable density in the z direction. Still other U.S. patents, such as 3,017,304; 3,779,246; 4,226,237; 4,377,615 and 4,223,677, teach the use of various layers of absorbents having different thicknesses and densities. They do not suggest the use of a single absorbent sheet which is folded upon itself.
There are other U.S. patents, such as 4,496,358; 4,449,979 and 3,900,027, which teach the advantages of having a variable density in the z direction. However, no mention is made of folding the absorbent material. Lastly, U.S. 4,315,507 issued to Whitehead teaches forming a fusible baffle on one surface of an absorbent which is then used in a sanitary napkin. However, the baffle is completely covered by an outer wrap and, therefore, does not have an external surface which contacts the undergarment.
Another compromise in single absorbency pads is strength.
Generally, an absorbent that has a higher density is stiffer and can prevent bending and twist' g of the pad while in use. However, a dense absorbent will not ft,, ds soft to the wearer and, therefore, sacrifices comfort in order to achieve stiffness.
Feminine pads having multiple layers of different densities have also been proposed. However, such pads are expensive and complicated to manufacture as they require formation and uniting of several different .i absorbent materials with good alignment at high speed and low cost.
Accordingly, there is a need for an absorbent article which has a soft feel and which has a variable density in the z direction.
Summary of the Invention 30 There is disclosed herein an absorbent article comprising: a) a liquid-permeable cover; and b) an absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction, said absorbent having at least two distinct portions, adjacent 35 ones of which are integrally joined together at a junction line, each portion having a thickness different from said at least one adjacent portion, said absorbent being folded along said junction line to obtain -2- 2 i 3491
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f f -!1 at least one upper layer and at least one lower layer, said upper layer having a thickness greater than at least one of said lower layers so as to quickly absorb body fluid and transfer said body fluid into one of said lower layers, said absorbent having a variable density in the z direction, and said folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
There is further disclosed herein an absorbent article comprising: a) a liquid-permeable cover; b) a liquid-impermeable baffle; and c) an absorbent positioned between said cover and said baffle, said absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction, said absorbent having at least three distinct portions, adjacent ones of which are integrally joined together by one of a pair of junction lines, each portion having a thickness different from said at least one adjacent portion, said absorbent being folded along said pail of junction lines to obtain an upper layer and at least one lower layer, said upper layer having a greater thickness than said lower layer so as to quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction, and said folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
There is further disclosed herein an absorbent article comprising: a) a liquid-permeable cover; b) a liquid-impermeable baffle; and c) an absorbent positioned between said cover and said baffle, said absorbent having a homogeneous composition with an essentially 30 constant density in any plane aligned perpendicular to the z direction, said absorbent having at least three distinct portions, adjacent ones of which are integrally joined together at one of a pair of junction lines, each portion having a thickness different from said at least one adjacent portion, said outer portions being C-folded at said junction lines with 35 opposite ends of the outer two portions abutting one another and aligned adjacent to.said baffle, said folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
-3- |ST' 3491 hINT O j 4~ There is further disclosed herein a method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction into at least two distinct portions which have different thicknesses, at least one of said portions being integrally joined together by a junction line; b) folding said absorbent on said junction line to obtain an upper layer and a lower layer, said upper layer having a greater thickness than said lower layer so as to quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction; and c) positioning a liquid-permeable cover about said absorbent to form an absorbent article.
There is further disclosed herein a method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction to form at least one compressed portion and at least one noncompressed portion, each having a different thickness, adjacent ones of said compressed and noncompressed portions being integrally joined together by a junction line; b) folding said absorbent on said junction line to vertically align said noncompressed portion over said compressed portion so as to 25 quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction; c) positioning a liquid-permeable cover adjacent to a surface of said absorbent; d) positioning a liquid-permeable baffle adjacent to an opposite surface of said absorbent; and e) securing said cover to said baffle to enclose said absorbent and form an absorbent article.
There is further disclosed herein a method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition to form at least one compressed portion and at least one noncompressed portion, each having a different thickness, rc~ n h i; i A/ 03491 3A adjacent ones of said compressed and noncompressed portions being integrally joined together by a junction line; b) folding said absorbent on said junction line to vertically align said compressed portion with said noncompressed portion to create a variable density in the z direction; c) heating an external surface of said compressed portion to a sufficient temperature to fuse said surface and form a liquid-impermeable layer; and d) positioning a liquid-permeable cover about said absorbent to form an absorbent article.
The absorbent article typically includes an absorbent having a homogeneous composition which has a constant density in any plane aligned perpendicular to the z direction. The absorbent also has at least two distinct portions which are integrally joined together by a junction line, and each portion has a thickness different from an adjacent portion. The absorbent is folded upon itself to obtain a variable density in the z direction. The folded absorbent has a uniform capillar size in any plane aligned perpendicular to the z direction and a variable capillar size in the z direction. The method of forming the article is also disclosed.
Brief Description of the Drawings A preferred form of the present invention will now be described by way of example with reference to the accompanying drawings, wherein: Fig. 1 is a top view of an absorbent pad.
Fig. 2 is a side view of the absorbent pad shown in Fig. 1.
Fig. 3 is a bottom view of the absorbent pad shown in Fig .1.
Fig. 4 is an end view of the absorbent pad shown in Fig. 1.
Fig. 5 is the cross-sectional view of Fig. 1 taken along line of Fig. 1.
30 Fig. 6 is a cross-sectional view of an alternative embodiment of the absorbent pad.
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Fig. 7 is a cross-sectional view of another alternative embodiment of the absorbent pad.
Fig. 8 is a cross-sectional view of an absorbent material before it is compressed.
Fig. 8A 's a cross-sectional view of a compressed absorbent material that can used in the absorbent pad.
Figs. 9 and 10 are side and end views, respectively, of apparatus which can compress the absorbent material.
Fig. 11 is a cross-sectional view of an absorbent material which has been compressed and can be used in the absorbent pad.
Fig. 12 is a cross-sectional view of an absorbent material which has been compressed to three different densities.
Fig. 13 is a cross-sectional view of an absorbent pad which has been formed from the compressed absorbent material shown in o. 15 Fig. 12.
Fig. 14 is a cross-sectional view of an absorbent material too* which has been compressed to three different densities.
499@ Fig. 15 is a cross-sectional view of an absorbent pad which S ,has been formed from the compressed abscrbent material shown in Fig. 14.
Fig. 16 is a cross-sectional view of an absorbent pad having a core formed from a compressed absorbent material and without a liquid-impermeable baffle.
•99 ,Fig. 17 is an enlarged view of a portion of the absorbent pad shown in Fig.16.
Fig. 18 is a perspective view of a bedpad utilizing a 9* 9 compressed absorbent material.
Fig. 19 is a cross-sectional view of a portion of the bedpad 3 taken ing line 19--19 of Fig. 18.
20 is a perspective view of an incontinent garment utilizing compressed absorbent material.
Fig. 21 is a graph depicting the inverse of the time required to absorb fluid (in seconds) versus the thickness of the sample (in inches).
-4- Detailed Description of the Preferred Embodimr-nts Referring to Figs. 1-5, an absorbent article 20 in the shape of a sanitary napkin is shown. It should be noted that the absorbent article can also be a diaper, training pants, an incontinent garment, a bedpad, etc. The absorbent article 20 includes a bodyside surface 22, a garment-facir- surface 23, distal ends seals 24 and 26 and a pair of longitudinally extending sides 28 and 30. The article further includes an absorben' 35, a liquid-permeable cover 38 and a liquid-impermeable baffle 46. The absorbent 35 is an integral sheet of absorbent material which has a homogeneous composition. The absorbent 35 has an essentially constant density in any plane aligned perpendicular to the z direction and is folded upon itself to have a variable density in the z direction.
The x and y directions refer to the length and width of the product and the z direction refers to the thickness of the product. The folded absorbent 35 also has a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction. The capillary size in the z direction can vary from large to small as one goes from the top to the bottom of the absorbent. The capillary size can also be altered so that the smaller sized capillaries are located in the center of the absorbent. The variable density can be obtained by compressing one or more portions of the absorbent 35 and then folding these portions relative to one or more noncompressed or less compressed portions as shown in Fig. 5. The compressed portions are generally thinner in thickness than the noncompressed or less compressed portions. Generally, for an initially homogeneous absorbent, the thickness decreases as the density increases. The compressed portions 'are attached to the noncompressed or less compressed portions by one or more junction lines The junction lines provide a good location for folding one portion relative to an adjacent portion.
The absorbent 35 can contain thermoplastic polymers which can be permanently deformed by the application of heat and pressure. Such materials include polypropylene, nylon, polyethylene, polyesters, etc.
Typical of such materials are bonded carded webs, meltblown and spunbond fabrics. Composites with a low temperature melting component, which can 35 be fused during compression and which t: ST 4I 0 Iii also have a high melting temperature or non-melting component for structural integrity, are especially good. A preferred material is coform. Coform is an air-formed blend of meltblown fibers and staple and/or pulp fibers. The formation of such material is disclosed in U.S. 4,.C0,324 issued to Anderson et al. It is also possible to add a high absorbency polymeric material, i.e. "superabsorbent", to the coform as suggested by British patent application 2,113,731 to Minto et al. and by U.S. 4,604,313 issued to McFarland et al. Coform formed from polypropylene meltblown and wood fibers, with or without superabsorbent particles, is preferred. Coform can be readily heatset at low temperatures, has good absorbency characteristics and is low in cost.
Referring to Fig. 5, the absorbent 35 consist of a o< 1 noncompressed portion 36 positioned adjacent to the liquid-permeable S* 15 cover 38 and two compressed portions 42 and 44 positioned therebelow.
S" The noncompressed portion 36 is softer and has a lower density than o the compressed portions 42 and 44. The noncompressed portion 36 is designed to quickly absorb body fluid which is discharged onto the sanitary napkin 20 and transfers it downward into the compressed portions 42 and 44. The dense compressed portions 42 and 44 are capable of retaining the body fluid and can keep it away from the skin of the user. This creates a dry feel at the bodyside surface 22 of the absorbent article 20 which is very desirable to the ultimate 6 user. The compressed portions 42 and 44 have the ability to resist giving up the body fluid should they be compressed further by body movement. The compressed portions 42 and 44 also provide strength and rigidity to the absorbent article In Fig. 5, the liquid-impermeable baffle 46 is positioned below the compressed portions 42 and 44 of the absorbent 35 and extends upward along the longitudinally extending sides 28 and 30 of the article 20. The baffle 46 prevents passage of body fluid from the absorbent 35 to the adjacent undergarment of the wearer. The baffle 46 can be constructed from any liquid-impermeable material.
Two preferred materials include polyethylene and polypropylene which can be formed as very thin films. These two materials are relatively low in cost and are quiet when worn.
-6i- ~i 'iiF i The liquid-permeable cover 38 wraps around the absorbent and the baffle 46 and can be overlapped upon itself on the garment-facing surface 23. The overlap can be secured by an adhesive The ends of the cover 38 are sealed at a location where the absorbent 35 is not present, such as by an ultrasonic seal, to form the end seals 24 and 26. The cover 38 should be constructed from a material which will allow rapid passage of body fluid therethrough.
Suitable materials include perforated films, woven materials and tissue. A preferred material is a polypropylene spunbond material because it has good strength, is comfortable and passes fluids easily.
The garment-facing surface 23 is provided with a removable peel strip 32 that is intended to be removed prior to use. By removing the peel strip 32, a garment attachment adhesive 34 is exposed which is designed to provide a means for attaching the S°absorbent article 20 to the inner crotch portion of an undergarment.
~Referring to Fig. 6, an alternative absorbent article 50, in .000 the -orm of a sanitary napkin, is shown. The absorbent article o°*,includes a liquid-permeable cover 52, a liquid-impermearie baffle 53 and an absorbent 55. The cover 52 is overlapped upon itself on the garment-facing side and is joined together by a construction adhesive 54. A garment attachment adhesive 56 is secured to the exterior surface of the cover 52 approximate the overlap and, in
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2 turn, is covered by a removable peel strip 58. Enclosed within the S 25 cover 52 is the absorbent 55 which includes a noncompressed portion S ,66 and compressed portions 62 and 64. Preferably, the absorbent is folded along two spaced-apart junction lines which are aligned with the axis of thickness change. The folded absorbent 55 is situated such that the noncompressed portion 60 is positioned °oo 30 adjacent to the cover 52 and the compressed portions 62 and 64 are C-folded beneath the noncompressed portion 60. The compressed portions 62 and 64 have a greater density than the noncompressed portion. It should be noted that the noncompressed portion 60 can be slightly compressed if desired, but that it should still have a lesser density than the compressed portions 62 and 64. A transfer layer 66 is positioned between the noncompressed portion 60 and the 7-
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compressed portions 62 and 64. The transfer layer 66 can be a strip of meltblown polymer which has the ability to retain body fluid and transfer the fluid longitudinally and traversely along its length and width.
Referring to Fig. 7, another embodiment of an absorbent article 70, in the form of a sanitary napkin, is shown. The absorbent article 70 includes a liquid-permeable cover 76, a liquid-impermeable baffle 80 and an absorbent 81. The cover 76 encloses both the baffle 80 and the absorbent 81 and is overlapped upon itself on the garment-facing side of the article 70. The overlap is secured by a construction adhesive 78. A garment attachment adhesive 72 is secured to the exterior surface of the cover 76 approximate the overlap and, in turn, is covered by a 1 removable peel strip 74. The absorbent 81 includes a pair of low S° 15 density portions 82 and 84 which are integrally joined to a higher density portion 86. The lower density portions 82 and 84 are C-folded at junction lines over the denser portion 86 and art.
*aligned adjacent to the bodyside cover 76. A transfer layer 88 is positioned between the two less dense portions 82 and 84 and the dense portion 86. As explained above, th? tr ansfer layer 88 facilitates the movement of body fluid from the liquid-permeable cover 76 downward and outward to distant areas of the dense absorbent portion 86.
o Referring to Fig. 8, an absorbent sheet 90 having a relatively 25 low density is shown before compression. The absorbent sheet 90 has S*a.o' a homogeneous composition with an essentially constant density in the x, y and z directions. In Fig. 8A, an absorbent 91 is shown having a noncompressed center portion 92 flanked by a pair of compressed portions 94 and 96. The compressed portions 94 and 96 are located along the longitudinal sides of the center portion 92. The density S of the compressed portions 94 and 96 is much greater than the noncompressed portion 92.
The density of the upper absorbent layer can be almost any desired value. This upper absorbent layer is soft and provides a cushiony feel adjacent to the wearer's skin. The upper absorbent layer also has good fluid transfer properties. A suitable density 8 6* a a a a. a a.
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for the upper absorbent layer, which also acts as a transfer layer, has been found to be between about 0.01 and about 0.07 grams per cubic centimeter. A preferred density for feminine care products has been found to be between about 0.02 and about 0.06 grams per cubic centimeter. This range is especially desirable when the material is coform which is made from a blend of 5-70% polypropylene and 95-30% divellicated wood fibers.
The density of the lower absorbent layer, which serves to stiffen and/or strengthen the product can be almost any desired value. The lower absorbent layer also functions as an absorbent reservoir which retains body fluids and prevents the fluid from being squeezed out when pressure is applied. It should be noted that the absorption properties of materials utilized for menstrual fluids are different from those for absorption of urine. A preferred density for feminine care products has been found to be between about 0.07 and about 0.30 grams per cubic centimeter. This range is especially desirable when the material is coform made from a blend of polypropylene and 70% divellicated wood fibers. The thickness of the lower layer can also vary relative to the thickness of the upper layer. Preferably, the thickness of the lower layer is less than about 80% of the thickness of the upper layer. More preferably, the thickness of the lower layer is about 10-70% of the thickness of the upper layer and, most preferably, the thickness of the lower layer is about 15-50% of the thickness of the upper layer.
Referring to Figs. 9 and 10, an apparatus is depicted for compressing the absorbent 90 into the configuration illustrated in Fig. 8A. The apparatus includes two pairs of rotatable pressure wheels or rolls 96 98 and 100 102. The pressure wheels 96 and 100 are mounted on an axle 104 while the pressure wheels 98 and 102 30 are mounted on an axle 106. The axles 104 and 106 are aligned parallel to one another and are rotatable by drive means (not shown).
The noncompressed absorbent 90 is fed into a nip formed between the two pairs of pressure wheels 96 98 and 100 102. As the absorbent passes between the nip formed by the pressure wheels 96 98 and 100 102, the compressed portions 94 and 96 are formed. The center portion 92 retains its original thickness since it was not subjected -9to any compression. The resulting configuration is absorbent 91 depicted in Fig. 8A.
Referring to Fig. 11, an absorbent 110 is shown having a compressed center portion 112 flanked by a pair of noncompressed or slightly compressed longitudinal end portions 114 and 115. An absorbent having this particular configuration could be used to form the absorbent article shown in Fig. 7.
It should be noted that the pressure wheels 96, 98, 100 and 102 can be rearranged, be reduced in number, or be combined with additional pressure wheels to form other configurations. The method of forming an absorbent article can also vary depending on the desired configuration of the product. One preferred method includes compressing at least a portion of a sheet of absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction into at least two distinct portions which have different thicknesses. The distinct portions should be integrally joined together by at least one junction line The absorbent is folded on the junction line(s) to obtain an upper layer and a lower layer. The overlying upper and lower layers provide a variable density in the z direction. An external surface of the lower layer is then heated to a sufficient temperature to fuse the surface and form a liquid-impermeable layer. A liquid-permeable cover can be positioned adjacent to the upper layer of the absorbent either during formation of the absorbent sheet or after the absorbent sheet has been compressed. It is also possible to position an extra layer of absorbent between the upper and lower layers of the folded absorbent to obtain the configuration shown in Fig. 7.
Another method includes compressing at least a portion of a sheet of absorbent material having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z 30 direction. The absorbent is compressed to form at least one compressed portion and at least one noncompressed portion. The compressed portion i' has a different thickness and a greater density than the noncompressed portion. The compressed portion and the noncompressed portion are integrally joined together by a junction line The absorbent is then 35 folded on the junction line to vertically align the compressed portion 7 10 el 91 91 with the noncompressed portion and create a variable density in the z direction. A liquid-permeable cover is positioned adjacent to a surface of the absorbent and a liquid-impermeable baffle is positioned adjacent to an opposite surface of the absorbent. The cover and the baffle are then secured together to enclose the absorbent.
Referring to Fig. 12, an absorbent 120 having a more complicated configuration is shown. The absorbent 120 has three separate and distinct portions which are integrally joined together.
Each portion has a different density and thickness. The absorbent 120 has a center portion 122 of greatest density and minimum thickness, a pair of longitudinal end portions 124 and 126 of lowest density and greatest thickness, and a pair of intermediate portions 128 and 130 each of which has a density greater than the center portion 122 but less than the end portions 124 and 126. The thickness of the intermediate portions 128 and 130 is less than the center portion 122 but greater than the end portions 124 and 126.
Referring to Fig. 13, an absorbent article 140 in the form of sanitary napkin is shown utilizing the absorbent 120 illustrated in Fig. 12. The absorbent article 140 includes a liquid-permeable cover 142 having a bodyside surface 141. The cover 142 encloses both the absorbent 120 and a liquid-impermeable baffle 144 and is overlapped upon itself on the garment-facing surface or backside of the 9: article 140. The overlap is secured by a construction adhesive 146.
S 25 Two spaced-apart garment adhesive strips 148 and 150 are secured to the backside of the cover 142 and are protected by a pair of removable peel strips 152 and 154, respectively. The garment adhesive strips 148 and 150 are designed to hold the absorbent article 140 secure to the inner crotch portion of an undergarment o 30 when the article 140 is being worn.
In Fig. 13, the absorbent article 140 is formed with the absorbent 120 being folded in four places and arranged with the lower density end portions 124 and 126 located adjacent to the cover 142. The intermediate dense portions 128 and 130 are located in the middle of the absorbent article 140 while the greatest density center portion 122 is located at the bottom, away from the body of the user.
11 The low density portions 124 and 126 can be easily deformed with little resistance and, therefore, provides a soft feel against the thighs of the user.
Referring to Fig. 14, another absorbent 160 is shown having a different configuration than that shown in Fig. 12. The absorbent 160 has three separate and distinct portions which are integrally joined together. Each portion has a different density and thickness.
The absorbent 160 has a center portion 162 of greatest thickness but of lowest density, a pair of longitudinal end portions 164 and 166 of minimum thickness and greatest density, and a pair of intermediate portions 168 and 170 each of which h? a density greater than the center portion 162 but less than the ,nd portions 164 and 166. The thickness of the intermediate portions 168 and 170 is less than the center portion 162 but greater than the end portions 164 and 166.
S 15 Referring to Fig. 15, an absorbent article 180 in the form of a sanitary napkin is shown utilizing the absorbent 160 illustrated in Fig. 14. The absorbent article 180 includes a liquid-permeable cover 182, the absorbent 160 and a liquid-impermeable baffle 184. The
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'baffle 184 covers the lower surface of the absorbent 160 and also extends upwards and wraps around the sides of the absorbent 160 to form external sides 186 and 188 of the article 180. The baffle 184 terminates at the periphery of the upper surface of the absorbent 160. The cover 182 and the baffle 184 are joined together, for example, by a construction adhesive at locations 190 and 192 to completely enclose the absorbent 160. The attachment at 190 and 192 can be in the form of a continuous line of adhesive or it can include a plurality of intermittent glue spots. The baffle 184 is also attached to the absorbent 160 by a construction adhesive at locations 9e** ,194 and 196. Again, the attachment at 194 and 196 can be in the form 30 of a continuous line of adhesive or it can include a plurality of
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intermittent glue spots.
In Fig. 15, the absorbent article 180 is formed with the absorbent 160 being folded in four places The high density end portions 154 and 166 are located in the center or middle of the article 180, the intermediate dense portions 168 and 170 are located adjacent to the lower surface of the absorbent article 180 and in 12 iii j contact with the baffle 184, and the low density portion 162 is located at the upper surface of the article 180 adjacent to the cover 182. The low density portion 162 can be easily deformed with little resistance and, therefore, provides a soft feel against the thighs of the user. The low density portion 162 has a large capillary structure which facilitates rapid transfer of body fluid from the bodyside cover 182 to the denser portions 164 and 166. The denser portions 164 and 166 have a smaller capillary structure which is capable of holding and retaining the body fluid. The dense portions 164 and 166 also provide transfer of body fluid in the longitudinal and transverse directions to the outer areas of the absorbent article 180. The intermediate dense portions 168 and 170 serve as storage areas for absorbed body fluid and provide strength to the absorbent article 180. The intermediate dense portions 168 S 15 and 170 also assist in preventing roping, bunching and twisting of the absorbent article 180 when it is being worn.
Ge. The absorbent article 180 also includes a pair of spaced-apart 000* garment adhesive strips 198 and 200 which are secured to an exterior n. surface of the baffle 184 on the garment-facing side. The garment adhesive strips 198 and 200 are covered by a removable peel strip 202. The garment adhesive strips 198 and 200 are designed to hold the absorbent article 180 secure to the inner crotch portion of an undergarment when the article 180 is being worn.
dov ,Referring to Fig. 16, an absorbent article 210 in the form of a sanitary napkin is shown. The absorbent article 210 includes a liquid-permeable cover 214 and an absorbent 215 which has an integrally formed liquid-impermeable layer 212. The liquid-impermeable layer 212 serves as a baffle and will prevent the 4passage of body fluid therethrough. The liquid-impermeable layer 212 can be formed by heating a surface of the absorbent 215 during the compression step such that a more dense layer or skin is obtained.
By subjecting the absorbent to sufficient heat and pressure, one can make at least one surface of the absorbent substantially liquid impermeable. The liquid-impermeable layer 212 is adhesively secured to the cover 214 at locations 216 and 218. The attachment at 216 13 and 218 can be in the form of a continuous line of adhesive or it can include a plurality of intermittent glue spots.
The absorbent 215 is an integral sheet of absorbent having a high density portion 222 flanked by a pair of low density portions 220 and 221. In the formation of the absorbent article 210, the absorbent 215 is C-folded at such that the two low density portions 220 and 221 are positioned toward the upper surface of the article 210 adjacent to the cover 214. The higher density portion 222 is located beneath the low density portions 220 and 221 and adjacent to the garment-facing surface of the article 210. The garment-facing surface is designed to contact the inner crotch portion of an undergarment.
The absorbent article 210 also includes a garment adhesive strip 224 secured to the liquid-impermeable layer 212 along the longitudinal central axis of the article 210. The adhesive strip 224 S"is covered by a removable peel strip 226. The peel strip 226 prevents the adhesive strip 224 from being contaminated by foreign debris. When the sanitary napkin 210 is ready to be worn, the wearer 4. ,will remove the peel strip 226 and attach the napkin to the inner surface of her undergarment via the garment adhesive strip 224.
Referring to Fig. 17, an enlarged view of a portion of the absorbent article 210 is shown which emphasizes the integral formation of the liquid-impermeable layer 212 and the high dense portion 222. As explained above, the liquid-impermeable layer 212 can be formed by heating a surface of the absorbent 210 during compression such that a polymer layer is formed. In reference to the equipment shown in Fig. 10, the pressure wheels 98 and 102 can be heated to an elevated temperature to enable the fibers at the surface of the absorbent to fuse together while the pressure wheels 96 and 100 would hq maintained at room temperature or at a lower temperature so that fu;,ng does not occur.
Referring to Figs. 18 and 19, a bedpad 240 is shown which includes a liquid-permeable cover 242, an absorbent 246 and a liquid-impermeable baffle 248. The absorbent 246 can be formed from a sheet of coform. Such a material is ordinarily formed on a substrate, such as a liquid-permeable spunbond material, that may 14 serve as the cover 242. It should be noted that the liquid-permeable cover 242 and the liquid-impermeable baffle 248 can be integrally formed with the absorbent 246 if desired. The cover 242 and the baffle 248 can be formed at the same time the absorbent 246 is being manufactured into a sheet. This can be accomplished by laying down a spunbond material on a forming wire and then depositing coform on the spunbond material. The combination is then directed through the nip of a pair of compression rollers. One of the compression rollers can be heated to an elevated temperature which will cause the fibers at the surface of the coform to fuse together while being compressed.
This fused layer can form the baffle 248 while the opposite spunbond layer can form the cover 242. It should be noted that the absorbent 246 can also be compressed by using platen presses in an intermittent process.
S 15 Referring to Fig. 20, an absorbent article 250 in the form of an incontinent garment is shown. The incontinent garment 250 contains four buttonholes 252 which are used for the insertion of elastic straps having a button attached to each end. A button is inserted through each buttonhole 252 and the elastic straps serve to hold the incontinent garment 250 about the wearer's torso. The present invention can also be used in connection with other types of incontinence garments that are held in place by garment adhesive strips which attach directly to an undergarment.
Lastly, referring to Fig. 21, a graph is depicted plotting the "thickness" of each sample in inches along the x axis and the "inverse of the time to absorb the fluid" in seconds along the y axis.
EXAMPLES
The following examples are intended to be illustrative of the invention.
A sheet of commercially produced 190 gram per square meter coform material containing 70% pulp and 30% meltblown polypropylene microfibers with some Triton X-102 wetting agent was used in all of the following examples. The coform was formed on a spunbond carrier sheet which had a basis weight of about 22 grams per square meter.
The meltblown insert, where used, had a basis weight of 2.65 oz./square yard (90 grams/square meter) and comprised a 6 inch square 15 sheet which was folded four times. The meltblown insert was inserted into the folded absorbent article and it had a dimension of 1 inches wide by 6 inches long. It was placed in the center of the absorbent article.
Example 1 Uncompressed Control A sheet of the above-described coform was not compressed but was used as received. Six samples were cut from the sheet. They were 6 inches long and 12 inches wide. The samples were divided into four quarters, each quarter being 11 inches wide by 12 inches long.
The left, two centers, and right quadrants were measured for thickness with a Dyer Gauge, Model number 9.210-026. The thickness of each sample was reported as sample numbers 1-6 on Table 1 and are identified as "uncompressed" samples. The "average sample thickness" 15 values for each of the four Example groups (Examples 1, 2, 3 and 4) of the six samples in the left, center and right locations are reported in Table 2. The material was folded at the left and right quadrant lines to form an absorbent article, such as that shown in Fig. 5, except that it had an absorbent with a uniform density in the x, y and z directions. The tests results are reported in Tables 3 and 4.
0 0 0 0 0 4 0**0 *.900 Example 2 Uniformly Compressed A sheet of the above-described coform was cut into six samples as explained above and were uniformly compressed in a Carver Laboratory Press, Model No. 2518. This equipment is available from Fred S. Carver, Inc., Menomonee Falls, Wisconsin. A spacer was placed next to the samples so that they were only partially compressed. The measured thickness (after partial compression) for the left and right quadrants and center one-half is listed in Table 1 as sample numbers 8-13 and are identified as "uniformly compressed" samples. The "average sample thickness" values at the left, center and right locations are reported in Table 2. The test results are reported in Tables 3 and 4.
16 Example 3 Compressed EdQes A sheet of the above-described coform was cut into six samples as explained in Example 1. Each sample was compressed only at the left and right quadrants. The thickness of each sample was measured as described above and is reported in Table 1 as sample numbers 14-19 and are identified as "compressed edges" samples. The "average sample thickness" values are reported in Table 2 and the test results are reported in Tables 3 and 4.
Example 4 Compressed Center A sheet of the above-described coform was cut into six samples as explained in Example 1. Each sample was compressed only in the center two quadrants by putting a metal plate over only the area to S. be compressed. When the platens of the press were brought together, 15 pressure was applied on the coform only where the thick metal plate *was positioned over the center two quadrants of the material so the left and right quadrants of the material remained uncompressed. The o thickness of each sample was measured as described above and is reported in Table 1 as sample numbers 20-25 and are identified as "compressed center" samples. The "average sample thickness" values are reported in Table 2 and the test results are reported in Tables 3 and 4.
ee..oi S" Test Results .The time in seconds required to absorb eight milliliters of 25 30% red blood cell bovine blood is reported in Table 3. Sample articles were run with and without meltblown inserts as listed in Table 3. As the time to absorb did not appear to be greatly affected :.by the presence or absence of the meltblown insert, all time numbers were averaged for each coform type and are reported in Column 3, 30 "overall average time (seconds)", with "standard deviations" in Column 4. As predicted, the time to absorb for the "uncompressed" and "compressed edges" samples was about the same at 10.4 seconds and 8.3 seconds, respectively. In both examples, the center absorbing coform was uncompressed. The "moderately densified" samples and the "uniformly compressed" samples had an absorbency time of almost seconds while the samples with the "compressed center" portions, where the absorbency was being evaluated, had an absorbency time in 17 excess of 60 seconds. A plot of the "sample thickness" versus "the inverse of the time to absorb the fluid" is shown in Fig. 21.
Test articles were also evaluated on the "blood wicker" test not using a meltblown insert.
The "blood wicker" test involved the supply of 30% red blood cell bovine blood at 37°C at a flow rate of three grams per hour for three hours to the absorbent article. The articles were then removed from the test stand and a blotter was placed on top of them. One pound per square inch (psi) of pressure was applied to the top of the blotter for three minutes. The blotter was then removed and weighed to determine the amount of fluid that could be wicked out of the top of the article. The value was reported ac the percentage by weight of the fluid that went back into the blotter versus the weight of S 15 fluid applied to the article. A low percentage value indicated a *e drier feeling article. It is readily apparent from Table 4 that the samples with the "compressed edges" had the lowest rewet value at 8.4% versus 22.4%, 26.2% and 27.5% for the other three article 4 4constructions.
The thickness of the four different article constructions without a meltblown insert can be estimated from Table 2 by adding the thickness of the center portion and the average thickness of the o right and left edges. Thus, the thickness of an article made from 4,4, the "uncompressed" sample would be 0.142 (0.144+0.143)/2 0.286 inches. The thickness of an article made from the "uniformly compressed" sample would be 0.154 inches. The thickness of an article made from the "compressed edges" would be 0.173 inches.
Lastly, thickness of an article made from the "compressed center" 44*4 would be 0.195 inches.
30 Accordingly, samples having "compressed edges" retained the desired thinness for comfort and discreetness while maintaining a soft, uncompressed material next to the body for comfort and rapid fluid absorbency. The "compressed edges," which form the bottom layer of.the article when folded into an absorbent article, act as a fluid-wicking material and reservoir to ensure a dry surface next to the skin of the wearer.
18 Table 1 Sample Number 1 2 3 4 6 8 9 11 12 13 Sample Identification Uncompressed (Ex. #1) it It Uniformly Compressed (Ex. #2) Sample Thickness (in Inches) Left Center Right .133 .139 .135 .164 .152 .144 .064 .065 .083 .066 .089 .094 .030 .032 .034 .031 .033 .034 .159 .139 .149 .153 .151 .149 .140 .158 .135 .130 .144 .145 .068 .068 .077 .074 .085 .086 .042 .142 .139 .131 .146 .147 .035 .042 .045 .044 .047 .050 .138 .134 .150 .144 .144 .146 .075 .079 .082 .072 .080 .086 .031 .034 .032 .031 .030 .031 .149 .167 .162 .147 .143 .146 -0.7 Compressed Compressed It Edges (Ex. #3) Center (Ex. #4) Note: "Number 7" was not used to identify any sample.
19 Table 2 Sample Identification Average Sample Thickness (in Inches) Left Center Right Uncompressed (Ex. #1) Uniformly compressed (Ex. #2) Compressed edges (Ex. #3) Compressed center (Ex.#4) Note: All thickness #9.210-026 0.144 0.08 0.077 0.013 0.0323 0.002 0.150 0.007 0.142 0.010 0.076 0.008 0.141 0.006 0.044 0.005 0.143 0.006 0.079 0.005 0.0315 0.001 0.152 0.010
S
S
.S9 00 5 95 measurements taken with a Dyer Gauge Model Table 3 8 Milliliter Absorbency Time (in Seconds) Without Meltblown Insert Coform Type Uncompressed (Ex. #1) 9* S 55 59 5 9550 S 9 13.4, 7.8, 11.1, 12.3, 10.6, 9.11 11.6 6.3 9.1 12.3 25.9 Uniformly compressed (Ex. #2) Compressed edges (Ex. #3) Compressed center (Ex. #4) With Meltblown Insert 10.4, 12.3 12.7, 10.4 8.9 18.6, 29.7 26.8, 31.3 18.6, 18.2 9.1, 6.0 8.7, (52.0*) 25.7 52.2, 36.6 108.4, 22.3 27.2 Overall Average Time,(Sec.) Standard Deviation (Sec.) 10.4 19.4 8.3 6.5, 4.7 3.9, 5.2 5.8 106.4, 52.8 113.9 65.0 36.0 Reading not used in average value; value over seven standard deviations from the mean.
20 L i Table 4 Blotter Rewet Values Without Meltblown Inserts Total Bovine Blood Blotter Average Standard Delivered, Rewet 1 psi Rewet Rewet Deviation Coform Type Grams Value,grams Uncompressed 9.29 2.05 22.1 (Ex. 8.85 1.77 20.0 22.4 2.2 9.46 2.39 25.3 Uniformly 8.33 2.37 28.4 compressed (Ex. 8.71 2.21 25.4 26.2 1.6 8.70 2.16 24.8 Compressed 8.66 0.66 7.6 Sedges (Ex. 9.09 1.03 11.3 8.4 2.2 8.97 0.55 6.1 Compressed 8.60 12.91 22.2 center (Ex. 8.66 2.78 32.1 27.5 4.1 8.80 2.49 28.3 While the invention has been described in conjunction with several specific embodiments, it is to be understood that many alternatives, modifications and variations will be apparent to those skilled in the art in light of the aforegoing description.
5 Accordingly, this invention is intended to embrace all such alternatives, modifications and variations which fall within the spirit and scope of the appended claims.
21
L^

Claims (23)

1. An absorbent article comprising: a) a liquid-permeable cover; and b) an absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to thile z direction, said absorbent having at least two distinct portions, adjacent ones of which are integrally joined together at a junction line, each portion having a thickness different from said at least one adjacent portion, said absorbent being folded along said junction line to obtain at least one upper layer and at least one lower layer, said upper layer having a thickness greater than at least one of said lower layers so as to quickly absorb body fluid and transfer said body fluid into one of said lower layers, said absorbent having a variable density in the z direction, and said folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
2. The absorbent article of claim 1 wherein said absorbent is folded into an upper layer and a lower layer, said lower layer having a thickness less than about 80% of the thickness of said upper layer.
3. The absorbent article of claim 2 wherein said lower layer has a thickness of between about 10-70% of the thickness of said upper layer.
4. The absorbent article of claim 3 wherein said lower layer has a thickness of between about 15-50% of the thickness of said upper layer. An absorbent article comprising: a) a liquid-permeable cover; b) a liquid-impermeable baffle; and c) an absorbent positioned between said cover and said baffle, said absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction, 30 said absorbent having at least three distinct portions, adjacent ones of which are integrally joined together by one of a pair of junction lines, each portion having a thickness different fromn said at least one adjacent portion, said absorbent being folded along said pair of junction lines to obtain an upper layer and at least one lower layer, said upper layer 35 having a greater thickness than said lower layer so as to quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction, and said -o22 22 I na~-- folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
6. The absorbent article of claim 5 wherein said absorbent is folded along said two junction lines.
7. The absorbent article of claim 5 wherein, as the thickness of a portion increases, the density of that portion decreases in the z direction.
8. The absorbent article of claim 5 wherein said portion having the greatest thickness is aligned adjacent to said cover.
9. The absorbent article of claim 5 wherein said portion having the minimum thickness is aligned adjacent to said baffle. The absorbent article of claim 5 wherein said portion having the lowest density in the z direction has a density of between about 0.01 and 0.07 grams per cubic centimeter.
11. The absorbent article of claim 5 wherein said portion having the lowest density in the z direction has a density of between about 0.02 and 0.06 grams per cubic centimeter.
12. An absorbent article comprising: a) a liquid-permeable cover; b) a liquid-impermeable baffle; and c) an absorbent positioned between said cover and said baffle, said absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction, said absorbent having at least three distinct portions, adjacent ones of which are integrally joined together at one of a pair of junction lines, each portion having a thickness different from said at least one adjacent portion, said outer portions being C-folded at said junction lines with opposite ends of the outer two portions abutting one another and aligned 30 adjacent to said baffle, said folded absorbent having a uniform capillary size in any plane aligned perpendicular to the z direction and a variable capillary size in the z direction.
13. The absorbent article of claim 12 wherein said portion of greatest thickness has a density of between about 0.01 and 0.07 grams per 35 cubic centimeter.
14. The absorbent article of claim 12 wherein said portion of minimum thickness has a density of between about 0.07 and 0.30 grams per cubic centimeter. 23 S ST/P03491 i i i, The absorbent article of claim 12 wherein said portion with the greatest thickness is aligned adjacent to said cover.
16. The absorbent article of claim 12 wherein said absorbent is a blend of thermoplastic polymer microfibers and wood pulp fibers.
17. The absorbent article of claim 15 wherein said absorbent is comprised of about 5-70% polypropylene fibers and about 95-30% wood pulp fibers.
18. The absorbent article of claim 17 wherein said absorbent is comprised of about 30% polypropylene fibers and about 70% wood pulp fibers.
19. A method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction into at least two distinct portions which have different thicknesses, at least one of said portions being integrally joined together by a junction line; b) folding said absorbent on said junction line to obtain an upper layer and a lower layer, said upper layer having a greater thickness than said lower layer so as to quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction; and c) positioning a liquid-permeable cover about said absorbent to form an absorbent article.
20. The method of claim 19 wherein said absorbent is folded along said junction line into an upper layer and a lower layer, and further including bonding said liquid-permeable cover to said upper layer. 1
21. The method of claim 20 wherein a liquid-impermeable baffle is secured to said lower layer. 30 22. The method of claim 20 wherein an extra layer of absorbent is positioned between said upper and lower layers of said folded absorbent.
23. The method of claim 19 wherein said absorbent is compressed with sufficient heat and pressure to render one surface substantially .liquid impermeable. 35 24. The method of claim 19 wherein said absorbent is compressed to form at least three distinct portions which are integrally joined together by a pair of junction lines, said two outer portions being 24 \STA/03491,' -f* C-folded at said junction lines with opposite ends of said outer portions abutting one another and aligned away from said liquid-permeable cover. A method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition with an essentially constant density in any plane aligned perpendicular to the z direction to form at least one compressed portion and at least one noncompressed portion, each having a different thickness, adjacent ones of said compressed and noncompressed portions being integrally joined together by a junction line; b) folding said absorbent on said junction line to vertically align said noncompressed portion over said compressed portion so as to quickly absorb body fluid and transfer said body fluid into said lower layer, said absorbent article having a variable density in the z direction; c) positioning a liquid-permeable cover adjacent to a surface of said absorbent; d) positioning a liquid-permeable baffle adjacent to an opposite surface of said absorbent; and e) securing said cover to said baffle to enclose said absorbent and form an absorbent article.
26. The method of claim 25 wherein said liquid-impermeable baffle is positioned adjacent to said compressed portion and said liquid-permeable cover is positioned adjacent to said noncompressed portion.
27. A method of forming an absorbent article comprising the steps of: a) compressing at least a portion of a sheet of absorbent having a homogeneous composition to form at least one compressed portion and at 30 least one noncompressed portion, each having a different thickness, adjacent ones of said compressed and noncompressed portions being S" integrally joine-' together by a junction line; b) folding said absorbent on said junction line to vertically align said compressed portion with said noncompressed portion to create a variable density in the z direction; c) heating an external surface of said compressed portion to a sufficient temperature to fuse said surface and form a liquid-impermeable 8 layer; and 25 STA/03491 d) positioning a liquid-permeable cover about said absorbent to form an absorbent article.
28. An absorbent article substantially as hereinbefore described with reference to the accompanying drawings.
29. A method of forming an absorbent article substantially as hereinbefore described with reference to the accompanying drawings. DATED this EIGHTEENTH day of FEBRUARY 1993 Kimberly-Clark Corporation Patent Attorneys for the Applicant SPRUSON FERGUSON e 6 **0 26 STA/03491 |i ABSORBENT ARTICLE HAVING AN ABSORBENT WITH A VARIABLE DENSITY IN THE Z DIRECTION AND A METHOD OF FORMING SAID ARTICLE Abstract i An absorbent article such as a sanitary napkin, a diaper, training pants, an incontinent garment or a bedpad is disclosed for absorption of human exudate. The absorbent article (20) includes an absorbent (35) having a homogeneous composition with an essentially constant density in the x-y plane. The absorbent (35) has at least two distinct portions which are integrally joined together by a junction line and each portion has a thickness different from an adjacent portion. The absorbent (35) is folded on the junction line to obtain a variable density along the z axis. The folded absorbent (35) also has a uniform capillary size in the x-y plane and a variable capillary size in the z direction. The absorbent article (20) further includes a liquid- 15 permeable cover (38) which is positioned adjacent to at least one surface c 0o of the absorbent A method of forming the article is also disclosed. 4 SO I 4 1@89 44 L Fig. Fig 1 GSA/2121M
AU84622/91A 1990-10-09 1991-09-19 Absorbent article having an absorbent with a variable density in the z direction and a method of forming said article Ceased AU636796B2 (en)

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US07/685,585 US5611879A (en) 1987-12-18 1991-04-15 Absorbent article having an absorbent with a variable density in the Z direction and a method of forming said article
US685585 1991-04-15

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3858585A (en) * 1971-03-22 1975-01-07 Personal Products Co Fluid absorption and retention products and methods of making the same
GB2157570A (en) * 1984-04-21 1985-10-30 Winkler Duennebier Kg Masch Absorbent pad for hygienic purposes and method of manufacture
DE3620077A1 (en) * 1986-06-14 1987-12-17 Pelz & Co Kg W Absorbent body as panty liner or sanitary towel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3858585A (en) * 1971-03-22 1975-01-07 Personal Products Co Fluid absorption and retention products and methods of making the same
GB2157570A (en) * 1984-04-21 1985-10-30 Winkler Duennebier Kg Masch Absorbent pad for hygienic purposes and method of manufacture
DE3620077A1 (en) * 1986-06-14 1987-12-17 Pelz & Co Kg W Absorbent body as panty liner or sanitary towel

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