AU632805B2 - Silica for dentifrice compositions more particularly compatible with metal cations - Google Patents

Silica for dentifrice compositions more particularly compatible with metal cations

Info

Publication number
AU632805B2
AU632805B2 AU54581/90A AU5458190A AU632805B2 AU 632805 B2 AU632805 B2 AU 632805B2 AU 54581/90 A AU54581/90 A AU 54581/90A AU 5458190 A AU5458190 A AU 5458190A AU 632805 B2 AU632805 B2 AU 632805B2
Authority
AU
Australia
Prior art keywords
silica
equal
aqueous suspension
electrical conductivity
expressed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU54581/90A
Other versions
AU5458190A (en
Inventor
Jacques Persello
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Publication of AU5458190A publication Critical patent/AU5458190A/en
Application granted granted Critical
Publication of AU632805B2 publication Critical patent/AU632805B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/152—Preparation of hydrogels
    • C01B33/154—Preparation of hydrogels by acidic treatment of aqueous silicate solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
    • C01B33/187—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates
    • C01B33/193—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by acidic treatment of silicates of aqueous solutions of silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/19—Oil-absorption capacity, e.g. DBP values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Cosmetics (AREA)
  • Silicon Compounds (AREA)
  • Dental Preparations (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Glass Compositions (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Silica compatible with metal ions such as zinc, tin or strontium, characterised by a surface OH<-> number expressed as OH<->/nm<2> lower than or equal to 10, a zero charge point (ZCP) of between 3 and 6.5 and resulting in an aqueous suspension whose pH varies as a function of its electrical conductivity according to the equation - pH = b - a log (D), in which a is a constant lower than or equal to 0.6, b is a constant lower than or equal to 8.5 and (D) represents the electrical conductivity of the aqueous suspension of silica, expressed in microsiemens cm<-><1>. Process for preparing the silica, consisting in reacting a silicate with an acid, thus resulting in a silica suspension or gel, in performing a first aging at a pH higher than or equal to 6 and lower than or equal to 8.5, then a second aging at a pH lower than or equal to 5.0, in separating off the silica, in subjecting it to washing with hot water until it produces an aqueous suspension whose pH measured on a suspension containing 20 % of SiO2 obeys the equation - pH = d - c log (D> in which c is a constant lower than or equal to 1.0, d is a constant lower than or equal to 8.5 and (D) denotes the electrical conductivity of the aqueous suspension of silica, expressed in microsiemens cm<-><1>; and finally in drying it. Dentifrice composition containing the silica described.
AU54581/90A 1989-05-03 1990-05-01 Silica for dentifrice compositions more particularly compatible with metal cations Ceased AU632805B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8905869 1989-05-03
FR8905869A FR2646665B1 (en) 1989-05-03 1989-05-03 SILICA FOR TOOTHPASTE COMPOSITIONS COMPATIBLE IN PARTICULAR WITH METAL CATIONS

Publications (2)

Publication Number Publication Date
AU5458190A AU5458190A (en) 1990-11-08
AU632805B2 true AU632805B2 (en) 1993-01-14

Family

ID=9381381

Family Applications (1)

Application Number Title Priority Date Filing Date
AU54581/90A Ceased AU632805B2 (en) 1989-05-03 1990-05-01 Silica for dentifrice compositions more particularly compatible with metal cations

Country Status (24)

Country Link
EP (1) EP0396460B1 (en)
JP (1) JPH0660010B2 (en)
KR (1) KR920008563B1 (en)
CN (2) CN1023105C (en)
AT (1) ATE81333T1 (en)
AU (1) AU632805B2 (en)
BR (1) BR9002064A (en)
CA (1) CA2015921C (en)
DE (1) DE69000369T2 (en)
DK (1) DK0396460T3 (en)
ES (1) ES2036093T3 (en)
FI (1) FI91387C (en)
FR (1) FR2646665B1 (en)
GR (1) GR3006675T3 (en)
HK (1) HK129893A (en)
IE (1) IE63592B1 (en)
IL (1) IL94248A0 (en)
MA (1) MA21827A1 (en)
NO (1) NO901884L (en)
PT (1) PT93950B (en)
SG (1) SG116793G (en)
TN (1) TNSN90057A1 (en)
TR (1) TR24206A (en)
ZA (1) ZA903325B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140271749A1 (en) * 2010-02-19 2014-09-18 J.M. Huber Corporation Silica Materials for Reducing Oral Malodor

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2714369B1 (en) * 1993-12-29 1996-01-26 Rhone Poulenc Chimie Abrasive silicas for toothpaste compositions.
GB9601084D0 (en) † 1996-01-19 1996-03-20 Unilever Plc Amorphous silicas and oral compositions
JP2001089128A (en) * 1998-04-10 2001-04-03 Asahi Glass Co Ltd Production of spherical silica particle
FR2886285B1 (en) * 2005-05-27 2008-05-30 Rhodia Chimie Sa PROCESS FOR THE PREPARATION OF PRECIPITATED SILICA, PRECIPITATED SILICA AND USES, IN PARTICULAR AS CHARGING IN SILICONE MATRICES
KR101317439B1 (en) * 2006-10-31 2013-10-10 (주)아모레퍼시픽 Toothpaste composition for tooth whitening
US20100047742A1 (en) * 2008-08-25 2010-02-25 Pitcock Jr William Henry Tubule-blocking silica materials for dentifrices
DE102009001512A1 (en) * 2009-03-12 2010-09-16 Evonik Degussa Gmbh Production of high-purity suspensions containing precipitated silicas by electrodialysis
US11052029B2 (en) 2009-06-16 2021-07-06 W. R. Grace & Co.-Conn. Cation compatible metal oxides and oral care compositions containing the metal oxides
AR079182A1 (en) * 2009-06-16 2012-01-04 Grace W R & Co CATIONICO METAL OXIDES - COMPATIBLE AND COMPOSITIONS FOR BUCODENTAL CARE CONTAINING METAL OXIDES
US10806685B2 (en) * 2011-09-30 2020-10-20 Rubicon Research Private Limited Oral care compositions
FR3014312B1 (en) * 2013-12-05 2016-11-25 Oreal COMPOSITIONS COMPRISING A SEBUM PUMP LOAD AND A HIGH QUANTITY OF MONO-ALCOHOL
EP3105178B1 (en) * 2014-02-14 2017-12-20 Rhodia Operations Process for the preparation of precipitated silicas, precipitated silicas and their uses, in particular for the reinforcement of polymers
JP6463369B2 (en) * 2014-02-14 2019-01-30 ローディア オペレーションズ Process for producing precipitated silicas, precipitated silicas and their use, in particular for strengthening polymers
CN106009782B (en) * 2016-05-20 2017-07-07 广州市飞雪材料科技有限公司 A kind of preparation method of surface modified silicon dioxide particle
CN106865557A (en) * 2017-02-10 2017-06-20 福建正盛无机材料股份有限公司 A kind of preparation method of Tire used in winter white carbon
EP3774655B1 (en) * 2018-03-29 2023-05-24 Tata Chemicals Limited A process for preparing precipitated silica
KR20210021520A (en) * 2018-06-19 2021-02-26 로디아 오퍼레이션스 Silica for oral care composition
WO2021069256A1 (en) 2019-10-07 2021-04-15 Rhodia Operations Silica for oral care compositions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4015996A (en) * 1974-10-31 1977-04-05 J. M. Huber Corporation Amorphous precipitated siliceous pigments
US4045240A (en) * 1972-09-06 1977-08-30 J. M. Huber Corporation Amorphous precipitated siliceous pigments and methods for their production
US4590052A (en) * 1984-04-06 1986-05-20 Rhone-Poulenc Chimie De Base Precipitated silica having improved morphological characteristics and process for the production thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2344805A1 (en) * 1972-08-24 1974-03-21 Sifrance Silicon oxide pigments used for toothpaste prodn
FR2632185B1 (en) * 1988-06-01 1992-05-22 Rhone Poulenc Chimie SILICA FOR TOOTHPASTE COMPOSITIONS COMPATIBLE IN PARTICULAR WITH ZINC

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4045240A (en) * 1972-09-06 1977-08-30 J. M. Huber Corporation Amorphous precipitated siliceous pigments and methods for their production
US4015996A (en) * 1974-10-31 1977-04-05 J. M. Huber Corporation Amorphous precipitated siliceous pigments
US4590052A (en) * 1984-04-06 1986-05-20 Rhone-Poulenc Chimie De Base Precipitated silica having improved morphological characteristics and process for the production thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140271749A1 (en) * 2010-02-19 2014-09-18 J.M. Huber Corporation Silica Materials for Reducing Oral Malodor

Also Published As

Publication number Publication date
TNSN90057A1 (en) 1991-03-05
IE63592B1 (en) 1995-05-17
PT93950A (en) 1991-01-08
SG116793G (en) 1994-04-15
BR9002064A (en) 1991-08-13
CN1081099A (en) 1994-01-26
CN1043845C (en) 1999-06-30
CA2015921C (en) 1998-12-29
IE901605L (en) 1990-11-03
DK0396460T3 (en) 1992-11-16
HK129893A (en) 1993-12-03
CA2015921A1 (en) 1990-11-03
FI902208A0 (en) 1990-05-02
PT93950B (en) 1996-11-29
NO901884D0 (en) 1990-04-27
NO901884L (en) 1990-11-05
GR3006675T3 (en) 1993-06-30
FR2646665A1 (en) 1990-11-09
DE69000369T2 (en) 1993-04-15
JPH02296712A (en) 1990-12-07
ZA903325B (en) 1991-02-27
JPH0660010B2 (en) 1994-08-10
KR900017908A (en) 1990-12-20
ATE81333T1 (en) 1992-10-15
ES2036093T3 (en) 1993-05-01
CN1023105C (en) 1993-12-15
EP0396460A1 (en) 1990-11-07
CN1046877A (en) 1990-11-14
FR2646665B1 (en) 1991-11-29
IL94248A0 (en) 1991-03-10
DE69000369D1 (en) 1992-11-12
TR24206A (en) 1991-07-01
EP0396460B1 (en) 1992-10-07
FI91387B (en) 1994-03-15
MA21827A1 (en) 1990-12-31
FI91387C (en) 1994-06-27
AU5458190A (en) 1990-11-08
KR920008563B1 (en) 1992-10-01

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