AU5198893A - Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines - Google Patents

Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines

Info

Publication number
AU5198893A
AU5198893A AU51988/93A AU5198893A AU5198893A AU 5198893 A AU5198893 A AU 5198893A AU 51988/93 A AU51988/93 A AU 51988/93A AU 5198893 A AU5198893 A AU 5198893A AU 5198893 A AU5198893 A AU 5198893A
Authority
AU
Australia
Prior art keywords
exhaust gas
gas purification
cold start
purification system
combustion engines
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU51988/93A
Other versions
AU666235B2 (en
Inventor
Bernd Engler
Dieter Lindner
Egbert Lox
Klaus Ostgathe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Degussa GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa GmbH filed Critical Degussa GmbH
Publication of AU5198893A publication Critical patent/AU5198893A/en
Application granted granted Critical
Publication of AU666235B2 publication Critical patent/AU666235B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9481Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0454Controlling adsorption
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0835Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2250/00Combinations of different methods of purification
    • F01N2250/12Combinations of different methods of purification absorption or adsorption, and catalytic conversion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00Selection of materials for exhaust purification
    • F01N2370/02Selection of materials for exhaust purification used in catalytic reactors
    • F01N2370/04Zeolitic material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00Engines characterised by fuel-air mixture compression
    • F02B1/02Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Abstract

The invention relates to an exhaust gas purification system for decreasing the emissions of hydrocarbons during the cold start of internal combustion engines. The exhaust gas purification system contains a hydrocarbon adsorber and a downstream catalyst system which can be composed of a single three-way catalyst or of a combination of oxidation, reduction and/or three-way catalysts in one or more beds. The hydrocarbon emissions during the cold start phase can be significantly decreased by using oxidation catalysts or three-way catalysts which, in comparison with conventional catalysts, have at least twice the loading of platinum and/or palladium.
AU51988/93A 1992-11-27 1993-11-26 Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines Ceased AU666235B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4239875A DE4239875C2 (en) 1992-11-27 1992-11-27 Exhaust gas purification system to reduce hydrocarbon emissions during the cold start of internal combustion engines
DE4239875 1992-11-27

Publications (2)

Publication Number Publication Date
AU5198893A true AU5198893A (en) 1994-06-09
AU666235B2 AU666235B2 (en) 1996-02-01

Family

ID=6473778

Family Applications (1)

Application Number Title Priority Date Filing Date
AU51988/93A Ceased AU666235B2 (en) 1992-11-27 1993-11-26 Exhaust gas purification system for reducing hydrocarbon emissions during the cold start of combustion engines

Country Status (18)

Country Link
EP (1) EP0601314B1 (en)
JP (1) JP3816113B2 (en)
KR (1) KR100283341B1 (en)
CN (1) CN1096712A (en)
AT (1) ATE157557T1 (en)
AU (1) AU666235B2 (en)
BR (1) BR9304864A (en)
CA (1) CA2110139C (en)
CZ (1) CZ288516B6 (en)
DE (2) DE4239875C2 (en)
ES (1) ES2108797T3 (en)
FI (1) FI104749B (en)
HU (1) HU212892B (en)
MX (1) MX9307424A (en)
NO (1) NO304502B1 (en)
PL (1) PL174499B1 (en)
TW (1) TW303307B (en)
ZA (1) ZA938864B (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5492679A (en) * 1993-03-08 1996-02-20 General Motors Corporation Zeolite/catalyst wall-flow monolith adsorber
DE4436890A1 (en) * 1994-10-15 1996-04-18 Degussa Process for the simultaneous reduction of the hydrocarbons, carbon monoxide and nitrogen oxides contained in the exhaust gas of an internal combustion engine
EP0716877A1 (en) * 1994-12-13 1996-06-19 Johnson Matthey Public Limited Company Catalytic purification of engine exhaust gas
US5510086A (en) * 1995-04-10 1996-04-23 General Motors Corporation Adcat exhaust treatment device
US6696389B1 (en) 1996-02-23 2004-02-24 Daimlerchrysler Ag Process and apparatus for cleaning a gas flow
DE19614540A1 (en) * 1996-04-12 1997-10-16 Degussa Diesel catalyst
EP0842700B1 (en) * 1996-11-11 1999-03-24 Degussa Ag Exhaust gas purifying catalyst with improved hydrocarbon conversion
JP3417309B2 (en) * 1997-10-28 2003-06-16 トヨタ自動車株式会社 Hydrocarbon adsorbent
DK1002186T3 (en) * 1997-11-30 2001-05-28 Wissenschaftliche Werkstatt Fu Method for recognizing defects in the engine and exhaust aftertreatment system by measuring the components of pollutants in the exhaust gas during cold start and driving
EP1129774A4 (en) * 1998-10-28 2003-04-16 Toyota Motor Co Ltd Adsorbent for hydrocarbon and catalyst for exhaust gas purification
DE10023049B4 (en) * 2000-05-11 2008-04-30 Volkswagen Ag Method for determining a mounting point of a precatalyst in the exhaust line of the internal combustion engine
ES2182721B1 (en) * 2001-07-27 2004-01-16 Univ Valencia Politecnica A CATALYTIC SYSTEM TO DECREASE EMISSIONS OF VOLATILE ORGANIC COMPOUNDS IN COMBUSTION GASES.
FR2841937B1 (en) 2002-07-08 2006-07-14 Faurecia Sys Echappement MECHANICAL POWER GENERATOR COMPRISING A DIESEL ENGINE AND A CATALYTIC CONVERTER
JP4507018B2 (en) * 2008-06-27 2010-07-21 三菱自動車工業株式会社 Exhaust gas purification device for internal combustion engine
DE102013210270A1 (en) 2013-06-03 2014-12-04 Umicore Ag & Co. Kg three-way
RU2670754C2 (en) 2013-10-30 2018-10-25 Джонсон Мэтти Паблик Лимитед Компани Three-way catalyst and use thereof in exhaust systems
DE102014204682A1 (en) 2014-03-13 2015-10-01 Umicore Ag & Co. Kg Catalyst system for reducing noxious gases from gasoline internal combustion engines
CN104307476A (en) * 2014-11-05 2015-01-28 上海纳米技术及应用国家工程研究中心有限公司 Method for preparation of low-concentration carbureted hydrogen gas adsorbing agent
WO2017003981A1 (en) 2015-06-29 2017-01-05 Corning Incorporated Porous ceramic body to reduce emissions
US9987626B2 (en) * 2015-08-20 2018-06-05 Ford Global Technologies, Llc Use of transition metals to reduce cold start emissions
US9879587B2 (en) * 2015-10-23 2018-01-30 GM Global Technology Operations LLC Diagnosing oxidation catalyst device with hydrocarbon storage
US10898886B2 (en) * 2016-08-26 2021-01-26 Ford Global Technologies, Llc Hydrocarbon and nitrogen oxides catalyst trap

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0615016B2 (en) * 1988-09-09 1994-03-02 トヨタ自動車株式会社 Automotive exhaust gas purification device
JPH0625538B2 (en) * 1989-10-24 1994-04-06 ニチアス株式会社 Exhaust gas purification device for methanol engine
JPH03141816A (en) * 1989-10-27 1991-06-17 Toyota Motor Corp Exhaust gas purifier
US5078979A (en) * 1990-07-20 1992-01-07 Uop Molecular sieve bed/catalyst to treat automotive exhaust
US5296198A (en) * 1990-11-09 1994-03-22 Ngk Insulators, Ltd. Heater and catalytic converter
US5271906A (en) * 1991-10-28 1993-12-21 Toyota Jidosha Kabushiki Kaisha Exhaust emission control apparatus using catalytic converter with hydrocarbon absorbent
DE4226394C2 (en) * 1992-08-10 1999-01-21 Degussa Process for catalytic exhaust gas cleaning with improved cold start behavior

Also Published As

Publication number Publication date
CZ288516B6 (en) 2001-07-11
ES2108797T3 (en) 1998-01-01
MX9307424A (en) 1994-07-29
CA2110139A1 (en) 1994-05-28
PL174499B1 (en) 1998-08-31
NO934269D0 (en) 1993-11-25
NO304502B1 (en) 1999-01-04
PL301228A1 (en) 1994-05-30
DE59307263D1 (en) 1997-10-09
EP0601314B1 (en) 1997-09-03
CZ255993A3 (en) 1994-06-15
HU9303345D0 (en) 1994-03-28
ZA938864B (en) 1994-08-02
NO934269L (en) 1994-05-30
KR100283341B1 (en) 2001-03-02
JPH06210136A (en) 1994-08-02
FI935278A (en) 1994-05-28
AU666235B2 (en) 1996-02-01
DE4239875C2 (en) 1999-02-11
TW303307B (en) 1997-04-21
FI104749B (en) 2000-03-31
BR9304864A (en) 1994-05-31
EP0601314A1 (en) 1994-06-15
CA2110139C (en) 1999-03-23
DE4239875A1 (en) 1994-06-01
JP3816113B2 (en) 2006-08-30
CN1096712A (en) 1994-12-28
HU212892B (en) 1996-12-30
ATE157557T1 (en) 1997-09-15
HUT70018A (en) 1995-09-28
FI935278A0 (en) 1993-11-26

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Legal Events

Date Code Title Description
MK14 Patent ceased section 143(a) (annual fees not paid) or expired