AU4765293A - Method for the manufacture of an antrifriction agent and antifriction agent - Google Patents
Method for the manufacture of an antrifriction agent and antifriction agentInfo
- Publication number
- AU4765293A AU4765293A AU47652/93A AU4765293A AU4765293A AU 4765293 A AU4765293 A AU 4765293A AU 47652/93 A AU47652/93 A AU 47652/93A AU 4765293 A AU4765293 A AU 4765293A AU 4765293 A AU4765293 A AU 4765293A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/04—Metals; Alloys
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
- C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
- C10M133/14—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/02—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1208—Inorganic compounds elements
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1233—Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/05—Metals; Alloys
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/10—Groups 5 or 15
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/14—Group 7
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/16—Groups 8, 9, or 10
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Lubricants (AREA)
- Enzymes And Modification Thereof (AREA)
Description
METHOD FOR MANUFACTURE OF AN ANTIFRICTION AGENT AND ANTIFRICTION AGENT
The subject of the invention is the method of the antifriction agent anufacture and the antifriction agent, made on a base of the particles of colloidal dispersion of copper or vanadium or chromium or cot alt or nickel or their oxides or their combinations. There are known additions to the lubricating media, mostly containing powders of tin(Su), copper(Cu), lead(Pb), zinc(Zn) or other metals, contents of which improves the characteristics which have an influence on the performance of plastic or liquid lubricants, thereby reducing friction and wear of co-acting parts and at the same time raising their electrical conductivity.
There are also known additions to fuels which have anti-smoke properties, decreasing the level of noxious substances in exhaust gases, especially in compression-ignition engines. Besides, there's known an addition to fuels which contains iron oxides thoroughly mixed with fuel. The optimum contents of iron oxides in fuel is 0.01 to 0.1 % of the fuel's weight, what allows to reduce the formation of soot by 21 %. However, the anti-smoke properties of this addition are poor and there's a disadvantage of a lack of anti-slide properties, what limits its broad application.
From the Polish description of the invention application No. P-293400, there is a known method of producing an addition, especially to the lubricating media, cutting fluids and fuels on the base of particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations, ace. to the invention where the method is, that to the necessary amount of the particles of the colloidial dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations - a liquid medium is added, at the best a low viscosity oil, so that per every two parts by weight of colloidal particles of pure metal there is one part by weight of the liquid medium. Then the ingredients are mixed. After that, a surface active agent is added, at the best oleic acid, so that per every two parts by weight of colloidal particles of pure metal there is one part by weight of the liquid medium and 0.8 to 1.5 parts by weight of surface active agent. Then the ingredients are mixed. Then the liquid medium is added to obtain such a proportion in which per two parts by weight of colloidal particles of pure metal there are two parts by weight of liquid medium and 0.8 to 1.5 parts by weight of surface active agent. The addition, especially to lubricating media, cutting tool lubricants and fuel, ace. to the Polish description of the application of invention No. P-293400 on the base of
particles of the colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations contains the percentage concentration of pure metal's atoms or ions in addition to the weight of lubricating media, cutting-tool lubricants or fuels from 1×10 -2 to 2.2×10 -4 . The purpose of the invention is the development of the method of manufacturing the antifriction agent and the antifriction agent itself, which increases the service life of co-acting parts. The method of the antifriction agent production on a basis of the particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations, according to the invention, depends on that to the necessary quantity of the particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations a liquid medium is added, at the best, low viscosity oil, so that per two parts by weight of colloidal particles of pure metal there's one to two parts by weight of liquid medium, mixing the ingredients at the same time. Then to the mixture a stabilizing surface active agent is added, at the best oleic acid, so after that, per two parts by weight of colloidal particles of pure metal there is one to two parts by weight of the liquid medium and 0.8 to 1.5 parts by weight of the surface active agent, mixing the ingredients. Then the liquid medium and aminobenzoic acid, at the best, are added until obtaining such a ratio where per two parts by weight of colloidal particles of pure metal we've got 2.0 to 47 parts by weight of liquid medium, 0.8 to 1.5 parts by weight of surface active agent and 2.5×10 -2 to 5.0x 10 -2 parts by weight of aminobenzoic acid.
The antifriction agent on a bases of particles of the collodial dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations, according to the invention contains from 1×10 -2 to 2.2×0 -4 atoms or ions of pure metal, 0.5×10 -2 to 1.1×10 -4 of surface active agent , at the best - oleic acid, and 2.75×10 -6 to 2.5×10 -4 of aminobenzoic acid - at the best, in relation to its weight.
EXAMPLE
Prepare a solution of 34.5 g of sodium hydroxide in 600ml of water and filtrate it. Prepare a solution of 100g of blue vitriol in 400ml of water and filtrate it as well. Warmed up to the temp, of 70 ° C, the solution of blue vitriol is added to the solution of sodium hydroxide and the achieved mixture is mixed for 15 minutes and then poured into the water to get the volume from 2 1 to 4 1. The obtained mixture is subjected to the decantation until all the SO 4 ions are separated, given, the separated water shouldn't become turbid in next 2 hours after adding barium chloride. Add the liquid medium to the obtained cupric oxide deposit, at the best, low viscosity oil, so that per two parts by weight of cupric oxide there is 1.5 parts by weight of the liquid medium. Mix the ingredients thoroughly, then add to the mixture the surface active agent at the best - oleic acid, to reach the proportion in which per two parts by weight of cupric oxide there is 1.5 parts by weight of the liquid medium and 0.9 parts by weight of surface active agent.
Such a mixture is filled up with the liquid medium, not interrupting mixing, until its such contents is obtained where per two parts by weight of cupric oxide there is 20 parts by weight of the liquid medium and 0.9 parts by weight of surface active agent.
On obtaining the intimate mixture, the liquid medium is added, at the best-aminobenzoic acid, until a ratio is obtained where per two parts by weight of
colloidal particies of pure metal there is 2.0 to 47 parts by weight of liquid medium and 2.5×10 -2 to 5.0×10 -2 pirts by weight of aminobenzoic acid.
Obtained in this was the mixture of the particles of colloidal dispersion of copper is added to lubricating media, cutting fluids and fuels.
Claims (2)
1. The method of the antifriction agent manufacture on the base of the particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations, distinguished by the fact that to the necessary quantity of particles of colloidal dispersion of copper or vanadium or chromium or cobalt or nickel or their oxides or their combinations a liquid medium is added, at the best low viscosity oil, in such a proportion that per two parts by weight of colloidal particles of pure metal there's one to two parts by weight of liquid medium, and the ingredients it are mixed at the same time. Then a stabilizing surface active agent, oleic acid at the best, is added, so per two parts by weight of colloidal particles of pure metal there is one to two parts by weight of the liquid medium and 0.8 to 1.5 parts by weight of the surface active agent, mixing the ingredients, and then the liquid medium and, at the best aminobenzoic acid are added until such ratio is obtained where per two parts by weight of colloidal particles of pure metal there's 2.0 to 47 parts by weight of the liquid medium, 0.8 to 1.5 parts by weight of surface active agent and 2.5×10 -2 to 5.0×10 -2 parts by weight of the aminobenzoic acid.
2. The antifriction agent on a base of the particles of colloidal dispersion of copper or vanadium or chromium or nickel or their oxides or their combinations, characterized by, that it contains 1×10 - 2 to 2.2×10 -4 atoms or ions of pure metal.
0.5×10 -2 to 1.1×10 -4 of surface active agent, at the best oleic acid, and most favourably 2.75×10 -6 to 2.5×10 -4 of aminobenzoic acid in ratio to its weight.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL92295708A PL170502B1 (en) | 1992-08-21 | 1992-08-21 | Method of obtaining an antifriction agent and antifriction agent as such |
PL295708 | 1992-08-21 | ||
PCT/PL1993/000014 WO1994004638A1 (en) | 1992-08-21 | 1993-08-18 | Method for the manufacture of an antrifriction agent and antifriction agent |
Publications (2)
Publication Number | Publication Date |
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AU4765293A true AU4765293A (en) | 1994-03-15 |
AU673684B2 AU673684B2 (en) | 1996-11-21 |
Family
ID=20058355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU47652/93A Ceased AU673684B2 (en) | 1992-08-21 | 1993-08-18 | Method for the manufacture of an antrifriction agent and antifriction agent |
Country Status (11)
Country | Link |
---|---|
JP (1) | JPH07507092A (en) |
KR (1) | KR100271189B1 (en) |
AU (1) | AU673684B2 (en) |
CA (1) | CA2121779A1 (en) |
CZ (1) | CZ121394A3 (en) |
DE (1) | DE4394035T1 (en) |
DK (1) | DK45694A (en) |
HU (1) | HUT67935A (en) |
PL (1) | PL170502B1 (en) |
SK (1) | SK58894A3 (en) |
WO (1) | WO1994004638A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8741821B2 (en) | 2007-01-03 | 2014-06-03 | Afton Chemical Corporation | Nanoparticle additives and lubricant formulations containing the nanoparticle additives |
US8333945B2 (en) | 2011-02-17 | 2012-12-18 | Afton Chemical Corporation | Nanoparticle additives and lubricant formulations containing the nanoparticle additives |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6289794A (en) * | 1986-10-08 | 1987-04-24 | Taihoo Kogyo Kk | Production of fuel additive |
SU1635904A3 (en) * | 1989-05-15 | 1991-03-15 | Л.А.Хохлов, Л.Г.Кошелев, Ю.Ю.Белоус, А.М.Романюха, И.Н.За ц и В.П.Барабан | Antifriction additive to lubrication oils |
DE4017914A1 (en) * | 1990-06-02 | 1991-12-05 | Peissig Werner | Addn. of oleic acid and copper powder to air intake in I.C. engine - to obtain improved friction coupling and environmental effects |
-
1992
- 1992-08-21 PL PL92295708A patent/PL170502B1/en unknown
-
1993
- 1993-08-18 CZ CZ941213A patent/CZ121394A3/en unknown
- 1993-08-18 AU AU47652/93A patent/AU673684B2/en not_active Ceased
- 1993-08-18 WO PCT/PL1993/000014 patent/WO1994004638A1/en not_active Application Discontinuation
- 1993-08-18 JP JP6506139A patent/JPH07507092A/en active Pending
- 1993-08-18 SK SK588-94A patent/SK58894A3/en unknown
- 1993-08-18 KR KR1019940701312A patent/KR100271189B1/en not_active IP Right Cessation
- 1993-08-18 HU HU9401532A patent/HUT67935A/en unknown
- 1993-08-18 CA CA002121779A patent/CA2121779A1/en not_active Abandoned
- 1993-08-18 DE DE4394035T patent/DE4394035T1/en not_active Withdrawn
-
1994
- 1994-04-20 DK DK045694A patent/DK45694A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
JPH07507092A (en) | 1995-08-03 |
CA2121779A1 (en) | 1994-03-03 |
HU9401532D0 (en) | 1994-09-28 |
SK58894A3 (en) | 1994-09-07 |
PL295708A1 (en) | 1994-03-07 |
AU673684B2 (en) | 1996-11-21 |
KR100271189B1 (en) | 2000-12-01 |
DK45694A (en) | 1994-06-13 |
WO1994004638A1 (en) | 1994-03-03 |
DE4394035T1 (en) | 1994-11-10 |
HUT67935A (en) | 1995-05-29 |
PL170502B1 (en) | 1996-12-31 |
CZ121394A3 (en) | 1994-11-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |