AU4753000A - Antiperspirant stick - Google Patents
Antiperspirant stick Download PDFInfo
- Publication number
- AU4753000A AU4753000A AU47530/00A AU4753000A AU4753000A AU 4753000 A AU4753000 A AU 4753000A AU 47530/00 A AU47530/00 A AU 47530/00A AU 4753000 A AU4753000 A AU 4753000A AU 4753000 A AU4753000 A AU 4753000A
- Authority
- AU
- Australia
- Prior art keywords
- weight
- carbon atoms
- stick composition
- antiperspirant stick
- fatty
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 230000001166 anti-perspirative effect Effects 0.000 title claims description 21
- 239000003213 antiperspirant Substances 0.000 title claims description 21
- 239000000203 mixture Substances 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 21
- -1 alkane diols Chemical class 0.000 claims description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 230000002401 inhibitory effect Effects 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 150000001983 dialkylethers Chemical class 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000010419 fine particle Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 239000000454 talc Substances 0.000 claims description 4
- 235000012222 talc Nutrition 0.000 claims description 4
- 229910052623 talc Inorganic materials 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004164 Wax ester Substances 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical class 0.000 claims description 2
- 235000003441 saturated fatty acids Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 150000003626 triacylglycerols Chemical class 0.000 claims description 2
- 235000019386 wax ester Nutrition 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229960001422 aluminium chlorohydrate Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- HAMGNFFXQJOFRZ-UHFFFAOYSA-L aluminum;zirconium(4+);chloride;hydroxide;hydrate Chemical compound O.[OH-].[Al+3].[Cl-].[Zr+4] HAMGNFFXQJOFRZ-UHFFFAOYSA-L 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- LVYZJEPLMYTTGH-UHFFFAOYSA-H dialuminum chloride pentahydroxide dihydrate Chemical compound [Cl-].[Al+3].[OH-].[OH-].[Al+3].[OH-].[OH-].[OH-].O.O LVYZJEPLMYTTGH-UHFFFAOYSA-H 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000012766 organic filler Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- ZQCIPRGNRQXXSK-UHFFFAOYSA-N 1-octadecoxypropan-2-ol Chemical compound CCCCCCCCCCCCCCCCCCOCC(C)O ZQCIPRGNRQXXSK-UHFFFAOYSA-N 0.000 description 1
- BXMZIUSKYCZVAK-UHFFFAOYSA-N 11,12-dihydroxyoctadecanoic acid Chemical compound CCCCCCC(O)C(O)CCCCCCCCCC(O)=O BXMZIUSKYCZVAK-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- CFSSWEQYBLCBLH-UHFFFAOYSA-N 14-methylpentadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCO CFSSWEQYBLCBLH-UHFFFAOYSA-N 0.000 description 1
- KSFOXDIJLHOECZ-UHFFFAOYSA-K 2,3-dihydroxybutanedioic acid trichloroalumane Chemical compound Cl[Al](Cl)Cl.OC(C(O)C(O)=O)C(O)=O KSFOXDIJLHOECZ-UHFFFAOYSA-K 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical group CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- JYZLSYFPFQTNNO-UHFFFAOYSA-N 2-octyldecan-1-ol Chemical compound CCCCCCCCC(CO)CCCCCCCC JYZLSYFPFQTNNO-UHFFFAOYSA-N 0.000 description 1
- XXBAQTDVRLRXEV-UHFFFAOYSA-N 3-tetradecoxypropan-1-ol Chemical compound CCCCCCCCCCCCCCOCCCO XXBAQTDVRLRXEV-UHFFFAOYSA-N 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241001440269 Cutina Species 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000011128 aluminium sulphate Nutrition 0.000 description 1
- YCLAMANSVUJYPT-UHFFFAOYSA-L aluminum chloride hydroxide hydrate Chemical compound O.[OH-].[Al+3].[Cl-] YCLAMANSVUJYPT-UHFFFAOYSA-L 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- XILPPDQAWPSZIL-UHFFFAOYSA-H dialuminum;dichloride;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[Cl-].[Cl-] XILPPDQAWPSZIL-UHFFFAOYSA-H 0.000 description 1
- 150000002009 diols Chemical group 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 150000002338 glycosides Chemical class 0.000 description 1
- UBHWBODXJBSFLH-UHFFFAOYSA-N hexadecan-1-ol;octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO.CCCCCCCCCCCCCCCCCCO UBHWBODXJBSFLH-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940044652 phenolsulfonate Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 229940078491 ppg-15 stearyl ether Drugs 0.000 description 1
- 229940116987 ppg-3 myristyl ether Drugs 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- WHYLHKYYLCEERH-UHFFFAOYSA-J tetrasodium;2-oxidopropanoate;zirconium(4+) Chemical compound [Na+].[Na+].[Na+].[Na+].[Zr+4].CC([O-])C([O-])=O.CC([O-])C([O-])=O.CC([O-])C([O-])=O.CC([O-])C([O-])=O WHYLHKYYLCEERH-UHFFFAOYSA-J 0.000 description 1
- VXYADVIJALMOEQ-UHFFFAOYSA-K tris(lactato)aluminium Chemical compound CC(O)C(=O)O[Al](OC(=O)C(C)O)OC(=O)C(C)O VXYADVIJALMOEQ-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
WO 00/67713 1 PCT/EP00/03863 Antiperspirant Stick This invention relates to an antiperspirant stick of the water-free or substantially water-free type in which the perspiration-inhibiting agents (perspiration inhibitors) are dispersed in a carrier consisting of a liquid nonpolar carrier material, solidifying fatty or wax components and 5 surfactants. There are various commercially available cosmetic preparations for inhibiting perspiration and for controlling body odor. Among these various preparations, sticks are particularly popular because they are simple and convenient to handle. The gel base of stick preparations is expected on 10 the one hand to have a certain hardness and dimensional stability but, on the other hand, to be able to be rubbed onto the skin under light pressure. These consistency properties can be achieved, for example, by aqueous/alcoholic or aqueous/glycolic preparations solidified with soaps to form a gel. Corresponding sticks have the disadvantage that acidic 15 aluminium salts, for example aluminium chlorohydrate, cannot be made up into such soap gel sticks. For this reason, so-called water-free dispersion sticks have acquired particular significance. Sticks of this type consist of a dispersion of fine particle astringent aluminium or zirconium salts in a nonpolar carrier liquid 20 solidified by gel formers or wax-like fatty components. Suitable nonpolar carrier liquids are, for example, hydrocarbons or silicone oils, preferably those with boiling points below 2000C or with a certain volatility, for example cyclic siloxanes (cyclomethicone) and mixtures thereof with skin softening oil components. 25 Water-free dispersion sticks of the type in question occasionally have the disadvantage that the onset of the perspiration-inhibiting effect of the astringent salts is not sufficiently quick or intensive.
WO 00/67713 2 PCT/EPOO/03863 The stick composition has already been hydrophilicized by the addition of surfactants which also improves the removal of residues from the skin or articles of clothing by washing. For example, US 4,151,272 describes antiperspirant sticks which contain up to 5% by weight of a fatty 5 alcohol polyglycol ether. EP 491 843 BI discloses antiperspirant stick compositions which contain an addition product of 10 mol propylene oxide onto butanediol for reducing the "white patch" effect. EP 777 463 BI describes antiperspirant sticks which contain an 11,12-dihydroxystearic acid as the solidifying fatty or wax component. 10 Unfortunately, the known stick compositions mentioned above still have various disadvantages. Thus, stick compositions with too low a content of solidifying wax components tend to secrete oil in heat. Stick compositions whose liquid carrier component does not contain any polar components have too weak an antiperspirant effect. It has now been found 15 that antiperspirant stick compositions, including those with a relatively high content of solidifying fatty or wax components, are extremely effective and rapidly develop their perspiration-inhibiting effect providing the liquid carrier component contains a relatively high percentage of polar oil components selected from liquid branched alkanols, alkane diols or liquid dialkyl ethers 20 containing 12 to 24 carbon atoms. Accordingly, the present invention relates to antiperspirant stick compositions which contain perspiration-inhibiting astringent salts dispersed in a paste dimensionally stable at 40 0 C but spreadable on the skin, said compositions containing 25 (A) 10 to 30% by weight of an astringent aluminium, zirconium or zinc salt, (B) 30 to 50% by weight of a liquid carrier component, (C) 18 to 30% by weight of solidifying fatty or wax components with a melting point of 40 to 80*C, 30 (D) 1 to 20% by weight of water-soluble surfactants, WO 00/67713 3 PCT/EPO/03863 characterized in that the liquid carrier component (B) contains 20 to 40% by weight of a nonpolar oil, preferably a low-boiling or liquid silicone oil, 10 to 30% by weight of a polar oil selected from liquid branched alkanols, 5 alkane diols, ether alcohols or dialkyl ethers containing 12 to 24 carbon atoms and addition products of 2 to 30 mol propylene oxide onto mono- or polyfunctional alkanols containing 3 to 20 carbon atoms, all the above percentages by weight being based on the stick composition as a whole. 10 Suitable perspiration inhibitors are, above all, astringent or protein coagulating aluminium, zirconium or zinc salts. Suitable antihydrotic salts such as these are, for example, aluminium chloride, aluminium hydroxychloride, aluminium dichlorohydrate, aluminium sesquichloro hydrate, complex compounds thereof with, for example, 1,2-propylene 15 glycol, aluminium hydroxyallantoinate, aluminium chloride tartrate, aluminium sulfate, sodium aluminium lactate, potassium aluminium sulfate (K alum), aluminium zirconium trichlorohydrate, aluminium zirconium tetrachlorohydrate, aluminium zirconium pentachlorohydrate and complex compounds thereof with amino acids such as, for example, glycine, for 20 example aluminium zirconium tetrachloroglycine complex, sodium zirconium lactate, zinc sulfate and Zn phenol sulfonate. The astringent salts should be finely particulate with a mean particle size below 100 pm and preferably below 50 pm. In a particularly preferred embodiment, the astringent salt is an aluminium hydroxychloride with the formula A1 2
(OH)
5 CI 25 2-3 H 2 0 present in a quantity of 15 to 25% by weight. In the interests of a rapid onset of effect and high effectiveness, it has proved to be particularly advantageous for the astringent salts to be coated or impregnated with a water-soluble nonionic surfactant. Surfactants which have proved to be particularly suitable for this purpose 30 are alkyl (oligo)glycosides which are applied to the surface of the salt WO 00/67713 4 PCT/EPOO/03863 particles in quantities of 0.1 to 5% by weight. Suitable solidifying fatty or wax components are more or less any saturated linear fatty acids and fatty alcohols containing 14 to 22 carbon atoms, triglycerides of saturated fatty acids containing 14 to 22 carbon 5 atoms, saturated linear wax esters (fatty acid/fatty alcohol esters) containing 28 to 44 carbon atoms or mixtures thereof. A mixture of 1 part by weight of hydrogenated castor oil and 2 to 4 parts by weight of a cetyl or stearyl alcohol has proved to be most particularly suitable. Suitable water-soluble surfactants are, basically, any surfactants 10 which form a 1% by weight solution in the system at 20*C and an at least 1% by weight solution in water at 20 0 C. Although the structure and ionicity are basically irrelevant, nonionic surfactants, particularly the addition products - solid at normal temperature (20 0 C) - of ethylene oxide onto fatty molecules containing at least one alkoxylatable group, appear to be 15 particularly suitable. Suitable surfactants of this type are, for example, the addition products of 10 to 40 mol ethylene oxide onto linear fatty alcohols containing 16 to 22 carbon atoms, onto fatty acids containing 12 to 22 carbon atoms, onto fatty acid alkanolamides, onto fatty acid monoglycerides, onto sorbitan fatty acid monoesters, onto fatty acid 20 alkanolamides, onto fatty acid glycerides, for example onto hydrogenated castor oil, onto methyl glucoside monofatty acid esters and mixtures thereof. The liquid carrier component consists of nonpolar and polar oil components. The principal component is a nonpolar oil, for example a 25 silicone oil or a hydrocarbon oil. The nonpolar oil is preferably a low-boiling or volatile, linear or cyclic dimethyl polysiloxane. Particularly suitable volatile silicone oils are the cyclic polydimethyl siloxanes with the formula
[(CH
3
)
2 -SiO]n where n = 4, 5 or 6. Products such as these are commercially available, for example under the name of Dow Corning@ 200, 30 244, 245, 344 or 345.
WO 00/67713 5 PCT/EPO/03863 A content of polar liquid carrier components has a particularly large bearing on the performance behavior and especially the spontaneous effect of the antiperspirant stick composition. Preferred polar liquid carrier components are liquid branched alkanols, alkanediols, ether alcohols and 5 dialkyl ethers containing 12 to 24 carbon atoms or addition products of 2 to 30 mol propylene oxide onto mono- or polyfunctional alkanols containing 3 to 20 carbon atoms. Addition products of ethylene oxide and propylene oxide onto these alkanols or polyols, for example glycerol, may also be used in accordance with the invention. 10 Suitable liquid branched alkanols are, for example, Guerbet alcohols with a single branch at carbon atom 2, for example 2-hexyl decanol or 2 octyl dodecanol. Other suitable liquid alcohols are, for example, isotridecanol, isohexadecanol and mixtures of such alcohols. Suitable alkanediols are the vicinal diols obtainable from C 12
.
24 15 epoxyalkanes by ring opening with water. Suitable ether alcohols are, for example, the monoalkyl ethers of glycerol, ethylene glycol, 1,2-propylene glycol or 1,2-butanediol and other products obtainable by ring opening of epoxyalkanes with monohydric alcohols providing they contain 12 to 24 carbon atoms. 20 Suitable dialkyl ethers are, for example, the alkyl methyl ethers or the di-n-alkyl ethers containing a total of 12 to 24 carbon atoms. A particularly suitable di-n-alkyl ether is the commercial product Cetiol@ OE (Henkel KGaA), a di-n-octyl ether. Suitable addition products of propylene oxide onto mono- or 25 polyhydric alcohols are, for example, PPG-3-myristyl ether (Witconol@ APM), PPG-14-butyl ether (Ucon Fluid@ AP) or PPG-15-stearyl ether (Arlamol@ E), PPG-9-butyl ether (Breox@ B 25) or PPG-10-butanediol (Macol@ 57). In one preferred embodiment, the antiperspirant stick compositions 30 contain as the polar oil a branched alkanol selected from 2-hexyldecanol, WO 00/67713 6 PCT/EPOO/03863 2-octyldecanol and mixtures of these alcohols with addition products of 2 to 20 mol propylene oxide onto C 3
-
2 0 alkanols. The stick compositions according to the invention may additionally contain typical auxiliaries and active skin-care ingredients. 5 Inert, fine particle, inorganic or organic fillers are particularly important in this regard. Inert fillers such as these are, for example, silicas, clays, talcum, Veegum or organic fillers such as, for example, polymer powders, starch or cellulose powders. In a preferred embodiment, the antiperspirant stick compositions according to the invention additionally 10 contain 1 to 20% by weight of a fine-particle filler selected from talcum, silica and mixtures thereof. Fillers such as these distinctly improve the strength, oil-binding capacity and rubbing behavior of the stick. Other auxiliaries typically encountered in deodorant and antiperspirant compositions are perfume oil, antioxidants, complexing 15 agents, antimicrobial agents, esterase-inhibiting deodorizers and odor absorbing polymers. Finally, dyes and colored or white pigments may also be added to increase the attractiveness of the sticks. The following Examples are intended to illustrate the invention without limiting it in any way. 20 Examples Stick compositions corresponding to formulations 1 to 5 were conventionally produced from the raw materials listed in the Table. Stick 25 compositions C1, C2, C3 and C4 containing - a lower percentage of polar oils (C1, C3) and/or - a lower percentage of solidifying fatty or wax components (C2) or - no water-soluble surfactants (C4) were produced for comparison. 30 The antiperspirant effect was comparatively tested by the Bio Skin WO 00/67713 7 PCT/EP00/03863 method (SOFW Journal, 123, Vol. 10/97, pages 639-642). The reduction in perspiration after application for 3 days was determined and compared with an untreated test zone. The results were assessed as follows: reduction in perspiration: ++ = very good, + = good, - = weak. The hardness of the antiperspirant sticks was evaluated after storage for 3 days at 50*C: hardness (50*C): ++ = very good, + = satisfactory, - = greasy, oil secretion 1 2 3 4 5 C1 C2 C3 C4 Silikon6l DC@ 245 Fluid 28 28 23 23 23 38 42 47 31 Eutanol@ G 16 10 - - 15 10 - 10 - 10 Cetiol@OE - 10 15 - - - - - Ucon Fluid@AP 5 5 5 5 5 5 5 5 5 Cutina@HR 6 6 6 6 6 6 2 5 6 Lorol@ C 18 20 20 20 - 20 20 - - 20 Lanette@0 - - - 20 - - 10 12 Eumulgin@B3 3 3 3 3 3 3 3 3 Cutina@ E 24 PF - - - - 5 - - - AHC 20 20 20 20 20 20 20 20 20 Talcum 8 8 8 8 8 8 8 8 8 Reduction in perspiration ++ ++ ++ + ++ + + + Hardness (50*172 h) ++ ++ ++ ++ ++ ++ - + ++ The following commercial products were used: Silikon6l@ DC 245 Fluid: dimethyl cyclopentasiloxane Eutanol@ G 16: 2-hexyl decanol Cetiol@ OE: di-n-octyl ether Ucon Fluid@ AP: PPG-14-butyl ether Cutina@ HR: hydrogenated castor oil WO 00/67713 8 PCT/EPO0/03863 Lorol@ C 18: stearyl alcohol Lanette@ 0: cetyl/stearyl alcohol (1:1) Eumulgin@ B 3: PEG-30-Cetyl/Stearylether Cutina@ E 24 PF: PEG-20-Glycerylstearate AHC (aluminium chlorohydrate): Micro Dry@ UF (Reheis/Interorgana)
Claims (6)
1. An antiperspirant stick composition which contains perspiration inhibiting agents dispersed in a paste dimensionally stable at 40*C but spreadable on the skin, said composition containing 5 (A) 10 to 30% by weight of an astringent aluminium, zirconium or zinc salt, (B) 30 to 50% by weight of liquid carrier components, (C) 18 to 30% by weight of solidifying fatty or wax components with a melting point of 40 to 90 0 C, 10 (D) 1 to 20% by weight of water-soluble surfactants, characterized in that the liquid carrier component (B) contains - based on the stick composition as a whole 20 to 40% by weight of a nonpolar oil, preferably a low-boiling or liquid silicone oil, 15 10 to 30% by weight of a polar oil selected from liquid branched alkanols, alkane diols, ether alcohols or dialkyl ethers containing 12 to 24 carbon atoms and addition products of 2 to 30 mol propylene oxide onto mono- or polyfunctional alkanols containing 3 to 20 carbon atoms.
2. An antiperspirant stick composition as claimed in claim 1, 20 characterized in that a low-boiling or volatile, linear or cyclic dimethyl polysiloxane is present as the nonpolar oil.
3. An antiperspirant stick composition as claimed in claim 1 or 2, characterized in that a single-branch alkanol selected from 2-hexyl decanol, 2-octyl dodecanol and mixtures of these alcohols with addition products of 25 2 to 20 mol propylene oxide onto C3.2o alkanols is present as the polar oil.
4. An antiperspirant stick composition as claimed in any of claims 1 to 3, characterized in that saturated linear fatty acids or fatty alcohols containing 14 to 22 carbon atoms, triglycerides of saturated fatty acids containing 16 to 22 carbon atoms, saturated linear wax esters containing 30 28 to 44 carbon atoms or mixtures thereof are present as the solidifying WO 00/67713 10 PCT/EPO/03863 fatty or wax component.
5. An antiperspirant stick composition as claimed in any of claims 1 to 4, characterized in that an aluminium hydroxychloride with the formula A1 2 (OH) 5 CI -2-3 H 2 0 is present as the astringent salt in a quantity of 15 to 5 25% by weight.
6. An antiperspirant stick composition as claimed in any of claims 1 to 5, characterized in that a fine-particle filler selected from talcum, silica and mixtures thereof is additionally present in a quantity of 1 to 20% by weight.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19921192A DE19921192A1 (en) | 1999-05-07 | 1999-05-07 | Antiperspirant pen |
DE19921192 | 1999-05-07 | ||
PCT/EP2000/003863 WO2000067713A1 (en) | 1999-05-07 | 2000-04-28 | Antiperspirant stick |
Publications (1)
Publication Number | Publication Date |
---|---|
AU4753000A true AU4753000A (en) | 2000-11-21 |
Family
ID=7907373
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU47530/00A Abandoned AU4753000A (en) | 1999-05-07 | 2000-04-28 | Antiperspirant stick |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1178775A1 (en) |
JP (1) | JP2002544153A (en) |
CN (1) | CN1349400A (en) |
AU (1) | AU4753000A (en) |
CA (1) | CA2373504A1 (en) |
CZ (1) | CZ20014011A3 (en) |
DE (1) | DE19921192A1 (en) |
HU (1) | HUP0201339A2 (en) |
NO (1) | NO20015425L (en) |
PL (1) | PL351592A1 (en) |
SK (1) | SK16032001A3 (en) |
WO (1) | WO2000067713A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0019232D0 (en) * | 2000-08-04 | 2000-09-27 | Unilever Plc | Antiperspirant formulations |
DE102004022252A1 (en) | 2004-05-04 | 2005-12-01 | Cognis Ip Management Gmbh | Glycerinethergemisch, this containing cosmetic composition and process for its preparation |
DE102004036689A1 (en) | 2004-07-28 | 2006-03-23 | Henkel Kgaa | Low-residue deodorant or antiperspirant stick based on an oil-in-water dispersion |
EP1888179B1 (en) | 2005-05-11 | 2012-04-11 | Henkel AG & Co. KGaA | Low-residue deodorant or antiperspirant stick based on an oil-in-water dispersion/emulsion |
DE102008028821A1 (en) | 2007-06-20 | 2009-01-29 | Henkel Ag & Co. Kgaa | Cosmetic stick based on a thickened oil-in-water dispersion / emulsion |
DE102008028822A1 (en) | 2007-06-20 | 2009-02-19 | Henkel Ag & Co. Kgaa | Cosmetic stick composition for application to the skin for treating acne, pimples, blackhead and cellulitis, and for skin tightening, comprises wax component, polymeric organic hydrogel forming substance and nonionic oil in water emulgent |
DE102008052747A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Antiperspirant stick without volatile carrier oils |
DE102008052748A1 (en) | 2008-10-22 | 2010-04-29 | Beiersdorf Ag | Anhydrous antiperspirant sticks with microcrystalline wax |
DE102009010665A1 (en) | 2009-02-27 | 2010-09-16 | Beiersdorf Ag | Use of charged surfactants to reduce textile staining by antiperspirants |
DE102009002371A1 (en) * | 2009-04-15 | 2010-10-21 | Evonik Goldschmidt Gmbh | Process for the preparation of odorless polyether alcohols by means of DMC catalysts and their use in cosmetic and / or dermatological preparations |
DE102010008320A1 (en) | 2010-02-17 | 2011-08-18 | Beiersdorf AG, 20253 | Use of substances to improve the washability of textile stains caused by UV filters |
DE102011090113A1 (en) | 2011-12-29 | 2013-07-04 | Beiersdorf Ag | Antiperspirant aerosol formulations with reduced textile staining |
US9717930B2 (en) | 2013-03-12 | 2017-08-01 | The Procter & Gamble Company | Antiperspirant compositions |
US20140271516A1 (en) | 2013-03-12 | 2014-09-18 | The Procter & Gamble Company | Methods of Making Solid Stick Antiperspirant Compositions |
MX367383B (en) | 2014-06-30 | 2019-08-19 | Procter & Gamble | Method of manufacturing stick comprising antiperspirant. |
MX360041B (en) | 2014-06-30 | 2018-10-18 | Procter & Gamble | Personal care compositions and methods. |
DE102021200919A1 (en) | 2021-02-02 | 2022-08-04 | Beiersdorf Aktiengesellschaft | Antiperspirant sprays with reduced fabric staining |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE146071T1 (en) * | 1989-09-15 | 1996-12-15 | Gillette Co | SWEAT-INHIBITANT AGENT |
CA2160364A1 (en) * | 1993-04-27 | 1994-11-10 | Philip Andrew Sawin | Antiperspirant stick compositions exhibiting improved wash-off performance |
US5607972A (en) * | 1994-08-08 | 1997-03-04 | The Procter & Gamble Company | Gelling compositions comprising optically enriched gellants |
-
1999
- 1999-05-07 DE DE19921192A patent/DE19921192A1/en not_active Withdrawn
-
2000
- 2000-04-28 EP EP00929459A patent/EP1178775A1/en not_active Withdrawn
- 2000-04-28 CA CA002373504A patent/CA2373504A1/en not_active Abandoned
- 2000-04-28 PL PL00351592A patent/PL351592A1/en unknown
- 2000-04-28 JP JP2000616741A patent/JP2002544153A/en active Pending
- 2000-04-28 AU AU47530/00A patent/AU4753000A/en not_active Abandoned
- 2000-04-28 WO PCT/EP2000/003863 patent/WO2000067713A1/en not_active Application Discontinuation
- 2000-04-28 SK SK1603-2001A patent/SK16032001A3/en unknown
- 2000-04-28 HU HU0201339A patent/HUP0201339A2/en unknown
- 2000-04-28 CZ CZ20014011A patent/CZ20014011A3/en unknown
- 2000-04-28 CN CN00807226.4A patent/CN1349400A/en active Pending
-
2001
- 2001-11-06 NO NO20015425A patent/NO20015425L/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CN1349400A (en) | 2002-05-15 |
HUP0201339A2 (en) | 2002-08-28 |
EP1178775A1 (en) | 2002-02-13 |
SK16032001A3 (en) | 2002-04-04 |
CZ20014011A3 (en) | 2002-04-17 |
WO2000067713A1 (en) | 2000-11-16 |
NO20015425D0 (en) | 2001-11-06 |
NO20015425L (en) | 2001-11-06 |
CA2373504A1 (en) | 2000-11-16 |
DE19921192A1 (en) | 2000-11-09 |
PL351592A1 (en) | 2003-05-05 |
JP2002544153A (en) | 2002-12-24 |
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