AU2784000A

AU2784000A - Unsealed or a sealed base, methods of producing the base and base compositions

Info

Publication number: AU2784000A
Application number: AU27840/00A
Authority: AU
Inventors: Kenneth J Charlton
Original assignee: RESOURCES STRATEGY SERVICES PT
Current assignee: WESCO TECHNOLOGIES Pty Ltd
Priority date: 1999-02-19
Filing date: 2000-02-21
Publication date: 2000-09-04
Anticipated expiration: 2020-02-21
Also published as: AU769470B2

Description

WO 00/49229 PCT/AU00/00092 1 UNSEALED OR A SEALED BASE, METHODS OF PRODUCING THE BASE AND BASE COMPOSITIONS Technical Field The present invention relates to an unsealed or a sealed base for a road, pathway, 5 pavement, floor or the like. The present invention also relates to methods of producing the base and base compositions. In particular, the present invention relates to an unsealed or a sealed base, a base composition or method of producing the base and base compositions comprising lignin or lignosulphonate containing materials. Background Of The Invention 10 Asphalt and/or bitumen/bituminous emulsion compositions are typically utilised in the formation of roads. The formation of the road or pathway comprises firstly the formation of a road or pathway base which is substantially based on soil and various other components. The road or pathway base may be graded and then sprinkled with water before the road or pathway base is compacted by suitable means such as road 15 rollers and the like. The means for compaction such as road rollers act to compact or compress the particles of soil together so as to provide a base, which is usually but not always substantially flat, before the asphalt and/or bitumen/bituminous emulsion compositions are then applied to an upper surface of the road or pathway base. The formation of an unsealed surface such as a road or a pathway comprises firstly 20 the formation of a road or pathway base which is substantially based on soil and various other components. The road or pathway base may be graded and then sprinkled with water before the road or pathway base is compacted by suitable means such as road rollers and the like. The means for compaction such as road rollers act to compact or compress the particles of soil together so as to provide a base, which is usually but not 25 always substantially flat, to form an unsealed surface of the road or pathway base. The use of various agents such as for use as binders and/or dispersants in the base act to strengthen the bonding of particles of soil in the road or pathway base composition. The increased resistance in wear and tear of a road is to some extent dependent upon the compaction and bonding of the soil particles in the base. 30 However, based on the inventor's observations in practice, the compositions for road or pathway bases do not seem to be sufficient in bonding or compacting the particles of soil of the base composition. In the case of an unsealed road base, the resulting upper surface of the unsealed road base subsequently tends to break down more readily thereby resulting in the roads and paths having a tendency to form more potholes and cracks 35 especially on those roads with high traffic loads. In the case of a sealed road base, the resulting asphalt and/or bitumen/bituminous emulsion compositions which are applied to the upper surface of the road base subsequently tend to break down more readily thereby WO 00/49229 PCT/AUOO/00092 2 resulting in the roads and paths having a tendency to form more potholes and cracks especially on those sealed roads with high traffic loads. The increased tendency for sealed and unsealed roads to break down and form cracks, potholes, etc results in decreased life of new roads which consequently leads to 5 eventual problems with repairing and maintaining roads especially in roads with heavy traffic usage. The present invention seeks to ameliorate the problems of the known base compositions and compositions for roads, pathways, pavements and the like by providing, at least, an unsealed or sealed base, an alternative composition for roads and 10 bases and a method of stabilising such road bases for sealed and unsealed roads. Summary Of The Invention According to one embodiment of the invention there is provided a method of producing a base comprising the following steps: (a) mixing 15 (i) at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) at least one additive selected from the group consisting of cement, lime, flyash. calcium sulphate and slag; and (iii) soil; 20 to form a base composition, and (b) compacting the base composition to form a base. Base as used throughout the specification and claims includes within its scope one or more layers selected from the group consisting of the base layer, the sub base layer the subgrade layer and other formation layers. Thus for example the base of a road may have 25 three or more layers the base layer. the sub base layer the subgrade layer and other formation layers and one or more of these layers may be a base formed in accordance with the process of the invention. Each layer may be independently formed with different relative amounts and with different types of materials. At least the base layer is prepared according to the method of the invention however, this will be dependent on the 30 particular requirements. For example, the sub base may be the only layer formed in accordance with the method of the invention. Usually the base is flexible under load and is resilient. Advantages of a base of the invention are that it has improved strength, flexibility and resilience as compared to bases not made in accordance with the method of the invention. 35 In the method of the invention step (a) may further comprise the step of mixing: (iv) water; Inith (i), (ii) and (iii). In the method of the invention step (a) may further comprise the step of mixing: WO 00/49229 PCT/AUOO/00092 3 (iv) water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition. In the method of the invention step (a) may further comprise the step of mixing: 5 (iv') a filler: with (i). (ii) and (iii) or with (i), (ii), (iii) and (iv). In one particular form of the method of the invention step (a) comprises: (a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group 10 consisting of lignin and lignosulphonate; (ii) in an amount of 0.1wt% - 15wt% at least one additive selected from the group consisting of cement, lime. flyash, calcium sulphate and slag; and 70wt% - 99.8wt% soil. In another particular form of the method step (a) comprises: 15 a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) in an amount of 0.1wt% - 15wt% at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; 20 (iii) 70wt% - 99.8wt% soil: and (iv) Owt%-25wt% water. Typically the amount of water is such that the base composition is at or about the optimum moisture content for maximum compaction. In another particular method of the invention step (a) comprises: 25 (a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; 30 (iii) 70wt% - 99.8wt% soil; and (iv) Owt%-25wt% water. In a further particular method of the invention step (a) comprises: (a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group 35 consisting of lignin and lignosulphonate; (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group consisting of cement. lime. flyash, calcium sulphate and slag: (iii) 70wt% - 99.7wt% soil and WO 00/49229 PCT/AUOO/00092 4 (iv') 0.1wt%-15wt% of a filler. In another particular method of the invention step (a) comprises: (a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group 5 consisting of lignin and lignosulphonate; (ii) in an amount of 0.1wt% - 15wt% at least one additive selected from the group consisting of cement. lime, flyash. calcium sulphate and slag; (iii) 70wt% - 99.7wt% soil; (iv) Owt%-25wt% water; and 10 (iv') 0.1wt%-15wt% of a filler. In another form of the method of the invention step (a) comprises: (a) mixing (i) in an amount of 0.1 wt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; 15 (ii) in an amount of 0.1wt% - 15wt% at least one additive selected from the group consisting of cement, lime. flyash, calcium sulphate and slag: (iii) 70wt% - 99.7wt% soil: (iv) Owt%-25wt% water; and (iv') 0.1wt%-25wt% of a filler. 20 Advantageously in the method of the invention step (a)(iv) comprises: (iv) I-15wt% water. The method of the invention may further comprise: (c) sealing the base with a sealant. According to another form of the invention there is provided a base composition 25 comprising: (i) at least one binder selected from the group consisting of lignin and I ignosulphonate; and (ii) at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag. 30 The base composition of may further comprise at least one component selected from the group consisting of (iii) soil; (iv') a filler; and (iv) water. Another form of the invention comprises a method of producing a base composition comprising the following steps: mixin 35 (i) at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; and WO 00/49229 PCT/AUO0/00092 5 (iii) soil; to form the base composition. A further form of the invention comprises a method of producing a base composition comprising the following steps: 5 Mixing (i) at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; and 10 (iii) soil; (iv) water; to form the base composition. The method of of the invention may comprise the step of mixing: (iv) water in an amount where the base composition is substantially at or about an 15 optimum moisture content that enables substantially maximum compaction of the base composition. The step of mixing may further comprise the step of mixing: (iv') a filler; with (i), (ii) and (iii), and where appropriate (iv). 20 Another embodiment of the invention provides a method of producing a base composition comprising the following steps: mixing (i) at least one binder selected from the group consisting of lignin and lignosulphonate; 25 (ii) at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; and (iv') a filler; to form the base composition. In the method the step of mixing may further comprise the step of mixing: 30 (iii) soil; with (i), (ii) and (iv'). In the method the step of mixing may further comprise the step of mixing: (iii) soil; (iv) water; 35 with (i). (ii) and (iv'). In the method the step of mixing may further comprise the step of mixing: (iii) soil having more than 10% -25% sieve analysis at a sizing of -0.075mm; Substitunt Sheni WO 00/49229 PCT/AUOO/00092 6 (iv) water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition. with (i). (ii) and (iv'). 5 The invention further provides (I) A base composition produced by a method of the invention: (II) A sealed base produced by a method of the invention; (III) A base produced by a method of the invention. According to one form of the present invention. there is provided a base composition comprising: 10 i) at least one binder selected from the group consisting of lignin and lignosulphonate: and ii) at least one additive selected from the group consisting of cement, lime, fiyash. calcium sulphate and slag. According to another embodiment of the present invention, there is provided a base I s composition comprising: i) at least one binder selected from the group consisting of lignin and lignosuLIphonate; ii) at least one additive selected from the group consisting of cement, lime, 11yash. calcium sulphate and slag; and 20 iii) soil. According to a further embodiment of the present invention, there is provided a base composition comprising: i) at least one binder selected from the group consisting of lignin and lig nosulphonate: 25 ii) at least one additive selected from the group consisting of cement, lime, liyash. calcium sulphate and slag; and iii) soil; and iv) water in an amount up to a point where the composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of 30 the base composition. According to another embodiment of the present invention, there is provided a base composition comprising: i) at least one binder selected from the group consisting of lignin and lignosulphonate: 35 ii) at least one additive selected from the group consisting of cement, lime, flvash. calcium sulphate and slag; and iii) soil; and WO 00/49229 PCT/AUOO/00092 7 iv) water in an amount that enables compaction of the base composition so as to form a base. Typically the slag comprises blast furnace slag. Typically, the amount of water is added to components i) to iii) either before, at the 5 same time or after the mixture of components i) to iii). The water is still typically added so as to not exceed the at or about optimum moisture content of the base composition although if more water is added suitable materials such as cement and/or lime and/or fivash and/or calcium sulphate and/or blast furnace slag may be added to absorb excess water so as to provide the at or about optimum moisture content. Further, the base 10 composition may be dried or evaporated by suitable means so to provide the at or about optimum moisture content of the base composition. The optimum moisture content will vary and be dependent 'on the types and the relative amounts of the components in the base composition as described for the embodiment of the present invention. The optimum moisture content will typically 15 decrease when more of component i) is present since lignin or lignosulphonates act as dispersants whilst the optimum moisture content will typically increase when more of component ii) is present since the component ii) acts as an absorbent material. The optimum moisture content will further depend on the modifiers added to the composition of the third embodiment of the present invention. 20 Throughout this specification, the term "optimum moisture" for the base composition is defined as the moisture content whereby maximum compaction of the composition occurs. The compositions of the invention may be such as to be about the optimum moisture content for maximum compaction of the composition of the invention (this refers to compositions of the invention that include soil) e.g. in the range optimum 25 moisture content ± 5wt%, optimum moisture content ± 4wt%., optimum moisture content ± 3wt%. optimum moisture content ± 2wt%, or optimum moisture content ± lwt%. Water is added as required to bring such compositions to the optimum moisture content or about the optimum moisture content. Lignosulphonate PLUS Additive PLUS Fillers 30 Always used- Usually at least two of - Not always used one or more of the Cement, Quick Lime one or more of types listed herein Hydrated Lime, Slag Bentonite usually at least two or three Fly ash, Fire Clay Silt 35 Typically, compaction tests are used to determine the optimum moisture content of the base composition of the present invention comprising a particular soil as component iii) which has to be compacted optionally together with other components in order to attain the maximum dry density. Still typically, the laboratory compactive effort is WO 00/49229 PCT/AUOO/00092 8 standardised upon the premise that it duplicates field compaction and thus the material is compacted at various moisture contents using a fresh portion of base composition for each moisture content applied. As the moisture content increases, dry density increases to a certain maximum but then decreases. The plotting of dry densities against moisture 5 contents provides a moisture content density curve corresponding to a given compaction effort for the base composition. This obviously shows that for each base composition there is a given maximum compaction that can be achieved for each moisture content. However. other compaction tests used in the field may also be utilised to provide an approximate moisture content of the base composition. For example, a hand test may be 10 used to provide an approximate optimum moisture content. The range of weight ratios of soil or soil having an optimum moisture content to the total weight ratio of other components in the mixture in those forms of the invention that concern soil are shown below in Table C by reading the "Third Component" as the weight ratio summation of the components other than soil. 15 The sealed surface is typically a sealing layer which seals the base of the invention to which it is overlayed. adhered or bonded, such as sealed with paving blocks, a concrete surface, a road, pathway, pavement or floor having sealed surface such as concrete, bitumen and/or asphalt, or a road, pathway, pavement, floor and the like sealed with another suitable sealing agent. The sealed surface is further typically a road, pathway or 20 pavement and still further typically the sealed surface is a road. The road is typically made from a composition comprising asphalt and/or bitumen/bituminous emulsion compositions which is designed to carry high volumes of traffic. Still typically, crushed stone and gravel are added to the bitumen/bituminous emulsion composition designed to carry high volumes of traffic.The sealed surface may also be a sealed railway track bed 25 below the ballast. The base of the invention may be effectively sealed when it is a base below concrete, a base below concrete foundations, a base below paving blocks or a shock absorbent base below a building structure, for example. In a particular form of the invention the base composition is in a powdered form which may be then blended with soil in an appropriate ratio and a suitable amount of 30 water added, if necessary, to bring the moisture content of the mix at or about the optimum moisture content for optimum compaction. In an alternative form, a suitable amount of water may be added to form a paste or slurry or moist mixture so as to provide an amount of moisture for the base composition which may or may not be at optimum but is an amount whereby the composition is suitable for compaction as a road base or a 35 base for some other purpose such as a footpath, pathway, parking area, etc. Usually the amount of water added is such so as to provide optimum moisture for the base composition. Throughout this specification, the term "optimum moisture" for the base composition is defined as the moisture content whereby maximum compaction of the SqnhQ1tiit R'hnni: WO 00/49229 PCT/AUOO/00092 9 composition can be effected by standard compaction techniques. Yet still typically, the amount of water added to the base composition is I to 20 weight %. The water may be added either before, at the same time or after mixing components a) and ii) and optionally iii) above. The amount of water added to the base composition 5 to provide optimum moisture will vary dependent upon the amounts of components i), ii) and iii) above and also the type of soils used for component iii) above. The component i) above will typically act as a dispersant thereby generally reducing the amount of water required for the base composition whilst the component ii) above will typically act as an absorbent material for water present in the base composition. 10 In one form of the invention the base composition is used as an unsealed surface having components i) and ii) above with iii) soil where component ii) is cement and/or lime and/or flyash. The unsealed surface is typically a road, pathway, floor, railroad track bed below the ballasts, or pavement or the like and still further typically the unsealed surface is a road. is The lignin or lignosulphonate is typically a salt of lignosulphonic acid including alkali metal salts thereof, alkaline earth metal salts thereof. transition metal salts thereof, ammonium salts thereof, ammonium polymerised salts thereof, chromium salts thereof, and other water soluble salts thereof. The alkali metal salts of lignosulphonic acid typically comprise lithium 20 lignosulphonate, sodium lignosulphonate, potassium lignosulphonate. The alkaline earth metal salts of lignosulphonic acid typically comprise calcium 1 inosul phonate, magnesium lignosulphonate. barium lignosulphonate. The transition metal salts of lignosulphonic acid typically comprise ferrous lignosulphonate. 25 The ammonium salt comprises ammonium lignosulphonate and a polymerised salt of lignosulphonic acid typically a polymerised alkylene napthalene lignosulphonic acids and the ammonium salt thereof. The lignin or lignosulphonate in the present invention may be either used individually as a single component or as a mixture of more than one component. The 30 ignin or lignosulphonate most typically used is ammonium lignosulphonate, calcium I ignosulphonate or sodium lignosulphonate which may be used either individually or as a mixture. The selection of the lignin or lignosulphonate is typically dependent upon the soil which is used in the said base composition. The lignin or lignosulphonate may also be admixed with alkali metal salts, alkaline 35 earth metal salts and ammonium polymerised salts of sulphonic acid to form a mixture of the lignin or lignosulphonates together with the aforesaid sulphonates. The cement is typically selected from hydraulic cements or non-hydraulic cements. The hydraulic cements include cements which are hydraulically active and may include Substitute Sheet WO 00/49229 PCT/AUOO/00092 10 materials such as hydraulic cement, slag and blends of hydraulic cement thereof. The term "hydraulic cements" refers to any inorganic cement which hardens or sets due to hydration. The term "hydraulically active" refers to properties of a cementitous material that allows the material to set in a manner like hydraulic cement. either with or without 5 additional activation. Hydraulically active cementitous materials may also contain minor amounts of fillers or extenders such as bentonite. gilsonite. and cementitous materials used either without any appreciable sand or aggregate material or admixed with a granular filling material such as sand. ground limestone and the like. Strength enhancers such as silica powder or silica flour may be employed as well. 10 Hydraulic cements typically comprise Portland cements, aluminous cements, pozzalan cements, fly ash cements, and the like. Thus, for example, any of the oilwell type cements of the class "A-H" and "J" as listed in the API Sped 10, (1st Edition), are suitable and fall within the definition of hydraulic cements. The typical cements which are utilised in the base composition are hydraulic 1s cements with Portland Cement being the most preferred cement. The Portland Cement may be Class G Portland Cement. ordinary Portland Cement and rapid hardening Portland Cement. The Portland cement may also be admixed with other cements such as aluminous cements, pozzalan cements. fly ash cements and the like. Typically. Portland cement is admixed with high alumina cement, anhydrous 20 calcium sulphate and a lithium salt which is used as an accelerator for setting of the cement. A strong base may also be added to the lithium salt in order to assist in the acceleration of the setting of the cement. Typically, the anhydrous calcium sulphate is in the form of an alpha-anhydrite calcium sulphate. beta-anhydrite calcium sulphate or a mixture thereof. Typically, the strong base is sodium hydroxide, potassium hydroxide or 25 sodium aluminate. Typically , the lithium salt is lithium carbonate, lithium hydroxide. The calcium sulfate may also be present in the form of a calcium sulphate di hydrate. calcium sulphate hemi hydrate and as a calcium sulphate hemi hydrate of gypsum. The calcium sulfate may also be used by itself in the base composition of the Iirst and second embodiments of the present invention as a component. 30 The lime typically used in the present invention is selected from the group of quicklime, hydrated or slaked lime, high calcium lime. limestone, gypsum, non magnesian and magnesian limes, etc. The lime used in the base composition is most typically hydrated or slaked lime. Hydrated lime is typically made by the reaction of quicklime (calcium oxide) with water to form slaked or hydrated lime. The hydrated 35 lime is typically selected from magnesian lime, high calcium lime and non magnesian lime. Sodium metasilicate may also be added to the composition instead of or additionally with lime. SnhtiininA Rht WO 00/49229 PCT/AUO0/00092 11 The lignosulphonates typically act as retarders. However a set retarder may also be added to the composition to prevent the setting of the slurry. The characteristics of these set retarders are diverse and important. An effective amount of set retarder allows the storage of the slurries with minimal changes in the characteristics of both the stored and 5 activated slurry. It is equally important that this effect is reversible after adding an e effective amount or low concentration of activator in the slurry. Typical set retarders comprise glucoheptanoates, such as sodium glucoheptanoate; calcium glucoheptanoate and magnesium glucoheptanoate: lignosulphonates such as sodium lignosulphonate. calcium sodium lignosulphonates; low molecular weight 10 lydroxy polycarboxylic acid and salts thereof including sodium, potassium and lithium salts thereof; alkaline hexametaphosphate, calcium chloride and/or a condensation product of mononapthalene sulphonic acid and formaldehyde; lithium, sodium and potassium salts of citric acid and tartaric acid. The lignosulphonates typically act as a dispersant. However a dispersant may also is he added to the composition and typical dispersants may be selected from the group of sodium di hydrogen phosphate buffer, ferrous sulphate, tannic acid or a mixture thereof. A surfactant may also be added to the composition and typical surfactants may be selected from the group of anionic, cationic or non-ionic surfactants comprising polyethoxylated alcohols especially polyethoxylated alkylphenol or polyethoxylated 20 methanol. ethanol and propanol surfactants. The flyash typically used in the present invention comprises flyash alone or in combination with blast furnace slag. The blast furnace slag may also be used as another optional component with the base composition of the first or second embodiment of the present invention. 25 The soils of the present invention include crushed rock based soils, soft soils, sand based soils. gravel based soils, shale based soils, soils of volcanic origin, peat based soils, crushed rock, soil containing crushed rock, other stone based soils, shell based soils, coral based soils, volcanic soils, organic based soils, other particulate based soils, clay based, silt based soils or a mixture of any one or more of the aforesaid soils. The soils 30 are still typically swamp clay soils, silt, volcanic silt or puggy black soil or any mixture thereof. The term soil also encompasses within its scope, mining waste materials, and mineral process plant waste materials including colliery waste materials and refuse. The soils may also contain additional particulate material such as required for use in sealed surfaces such as typically roads, pathways, pavements or the like. Typically, any soil that 35 has particles which achieve more than 10% sieve analysis at a sizing of -0.075mm and further typically at more than 20% sieve analysis at a sizing of -0.075mm is suitable for the present invention. However, soil with particles less than 10% sieve analysis may be WO 00/49229 PCT/AUOO/00092 12 used by blending soil with other fillers, such as fire clay, volcanic silts. bentonite, and the like. The typical percentage ratio of component i) lignin or lignosulphonate in respect of the combination of components i) and ii) is: 5 typically 1 to 99 percent by weight, further typically 25 to 95 percent by weight, still further typically 30 to 95 percent by weight, still further typically 35 to 95 percent by weight still further typically 40 to 95 percent by weight. 10 still further typically 45 to 95 percent by weight, still further typically 50 to 95 percent by weight. The typical percentage ranges of component ii) cement and/oi hydrated lime and/or calcium sulphate and/or blast furnace slag. and/or flash in respect of components i) and ii) is typically 1 to 99 percent by weight. further typically 25 to 95 percent by weight. still 15 further typically 30 to 95 percent by weight, still further typically 35 to 95 percent by weight. still further typically 40 to 95 percent by weight, still further typically 45 to 95 percent by weight. still further typically 50 to 95 percent by weight, The typical range for the cement in component ii) is typically 0 to 100 percent by weight. further typically 0 to 90 percent by weight, still further typically 0 to 80 percent 20 by weight, still further typically 0 to 70 percent by weight, still further typically 0 to 60 percent by weight. still further typically 0 to 50 percent by weight. still further typically 0 to 40 percent by weight. still further typically 0 to 35 percent by weight. The preferred range for the lime in component ii) is typically 0 to 100 percent by weight. further typically 0 to 90 percent by weight, still further typically 0 to 80 percent 25 by weight, still further typically 0 to 70 percent by weight, still further typically 0 to 60 percent by weight, still further typically 0 to 50 percent by weight. still further typically 0 to 40 percent by weight. still further typically 0 to 35 percent by weight. The preferred range for the flyash in component ii) is : typically 0 to 100 percent by weight. further typically 0 to 90 percent by weight, 30 still further typically 0 to 80 percent by weight. still further typically 0 to 70 percent by weight. still further typically 0 to 60 percent by weight. still further typically 0 to 50 percent by weight, still further typically 0 to 40 percent by weight, still further typically 0 to 35 percent by weight: subject to the proviso that at least one of cement, lime or flash is present in component ii) in an amount of at least 1 weight percent. 35 The typical percentage ranges of component iii) soil in respect of the total composition is typically 75 to 99.7 percent by weight, still further typically 80 to 95.0. percent by weight, and still further typically 90 to 95.0 percent by weight.

WO 00/49229 PCT/AUOO/00092 13 The typical percentage range of component iv) water is typically 0 to 25 percent by weight. typically I to 15 percent by weight. further typically I to 10 percent by weight, and still further typically 1 to 5 percent by weight and is still typically dependent upon soil conditions and the soil. Typically water is added to the soil in an amount of 3 5 18wt%. 5-15wt%, 8-12wt% or 10-12wt%. The optimum typical percentage range of water in the base composition is the point of achieving optimum moisture in soil as previously defined. Further, the soil may comprise a composition of or include residual cement, residual concrete bitumen or asphalt. or residual broken paving blocks. 10 Accordingly, in another embodiment. the present invention provides a composition comprising: i) at least one binder selected from the group consisting of lignin and lignosulphonate; ii) at least one additive selected from the group consisting of cement, hydrated lime, 15 lime. flyash. calcium sulphate and blast furnace slag; iii) soil, and d) a sealant. Typically, the sealant is selected from asphalt. bitumen, bituminous emulsions or a combination thereof, concrete, cement, or other sealing compounds or admixtures. The 20 composition is still typically asphalt and/or bitumen or bituminous emulsion compositions. The asphalt and/or bitumen or bituminous emulsion compositions provide a strong bonding strength with the components i), ii) and iii) when admixed such that the durability of the sealed surface is increased. Accordingly in a further embodiment. the present invention also provides a sealed 25 Surface composition comprising: i) at least one binder selected from the group consisting of lignin and lignosulphonate; ii) at least one additive selected from the group consisting of cement, hydrated lime. lime. flyash. calcium sulphate and blast furnace slag; 30 iii) soil; iv) water in an amount up to a point where the base composition is substantially at or about an optimum moisture content that results in maximum compaction of the base composition.; and e) asphalt and/or bitumen or bituminous emulsion compositions. 35 The sealed surface is further typically a road, pathway or pavement and still further typically the sealed surface is a road. The sealed surface is typically made from a composition comprising asphalt and/or bitumen/bituminous emulsion compositions which is designed to carry significant traffic.

WO 00/49229 PCT/AU00/00092 14 The typical percentage ratio of component i) lignin or lignosulphonate in respect of the total composition is typically 0. 1 to 15 percent by weight. further typically 0.5 to 10 percent by weight, and still further typically 0.75 to 5 percent by weight. The typical percentage ranges of component ii) cement and/or hydrated lime and/or 5 flash in respect of the total composition is typically 0 to 5 percent by weight, further typically 0.5 to 3 percent by weight. The typical range for the cement in component ii) is typically 0 to 5 percent by weight. further typically 0.5 to 3 percent by weight. 10 The typical range for the lime in component ii) is typically 0 to 5 percent by weight. further typically 0.5 to 3 percent by weight, subject to the proviso that at least one of cement, lime or flash is present in component ii) in an amount of at least 0. 1 weight percent. is The typical percentage ranges of component iii) soil in respect of the total composition is typically 70 to 99.7 percent by weight, still further typically 30 to 95 percent by weight, still further typically 85 to 95 percent by weight, still further typically 90 to 95 percent by weiLuht. 20 The percentage range of component iv) water is typically 0 to 25 percent by weight, further typically 1 to 15 percent by weight. further typically I to 10 percent by weight, and still further typically 1 to 5 percent by weight and is yet still typically dependent upon soil conditions. The optimum typical percentage range of water in the base composition is the point of achieving optimum moisture content in soil as previously 25 defined. The typical percentage range of component e) asphalt and/or bitumen/bituminous emulsion composition is typically 5 to 95 percent by weight. further typically 10 to 90 pCrcent by weight, typically 15 to 80 percent by weight, typically 20 to 70 percent by weight: further typically 25 to 60 percent by weight, still further typically 30 to 50 30 percent by weight, still further typically 35 to 40 percent by weight. Accordingly in a sixth embodiment, the present invention also resides in a method for producing a base of a sealed surface comprising the following steps: a) treating the soil with a mixture of: i) lignin or lignosulphonate : and 35 ii) cement and/or lime and/or flash and/or calcium sulphate and/or blast furnace slag: WO 00/49229 PCT/AUOO/00092 15 iii) adding water in an amount up to a point where the base composition is substantially at or about an optimum moisture content that results in maximum compaction of the base composition. b) compacting the resulting composition by suitable means to form a base. 5 In another embodiment, the present invention also resides in a method for producing a base comprising the following steps: a) treating the soil with a mixture of: i) lignin or lignosulphonate ; and i) cement and/or lime and/or flash and/or calcium sulphate and/or blast furnace 10 slaa: compacting the resulting composition by suitable means to form base. In a further embodiment, the present invention resides in a method for producing a base having an unsealed surface comprising the following steps: a) treating the soil with a mixture of: 15 i) lignin or lignosulphonate; and cement and/or lime and/or flyash and/or calcium sulphate and/or blast furnace slag; and water in an amount up to a point where the base composition is substantially at or about an optimum moisture content; b) compacting the resulting composition to form a base having an unsealed 20 surface. In a typical embodiment, the method further comprises c) adding a sealant to the base composition to form a sealed surface. Typically c) comprises forming a sealing layer of sealant over the base. Thus a sealant may be spread over the base and hot rolled so as to form a sealing layer of sealant over the base. 25 The sealed surface comprises or is typically paving blocks, a concrete surface, road, pathway, pavement, floor and the like. The sealed surface is further typically a road, pathway or pavement and still further typically the sealed surface is a road. The sealed surface is typically made from a composition comprising asphalt and bitumen which is designed to carry significant traffic. so Typically the step a) above may be carried out by adding either component i) lignin or lignosulphonate first, after or together with component ii) cement and /or lime and/or [lyash with soil. However, the mixture of component i) lignin or lignosulphonate and component ii) cement and/or lime and /or flyash may also be added before the introduction with soil. 35 Usually components (i) and (ii) or (i), (ii) and (iv') are premixed in the required relative proportions to form a premix. The premix is then mixed in the desired proportion with the soil prior to adding water. Water is then added and mixed in as required, the water added usually in being an amount to achieve optimum compaction or to achieve about WO 00/49229 PCT/AUOO/00092 16 optimum compaction (typically ± 5% of optimum compaction. more typically ± 5% of optimum compaction. Typically, step b) is carried out after the treatment of soil with the mixture of component i) lignin or lignosulphonate; and ii) cement and /or lime and/or flyash. Typically, 5 the step c) is carried out after steps a) and b) have been completed and is typically achieved by use of road rollers. However, the addition of water is usually made in situ after preparing a base composition of soil. component i) lignin or lignosulphonate and ii) ccment and /or lime and/or flyash and/or calcium sulphate and/or blast furnace slag, and (iv'), if required. 10 Typically, the method also additionally comprises step d) which is the introduction of a sealant typically a bitumen/bituminous emulsion composition and/or asphalt which is provided as a layer over the top of the base and formed into a sealed surface by suitable means, so as to form a road, pavement, pathway, floor and the like. The introduction of said asphalt and/or bitumen/bituminous emulsion compositions firstly typically 15 comprises the addition of bitumen/bituminous emulsion composition before the addition of asphalt when both of these materials are used as a sealant. Typically the base composition is added in an amount in the range 20 - 100kg per cubic metre of soil (typically 20. 30, 40, 50, 60. 70, 80, 90 or 100kg per cubic metre). Where a depth of 100mm is required the base composition is typically added in an amount of 2 20 1 2, typically 4 - 10 kg per square metre, for 150 mm 4 - 18, typically 6 - 15kg per square metre. and for 200 mm 6 - 24, typically 8 - 20 kg per square metre. In one form of the invention, steps a) and b) are carried out such that a slurry of components i) lignin or Iignosulphonate: and ii). in water, are formed, subject to the condition that the amount of water added is to provide an optimum moisture content as previously defined. 25 Typically. step a) above may be also carried out by firstly adding a powdered form of the mixture of cement and/or lime and/or flyash with water so as to provide optimum moisture content as previously defined. The lignin or lignosulphonate may also be added to the powdered mixture together with any desired additives such as dispersants, binders and the like. 30 Typically, the lignin or lignosulphonate may be a salt of lignosulphonic acid including alkali metal salts thereof, alkaline earth metal salts thereof, ammonium, ammonium polymerised, chromium, and other water soluble lignosulphonates either used individually or as a mixture. The lignosulphonate preferably used is ammonium, calcium or sodium lignosulphonate either individually or as a mixture. 35 The cement is typically selected from hydraulic cements or non-hydraulic cements. The hydraulic cements include cements which are hydraulically active and may include materials such as hydraulic cement, slag and blends of hydraulic cement thereof. The term "hydraulic cements" refers to any inorganic cement which hardens or sets due to SuhatiiifnP qhchpt WO 00/49229 PCT/AUOO/00092 17 hydration. The term "hydraulically active" refers to properties of a cementitous material that allows the material to set in a manner like hydraulic cement. either with or without additional activation. Hydraulically active cementitous materials may also contain minor amounts of extenders such as bentonite, gilsonite. and cementitous materials used either S withoutt any appreciable sand or aggregate material or admixed with a granular filling material such as sand, ground limestone and the like. Strength enhancers such as silica powder or silica flour may be employed as well. Hydraulic cements typically comprise Portland cements. aluminous cements, pozzalan cements, fly ash cements, and the like. Thus, for example. any of the oilwell 10 type cements of the class "A-H" and "J" as listed in the API Spec 10, (1st Edition), are suitable and fall within the definition of hydraulic cements. Hydraulic cements are most typically used in the method and Portland Cement is the preferred cement used in the method of producing a base for a sealed surface. The lime typically used in the present invention is selected from the group of 15 hydrated lime. lime , etc. The flyash typically used in the present invention comprises flyash, alone or in combination with blast furnace slag. The blast furnace slag may also be used as another optional component with the base composition of the first or second embodiment of the present invention. 20 The soils of the present invention are typically selected from the group of crushed rock based soils, sand based soils, gravel based soils, other stone or other particulate based soils, clay based. silt based soils or a mixture thereof. The soils are still typically swamp clay. silt. volcanic silt (e.g. silt surrounding Auckland Harbour) and puggy black soil. The soils may also contain additional particulate material such as required for 25 particulate roads. pathways, pavements or the like. Typically, any soil that has particles which achieve more than 10% sieve analysis at a sizing of -0.075mm and further typically at more than 15% or 20% is suitable for the present invention. A soil that achieves a sieve analysis in the range 10 - 100%, 10 - 90%, 10 - 80%. 10 - 70%, 10 60%. 10 - 50%. 15 - 100%, 15 - 90%. 15 - 80%, 15 - 70%, 15 - 60%, 15 - 50%, 15 30 40%. 15 - 30%, 10 - 25%. 12-25%, 12-20%. 15-25%, 15-20%. 15-23% at a sizing of 0.075mm is particularly suitable. Where the sieve analysis of the soil falls outside these ranges it is desirable to blend additional particulate material (such as a filler e.g. bentonite, fire clay, silt, other fines. etc) to the soil to bring it into one of these ranges. Typically 15 - 25% fines at a sizing of -0.075mm is preferred. 35 The following Table A provides a typical blend proportion of component i) lignin or lignosulphonate and ii) Portland Cement and/or hydrated Lime and/or Flyash and/or Blast Furnace Slag and/or Calcium Sulphate when admixed together. Table A illustrates for entries numbered 1-24 the blend proportion a:b (parts by weight) where a is selected WO 00/49229 PCT/AUOO/00092 18 From the group of a value presented in the column headed "a" in Table A below at one of entries 1-24. and b is selected from the group of the values presented in the column headed "b" adjacent the corresponding "a" entry. The lignin or lignosulphonate proportion is shown under the column headed "a" whilst the Portland Cement and/or 5 hydrated lime and/or flyash and/or blast furnace slag and/or calcium sulphate proportion is shown under the column headed "b". Table A Entry a b 1 10 0.5, 1.0, 1.25, 1.5, 1.75. 2.0, 2.25. 2.5, 2.75, 3.0, 3.25, 3.5. 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25. 5.5, 5.75. 6.0, 6.25, 6.5, 6.75, 7.0, 7.25, 7.5. 7.75. 8.0. 8.25, 8.5, 8.75, 9.0, 9.25. 9.5, 9.75, 10.0. 50. 2 9.80 0.5, 1.0. 1.25, 1.5. 1.75, 2.0. 2.25. 2.5, 2.75. 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25, 7.5, 7.75, 8.0, 8.25, 8.5, 8.75. 9.0, 9.25, 9.5. 9.75. 10.0. 50. 3 9.75 0.5, 1.0. 1.25, 1.5, 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5, 3.75, 4.0. 4.25, 4.5. 4.75. 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5. 6.75, 7.0, 7.25, 7.5, 7.75. 8.0, 8.25, 8.5, 8.75. 9.0, 9.25. 9.5. 9.75. 10.0. 50. 4 9.50 0.5, 1.0, 1.25, 1.5. 1.75, 2.0, 2.25. 2.5, 2.75, 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25, 7.5. 7.75, 8.0. 8.25, 8.5, 8.75, 9.0. 9.25, 9.5. 9.75, 10.0, 50. 5 9.25 0.5, 1.0, 1.25, 1.5. 1.75, 2.0. 2.25. 2.5. 2.75, 3.0, 3.25, 3.5, 3.75. 4.0, 4.25, 4.5. 4.75. 5.0. 5.25. 5.5, 5.75, 6.0, 6.25, 6.5. 6.75, 7.0. 7.25. 7.5. 7.75, 8.0, 8.25, 8.5, 8.75. 9.0. 9.25, 9.5. 9.75. 10.0. 50. 6 9.0 0.5, 1.0, 1.25, 1.5. 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5, 3.75. 4.0, 4.25. 4.5. 4.75, 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0, 7.25, 7.5, 7.75, 8.0, 8.25, 8.5, 8.75. 9.0. 9.25, 9.5. 9.75. 10.0. 50. 7 8.75 0.5, 1.0, 1.25. 1.5. 1.75. 2.0. 2.25. 2.5, 2.75. 3.0, 3.25, 3.5, 3.75, 4.0, 4.25. 4.5, 4.75. 5.0. 5.25, 5.5, 5.75, 6.0, 6.25. 6.5, 6.75, 7.0, 7.25. 7.5. 7.75, 8.0, 8.25, 8.5, 8.75, 9.0, 9.25, 9.5, 9.75, 10.0, 50.

WO 00/49229 PCT/AUOO/00092 19 8 8.50 0.5, 1.0, 1.25, 1.5, 1.75, 2.0, 2.25, 2.5. 2.75, 3.0, 3.25, 3.5, 3.75, 4.0. 4.25, 4.5, 4.75. 5.0, 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25, 7.5, 7.75. 8.0. 8.25, 8.5, 8.75. 9.0, 9.25, 9.5. 9.75. 10.0. 50. 9 8.25 0.5, 1.0, 1.25. 1.5, 1.75, 2.0. 2.25, 2.5, 2.75, 3.0, 3.25, 3.5, 3.75, 4.0. 4.25, 4.5. 4.75. 5.0, 5.25. 5.5, 5.75, 6.0, 6.25. 6.5. 6.75, 7.0. 7.25, 7.5, 7.75. 8.0, 8.25, 8.5, 8.75, 9.0. 9.25, 9.5. 9.75. 10.0, 50. 10 8.00 0.5. 1.0, 1.25, 1.5. 1.75, 2.0, 2.25. 2.5, 2.75, 3.0, 3.25, 3.5, 3.75. 4.0, 4.25. 4.5, 4.75. 5.0, 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0, 7.25. 7.5. 7.75. 8.0, 8.25. 8.5, 8.75, 9.0, 9.25. 9.5. 9.75, 10.0, 50. 11 7.75 0.5, 1.0, 1.25. 1.5, 1.75. 2.0. 2.25, 2.5, 2.75. 3.0, 3.25, 3.5, 3.75, 4.0. 4.25. 4.5, 4.75, 5.0, 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25. 7.5, 7.75. 8.0. 8.25, 8.5, 8.75, 9.0. 9.25. 9.5, 9.75, 10.0, 50. 12 7.50 0.5, 1.0, 1.25, 1.5, 1.75, 2.0, 2.25, 2.5. 2.75, 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75, 5.0, 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25, 7.5, 7.75, 8.0, 8.25, 8.5, 8.75, 9.0, 9.25. 9.5. 9.75. 10.0, 50. 13 7.25 0.5, 1.0. 1.25, 1.5. 1.75, 2.0, 2.25. 2.5. 2.75, 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75. 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25, 7.5, 7.75. 8.0, 8.25, 8.5, 8.75. 9.0, 9.25. 9.5. 9.75, 10.0. 50. 14 7.00 0.5, 1.0, 1.25, 1.5. 1.75, 2.0, 2.25, 2.5. 2.75. 3.0, 3.25, 3.5, 3.75, 4.0, 4.25. 4.5, 4.75, 5.0, 5.25. 5.5, 5.75, 6.0, 6.25, 6.5. 6.75, 7.0, 7.25, 7.5, 7.75, 8.0. 8.25, 8.5, 8.75. 9.0, 9.25, 9.5, 9.75. 10.0, 50. 16 6.75 0.5, 1.0. 1.25. 1.5. 1.75, 2.0, 2.25. 2.5. 2.75, 3.0, 3.25, 3.5, 3.75, 4.0. 4.25, 4.5, 4.75, 5.0. 5.25. 5.5, 5.75, 6.0. 6.25. 6.5, 6.75, 7.0, 7.25, 7.5. 7.75, 8.0, 8.25, 8.5, 8.75. 9.0, 9.25, 9.5. 9.75, 10.0, 50. 17 6.50 0.5. 1.0., 1.25, 1.5. 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5. 3.75, 4.0. 4.25, 4.5. 4.75. 5.0, 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0, 7.25, 7.5, 7.75, 8.0, 8.25, 8.5, 8.75, 9.0. 9.25. 9.5. 9.75, 10.0, 50.

WO 00/49229 PCT/AUOO/00092 20 18 6 0.5, 1.0, 1.25. 1.5, 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5. 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25. 5.5, 5.75, 6.0, 6.25. 6.5, 6.75, 7.0. 7.25. 7.5. 7.75. 8.0. 8.25, 8.5, 8.75, 9.0, 9.25, 9.5. 9.75, 10.0, 50. 19 5.5 0.5, 1.0, 1.25, 1.5, 1.75, 2.0. 2.25. 2.5, 2.75, 3.0, 3.25, 3.5. 3.75. 4.0. 4.25. 4.5, 4.75. 5.0. 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0, 7.25. 7.5. 7.75, 8.0, 8.25, 8.5, 8.75, 9.0, 9.25, 9.5, 9.75. 10.0. 50. 20 5 0.5, 1.0, 1.25, 1.5, 1.75. 2.0, 2.25. 2.5, 2.75, 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5. 6.75. 7.0, 7.25. 7.5, 7.75, 8.0, 8.25, 8.5, 8.75, 9.0, 9.25. 9.5. 9.75. 10.0. 50. 21 4 0.5, 1.0. 1.25, 1.5, 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5. 3.75. 4.0. 4.25, 4.5, 4.75. 5.0. 5.25. 5.5, 5.75, 6.0, 6.25. 6.5, 6.75, 7.0, 7.25. 7.5, 7.75, 8.0, 8.25. 8.5, 8.75. 9.0. 9.25, 9.5, 9.75. 10.0, 50. 29 3 0.5, 1.0, 1.25, 1.5, 1.75, 20 2.25, 2.5. 2.75. 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5. 4.75, 5.0, 5.25. 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0, 7.25. 7.5. 7.75, 8.0, 8.25, 8.5, 8.75, 9.0, 9.25, 9.5, 9.75, 10.0, 50. 23 2 0.5, 1.0, 1.25, 1.5, 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.25, 3.5, 3.75, 4.0, 4.25, 4.5, 4.75, 5.0. 5.25, 5.5, 5.75, 6.0, 6.25. 6.5, 6.75, 7.0, 7.25. 7.5. 7.75, 8.0. 8.25, 8.5, 8.75, 9.0. 9.25, 9.5. 9.75, 10.0, 50. 24 1 0.5, 1.0, 1.25. 1.5, 1.75, 2.0. 2.25, 2.5, 2.75, 3.0. 3.25, 3.5, 3.75. 4.0. 4.25. 4.5, 4.75, 5.0. 5.25, 5.5, 5.75, 6.0, 6.25, 6.5, 6.75, 7.0. 7.25. 7.5, 7.75, 8.0, 8.25, 8.5, , 8.75, 9.0. 9.25, 9.5, 9.75, 10.0, 50. Typically, the concentration and presence of either calcium lignosulphonate, sodium lignosulphonate and ammonium lignosulphonate further depends on the type of soils used in the present invention, especially for use in sealed surfaces. Description Of The Preferred Embodiment(s) And Example(s) Of The Invention The following description of the preferred embodiment serves only to further illustrate the present invention and should not be construed as limiting the generality of the above description. The present invention will now be described, by way of example only, with reference to the accompanying schematic flow diagram: in which: Substitute Shnnk WO 00/49229 PCT/AUOO/00092 21 Figure 1 is a schematic flow diagram illustrating the method of producing a base composition and a sealed surface thereof according to the present invention. In Figure 1 of the accompanying drawings , there is shown a schematic flow diagram of a process according to the present invention. A lignosulphonate composition 5 (10) of calcium lignosulphonate. sodium lignosulphonate and ammonium lignosulphonate is premixed and added to a soil composition (12) either in a container (14) or on a ground surface (not shown). The lignosulphonate composition (10) and soil composition (12) is mixed by suitable means (16) such as a rotary mixer and water is added to the resulting mixture to 10 form a road base composition (18) according to the present invention substantially at or about the optimum moisture content for maximum compaction as previously defined. The road base composition (18) is then compacted to form a compacted road base composition by suitable means (20) such as a road roller which compacts and bonds the particles of the soil together with the assistance of the lignosulphonate composition (12). 15 The road or base may be profiled so as to drain excess water from its surface or layers. Typically, after the compacted road base composition is formed after sufficient time in rolling, watering and is of sufficient compaction, and after drying, a sealing composition comprising an asphalt and/or bitumen/bituminous emulsion composition (22) is applied to an upper surface of the compacted road base composition. A bitumen, 20 bituminous emulsion and/or an asphalt composition (24) is then added which forms the sealing road composition according to the present invention. Some asphalt needs bitumen or a bituminous emulsion first before being applied whilst other asphalts and hitumen/bituminous emulsions are able to be applied alone. The surface sealing layer is then formed over the compacted road base composition in the usual manner known to the 25 skilled addressee such as by hot and/or cold rolling. Further, in another example. concrete is able to be applied over the base composition of the present invention to form a road, pathway. floor and the like surface. The following examples serve only to further illustrate the present invention and should not be construed as limiting the generality of the above description. 30 Examples A lignosulphonate compound or a mixture of lignosulphonate compounds defining a first composition comprises the following: A. Calcium lignosulphonate. B. Sodium lignosulphonate. and 35 C. Ammonium lignosulphonate. The said first composition includes a mixture of A, B and/or C, with the proviso that there must be at least one of A. B or C present as a single component or in the coriposition.

WO 00/49229 PCT/AUO0/00092 22 A second component or mixture of components defining a second composition comprises the following compounds: D. Portland Cement. E. Hydrated Lime, 5 F. Flvash. G. calcium Sulphate, and H. Blast Furnace Slag The said second composition includes a mixture of D. E. F, G and/or H with the proviso that there must be at least one of D. E, F. G and/or H present as a single component or in the composition. 10 The said first and second compositions are blended into a two part product in the ranges as set out below in Table B, according to the requirements of the particular use, whereby for each entry numbered I to 24 there is provided a value indicating the proportion (parts by weight) of the First Composition (A, B & C) and the Second Composition (D. E. F. G & H) which is also indicated by parts by weight. 15 TABLE B Entry First Second Composition Composition 1 10 0.5. 1. 1.25. 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00, 3.25, 3.50. 3.75. 4.00. 4.25, 4.50. 4.75. 5.00, 5.25, 5.50. 5.75, 6.00. 6.25. 6.50. 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50. 8.75, 9.00, 9.25, 9.50, 9.75, 10.0. 50. 2 9.5 0.5, 1. 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00, 3.25, 3.50. 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00, 6.25, 6.50, 6.75, 7.00, 7.25, 7.50. 8.00, 8.25, 8.50. 8.75. 9.00, 9.25, 9.50, 9.75, 10.0. 50. 3 9.0 0.5, 1, 1.25. 1.50, 1.75. 2.00, 2.25, 2.50, 2.75, 3.00. 3.25. 3.50. 3.75, 4.00. 4.25. 4.50. 4.75. 5.00, 5.25, 5.50. 5.75, 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50. 8.00. 8.25, 8.50. 8.75, 9.00, 9.25, 9.50, 9.75, 10.0, 50. An~hatffhitna hn WO 00/49229 PCT/AUO0/00092 23 4 8.5 0.5, 1, 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00. 6.25, 6.50, 6.75. 7.00, 7.25, 7.50, 8.00, 8.25, 8.50, 8.75, 9.00. 9.25, 9.50, 9.75, 10.0. 50. 5 8.0 0.5. 1. 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25. 5.50, 5.75. 6.00, 6.25. 6.50, 6.75, 7.00, 7.25, 7.50, 8.00. 8.25, 8.50. 8.75. 9.00. 9.25, 9.50, 9.75, 10.0. 50. 6 7.5 0.5, 1, 1.25. 1.50, 1.75, 2.00, 2.25, 2.50. 2.75, 3.00, 3.25, 3.50, 3.75. 4.00, 4.25. 4.50, 4.75, 5.00, 5.25. 5.50. 5.75, 6.00. 6.25. 6.50. 6.75., 7.00, 7.25, 7.50. 8.00. 8.25, 8.50. 8.75, 9.00. 9.25, 9.50, 9.75, 10.0. 50. 7 7.0 0.5, 1, 1.25, 1.50. 1.75, 2.00, 2.25, 2.50, 2.75, 3.00, 3.25, 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50. 5.75, 6.00, 6.25, 6.50, 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50. 8.75, 9.00, 9.25, 9.50, 9.75, 10.0, 50. 8 6.5 0.5, 1, 1.25, 1.50. 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75. 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50. 5.75, 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50. 8.00. 8.25, 8.50. 8.75. 9.00, 9.25, 9.50, 9.75, 10.0. 50. 9 6.0 0.5. 1, 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25. 3.50, 3.75. 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50. 5.75, 6.00. 6.25. 6.50, 6.75, 7.00, 7.25, 7.50, 8.00. 8.25, 8.50. 8.75, 9.00, 9.25, 9.50, 9.75, 10.0, 50. 10 5.5 0.5, 1, 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00, 3.25, 3.50, 3.75, 4.00, 4.25. 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50. 8.00, 8.25, 8.50. 8.75. 9.00, 9.25, 9.50, 9.75, 10.0, 50. Snhatfiinto Rhoot WO 00/49229 PCT/AUOO/00092 24 11 5.0 0.5, 1. 1.25, 1.50. 1.75, 2.00. 2.25, 2.50, 2.75, 3.00. 3.25, 3.50. 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25. 5.50, 5.75, 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50, 8.75, 9.00. 9.25, 9.50, 9.75, 10.0. 50. 12 4.5 0.5. 1. 1.25, 1.50, 1.75, 2.00. 2.25, 2.50, 2.75, 3.00. 3.25. 3.50, 3.75, 4.00, 4.25. 4.50. 4.75. 5.00, 5.25. 5.50. 5.75. 6.00, 6.25. 6.50. 6.75. 7.00. 7.25, 7.50. 8.00, 8.25, 8.50. 8.75, 9.00. 9.25, 9.50, 9.75, 10.0. 50. 13 4.0 0.5. 1., 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75, 4.00, 4.25. 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50. 8.00, 8.25. 8.50. 8.75, 9.00. 9.25, 9.50, 9.75, 10.0. 50. 14 3.5 0.5. 1. 1.25. 1.50. 1.75. 2.00. 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00, 6.25, 6.50, 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50, 8.75, 9.00, 9.25, 9.50, 9.75, 10.0. 50. 15 3.0 0.5, 1. 1.25, 1.50, 1.75. 2.00, 2.25. 2.50, 2.75, 3.00. 3.25. 3.50, 3.75. 4.00, 4.25. 4.50, 4.75, 5.00, 5.25. 5.50, 5.75, 6.00. 6.25. 6.50. 6.75. 7.00, 7.25, 7.50. 8.00. 8.25. 8.50. 8.75. 9.00. 9.25. 9.50, 9.75, 10.0, 50. 16 2.5 0.5, 1. 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25, 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00, 6.25, 6.50, 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50, 8.75, 9.00, 9.25, 9.50, 9.75, 10.0, 50. 17 2.0 0.5. 1. 1.25, 1.50, 1.75, 2.00, 2.25, 2.50, 2.75, 3.00. 3.25. 3.50, 3.75, 4.00, 4.25, 4.50, 4.75, 5.00, 5.25. 5.50. 5.75, 6.00, 6.25. 6.50, 6.75, 7.00, 7.25, 7.50, 8.00, 8.25, 8.50, 8.75, 9.00. 9.25, 9.50, 9.75, 10.0, 50. Anhqftitntap Rqhpnpt WO 00/49229 PCT/AUOO/00092 25 18 1.5 0.5. 1, 1.25. 1.50. 1.75. 2.00, 2.25, 2.50, 2.75, 3.00, 3.25. 3.50. 3.75. 4.00, 4.25, 4.50, 4.75, 5.00, 5.25, 5.50, 5.75, 6.00, 6.25. 6.50, 6.75, 7.00, 7.25, 7.50. 8.00, 8.25, 8.50. 8.75, 9.00, 9.25. 9.50. 9.75, 10.0. 50. 19 1.25 0.5, L, 1.25. 1.50, 1.75, 2.00, 2.25. 2.50, 2.75, 3.00, 3.25, 3.50. 3.75. 4.00, 4.25, 4.50, 4.75, 5.00, 5.25. 5.50. 5.75. 6.00. 6.25, 6.50, 6.75, 7.00, 7.25, 7.50, 8.00. 8.25, 8.50. 8.75, 9.00. 9.25, 9.50, 9.75, 10.0..50. 20 1.0 0.5, 1, 1.25. 1.50, 1.75. 2.00. 2.25, 2.50, 2.75, 3.00, 3.25, 3.50, 3.75. 4.00, 4.25. 4.50, 4.75, 5.00, 5.25, 5.50. 5.75. 6.00, 6.25, 6.50, 6.75. 7.00, 7.25, 7.50. 8.00. 8.25, 8.50. 8.75, 9.00, 9.25, 9.50, 9.75, 10.0, 50. The two part product which is blended together as shown in Table B above defines a third composition which is then admixed with soil, for example. crushed rock based soil, sand based soil, gravel based soil, other stone or other particulate based soil, clay based. silt based soil or a mixture thereof. 5 The blends of the Third Composition with Soil is shown as follows in Table C: Table C Soil (weight percent) Third Composition (weight percent) 99.8 0.2 99.7 0.3 99.5 0.5 99.4 0.6 99.3 0.7 99.2 0.8 99.1 0.9 99.0 1.0 98.9 1.1 98.8 1.2 98.7 1.3 98.6 1.4 98.5 1.5 98.4 1.6 Substfiiin qRhciat WO 00/49229 PCT/AU0O/00092 26 98.3 1.7 98.2 1.8 98.1 1.9 98.0 2.0 97.9 2.1 97.8 2.2 97.7 2.3 97.6 2.4 97.5 2.5 97.4 2.6 97.3 2.7 97.2 2.8 97.1 2.9 97.0 3.0 96.9 3.1 96.8 3.2 96.7 3.3 96.6 3.4 96.5 3.5 96.4 3.6 96.3 3.7 96.2 3.8 96.1 3.9 96.0 4.0 95.9 4.1 95.8 4.2 95.7 4.3 95.6 4.4 95.5 4.5 95.4 4.6 95.3 4.7 95.2 4.8 95.1 4.9 95.0 5.0 94.9 5.1 94.8 5.2 94.7 5.3 WO 00/49229 PCT/AUOO/00092 27 94.6 5.4 94.5 5.5 94.4 5.6 94.3 5.7 94.2 5.8 94.1 5.9 94.0 6.0 93.9 6.1 93.8 6.2 93.7 6.3 93.6 6.4 93.5 6.5 93.4 6.6 93.3 6.7 93.2 6.8 93.1 6.9 93.0 7.0 92.9 7.1 92.8 7.2 92.7 7.3 92.6 7.4 92.5 7.5 92.4 7.6 92.3 7.7 92.2 7.8 92.1 7.9 92.0 8.0 91.9 8.1 91.8 8.2 91.7 8.3 91.6 8.4 91.5 8.5 91.4 8.6 91.3 8.7 91.2 8.8 91.1 8.9 91.0 9.0 Substitunt Rhpc,: WO 00/49229 PCT/AUOO/00092 28 90.9 9.1 90.8 9.2 90.7 9.3 90.6 9.4 90.5 9.5 90.4 9.6 90.3 9.7 90.2 9.8 90.1 9.9 90.0 10.0 As already mentioned water is added as required to bring the moisture content to or about the optimum moisture content for compaction. If too much water is accidently added, the composition can be left to dry out for a time sufficient for the moisture content to drop to at or about the optimum moisture content for maximum compaction. Compaction of the 5 base is then carried out. The details of determining optimum moisture content of the mixture are described below. Example of determination of dry density/moisture content relationship of base composition The following example demonstrates a method of measuring moisture content 10 which in turn allows the prediction of maximum compaction of the base composition at various moisture contents. The collation of this data will assist in determining the optimum moisture content of the base composition. - In this example a 2.5kg rammer falling through a height of 300mm is used to compact the base composition in three layers into a one litre mould. 15 - The base composition is firstly weighed in a prepared sample. - The mould is weighed with a baseplate attached to 1g, this value being, and the internal dimensions are measured to within 0.1mm. - The extension to the mould is attached and the mould assembly is placed on a base. - 2%. by weight, of water is added to the prepared base composition and mixed 20 thoroughly by hand. - A quantity of moist soil is inserted in mould body such that when compacted it occupies a little over one-third of the height of the mould body. - Twenty seven blows from the rammer is dropped from a height of 300 mm above the base composition. distribute the blows evenly over the surface and ensure that the 25 rammer always falls freely and is not obstructed by soil in a guide member formed in the mould body. Substitnta Shent WO 00/49229 PCT/AUO0/00092 29 - The blows are repeated twice so that the amount of base composition used is sufficient to fill the mould body, with the surface not more than 6mm proud of the upper edge of the mould and it is important to ensure that no more than 6mm stands proud. - The extension is removed and the excess soil is removed and the surface of the 5 compacted soil is levelled carefully to the top of the mould body using a straight edge. Any coarse particles removed in the levelling process and replaced by finer material from the sample, and well pressed in, the base composition and mould is weighed and with the baseplate to within Ig this value is X 2 - The remainder of the soil is broken up, and mixed with the remainder of the 10 prepared sample. A suitable increment of water (2wt%) is added and mixed thoroughly into the soil, the water added for each stage of the test should be such that a range of moisture contents is obtained which includes the optimum moisture content. - Typically additions of 1 & 2wt% are suitable for sandy gravelly soils and 2 to 4wt% for cohesive soils, to increase the accuracy of the test it is often advisable to reduce Is the increments of water in the region of the optimum moisture content. - Typically the above procedure is repeated to give a total of five determinations. The moisture content of each determination is such that the optimum moisture content is that which the maximum dry density occurs near the middle of the range. The internal volume V in cm 3 of the mould is calculate as follows. 20 The bulk density p in Mg/m 3 of each compacted specimen is obtained from the equation P=X, - X, p= V where X, is the mass of mould and baseplate (in g); where X 2 is the mass of mould, baseplate and compacted soil (in g). 25 Calculate the dry density Pa in Mg/m 3 of each compacted specimen from the equation 100 100+ w where w is the moisture content of the soil (in wt%). The dry densities obtained from a series of determinations are plotted as ordinates 30 against the corresponding moisture contents. A curve of best fit is drawn to the plotted points and the position of the maximum of this curve is identified. The values of dry density are read off to. On the same graph the curves are plotted corresponding to 0%, 5%, and 10% air voids, calculated from the equation. V 100 1 w p, 100 p" Substitnt Shent WO 00/49229 PCT/AUO0/00092 30 Where Pa is the dry density in Mg/m3 Where Ps is the particle density in Mg/m 3 . assumed equal to 2.65 or 2.70 Where Pw is the density of water in Mg/m 3 assumed equal to 1 Where Va is the volume of air voids in the soil, expressed as a percentage of the 5 total volume of the soil (equal to 0%. 5%. 10% for the purpose of this example). Where w is the moisture content in wt% An example of optimum moisture content measured and evaluated by the procedures above are as follows. Soil Sample: ridge grave, brown i0 ex Lemon Tree Passage Quarry Stabilised with a blend containing Lignosulphonate 1 part Cement 2 parts Hydrated Lime I part 15 at 80kg per compacted cubic metre Maximum dry density 2.00 tonne per cubic metre Optimum moisture content 11 .Owt% However, it should be appreciated that in the field, the optimum moisture content is approximately determined by a hand test where the base composition is compacted in the 20 palm and suitable increments of water are added until the approximate point of maximum compaction is achieved. The blended compositions of the Third composition and the soil in Table C above are spread on to a ground surface where it is desired to form a base for an unsealed or sealed surface such as a road, pathway, pavement, floor and the like. 25 A rotary hoe together with a water cart adds water to the composition to achieve optimum moisture content which results in a substantially dust free base since the soil particles are cohesively bonded together. Alternatively, the Third composition and the soil are also mixed with water in a pug mill mixer which is located alongside, adjacent or at a location remote from the proposed so location of the road base. Further, the Third composition and soil are also mixed are also blade mixed by a grader with the addition of water. The Third composition can also be formed into a slurry to obtain substantially optimum moisture content as previously defined so as to provide maximum compaction to the base composition. 3s 5The optimum moisture content for a particular soil or soil composition of the present invention is determined by suitable compaction tests. The compaction tests are used to determine the optimum moisture content at which a particular soil or soil composition has to be compacted in order to attain the maximum dry density. The Substitute Sheet WO 00/49229 PCT/AU0O/00092 31 compaction tests are used to determine the optimum moisture content at which a given soil has to compacted in order to attain the maximum dry density. The laboratory compactive effort is standardized and it is assumed that it duplicates field compaction effort and vice versa. The material is compacted at various moisture contents using a 5 fresh portion of soil for each moisture content applied. As the moisture content increases, dry density increases to a certain maximum but then decreases. Plotting dry densities against moisture contents gives a moisture content density curve corresponding to a given compaction effort. This obviously shows that for each soil there is a given maximum compaction that can be achieved for each moisture content. 10 Thereafter suitable compaction and binding by the lignosulphonate composition allows the bitumen and/or asphalt composition to be applied in the case of a sealed base. The composition of the present example potentially achieves this result up to the range of approximately 50 to 70 percent reduction in costs due to a lesser amount of material being required to form the substantially dust free and cohesively bonded state 1 5 when compared to the prior art. After the base for the sealed surface has been forced, a bitumen/bituminous emulsion and /or asphalt is layed over the base to form a sealed surface. The bond strength between the base composition of the present invention and the asphalt and/or bitumen/bituminous emulsion composition is observed to be increased 20 EXAMPLES The objective is to create an impervious, bound, flexible, resilient pavement with the high resilient modulus that will achieve a relatively high "soaked California Bearing Ratio". an improved unconfined compressive strength, and, in the case of sealed surfaces, a high strength bond to bitumen, asphalt, and to the sub grade materials. 25 Under standard pavement "Atterburg Limits"" testing, various mixes will provide high strength, reliable pavements where plasticity indices range 0 to 40, or greater. Because there is almost an infinite range of soil types in the above classification range, a wide selection of blend variations between the lignosulphonates and some or all of the other materials nominated is required to achieve the high strengths and good to optimal 30 performance and efficiency at the lowest possible costs. To achieve an efficient and effective, flexible, resilient bound pavement, a dry sieve analysis of the soils to be stabilised is desirable. Ideally the soil has a 15% minimum, and preferably 20% or more sieve fraction less than 0.075mm (i.e. -0.075mm). If this is not available in the soil then the "other" material selected in the PP product blend is 35 proportionally adjusted to achieve the objective. Lignosulphonates should not be considered as part of the additional fines required. The most commonly used lignosulphonates are ammonium, sodium and calcium, usually in combinations of two or three. They are required for four purposes Substitute Sheet WO 00/49229 PCT/AUOO/00092 32 1. to act as a flexible, high strength, resilient binder 2. to react with the soil, cement, and lime and the other material to provide chemical stability, and therefore soil stability 3. With the other materials, they bind the soil to form an impervious mass with a 5 verv high level of water resistance 4. The blended impervious mass forms its own carbonaceous "primer" to bond strongly to bitumen or asphalt Soil stabilisation procedures are basically the same as when lime, cement, slay, flyash, etc are mixed in individually, or in combination blends into soil. Moisture is controlled 10 to modified optimum and the pavement is compacted to the maximum practical level. Good compaction is critical to the process, and it is not difficult to achieve high density and compaction levels in excess of 100%. Other advantages are the ease of compaction and the ability to achieve very high densities. Commonly, lignin percentages for most road materials are 0.5% to 2wt%. However, 1 s soil tests may reveal the need to go outside this range. Stabilisation depths for public roads (sealed or unsealed) are commonly in 100mm to 200mm range, more typically 150mm to 200mm, but sometimes greater e.g. 200 350mm or 200 -250mm, or 200 -300mm. Summarising design of the blend as per PP is achieved by taking into account the 20 following factors and blending and laboratory testing to achieve the most economic best bind performance. The factors - Traffic loading and type Climate Soil type 25 Sub grade of pavement Type of surface finish or seal 1. Highway blend designed for in excess of 1000 heavy vehicles per day and assuming area subject to periodic flooding: Base soil - high clay content plasticity index 15 to 20 average soaked CBR 13.5 30 (98wt% soil+water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition). Sub grade - soil high clay content plasticity index 20 to 40 average soaked CBR Rehabilitation of 1km of 11 m wide road with a blend to a depth of 200mm in base 35 Blend lwt% (50/50) ammonium lignosulphonate and sodium lignosulphonate, 1% general purpose cement, lwt% hydrated lime 2. Designed for public highway heavy traffic Suhtiinin RaPt WO 00/49229 PCT/AUOO/00092 33 Base soil - medium clay content with plasticity index 8 to 15 (98wt% soil+water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition) to depth ~ 200mm. 5 Blend lwt% (one third each ammonium, sodium, calcium lignosulphonates), 0.5wt% general purpose cement and 0.5wt% hydrated lime. 3. Designed for public highway, heavy traffic Base soil - gravel with very low plasticity index (98wt% soil+water in an amount where the base composition is substantially at or about an optimum moisture content 10 that enables substantially maximum compaction of the base composition) Construction/rehabilitation depth ~150mm. 0.5wt% (50/50 ammonium sodium lignosulphonate) 0.5wt% bentonite 0.5wt% general purpose cement 15 0.5wt% hydrated lime 4. Architectural Pavement High strength hard wearing decorative image pavement. Base soil - decomposed granite with very limited fines and zero plasticity index (95wt%). 20 Stabilisation to high strength hard wearing pavement using a blend of lwt% (50/50 ammonium lignosulphonate/sodium lignosulphonate), lwt% bentonite, 1wt% hydrated lime, 2 wt % general purpose cement. The advantages of the compositions and methods of the present invention are potentially as follows: 25 -environmentally friendly compositions with a very low LD 50 which are substantially non-toxic and non-carcinogenic: -in the case of a sealed base, useful in a wide variety of sealed surfaces from pavers, pathways, roads, floors and the like; -in the case of an unsealed base, useful in a wide variety of unsealed surfaces from 30 pavers, pathways, roads, floors and the like; -a stronger base with a strength of potentially up to 35mPa which is useful for sealed and unsealed surfaces: -useful for a wide variety of soils including but not limited to clay based and silt based soils: 35 The processes and compositions of the present invention typically leads to the following advantages compared with known compositions and methods. - Potentially increased wear of asphalt/bitumen/bituminous emulsion composition for sealed surfaces especially roads: and Substitute Shant WO 00/49229 PCT/AUO0/00092 34 - a stronger base for sealed surfaces which produces a highly resilient, shock absorbent surface with increased strength to withstand dynamic stresses imported to said sealed surfaces. - increased speed of laying down road base. 5 - potentially 50 to 70 percent cost reduction in the amount of binding composition required for unsealed surfaces such as loose dirt, gravel and clay based road bases: - increased wear of unsealed roads; and - a stronger base for unsealed surfaces which produces a highly resilient, shock absorbent surface with increased strength to withstand dynamic stresses imported to said 10 surfaces. - increases speed of laying down base for unsealed surfaces. Modifications and variations such as would be apparent to a skilled addressee are deemed to be within the scope of the present invention. It is also to be understood that the present invention should not be restricted to the particular embodiment(s) or 15 example(s) illustrated under the description of the preferred embodiment of the invention. Throughout the specification, unless the context clearly indicates otherwise, the word. "comprise", "comprises", "comprising" or other variations thereof shall be understood as meaning that the stated integer is included and does not exclude other integers from being present even though those other integers are not explicitly stated. 20 Snbtitut ShAnt

Claims

1. A method of producing a base comprising the following steps: (a) mixing (i) at least one binder selected from the group consisting of lignin and 5 lignosulphonate; (ii) at least one additive selected from the group consisting of cement, lime, flyash. calcium sulphate and slag; and (iii) soil; to form a base composition, and I0 (h) compacting the base composition to form a base.

2. The method of claim 1 wherein step (a) further comprises the step of mixing: (iv) water; with (i), (ii) and (iii).

3. The method of claim 1 wherein step (a) further comprises the step of mixing: 15 (iv) water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition.

4. The method of claim 1 wherein step (a) further comprises the step of mixing: (iv') a filler; 20 with (i). (ii) and (iii).

5. The method of claim 2 wherein step (a) further comprises the step of mixing: (iv') a filler; with (i). (ii). (iii) and (iv).

6. The method of claim 3 wherein step (a) further comprises the step of mixing: 25 (iv') a filler; wvith (i), (ii), (iii) and (iv).

7. The method of claim I wherein step (a) comprises: (a) mixing (i) in an amount of 0.1wt% - 15wt% at least one binder selected from the group 30 consisting of lignin and lignosulphonate; (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag: and 70wt% - 99.8wt% soil.

8. The method of claim 2 wherein step (a) comprises: 35 a ) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; Substitute Sheet WO 00/49229 PCT/AU0O/00092 36 (ii) in an amount of 0.1wt% - 15wt% at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; (iii) 70wt% - 99.8wt% soil; and (iv) Owt%-25wt% water. 5 9. The method of claim 3 wherein step (a) comprises: (a) mixing (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group 1a consisting of cement, lime, flyash, calcium sulphate and slag; (iii) 70wt% - 99.8wt% soil; and (iv) Owt%-25wt% water.

10. The method of claim I wherein step (a) comprises: (a) mixing 15 (i) in an amount of 0.lwt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; (iii) 70wt% - 99.7wt% soil and 20 (iv') 0.1wt%-15wt% of a filler. I1. The method of claim 2 wherein step (a) comprises: (a) mixing (i) in an amount of 0.1 wt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate: 25 (ii) in an amount of 0.lwt% - 15wt% at least one additive selected from the group consisting of cement, lime. flyash, calcium sulphate and slag; (iii) 70wt% - 99.7wt% soil; (iv) Owt%-25wt% water; and (iv') 0.1wt%-I5wt% of a filler. o 12. The method of claim 3 wherein step (a) comprises: (a) mixing (i) in an amount of 0.1 wt% - 15wt% at least one binder selected from the group consisting of lignin and lignosulphonate; (ii) in an amount of 0. lwt% - 15wt% at least one additive selected from the group 35 consisting of cement, lime, flash. calcium sulphate and slag; (iii) 70wt% - 99.7wt% soil; (iv) Owt%-25wt% water: and (iv') 0. 1 wt%-25wt% of a filler. Substitute Sheet WO 00/49229 PCT/AUO0/00092 37 1 3. The method of claim 2 wherein step (a)(iv) comprises: (iv) ]-15wt% water.

14. The method of claim 3 wherein step (a)(iv) comprises: (iv) 1-15wt% water. 5 15. The method of claim 9 wherein step (a)(iv) comprises: (iv) 1-15wt% water.

16. The method of claim 12 wherein step (a)(iv) comprises: (iv) l-15wt% water. I 7. The method of any one of claims 1-16 further comprising: 10 (d) sealing the base with a sealant.

18. The method of any one of claims further comprising: (e) sealing the base with a sealant. 1 8. A base composition comprising: (i) at least one binder selected from the group consisting of lignin and 15 lignosulphonate; and (ii) at least one additive selected from the group consisting of cement, lime, flash, calcium sulphate and slag.

19. The base composition of claim 18 further comprising: (iii) soil. 20 20. The base composition of claim 18 further comprising: (iv') a filler.

21. The base composition of claim 19 further comprising: (iv') a filler.

22. The base composition of any one of claims 18 - 21 further comprising: 25 (iv) water.

23. A method of producing a base composition comprising the following steps: mixing (i) at least one binder selected from the group consisting of lignin and lignosulphonate; 30 (ii) at least one additive selected from the group consisting of cement, lime, flyash, calcium sulphate and slag; and (iii) soil; to form the base composition.

24. A method of producing a base composition comprising the following steps: 35 mixing (i) at least one binder selected from the group consisting of lignin and lignosulphonate; Substitute Sheet WO 00/49229 PCT/AUOO/00092 38 (ii) at least one additive selected from the group consisting of cement, lime, flyash. calcium sulphate and slag; and (iii) soil having 10% -25% sieve analysis at a sizing of -0.075mm; to form the base composition. 5 25. The method of claim 24 wherein the step of mixing further comprises the step of mixing: (iv) water: with (i), (ii) and (iii).

26. The method of claim 24 wherein the step of mixing further comprises the step of 10 nixing: (iv) water in an amount where the base composition is substantially at or about an optimum moisture content that enables substantially maximum compaction of the base composition.

27. The method of claim 24 wherein the step of mixing further comprises the step of 1 mixing: (iv') a filler; with (i), (ii) and (iii).

28. The method of claim 25 wherein the step of mixing further comprises the step of inmxinu,: 20 (iv') a filler; with (1). (ii), (iii) and (iv).

29. The method of claim 25 wherein the step of mixing further comprises the step of mixing: (iv') a filler; 25 with (i). (ii), (iii) and (iv).

31. A method of producing a base composition comprising the following steps: mixing (i) at least one binder selected from the group consisting of lignin and lignosulphonate; 30 (ii) at least one additive selected from the group consisting of cement, lime, flyash. calcium sulphate and slag; and (iv') a filler; to form the base composition.

32. The method of claim 31 wherein the step of mixing further comprises the step of 35 mixing: (iii) soil; with (i). (ii) and (iv'). Substitute Sheet WO 00/49229 PCT/AUO0/00092 39 32. The method of claim 31 wherein the step of mixing further comprises the step of mixing: (iii) soil; (iv) water; 5 with (i). (ii) and (iv').

33. The method of claim 3 1 wherein the step of mixing further comprises the step of mixi ng: (iii) soil having 10% -25% sieve analysis at a sizing of -0.075mm: (iv) water in an amount where the base composition is substantially at or about an 10 optimum moisture content that enables substantially maximum compaction of the base composition. with (i). (ii) and (iv').

34. A base composition produced by the method of claim 24.

35. A sealed base produced by the method of claim 18. s 36. A base produced by the method of claim 1. Substitute Sheet