AU2423700A - Cold rolled steel - Google Patents

Description

WO00/42228 PCT/AU00/00010 COLD ROLLED STEEL TECHNICAL FIELD The invention provides a method of producing 5 plain carbon steel strip which has an excellent balance of ultimate tensile strength and elongation to break making it particularly suitable for the production of structural steel products. Strip produced in accordance with the invention may for example be used as a feed material that 10 is hot dip coated with zinc or aluminium/zinc alloys to produce roof decking, guttering and other structural steel products. The term "strip" as used in the specification is to be understood to mean a product of 5mm thickness or 15 less. Recent developments in continuous casting techniques have included the casting of steel strip by continuous casting in a twin roll caster. In this technique molten metal is introduced between a pair of 20 contra-rotated horizontal casting rolls which are internally water cooled so that metal shells solidify on the moving rolls surfaces and are brought together at the nip between them to produce a solidified strip product delivered downwardly from the nip between the rolls, the 25 term "nip" being used to refer to the general region at which the rolls are closest together. The molten metal may be poured from a ladle into a smaller vessel from which it flows through a metal delivery nozzle located above the nip so as to direct it into the nip between the rolls, so 30 forming a casting pool of molten metal supported on the casting surfaces of the rolls immediately above the nip and extending along the length of the nip. This casting pool is usually confined between side plates or dams held in sliding engagement with end surfaces of the rolls so as to 35 dam the two ends of the casting pool against outflow, although alternative means such as electromagnetic barriers have also been proposed. The casting of steel strip in WO00/42228 PCT/AU00/00010 - 2 twin roll casters of this kind is for example described in United States Patents 5,184,668, 5,277,243 and 5,934,359. We have determined that it is possible by continuous strip casting to produce strip which is highly 5 susceptible to work hardening by cold rolling, ie. the ultimate tensile strength of the strip can be dramatically increased by moderate cold rolling. It has been further found that this work hardening effect is particularly pronounced in the case of silicon/manganese killed plain 10 carbon steel, and increases with increasing manganese and silicon contents in the steel chemistry. Silicon/manganese killed steels are particularly suited to twin roll strip casting since aluminium killed or partially killed steels cannot be cast satisfactorily due to formation of solid 15 inclusions which agglomerate and clog the fine flow passages in the metal delivery system of the caster to produce effects and discontinuities in the resulting strip product. A silicon/manganese killed steel will generally have a manganese content of not less than 0.20% (typically 20 about 0.6%) by weight and a silicon content of not less than 0.10% (typically about 0.3%) by weight. By an extensive test program we have determined that it is possible by cold rolling continuously cast plain carbon steel strip to produce a strip with an ultimate 25 tensile strength of at least 680 MPa and an elongation-to break in the range 8% to 12% which is an excellent balance of properties for use in many structural steel products such as roof decking and guttering. So far as the applicants are aware, prior to the 30 subject invention, it has not been possible to produce hot dip coated steel strip having this combination of properties from plain carbon steel and, as a consequence, it has been necessary to produce the steel strip from more expensive grades of steel, such as low alloy steels which 35 include specific additions of strengthening elements. One known type of plain carbon steel strip that is used as a feed material for hot dip coating with WO00/42228 PCT/AUOO/00010 - 3 aluminium/zinc alloys is produced by BHP Steel (JLA) Pty Ltd (one of the applicants herein) under the code name G550. G550 steel strip is produced by casting plain carbon steel slabs, hot rolling the slabs to form strip and 5 thereafter coiling the strip, uncoiling and thereafter cold rolling the strip to a final product size of 0.25-2 mm, and heat treating the cold rolled strip to produce the final product. G550 steel strip has a guaranteed minimum ultimate tensile strength of 550 MPa and in a number of 10 instances has ultimate tensile strengths above 700 MPa. For example, one commercially available G550 steel strip (Zincalume G550 coated steel) that is produced from plain carbon steel and is used for roof decking has an ultimate tensile strength of 680-780 MPa (based on a test sample of 15 0.42 mm thickness and an original gauge length of 80 mm). However, this G550 steel strip only has an elongation-to break of 1-6%. The present invention enables production of a plain carbon steel strip of comparable tensile strength but an even better elongation-to-break. 20 DISCLOSURE OF THE INVENTION According to the present invention there is provided a method of producing steel strip, comprising continuously casting plain carbon steel into a strip of no 25 more than 5mm thickness, coiling the strip, uncoiling the strip, cold rolling the uncoiled strip; and annealing the cold rolled strip to produce a 30 stress relieved microstructure therein; wherein the cold rolling produces a cold reduction in a range which is sufficient to increase the tensile strength of the strip to at least 680 MPa but such that the total elongation to break of the strip after said 35 annealing is in the range 8% to 12%. The tensile strength of the strip may be at least 700MPa.

WO00/42228 PCT/AUOO/00010 -4 The continuous strip casting step may be carried out by means of a twin roll strip caster. The term "plain carbon steel" is understood to mean steel of the following composition, in weight percent: 5 C: 0.02-0.08; Si: 0.5 or less; Mn: 1.0 or less; residual/incidental impurities: 1.0 or less; and 10 Fe: balance. The term "residual/incidental impurities" covers levels of elements, such as copper, tin, zinc, nickel, chromium, and molybdenum, that may be present in relatively 15 small amounts, not as a consequence of specific additions of these elements but as a consequence of standard steel making. By way of example, the elements may be present as a result of using scrap steel to produce plain carbon steel. 20 The term "residual/incidental impurities" excludes: (a) amounts of the elements silicon and manganese outside the ranges given with 25 definition of "plain carbon steel"; and (b) amounts of elements, such as the elements listed in the preceding paragraph that are specifically added to the steel for the purpose 30 of strengthening the steel. The plain carbon steel may be silicon/manganese killed and may have the following composition by weight: Carbon 0.02 - 0.08% Manganese 0.30 - 0.80% 35 Silicon 0.10 - 0.40% Sulphur 0.005 - 0.05% Aluminium less than 0.01% WO00/42228 PCT/AUOO/00010 A typical composition is as follows: Carbon 0.06% Manganese 0.66% 5 Silicon 0.32% Sulphur 0.01% Total oxygen content 60 ppm @ 1600 0 C. Preferably, the cold rolling produces a cold 10 reduction of the strip thickness in the range 40% to 80%. Preferably further, said annealing produces the stress relieved microstructure with no more than 10% recrystallisation and an elongation-to-break of at least 10%. 15 The annealing temperature is preferably at least 450 0 C. More particularly, it is preferred that the annealing temperature be in the range 500 0 C to 600 0 C. Optionally, the continuously cast strip may be in-line hot rolled to reduce the thickness of the strip 20 prior to coiling. Preferably, the hot rolling produces a thickness reduction of no more than 40%. In cases where the strip is hot rolled, it is preferred that the subsequent cold rolling produces a cold reduction of the strip in the range 40% to 60%. 25 The invention further provides a plain carbon steel strip having an ultimate tensile strength of at least 700 MPa and an elongation to break in the range of 8% to 12%. 30 BRIEF DESCRIPTION OF THE DRAWINGS In order that the invention may be more fully explained, some examples will be described with reference to the accompanying drawings, in which: Figure 1 illustrates a strip casting installation 35 incorporating an in-line hot rolling mill and coiler; Figure 2 illustrates details of the twin roll strip caster; WO00/42228 PCT/AU00/00010 -6 Figure 3 illustrates an uncoiling and cold rolling installation; Figures 4 to 13 provide test data obtained from a series of experiments in which plain carbon steel strips 5 cast in a twin roll caster were subjected to cold roll reduction, and in some cases to initial in-line hot rolling, and were subsequently annealed at various annealing temperatures. 10 DETAILED DESCRIPTION OF THE PREFFERED EMBODIMENT Figures 1 and 3 illustrates successive parts of a production line whereby steel strip can be produced in accordance with the present invention. Figures 1 and 2 illustrates a twin roll caster denoted generally as 11 15 which produces a cast steel strip 12 that passes in a transit path 10 across a guide table 13 to a pinch roll stand 14 comprising pinch rolls 14A. Immediately after exiting the pinch roll stand 14, the strip passes into a hot rolling mill 16 comprising a pair of reduction rolls 20 16A and backing rolls 16B by in which it is hot rolled to reduce its thickness. The rolled strip passes onto a run out table 17 on which it may be force cooled by water jets 18 and through a pinch roll stand 20 comprising a pair of pinch rolls 20A, and thence to a coiler 19. 25 As shown in Figure 2, twin roll caster 11 comprises a main machine frame 21 which supports a pair of parallel casting rolls 22 having casting surfaces 22A. Molten metal is supplied during a casting operation from a ladle (not shown) to a tundish 23, through a refractory 30 shroud 24 to a distributor 25 and thence through a metal delivery nozzle 26 into the nip 27 between the casting rolls 22. Molten metal thus delivered to the nip 27 forms a pool 30 above the nip and this pool is confined at the ends of the rolls by a pair of side closure dams or plates 35 28 which are applied to the ends of the rolls by a pair of thrusters (not shown) comprising hydraulic cylinder units connected to the side plate holders. The upper surface of WO00/42228 PCT/AUOO/00010 - 7 pool 30 (generally referred to as the "meniscus" levAl) may rise above the lower end of the delivery nozzle so that the lower end of the delivery nozzle is immersed within this pool. 5 Casting rolls 22 are water cooled so that shells solidify on the moving roll surfaces and are brought together at the nip 27 between them to produce the solidified strip 12 which is delivered downwardly from the nip between the rolls. 10 The twin roll caster may be of the kind which is illustrated and described in some detail in United States Patents 5,184,668 and 5,277,243 or United States Patent 5,488,988 and reference may be made to those patents for appropriate constructional details which form no part of 15 the present invention. Figure 3 illustrates an uncoiler 31 by which a coil produced on the apparatus may be uncoiled. The uncoiled strip 12 is passed through a pinch roll stand 32 to a cold rolling mill 33 comprising reduction rolls 33A 20 and backing rolls 33B and thence through an annealing enclosure 34. The process of microstructure evolution in strip casting is fundamentally different from that in conventional hot strip mills. Hot strip mill products 25 undergo large reduction which breaks up the original slab microstructure through enhanced recrystallisation kinetics resulting in significant refinement of austenite grains (approximately 20 microns), which upon transformation produce a fine equiaxed ferrite grain structure 30 (approximately 10 microns - this is a completely polygonal microstructure). The austenite grain size (typically 150 250 microns in width and 500 microns in length) in cast strip is entirely governed by the casting process and such coarse austenite grains when transformed result in a mixed 35 microstructure consisting of coarse polygonal ferrite grains (typically 10-50/50-250 microns width/length and 30 60% in volume fraction for standard cooling/coiling WO00/42228 PCT/AU00/00010 -8 conditions) and relatively fine Widmanstatten/acicular ferrite. Scope for grain refinement is limited, primarily because the coarse austenite grains are inherently resistant to recrystallisation and also due to the fact 5 that only a single hot rolling pass is available under normal strip casting plant layout. However, considerable amount of grain refinement is observed when the amount of hot reduction is greater than 30%, resulting in polygonal ferrite content of greater than 80% with grains in the 10 range of 10-50 microns. For the typical strip cast and strip cast/hot rolled microstructure occurring in silicon/manganese killed steels, we have observed enhanced work hardening by cold rolling. For example, 40% cold reduction is sufficient to 15 increase the cold rolled tensile strength from about 420 MPa to greater than 750 MPa, resulting in a recovery annealed tensile strength of around 700 MPa. Because of this, products with tensile strength of 680 MPa and above can be obtained for a range of cold reductions, from 40% to 20 as high as 80%; 40-60% are generally preferred because the elongation tends to suffer at high cold reductions. The run-out-table cooling/coiling conditions determine the initial as-cast microstructure. The microstructure described previously is obtained under 25 typical operating conditions; cooling rate of 10-20 0 C/s and coiling temperature of 600-700 0 C. These conditions usually result in total elongation values of 20-30% and such initial properties are ideal to produce strip with the necessary balance of tensile strength and elongation. For 30 fast cooling and low coiling conditions (500 0 C coiling temperature for example), the initial elongation can be as low as 15% and this will reduce the cold rolling range to produce the required elongation value in the final product. These considerations are demonstrated by the following 35 experimental results. A first series of experiments was carried out on samples of 2.17 mm thickness as-cast plain carbon steel WO00/42228 PCT/AUOO/00010 - 9 strip cast at a casting speed of 34m/min. The steel was a silicon/manganese killed steel with a carbon content of 0.06% (by weight), a manganese content of 0.6%, a silicon content of 0.3% and a sulphur content of 0.01%. 5 The samples were divided into groups and were cold rolled to produce thickness reductions of 20%, 40%, 60%, 80% and 90%. A set of the samples from each group was then heat treated in a fluidised bed furnace for 60 seconds at 500 0 C. A further set of the samples from each group was 10 heat treated for 60 seconds at 550oC in the furnace. Finally, a third set of the samples from each group was heat treated for 60 seconds at 600 0 C in the furnace. The cold rolled and annealed sets of samples and a fourth set of the cold rolled samples were then tested in a tensile 15 testing machine to determine the ultimate tensile strengths and elongations-to-break of the samples. The tensile tests were carried out according to Australian Standard 1391 (AS1391). The test samples had a gauge length of 12 mm and a parallel length of 22 mm. 20 Figure 4 is a graph of ultimate tensile strength and elongation-to-break versus cold reduction for the samples. A second series of experiments was carried out on samples of 2.17 mm thickness as-cast plain carbon steel 25 strip that were hot rolled at 865 0 C to produce a thickness reduction of 36%. Samples from the hot rolled coil were then cold rolled and annealed as per the first series of experiments. Figure 5 is a graph of ultimate tensile strength 30 and elongation-to-break versus cold reduction for the samples. It can be seen from Figures 4 and 5 that by the method of the present invention it is possible to produce final products having ultimate tensile strengths of at 35 least 680 MPa and an elongations-to-break of at least 10%. By way of example, it can be seen from Figure 4 that as-cast plain carbon steel strip that was cold rolled WO00/42228 PCT/AUOO/00010 - 10 to a thickness reduction of 60% and then heat treated at 550 0 C for 60 seconds had a ultimate tensile strength of approximately 720 MPa and an elongation-to-break of 15%. By way of further example, it can be seen from 5 Figure 4 that as-cast plain carbon steel strip that was cold rolled to a thickness reduction of 60% and then heat treated at 500 0 C for 60 seconds had a ultimate tensile strength of approximately 740 MPa and an elongation-to break of approximately 12%. 10 Figures 4 and 5 demonstrate a significant drop in elongation occurring at 80% cold reduction for strip which is cold rolled in the as cast condition and at 60% cold reduction for the hot rolled strip. This indicates that when the strip is initially hot rolled, this will reduce 15 the maximum allowable cold reduction with the minimum elongation-to-break of 8% is to be maintained. Figures 6 and 7 provide the same experimental data as previously presented in Figures 4 and 5 with some additional data obtained with 50mm gauge samples. This 20 shows that ultimate tensile strength values of at least 680 MPA and elongation-to-break of at least 10% are also measured for 50mm gauge samples. Figures 8 and 9 show the increased recovery effects on total elongation with increased annealing 25 temperatures in the range from 500 0 C to 600 0 C. Figure 8 is derived from data initially presented in Figure 4 and plots the ratio of increased elongation on annealing for differing percentages of cold reduction and that annealing temperatures of 500 0 C, 550 0 C and 600'C. 30 Figure 9 plots equivalent values obtained from the initially hot rolled strips as initially plotted in Figure 5. No recrystallisation was observed except in the case of the samples subjected to 80% and 90% cold reduction 35 and 600 0 C annealing temperature. Even in these cases there was less than 10% re-crystallisation. The data plotted on Figures 8 and 9 indicates that the maximum elongation WO00/42228 PCT/AUOO/00010 - 11 recovery effect is achieved at 80% cold reduction on as cast strip and at around 60% cold reduction on initially hot rolled strip. Figures 10 and 11 plot data obtained from a 5 series of experiments carried out with plain carbon steel strip samples produced at different casting speeds resulting in different initial microstructure and different initial elongation properties in the as cast strip. The steel was a silicon/manganese killed steel of essentially 10 the same composition as for the previous experiments which produced the data of Figures 4 to 9. Figure 10 plots tensile strength values obtained on 50mm gauge samples of 2.07mm strip which was cast at a casting speed of 37 m/min and had an initial elongation-to 15 break of around almost 30% in the as cast condition, the strip then being subjected to cold reductions of 20%, 40%, 60%, 80% and 90% and subsequent annealing at temperatures of 500 0 C, 550 0 C and 600 0 C. Figure 11 plots comparable results obtained from 20 50mm gauge samples of a cast strip cast at a casting speed of 100 m/min and having an initial thickness of 1.30mm and an initial total elongation-to-break of around 20% in the as cast condition. The data plotted in Figures 10 and 11 shows that with a high elongation starting material it is 25 possible to achieve tensile strengths of 700 MPa and elongation-to-break values in the range 8% to 12% with up to 80% cold reduction. However, with a low elongation starting material (about 20% elongation), it is necessary to limit the cold reduction to a maximum of 60%. It is 30 possible to promote high elongation in the as cast material by increasing the temperature at which the strip is coiled. For this reason it is preferred that the coiling temperature be in excess of 650 0 C. More particularly, coiling temperatures of at least 700 0 C are preferred. 35 Figures 12 and 13 provide data obtained from experiments on strip produced by twin roll casting from a silicon/manganese killed plain carbon steel with high WO00/42228 PCT/AU0O/00010 - 12 residuals, specifically a steel having the maximum residuals of 0.2 Cr, 0.2 Ni, 0.2 Mo, 0.2 Sn and 0.5 Cu. The strip was cast at a casting speed of 55 m/min and was in-line hot rolled to a 25% reduction at 1050 0 C. Various 5 samples from the hot rolled coil were then cold rolled to 20%, 40%, 60% and 80% reduction and annealed at various annealing temperatures from 500 0 C to 800 0 C. Figure 12 shows the evolution of measured tensile strength of the samples during annealing and Figure 13 shows the evolution 10 of total elongation during annealing. This data shows tensile strength values of 700 to 850 MPa and elongation values in the range 8% to 12% (on a 50mm gauge) for a range of cold rolling reductions of 20% to 60% at annealing temperatures of 600 0 C to 660 0 C. Residuals severely 15 retarded the onset of recrystallisation thereby allowing high annealing temperatures of 600'C to 660 0 C to be employed without any observable recrystallisation during annealing. These results show residuals can be extremely beneficial and can produce an extended range of properties. 20 Moreover, the inclusion of high residuals can offset reduced work hardening with lower manganese and silicon contents and may even permit the required balance of tensile strength and elongation values to be achieved with aluminium killed plain carbon steel.

Claims (18)

1. A method of producing steel strip, comprising continuously casting plain carbon steel into a strip of no more than 5mm thickness, 5 coiling the strip, uncoiling the strip, cold rolling the uncoiled strip; and annealing the cold rolled strip to produce a stress relieved microstructure therein; 10 wherein the cold rolling produces a cold reduction in a range which is sufficient to increase the tensile strength of the strip to at least 680 MPa but such that the total elongation to break of the strip after said annealing is in the range 8% to 12%. 15

2. A method as claimed in claim 1, wherein the tensile strength of the strip is increased to at least 700 MPa.

3. A method as claimed in claim 1 or claim 2, wherein the cold rolling produces a cold reduction of the 20 strip thickness in the range 40% to 80%.

4. A method as claimed in any one of claims 1 to 3, wherein said annealing produces a stress relieved microstructure with no more than 10% re-crystallisation and an elongation to break of at least 10%. 25

5. A method as claimed in claim 4, wherein the annealing temperature is in the range 500 0 C to 600 0 C.

6. A method as claimed in any one of the preceding claims, wherein the continuously cast strip is in-line hot rolled prior to coiling. 30

7. A method as claimed in claim 6, wherein the hot rolling produces a strip thickness reduction of no more than 40%.

8. A method as claimed in claim 6 or claim 7, wherein the cold rolling step produces a strip thickness 35 reduction in the range 40% to 60%.

9. A method as claimed in any one of the preceding claims, wherein the strip is continuously cast to a WO00/42228 PCT/AUOO/00010 - 14 thickness of no greater than 2mm prior to any rolling.

10. A method as claimed in claim 9, wherein the strip is continuously cast to a thickness of no greater than 1.5mm prior to any rolling and is reduced to a thickness in 5 the range 0.4mm to 1mm by said cold rolling and/or hot rolling.

11. A method as claimed in any one of the preceding claims wherein the plain carbon steel is a silicon/manganese killed steel having the following 10 composition by weight: Carbon 0.02 - 0.08% Manganese 0.30 - 0.80% Silicon 0.10 - 0.40% Sulphur 0.005 - 0.05% 15 Aluminium less than 0.01%

12. A method as claimed in claim 11, wherein the steel has a manganese content of about 0.6% and a silicon content of about 0.3% by weight.

13. A plain carbon steel strip having a ultimate 20 tensile strength of at least 680 MPa and an elongation to break in the range 8% to 12%.

14. A plain carbon steel strip as claimed in claim 13, having a tensile strength of at least 700 MPa.

15. A plain carbon steel strip as claimed in claim 13 25 or claim 14 having a thickness in the range 0.2mm to 1.0mm.

16. A plain carbon steel strip as claimed in any one of claims 13 to 15 and having an elongation to break of at least 10%.

17. A plain carbon steel strip as claimed in any one 30 of claims 13 to 16, wherein the plain carbon steel is a silicon/manganese killed steel having the following composition by weight: Carbon 0.02 - 0.08% Manganese 0.30 - 0.80% 35 Silicon 0.10 - 0.40% Sulphur 0.005 - 0.05% Aluminium less than 0.01% WO00/42228 PCT/AU00/00010 - 15

18. A plain carbon steel strip as claimed in claim 17, wherein the steel has a manganese content of about 0.6% and a silicon content of about 0.3% by weight.