AU2019100825A4

AU2019100825A4 - Flotation cell

Info

Publication number: AU2019100825A4
Application number: AU2019100825A
Authority: AU
Inventors: Peter Bourke; Aleksi Peltola; Antti Rinne; Steve Schmidt; Jere Tuominen; Valtteri VAARNA
Original assignee: Outotec Finland Oy
Current assignee: Outotec Finland Oy
Priority date: 2018-08-01
Filing date: 2019-07-29
Publication date: 2019-08-29
Anticipated expiration: 2027-07-29
Also published as: WO2020025853A1; CN210965531U; EP3829773A1; MX2021001128A; EP3829773A4; CN110787916A; AU2018434575A1; CN110787916B; PE20210791A1; ZA202101401B; PE20191428Z; CL2019002141U1

Abstract

A flotation cell (1) is disclosed for treating particles suspended in slurry and for separating the slurry into an underflow (400) and an overflow (500). The flotation cell comprises a flotation tank (10) with a centre (11), a perimeter (12), a substantially horizontal level bottom (13), and a side wall (14); a launder (2) and a launder lip (21) surrounding the perimeter (12) of the tank (11) ; and a bottom structure (7) arranged on the bottom (13), and having a shape that allows particles suspended in slurry to be mixed in a mixing zone (A) over the bottom structure, and to settle down in a settling zone (B) surrounding the bottom structure. The flotation tank further comprises blast tubes (4) for introducing flurry infeed (100) into the tank. (Fig. 2) Fig. 2

Description

FLOTATION CELL

TECHNICAL FIELD

The current disclosure relates to a flotation cell for 5 separating valuable material containing particles from particles suspended in slurry.

SUMMARY OF THE INVENTION

The current disclosure provides a flotation cell for 10 treating particles suspended in slurry and for separating the slurry into an underflow and an overflow, the flotation cell comprising a flotation tank comprising a centre, a perimeter, a substantially horizontal level bottom, and a side wall;

a launder and a launder lip surrounding the perimeter of the tank; and a bottom structure arranged on the bottom, and having a shape that allows particles suspended in slurry to be mixed in a mixing zone over the bottom structure, and to settle down in 20 a settling zone surrounding the bottom structure, wherein the flotation tank further comprises blast tubes for introducing flurry infeed into the tank, a blast tube comprising an inlet nozzle for feeding slurry infeed into the blast 25 tube;

an inlet for pressurized gas, the slurry infeed subjected to the pressurized gas as it is discharged from the inlet nozzle;

an elongated chamber arranged to receive under pressure 30 the slurry infeed;

an outlet nozzle configured to restrict flow of slurry infeed from the outlet nozzle, and to maintain slurry infeed in the elongated chamber under pressure; and in that the blast tubes are disposed at a position relative to the bottom structure so 35 as to induce mixing at the mixing zone.

A flotation cell is provided for treating particles suspended in slurry and for separating the slurry into an

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2019100825 29 Jul 2019 underflow and an overflow. The flotation cell comprises a flotation tank comprising a centre, a perimeter, a substantially horizontal, level bottom, and a side wall; a launder and a launder lip surrounding the perimeter of the tank; and a bottom 5 structure arranged on the bottom and having a shape that allows particles suspended in slurry to be mixed in a mixing zone over the bottom structure, and to settle down in a settling zone surrounding the bottom structure. The flotation cell is characterized in that the flotation tank further comprises blast 10 tubes for introducing slurry infeed into the flotation tank. A blast tube comprises an inlet nozzle for feeding slurry infeed into the blast tube; an inlet for pressurized gas, the slurry infeed subjected to the pressurized gas as it is discharged from the inlet nozzle; an elongated chamber arranged to receive under 15 pressure the slurry infeed; and an outlet nozzle configured to restrict flow of slurry infeed from the outlet nozzle, and to maintain slurry infeed in the elongated chamber under pressure; and in that the blast tubes are disposed at a position relative to the bottom structure so as to induce mixing at the mixing 20 zone.

With the invention described herein, the recovery of fine particles in a flotation process may be improved. The particles may, for example, comprise mineral ore particles such as particles comprising a metal.

In froth flotation for mineral ore, upgrading the concentrate is directed to an intermediate particle size range between 40 pm to 150 pm. Fine particles are thus particles with a diameter of 0 to 40 pm, and ultrafine particles can be identified as falling in the lower end of the fine particle size 30 range. Coarse particles have a diameter greater than 150 pm. In froth flotation of coal, upgrading the concentrate is directed to an intermediate particle size range between 40 pm to 300 pm.

Fine particles in coal treatment are particles with a diameter of 0 to 40 pm, and ultrafine particles those that fall into the 35 lower end of the fine particle size range. Coarse coal particles have a diameter greater than 300 pm.

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2019100825 29 Jul 2019

Recovering very coarse or very fine particles is challenging, as in a traditional mechanical flotation cell, fine particles are not easily entrapped by flotation gas bubbles and may therefore become lost in the tailings. Typically in froth 5 flotation, flotation gas is introduced into a flotation cell or tank via a mechanical agitator. The thus generated flotation gas bubbles have a relatively large size range, typically from 0,8 to 2,0 mm, or even larger, and are not particularly suitable for collecting particles having a finer particle size.

Fine particle recovery may be improved by increasing the number of flotation cells within a flotation line, or by recirculating the once-floated material (overflow) or the tailings flow (underflow) back into the beginning of the flotation line, or to precedent flotation cells. A cleaner 15 flotation line may be used in order to improve recovery of fine particles. In addition, a number of flotation arrangements employing fine flotation gas bubbles or even so-called microbubbles have been devised. Introduction of these smaller bubbles or microbubbles may be done prior to feeding the slurry 20 into the flotation cell, i.e. the ore particles are subjected to fine bubbles in a feed connection or the like to promote formation of ore particle-fine bubble agglomerates, which may then be floated in flotation cells such as flash flotation cells or column cells. Alternatively, fine bubbles or microbubbles may 25 be introduced directly into the flotation cell, for example by spargers utilising cavitation. These kinds of solutions are not necessary feasible in connection with mechanical flotation cells, as the turbulence caused by mechanical agitation may cause the ore particle-fine bubble agglomerates to disintegrate before 30 they are able to rise into the froth layer to be collected into overflow and thus recovered.

Column flotation cells act as three phase settlers where particles move downwards in a hindered settling environment counter-current to a flow of rising flotation gas bubbles 35 generated by spargers located near the bottom of the cell. While column flotation cells may improve the recovery of finer particles, the particle residence time is dependent on settling

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2019100825 29 Jul 2019 velocity, which may impact on the flotation of large particles. In other words, while the aforementioned flotation solutions may have a beneficial effect for recovery of fine particles, the overall flotation performance (recovery of all valuable 5 material, grade of recovered material) may be undermined by the negative effect on recovery of larger particles.

To overcome the above problems, so-called pneumatic flotation cells are used, where flotation gas is introduced in a high-shear device such as a downcomer with slurry infeed, 10 thereby creating finer flotation gas bubbles that are able entrap also finer particles already during the bubble formation in the blast tube. However, such high-throughput flotation cells may require a vacuum to be created in the downcomer to effectively achieve the required bubble formation rate to entrap the desired 15 particles in the short time slurry infeed resides in the blast tube .

Once having exited the downcomer, the flotation gas bubble-particle agglomerates rise immediately towards the froth layer on the top part of the flotation cell, and no further 20 entrapment of particles take place in the part of the flotation cell downwards from the blast tube outlet. This may lead to significant part of particles comprising a desired material (mineral) to simply drop to the bottom of the flotation tank and ending up in tailings, which reduces the recovery rate of the 25 flotation cell.

However, typically the so-called high-throughput flotation cells or pneumatic flotation cells of the Jameson cell type do not include any flow restriction for controlling the pressure within the downcomer after the formation of flotation 30 air bubble-particle agglomerates has taken place. Such control of pressure is advantageous also in view of the pressure at which flotation gas bubbles are formed (effect on bubble size), but also for the adjustment of relative pressure at which they are to be used in the flotation tank. In that way, the coalescence 35 of bubbles may be minimized after their formation. This is especially advantageous, as the rate of entrapment of particles

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2019100825 29 Jul 2019 by flotation gas bubbles decreases as the bubble size increases (provided that the air to liquid ratio remains the same).

In addition, the so-called high-throughput flotation cells may be used in coal liberation operations, where there typically is a flotation line comprising one or two such flotation cells at the end of the liberation circuit for the recovery of especially fine coal particles. In the liberation circuit, a process water recirculation system circulating water from the end part of the circuit (i.e. from the flotation line 10 and a dewatering circuit) back to the front circuit (beginning of the liberation circuit). Flotation chemicals, especially frothers, typically cause problems in the processes preceding the flotation line. The problems may be alleviated to some extent by minimizing the use of frothers in the flotation line, but if 15 not enough frother is added into the flotation process, the froth formation in blast tubes according to state of the art may suffer, which leads to unstable process conditions and especially unstable downcomer operation and froth layer in a flotation cell, which in turn affects the recovery of desired 20 particles negatively. Recovery of particles within the entire particle size distribution of a slurry is affected as bubble size increases with lower frother dosage, in particular that of coarse particles .

In prior art downcomers, flotation gas is introduce in 25 a self-aspirating manner due to the formation of a vacuum within the downcomer. There is a very short residence time of flotation air to be entrained into the slurry, so the system is very sensitive to process variations. Frothers need to be constantly added to overcome the effect of restriction to air flowrate 30 needed to maintain or even increase the vacuum inside the downcomer to keep the conditions as constant as possible for bubble-particle engagement, as frothers prevent bubbles from coalescing and rising back into the airspace not filled by slurry inside the downcomer. However, adding an amount of frothers 35 required by the steady utilization of a prior art downcomer creates problems in other parts of the process, particularly in coal operations, as described above. Therefore the solution has

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2019100825 29 Jul 2019 been to decrease the frother dosage, which affects the downcomer vacuum, bubble formation, as well as bubble size and surface area negatively, and decreases recovery of desired particles significantly, making the high-throughput flotation cells known 5 in the prior art inefficient in that application.

By using a flotation cell according to the present invention, the amount of frother required to optimize the flotation process may be significantly reduced without significantly compromising bubble formation, bubble to particle 10 engagement, stable froth layer formation or the recovery of desired material. At the same time, problems associated with recirculating process water from downstream circuit to front circuit can be alleviated. A blast tube operating under pressure is completely independent of the flotation tank. A better 15 flotation gas flowrate may be reached, and finer bubbles created, and frother usage optimized, as the blast tube operation is not dependent of frother dosage.

In the solutions known from prior art, problems relate especially to limitations to the amount of flotation gas that 20 can be supplied relative to the amount of liquid flowing through the downcomer, and to the need for relatively high concentrations of frothers or other expensive surface-active agents to produce small bubbles. With the invention presented here, flotation of fine and ultrafine particles comprising for example mineral ore 25 or coal may be improved by reducing the size of the flotation gas bubbles introduced to slurry infeed in a blast tube, by increasing the flotation gas supply rate relative to the flow rate of particles suspended in the slurry, and by increasing the shear intensity or energy dissipation rate either in or adjacent 30 to the blast tube. The probability of finer particles attaching to or being entrapped by smaller flotation gas bubbles is increased, and the recovery rate of desired material such as a mineral or coal, improved. In a flotation cell according to the invention, sufficiently small flotation gas bubbles, so-called 35 ultra-fine bubbles, may be created to ensure efficient entrapment of fine ore particles. Typically, ultra-fine bubbles may have a bubble size distribution of 0,05 mm to 0,7 mm. For

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2019100825 29 Jul 2019 example, decreasing the mean flotation gas bubble size to a diameter of 0,3 to 0,4 mm means that the number of bubbles in 1 m³ of slurry may be as high as 30 to 70 million, and the total mean surface area of the bubbles 15 to 20 m² . In contrast, if 5 the mean bubble size is around 1 mm, the number of bubbles in 1 m² of slurry is around 2 million, and the total mean surface area 6m². In the flotation cell according to the invention it may thus be possible to reach 2,5 to 3 times higher bubble surface area than in flotation cells according to prior art 10 solutions. It goes without saying that the effect of such increase in bubble surface area in recovery of valuable material comprising particles is significant.

At the same time, recovery of coarser particles may be kept at an acceptable level by achieving a high flotation gas 15 fraction in the slurry, and by the absence of high turbulence areas in the region below the forth layer. I.e. the known benefits of mechanical flotation cells may be employed, even though there may not necessarily be any mechanical agitation present in the flotation cell. Further, the upwards motion of 20 slurry or pulp within the flotation tank increases the probability of also coarser particles rise towards the froth layer with the flow of slurry.

One of the effects that may be gained with the present invention is the increased depth or thickness of a froth layer.

A thicker froth layer contributes to increased recovery of smaller particles, and a separate froth washing step, typical for column flotation cells, may be discarded.

By disposing a number of blast tube blast tubes into a flotation cell according to the invention, the probability of 30 collisions between flotation gas bubbles, as well as between gas bubbles and particles can be increased. Having a number of blast tubes may ensure an improved distribution of flotation gas bubbles within a flotation tank, and the bubbles exiting the blast tubes are distributed evenly throughout the flotation 35 tank, the distribution areas of individual blast tubes have the possibility of intersecting each other and converging, thus promoting an extensively even flotation gas bubble distribution

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2019100825 29 Jul 2019 into the flotation tank, which in turn may affect the recovery of especially smaller particles beneficially, and also contribute to the aforementioned even and thick froth layer. When there are several blast tubes, collisions between flotation 5 gas bubbles and/or particles in the slurry infeed from different blast tubes are promoted as the different flows intermingle and create local mixing subzones . As the collisions are increased, more bubble-particle agglomerates are created and captured into the froth layer, and therefore recovery of valuable material may 10 be improved.

By generation of fine flotation gas bubble or ultrafine bubbles, by bringing them into contact with the particles, and by controlling the flotation gas bubble- particle agglomerates-liquid mixture of slurry, it may be possible to 15 maximize the recovery of hydrophobic particles into the forth layer and into the flotation cell overflow or concentrate, thus increasing the recovery of desired material irrespective of its particle size distribution within the slurry. It may be possible to achieve a high grade for a part of the slurry stream, and at 20 the same time, high recovery for the entire slurry stream passing through a flotation line.

By disposing the blast tubes at a position relative to the bottom structure slurry mixing can be induced and improved at a mixing zone surrounding the bottom structure. For example, 25 the outlet nozzles of the blast tubes may be disposed at a suitable depth, i.e. disposing them at a specific vertical distance from the launder lip, the distribution of flotation gas bubbles may be optimized in an even and constant manner. As the residence time of bubbles within a mixing zone may be kept high 30 enough by a suitable depth of the blast tube outlet nozzles, the bubbles may be able to contact and adhere to the fine particles in the slurry efficiently, thus improving the recovery of smaller particles, and also promoting froth depth, stability and evenness at the top of the flotation tank.

By a mixing zone is meant herein a vertical part or region of the flotation tank in which active mixing of particles suspended in slurry with flotation gas bubbles takes place. In

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2019100825 29 Jul 2019 addition to this mixing zone created into an entire vertical section of the flotation tank, separate and regional individual mixing subzones may be created at areas where slurry flows directed radially outwards by individual impingers meet and 5 become intermingled. This may further promote contacts between flotation gas bubbles and particles, thereby increasing the recovery of valuable particles. Further, this additional mixing may eliminate the need for a mechanical mixer for suspending solids in the slurry.

By a settling zone is meant a vertical part of region of the flotation tank in which particles not associated with flotation gas bubbles or otherwise not able to rise towards the froth zone on the top part of the flotation tank descend and settle towards the tank bottom to be removed in the tailings as underflow. The settling zone is below the mixing zone.

The flotation cell according to the invention have the technical effect of allowing the flexible recovery of various particle sizes, as well as efficient recovery of valuable mineral containing ore particles from poor ore raw material with 20 relatively low amounts of valuable mineral initially. The advantages provided by the structure of the flotation line allow the accurate adjustment of the flotation line structural parameters according to the target valuable material at each installation .

By treating the slurry according to the present invention as defined by this disclosure, recovery of valuable material containing particles may be increased. The initial grade of recovered material may be lower, but the material (i.e. slurry) is also thus readily prepared for further processing, which may include for example regrinding and/or cleaning.

In this disclosure, the following definitions are used regarding flotation.

Basically, flotation aims at recovering a concentrate of ore particles comprising a valuable mineral. By concentrate 35 herein is meant the part of slurry recovered in overflow or underflow led out of a flotation cell. By valuable mineral is meant any mineral, metal or other material of commercial value.

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2019100825 29 Jul 2019

Flotation involves phenomena related to the relative buoyancy of objects. The term flotation includes all flotation techniques. Flotation can be for example froth flotation, dissolved air flotation (DAF) or induced gas flotation. Froth 5 flotation is a process for separating hydrophobic materials from hydrophilic materials by adding gas, for example air or nitrogen or any other suitable medium, to the process. Froth flotation could be made based on natural hydrophilic/hydrophobic difference or based on hydrophilic/hydrophobic differences made 10 by addition of a surfactant or collector chemical. Gas can be added to the feedstock subject of flotation (slurry or pulp) by a number of different ways.

A flotation cell meant for treating mineral ore particles suspended in slurry by flotation. Thus, valuable 15 metal-containing ore particles are recovered from ore particles suspended in slurry. By flotation line herein is meant a flotation arrangement where a number of flotation cells are arranged in fluid connection with each other so that the underflow of each preceding flotation cell is directed to the 20 following or subsequent flotation cell as a infeed until the last flotation cell of the flotation line, from which the underflow is directed out of the line as tailings or reject flow. Slurry is fed through a feed inlet to the first flotation cell of the flotation line for initiating the flotation process. A 25 flotation line may be a part of a larger flotation plant or arrangement containing one or more flotation lines. Therefore, a number of different pre-treatment and post-treatment devices or stages may be in operational connection with the components of the flotation arrangement, as is known to the person skilled 30 in the art.

The flotation cells in a flotation line are fluidly connected to each other. The fluid connection may be achieved by different lengths of conduits such as pipes or tubes, the length of the conduit depending on the overall physical construction of 35 the flotation arrangement. Alternatively, the flotation cells may be arranged in direct cell connection with each other. By direct cell connection herein is meant an arrangement, whereby

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2019100825 29 Jul 2019 the outer walls of any two subsequent flotation cells are connected to each other to allow an outlet of a first flotation cell to be connected to the inlet of the subsequent flotation cell without any separate conduit. A direct contact reduces the 5 need for piping between two adjacent flotation cells. Thus, it reduces the need for components during construction of the flotation line, speeding up the process. Further, it might reduce sanding and simplify maintenance of the flotation line. The fluid connections between flotation cells may comprise various 10 regulation mechanisms.

By neighbouring, adjacent, or adjoining flotation cell herein is meant the flotation cell immediately following or preceding any one flotation cell, either downstream or upstream, or either in a rougher flotation line, in a scavenger flotation 15 line, or the relationship between a flotation cell of a rougher flotation line and a flotation cell of a scavenger flotation line into which the underflow from the flotation cell of the rougher flotation line is directed.

By a flotation cell is herein meant a tank or vessel in 20 which a step of a flotation process is performed. A flotation cell is typically cylindrical in shape, the shape defined by an outer wall or outer walls. The flotation cells regularly have a circular cross-section. The flotation cells may have a polygonal, such as rectangular, square, triangular, hexagonal or 25 pentagonal, or otherwise radially symmetrical cross-section, as well. The number of flotation cells may vary according to a specific flotation line and/or operation for treating a specific type and/or grade of ore, as is known to a person skilled in the art.

The flotation cell may be a froth flotation cell, such as a mechanically agitated cell, for example a TankCell, a column flotation cell, a Jameson cell, or a dual flotation cell. In a dual flotation cell, the cell comprises at least two separate vessels, a first mechanically agitated pressure vessel with a 35 mixer and a flotation gas input, and a second vessel with a tailings output and an overflow froth discharge, arranged to receive the agitated slurry from the first vessel. The flotation

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2019100825 29 Jul 2019 cell may also be a fluidized bed flotation cell (such as a HydroFloatTM cell), wherein air or other flotation gas bubbles which are dispersed by the fluidization system percolate through the hindered-setting zone and attach to the hydrophobic 5 component altering its density and rendering it sufficiently buoyant to float and be recovered. In a fluidized bed flotation cell axial mixing is not needed. The flotation cell may also be an overflow flotation cell operated with constant slurry overflow. In an overflow flotation cell, the slurry is treated 10 by introducing flotation gas bubbles into the slurry and by creating a continuous upwards flow of slurry in the vertical direction of the first flotation cell. At least part of the valuable metal containing ore particles are adhered to the gas bubbles and rise upwards by buoyancy, at least part of the valuable metal containing ore particles are adhered to the gas bubbles and rise upwards with the continuous upwards flow of slurry, and at least part of the valuable metal containing ore particles rise upwards with the continuous upwards flow of slurry. The valuable metal containing ore particles are 20 recovered by conducting the continuous upwards flow of slurry out of the at least one overflow flotation cell as slurry overflow. As the overflow cell is operated with virtually no froth depth or froth layer, effectively no froth zone is formed on the surface of the pulp at the top part of the flotation cell. 25 The froth may be non-continuous over the cell. The outcome of this is that more valuable mineral containing ore particles may be entrained into the concentrate stream, and the overall recovery of valuable material may be increased.

All of the flotation cells of a flotation line according 30 to the invention may be of a single type, that is, rougher flotation cells in the rougher part, scavenger flotation cells in the scavenger part, and scavenger cleaner flotation cells of the scavenger cleaner flotation line may be of one single flotation cell type so that the flotation arrangement comprises 35 only one type of flotation cells as listed above. Alternatively, a number of flotation cells may be of one type while other cells

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2019100825 29 Jul 2019 are of one or more type so that the flotation line comprises two or more types of flotation cells as listed above.

Depending on its type, the flotation cell may comprise a mixer for agitating the slurry to keep it in suspension. By a 5 mixer is herein meant any suitable means for agitating slurry within the flotation cell. The mixer may be a mechanical agitator. The mechanical agitator may comprise a rotor-stator with a motor and a drive shaft, the rotor-stator construction arranged at the bottom part of the flotation cell. The cell may 10 have auxiliary agitators arranged higher up in the vertical direction of the cell, to ensure a sufficiently strong and continuous upwards flow of the slurry.

A flotation cell may comprise one or more froth crowders. A froth crowder herein is meant a froth blocker, a 15 froth baffle, or a crowding board, or a crowding board device, or any other such structure or side structure, for example a sidewall, inclined or vertical, having a crowding effect, i.e. a crowding sidewall, which can also be a crowding sidewall internal to the flotation tank, i.e. an internal perimeter 20 crowder.

By utilising a froth crowder, it may be possible to direct so-called brittle froth, i.e. a loosely textured froth layer comprising generally larger flotation gas bubbles agglomerated with the mineral ore particles intended for 25 recovery, more efficiently and reliably towards the forth overflow lip and froth collection launder. A brittle froth can be easily broken, as the gas bubble-ore particle agglomerates are less stable and have a reduced tenacity. Such froth or forth layer cannot easily sustain the transportation of ore particles, 30 and especially coarser particles, towards the froth overflow lip for collection into the launder, therefore resulting in particle drop-back to the pulp or slurry within the flotation cell or tank, and reduced recovery of the desired material. Brittle froth is typically associated with low mineralization, i.e. gas 35 bubble-ore particle agglomerates with limited amount of ore particles comprising a desired mineral that have been able to attach onto the gas bubbles during the flotation process within

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2019100825 29 Jul 2019 a flotation cell or tank. The problem is especially pronounced in large-sized flotation cells or tanks with large volume and/or large diameter. With the invention at hand, it may be possible to crowd and direct the froth towards the froth overflow lip, to 5 reduce the froth transportation distance (thereby reducing the risk of drop-back) , and, at the same time, maintain or even reducing the overflow lip length. In other words, the handling and directing of the froth layer in a froth flotation cell or tank may become more efficient and straightforward.

It may also be possible to improve froth recovery and thereby valuable mineral particle recovery in large flotation cells or tanks from brittle froth specifically in the later stages of a flotation line, for example in the rougher and/or scavenger stages of a flotation process.

Further, with the invention described herein, the area of froth on the surface of the slurry inside a flotation tank may be decreased in a robust and simple mechanical manner. At the same time, the overall overflow lip length in a froth flotation unit may be decreased. Robust in this instance is to 20 be taken to mean both structural simplicity and durability. By decreasing the froth surface area of a flotation unit by a froth crowder instead of adding extra froth collection launders, the froth flotation unit as a whole may be a simpler construction, for example because there is no need to lead the collected froth and/or overflow out of the added crowder. In contrast, from an extra launder, the collected overflow would have to be led out, which would increase the constructional parts of the flotation unit.

Especially in the downstream end of a flotation line, 30 the amount of desired material that can be trapped into the froth within the slurry may be very low. In order to collect this material from the froth layer to the froth collection launders, the froth surface area should be decreased. By arranging a froth crowder into the flotation tank, the open froth surface between 35 the forth overflow lips may be controlled. The crowder may be utilised to direct or guide the upwards-flowing slurry within the flotation tank closer to a froth overflow lip of a froth

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2019100825 29 Jul 2019 collection launder, thereby enabling or easing froth formation very close to the froth overflow lip, which may increase the collection of valuable ore particles. The froth crowder may also influence the overall convergence of flotation gas bubbles 5 and/or gas bubble-ore particle agglomerates into the froth layer. For example, if the gas bubbles and/or gas bubble-ore particle agglomerate flow becomes directed towards the centre of a flotation tank, a froth crowder may be utilised to increase the froth area at the perimeter of the tank, and/or closer to 10 any desired froth overflow lip. In addition, it may be possible to reduce the open froth surface in relation to the lip length, thereby improving the efficiency of recovery in the froth flotation cell.

By a blast tube is meant a dual high-shear device in 15 which flotation gas is introduced into slurry infeed, thereby creating finer flotation gas bubbles that are able entrap also finer particles already during the bubble formation in the blast tube. In particular, a blast tube in a flotation cell according to the invention operates under pressure, and not vacuum is 20 needed.

By overflow herein is meant the part of the slurry collected into the launder of the flotation cell and thus leaving the flotation cell. Overflow may comprise froth, froth and slurry, or in certain cases, only or for the largest part slurry.

In some embodiments, overflow may be an accept flow containing the valuable material particles collected from the slurry. In other embodiments, the overflow may be a reject flow. This is the case in when the flotation arrangement, plant and/or method is utilized in reverse flotation.

By underflow herein is meant the fraction or part of the slurry which is not floated into the surface of the slurry in the flotation process. In some embodiments the underflow may be a reject flow leaving a flotation cell via an outlet which typically is arranged in the lower part of the flotation cell.

Eventually the underflow from the final flotation cell of a flotation line or a flotation arrangement may leave the entire arrangement as a tailings flow or final residue of a flotation

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2019100825 29 Jul 2019 plant. In some embodiments, the underflow may be an accept flow containing the valuable mineral particles. This is the case in when the flotation cell or flotation line is utilized in reverse flotation .

By reverse flotation herein is meant an inverse flotation process typically utilized in the recovery of iron. In that case, the flotation process is directed for collecting the non-valuable part of the slurry flow into the overflow. The overflow in reverse flotation process for iron contains 10 typically silicates, while the valuable iron-containing mineral particles are collected in the underflow. Reverse flotation may also be used for industrial minerals, i.e. geological mineral mined for their commercial values which are not fuel, nor sources of metals, such as bentonite, silica, gypsum, and talc.

By downstream herein is meant the direction concurrent with the flow of slurry towards the tailings (forward current, denoted in the figures with arrows), and by upstream herein is meant the direction counter current with or against the flow of slurry.

By concentrate herein is meant the floated part or fraction of slurry of ore particles comprising a valuable mineral. In normal flotation, concentrate is the part of the slurry that is floated into the froth layer and thereby collected into the launders as overflow. A first concentration concentrate 25 may comprise ore particles comprising one valuable mineral, where as a second concentration concentrate may comprise ore particles comprising another valuable mineral. Alternatively, the distinctive definitions first, second, may refer to two concentrations concentrates of ore particles comprising the same valuable mineral but two distinctly different particle size distributions .

By a rougher flotation, rougher part of the flotation line, rougher stage and/or rougher cells herein is meant a flotation stage that produces a concentrate. The objective is to 35 remove a maximum amount of the valuable mineral at as coarse a particle size as practical. The primary objective of a rougher

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2019100825 29 Jul 2019 stage is to recover as much of the valuable minerals as possible, with less emphasis on the quality of the concentrate produced.

The rougher concentrate is normally subjected to further stages of cleaner flotation in a rougher cleaner 5 flotation line to reject more of the undesirable minerals that have also reported to the froth, in a process known as cleaning. The product of cleaning is known as cleaner concentrate or final concentrate .

Rougher flotation is often followed by scavenger 10 flotation that is applied to the rougher tailings. By a scavenger flotation, a scavenger part of the flotation line, scavenger stage and/or a scavenger cell is meant a flotation stage wherein the objective is to recover any of the valuable mineral material that was not recovered during the initial rougher stage. This 15 might be achieved by changing the flotation conditions to make them more rigorous than the initial roughing, or, in some embodiments of the invention, by the introduction of microbubble into the slurry. The concentrate from a scavenger cell or stage could be returned to the rougher feed for re-floating or directed 20 to a regrinding step and thereafter to a scavenger cleaner flotation line.

By cleaner flotation, a rougher/scavenger cleaner line, cleaner/cleaning stage and/or a cleaner cell is meant a flotation stage wherein the objective of cleaning is to produce as high a concentrate

By processing separation, conditioning grade as possible, pre-treatment and/or post-treatment and/or further is meant for screening, or cleaning, known to a person example comminution, grinding, classification, fractioning, all of which are conventional processes as processing may include also at further flotation cell, which skilled in the art. A further least one of the following: a may be a conventional cleaner flotation cell, a recovery cell, a rougher cell, or a scavenger cell.

By slurry surface level herein is meant the height of the slurry surface within the flotation cell as measured from the bottom of the flotation cell to the launder lip of the

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2019100825 29 Jul 2019 flotation cell. In effect, the height of the slurry is equal to the height of a launder lip of a flotation cell as measured from the bottom of the flotation cell to the launder lip of the flotation cell. For example, any two subsequent flotation cells 5 may be arranged in a stepwise fashion in a flotation line so that the slurry surface level of such flotation cells is different (i.e. the slurry surface level of the first of such flotation cells is higher than the slurry surface level of the second of such flotation cells). This difference in the slurry 10 surface levels is defined herein as step between any two subsequent flotation cells. The step or the difference in slurry surface levels is a difference allowing the flow of slurry be driven by gravity or gravitation force, by creating a hydraulic head be-tween the two subsequent flotation cells.

By a flotation line herein is meant an assembly or arrangement comprising a number of flotation units or flotation cells in which a flotation stage is performed, and which are arranged in fluid connection with each other for allowing either gravity-driven or pumped slurry flow between flotation cells, to 20 form a flotation line. In a flotation line, a number of flotation cells are arranged in fluid connection with each other so that the underflow of each preceding flotation cell is directed to the following or subsequent flotation cell as a infeed until the last flotation cell of the flotation line, from which the 25 underflow is directed out of the line as tailings or reject flow.

It is also conceivable that a flotation line may comprise only one flotation stage performed either in one flotation cell or for example in two or more parallel flotation cells.

Slurry is fed through a feed inlet to the first 30 flotation cell of the flotation line for initiating the flotation process. Flotation line may be a part of a larger treatment plant containing one or more flotation lines, and a number of other process stages for the liberation, cleaning and other treatment of a desired material. Therefore, a number of different pre35 treatment and post-treatment devices or arrangements may be in operational connection with the components of the flotation line, as is known to the person skilled in the art.

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By ultra-fine bubbles herein is meant flotation gas bubbles falling into a size range of 0,05 mm to 0,7 mm, introduced into the slurry in a blast tube. In contrast, normal flotation gas bubbles utilized in froth flotation display a size 5 range of approximately 0,8 to 2 mm. Larger flotation gas bubbles may have a tendency to coalesce into even larger bubbles during their residence in the mixing zone where collisions between particles and flotation gas bubbles, as well as only between flotation gas bubbles take place. As ultra-fine bubbles are 10 introduced into slurry infeed prior to its feeding into a flotation tank, such coalescence is not likely to happen with ultra-fine bubbles, and their size may remain smaller throughout their residence in the flotation cell, thereby affecting the ability of the ultra-fine bubbles to catch fine particles.

In an embodiment of the flotation cell according to the invention, the outlet nozzle is configured to produce a supersonic shockwave into the slurry infeed, the supersonic shockwave inducing formation of flotation gas bubble - particle agglomerates .

A supersonic shockwave is created when the velocity of slurry infeed passing through the outlet nozzle exceeds the speed of sound, i.e. the flow of slurry infeed becomes choked when the ratio of the absolute pressure upstream the outlet nozzle to the absolute pressure downstream of the throttle of the outlet nozzle 25 exceeds a critical value. When the pressure ratio is above the critical value, flow of slurry infeed downstream of the throttle part of the outlet nozzle becomes supersonic and a shock wave is formed. Small flotation gas bubbles in slurry infeed mixture are split into even smaller by being forced through the shock wave, 30 and forced into contact with hydrophobic ore particles in slurry infeed, thus creating flotation gas bubble-ore particle agglomerates. The supersonic shockwave produced into the slurry infeed at the outlet nozzle discharge carries into the slurry within the flotation tank immediately adjacent to an outlet 35 nozzle, thereby promoting the formation of flotation gas bubbles also in the slurry outside the outlet nozzles. After exiting the outlet nozzle, fine ore particles may contact the small flotation

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2019100825 29 Jul 2019 gas bubbles a second time, as there are several of such blast tubes/outlet nozzles discharging into a common mixing area in which the probability of secondary contacts between bubbles and particles is increased by the intermixing flows of slurry exiting 5 the blast tubes .

In an embodiment of the flotation cell, a height of the flotation tank, measured as the distance from the bottom to the launder lip, is at the perimeter of the flotation tank at most 20 % lower than at the centre of the flotation tank.

In an embodiment of the flotation cell, the vertical cross-section of the bottom structure is a functional triangle comprising a first vertex pointing away from the bottom of the flotation tank, a second vertex and a third vertex; a first side between the first vertex and the second vertex; a second side between the first vertex and the third vertex; and a base between the second and third vertexes on the bottom of the flotation tank; and a central axis substantially concentric with the centre of the flotation tank.

In a further embodiment of the flotation cell, the base 20 angle between the first side and the base, or second side and the base in relation to the bottom of the flotation tank is 20 to 60°.

In a further embodiment of the flotation cell, the included angle between the first side and the second side is 20 to 100°, preferably 20 to 80°.

In a further embodiment of the flotation cell, the bottom structure comprises a base on the bottom of the flotation tank and defined by the base of the functional triangle, and a mantle defined at least by the first, second and third vertexes 30 of the functional triangle.

In a yet further embodiment of the flotation cell, the mantle is at least partly defined by the first and second sides of the functional triangle.

In an embodiment of the flotation cell, a height of the bottom structure is greater than 1/5 and less than 3/4 of a height of the flotation tank (10), measured as the distance from the bottom to the launder lip.

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By arranging a bottom structure at the bottom of a flotation tank, the bottom structure extending upwards in the flotation tank, it may be possible to obtain better distribution of fine and/or small particles suspended in slurry. At the centre 5 of the flotation tank, particles cannot descend and settle, as the flow of slurry infeed from the blast tubes may reach the raised centre part of the flotation tank, which ensures good mixing at that part. Particles that may have already detached from flotation gas bubbles and began their descent may be 10 recaptured by the bubbles on account of the turbulent conditions in the mixing zone. On the other hand, the flotation tank bottom nearer the tank perimeter has a zone of a sufficient depth that allows for unfloated, most likely valueless particles to settle down and descend to be efficiently removed from the flotation 15 tank. This settling zone is not affected by the slurry infeed flow from the blast tubes. Further, such relatively calm zone may inhibit formation of short circuiting of the slurry flows within the flotation tank, where the same slurry material keeps recirculating within the tank without being properly separated 20 or settled. The above features may promote increased recovery of fine particles.

In an embodiment of the flotation cell, the flotation tank further comprises a central froth crowder arranged at a distance from the bottom of the flotation tank.

In a further embodiment of the flotation cell, a height of the bottom structure is 1/3 to 3/4 of the distance of the central froth crowder from the bottom of the flotation tank.

In an embodiment of the flotation cell, the flotation tank further comprises an internal perimeter froth crowder, a 30 lowest point of the internal perimeter froth crowder arranged at a distance from the bottom of the flotation tank.

In a further embodiment of the flotation cell, the ratio of a height of the bottom structure to the distance of the lowest point of the internal perimeter forth crowder from the bottom of 35 the flotation tank is 1,0 or lower.

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In an embodiment of the flotation cell, a diameter of a base of the bottom structure is 1/4 to 3/4 of a diameter of the bottom of the flotation tank.

In an embodiment of the flotation cell, the surface 5 area of a base of the bottom structure is 25 to 80 % of the surface area of the bottom of the flotation tank.

In an embodiment of the flotation cell, the ratio of height of the flotation tank, measured as the distance from the bottom to the launder lip, to diameter of the flotation tank, 10 measured at a height of the outlet nozzle from the bottom is 0,5 to 1,5; i.e. the ratio of tank height to tank diameter is 0,5 to 1,5.

In an embodiment of the flotation cell, the volume of the flotation tank is at least 20 m³, preferably 20 to 1000 m³.

By arranging a flotation tank to have a sufficient volume the flotation process may be better controlled. The ascent distance to the froth layer on the top part of the flotation tank does not become too large, which may help to ensure that the flotation gas bubble-ore particle agglomerates remain 20 together until the froth layer and particle drop-back may be reduced. Further, a suitable bubble rise velocity may be reached to maintain a good concentrate quality. Utilizing flotation cells with a sufficient volumetric size of increases the probability of collisions between gas bubbles created into the 25 flotation cells for example by means of a rotor, and the particles comprising valuable mineral, thus improving the recovery rate for the valuable mineral, as well as the overall efficiency of the flotation arrangement. Larger flotation cells have a higher selectivity as more collisions between the gas 30 bubbles and the ore particles may take place due to the longer time the slurry stays in the flotation cell. Therefore most of the ore particles comprising valuable mineral may be floated. In addition, the backdrop of buoyant ore particles may be higher, which means that ore particles comprising very low amount of 35 valuable mineral drop back into the bottom of the flotation cell.

Thus the grade of overflow and/or concentrate from larger flotation cells may be higher. These kinds of flotation cells

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2019100825 29 Jul 2019 may ensure high grade. Further, the overall efficiency of the flotation cell and/or the entire flotation line may be improved. In addition, in case the first flotation cells in a flotation line have a relatively large volume, there may be no need for 5 large subsequent flotation cells, but rather, the flotation cells downstream from the first flotation cell or cells may be smaller and therefore more efficient. In flotation processes of certain minerals, it may be easy to float a significant part of the ore particles comprising valuable mineral with high grade.

In that case it may be possible to have flotation cells of smaller volume downstream in the flotation line and still achieve high recovery rate .

In an embodiment of the flotation cell according to the invention, the flotation cell comprises 2 to 40 blast tubes, 15 preferably 4 to 24 blast tubes.

The number of blast tubes directly influences the amount of flotation gas that can be dispersed in the slurry. In conventional froth flotation, dispersing an increasing amount of flotation gas would lead to increased flotation gas bubble size. 20 For example, in a Jameson cell, an air-to-bubble ratio of 0,50 to 0,60 is utilized. Increasing the average bubble size will affect the bubble surface area flux (Sb) detrimentally, which means that recovery may be decreased. In a flotation cell according to the invention, with pressurized blast tubes, 25 significantly more flotation gas may be introduced into the process without increasing the bubble size or decreasing Sb, as the flotation gas bubbles created into the slurry infeed remain relatively small in comparison to the conventional processes. On the other hand, by keeping the number of blast tubes as small as 30 possible, costs of refitting existing flotation cells, or capital expenditure of setting up such flotation cells may be kept in check without causing any loss of flotation performance of the flotation cells .

In an embodiment of the flotation cell, the blast tubes 35 are arranged concentric to the perimeter of the flotation tank at a distance from the centre of the flotation tank.

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In an embodiment of the flotation cell, the blast tubes are arranged parallel to the sidewall of the flotation tank, at a distance from the side wall.

The exact number of blast tubes within a flotation cell 5 may depend on the flotation tank size or volume, on the type of material to be collected and other process parameters. By arranging a sufficient number of blast tubes into a flotation cell, and by arranging them in a specific manner in relation to the flotation tank centre and perimeter and/or side wall, even 10 distribution of ultra-fine bubbles may be ensured, as well as even mixing effect caused by the shear forces within tank secured.

In an embodiment of the flotation cell, a blast tube further comprises an impinger configured to contact a flow of 15 slurry infeed from the outlet nozzle and to direct the flow of slurry infeed radially outwards and upwards of the impinger.

An impinger deflects the flow of slurry infeed radially outwards to the flotation tank sidewall and upwards towards the flotation tank upper surface (i.e. to the froth layer) so the 20 fine flotation gas bubble - ore particle agglomerates do not short circuit into the tailings. All of the slurry infeed from the blast tubes are forced to rise up towards the froth layer at the top region of the flotation tank before gravity has the chance to influence the particles not adhered to flotation gas 25 bubbles, forcing them to descend and eventually report to tailings flow or underflow. Thereby the probability of valuable material containing particles short-circuiting may be diminished. Slurry is highly agitated by the energy of the deflected flow, and forms mixing vortexes in which the size of 30 the bubbles may be further reduced by the shear forces acting upon them. The high-shear conditions favourably also induce high number of contacts between flotation gas bubbles and particles in the slurry within the flotation tank. As the flow of slurry is forced upwards towards the froth layer, turbulence reduces 35 and the flow becomes relatively uniform, which may contribute to the stability of the already formed bubbles, and flotation gas

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2019100825 29 Jul 2019 bubble- particle agglomerates, especially those comprising coarser particles .

By arranging the outlet nozzle and the impinger at an optimum distance from each other, the impinger may be configured 5 to deflect and direct the flow of slurry infeed radially outwards and upwards of the impinger to create the earlier mentioned mixing zones within the flotation tank, and to promote the ascent of particles towards the froth layer. At the same time, it may be necessary to minimise the wear caused by high-velocity flows 10 of slurry on the impinger. By positioning the outlet nozzle and the impinger at a certain relation to each other, it may be possible to optimise the flotation process within a flotation cell equipped with blast tubes, as well as minimise wear to the impinger parts .

In a further embodiment of the flotation cell, the volume of the flotation tank taken by the bottom structure is 30 to 70 % of the volume of the flotation tank taken by the mixing zone .

By arranging the bottom structure to have a certain 20 size, especially in respect to the mixing zone, the mixing zone and the settling zone may be designed to have desired characteristics (size, depth, turbulence, residence time of particles in the mixing zone, settling speed and probability of valueless fraction in the settling zone etc.). In a conventional 25 flotation cell, a majority of this area (without any mechanical mixing at the bottom of the flotation tank) would be subjected to sanding, as there is little or no mixing. If the area fills up with solids, a risk of this solid matter slumping in and at the same time blocking a tailings outlet and/or a recirculate 30 outlet located at the settling zone.

In an embodiment of the flotation cell, it further comprises a conditioning circuit.

In a further embodiment of the flotation cell, the conditioning circuit comprises a pump tank in fluid 35 communication with the flotation tank, in which pump tank infeed of fresh slurry and a slurry fraction taken from the flotation

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2019100825 29 Jul 2019 tank via an outlet are arranged to be combined into slurry infeed.

In yet another embodiment of the flotation cell, the outlet is arranged at the sidewall of the flotation tank, at a 5 distance from the bottom of the flotation tank.

In yet another embodiment of the flotation cell, the distance of the outlet from the bottom of the flotation tank is 0 to 50 % of the height of the flotation tank.

In a further embodiment of the flotation cell, the 10 conditioning circuit further comprises a pump arranged to intake the slurry fraction from the flotation tank and to forward slurry infeed from the pump tank.

In a further embodiment of the flotation cell, the conditioning circuit further comprises a distribution unit 15 arranged to distribute slurry infeed.

By taking slurry from the bottom of a flotation cell it may be ensured that the finer particles settled to the bottom of the flotation tank may be efficiently reintroduced into the part of the flotation tank where active flotation process takes place, 20 before the finer particles are reported to tailings. Thus the recovery rate of valuable material may be improved as the particles comprising even minimal amounts of valuable material may be collected into the concentrate.

By recirculating into blast tubes a slurry fraction 25 from the lower part of the flotation tank via an outlet arranged at the side wall of the flotation tank, the recirculated fraction becomes thus obtained at a zone where the slurry by most parts comprises particles descending or settling towards the tank bottom. Due to the probabilistic nature of a flotation process, 30 the particles may, however, still comprise valuable material.

Especially at the settling zone closest to the flotation tank side wall, the slurry may comprise such valuable material comprising particles that have not been captured by the flotation gas bubbles and/or by the upwards directed flow of slurry near 35 the impingers at the mixing zone. At this position, the slurry is also affected by the flow of slurry infeed from a single blast tube creating turbulence. There is thus a higher probability of

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2019100825 29 Jul 2019 particles comprising valuable material not being captured by the flotation gas bubbles and/or the upwards directed flow of slurry. In order to recover valuable material from these particles as well, it may be favourable to treat this slurry fraction again 5 in the same flotation cell, for example as a part of the slurry infeed. Therefore, the overall recovery may be further improved In an embodiment of the flotation cell, the flotation tank further comprises a tailings outlet for removing underflow.

In a further embodiment of the flotation cell, the 10 tailings outlet is arranged at the side wall of the flotation tank, at a distance from the bottom of the flotation tank.

In a yet further embodiment of the flotation cell, that the distance of the tailings outlet from the bottom of the flotation tank is 1 to 15 % of a height of the flotation tank, 15 measured as the distance from the bottom to the launder lip.

The tailings outlet may be positioned at the bottom of the flotation tank, or at the side wall of the flotation tank, at the settling zone.

By disposing a tailings outlet at the side wall of the flotation tank, underflow may be removed at a zone where the slurry by most parts comprises particles descending or settling towards the tank bottom. In the flotation cell according to the invention, the settling zone is deeper near the side wall of the flotation tank. At this area, mixing action and turbulence 25 created by the blast tubes does not affect the settling particles, which, for the most part, do not comprise any valuable material, or comprise only a very small amount of valuable material. At this part, the settling action is also most pronounced due to the lack of turbulence interfering the descent 30 by gravity of the particles. In addition, friction forces created by the tank side wall further decrease the turbulence and/or flows. Thus, taking underflow out of the flotation tank at a position arranged on this relatively calm settling zone, it may be ensured that as little as possible of the valuable material 35 comprising particles are removed from the flotation tank - these particles should, rather, be floated, or, if for some reason having ended up in the settling zone, recirculated back into the

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2019100825 29 Jul 2019 flotation tank as slurry infeed through the blast tubes. Further, by removing underflow from the settling zone near the side wall of the flotation tank, the entire volume of the flotation tank may be efficiently utilized - there is no need to configure a 5 separate lower settling zone below the blast tubes, as is the case in for example a Jameson cell. In some embodiments, it is even foreseeable that the volume of the flotation tank may be decreased at the centre of then tank, thereby decreasing the volume of the settling zone where the turbulence caused by slurry 10 infeed from the blast tubes may influence the probability of particles settling towards the bottom of the tank, and allowing full use of the flotation tank volume. The volume of the flotation tank may be decreased at the centre of the tank for example by arranging a bottom structure at the flotation tank 15 bottom, at the centre of the tank. In addition, it may be possible to dispose the blast tubes (the outlet nozzles) relatively deep into the flotation tank, and still ensure a sufficient calm settling zone at the side wall of the flotation tank. Also this further promotes to the efficient use of the 20 entire volume of the flotation tank.

In a flotation line, the flotation cell according to the invention may be preceded by a flotation cell. The preceding flotation cell may be of any suitable type.

The flotation cell according to the invention may be 25 preceded by a mechanical flotation cell.

A flotation line may comprise a rougher part with a flotation cell; a scavenger part with a flotation cell arranged to receive underflow from the rougher part; and a scavenger cleaner part with a flotation cell arranged to receive overflow 30 from the scavenger part, wherein the last flotation cell of the scavenger part and/or the scavenger cleaner part is a flotation cell according to the invention.

The invention is particularly intended for recovering mineral ore particles comprising nonpolar minerals such as 35 graphite, sulphur, molybdenite, coal, and talc.

Treatment of slurries for the recovery of such industrial minerals as bentonite, silica, gypsum, or talc, may

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2019100825 29 Jul 2019 be improved by using reverse flotation. In recovering industrial minerals, the goal of flotation may be, for example, the removal of dark particles into the overflow reject, and recovery of white particles into the underflow accept. In that kind of process, some of the lighter, finer white particles may end up into the overflow. Those particles could be efficiently recovered by the invention according to the present disclosure. In reverse flotation, particles comprising undesirable material are removed from the slurry by arranging the gas bubbles to adhere to those 10 particles and removing them from the flotation cell in the overflow, whereas the valuable material comprising particles are recovered in the underflow, thus inversing the conventional flotation flows of accept into overflow and reject into underflow. Typically in reverse flotation, the large mass pull

of invaluable material	may cause	significant	problems	in
controlling the flotation	process .
The invention	may be	particularly	intended	in
recovering particles comprising pola	r minerals .
The invention	may be	particularly	intended	in

recovering particles from minerals having a Mohs hardness of 2 to 3, such as galena, sulfide minerals, PGM minerals, and/or REO minerals .

The invention may	be	particularly	intended	in
recovering particles comprising	Pt.
The invention may	be	particularly	intended	in
recovering particles comprising	Cu	from minerals	having a	Mohs
hardness from 3 to 4.
The invention may	be	particularly	intended	in
recovering particles comprising	Cu	from low grade	ore .

Valuable mineral may be for example Cu, or Zn, or Fe, or pyrite, or metal sulfide such as gold sulfide. Mineral ore particles comprising other valuable mineral such as Pb, Pt, PGMs (platinum group metals Ru, Rh, Pd, Os, Ir, Pt), oxide mineral, industrial minerals such as Li (i.e. spodumene), petalite, and rare earth minerals may also be recovered, according to the different aspects of the present invention.

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For example, in recovering copper from low grade ores obtained from poor deposits of mineral ore, the copper amounts may be as low as 0,1 % by weight of the feed, i.e. infeed of slurry into the flotation line. The flotation line according to 5 the invention may be very practical for recovering copper, as copper is a so-called easily floatable mineral. In the liberation of ore particles comprising copper, it may be possible to get a relatively high grade from the first flotation cells of the flotation line. Recovery may be further increased by a flotation 10 cell according to the invention.

By using the flotation arrangement according to the present invention, the recovery of such low amounts of valuable mineral, for example copper, may be efficiently increased, and even poor deposits cost-effectively utilized. As the known rich 15 deposits have increasingly already been used, there is a tangible need for processing the less favourable deposits as well, which previously may have been left unmined due to lack of suitable technology and processes for recovery of the valuable material in very low amounts in the ore.

BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying drawings, which are included to provide a further understanding of the current disclosure and which constitute a part of this specification, illustrate 25 embodiments of the disclosure and together with the description help to explain the principles of the current disclosure. In the drawings :

Fig. 1 is a 3D projection of a flotation cell according to an embodiment of the invention,

Fig .	2	depicts a flotation cell	according	to	an
embodiment of	the	invention, as seen from above,
Fig .	3	depicts a flotation cell	according	to	an
embodiment of	the	invention in side view,
Fig .	4a	is a vertical cross-section	of the flotation

cell of Fig. 3 along a section A-A,

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Fig. 4b shows a vertical cross-section of a further embodiment of the flotation cell of Fig. 3 along the section AA,

Fig. 5 is a schematic illustration of a flotation cell according to the invention, detailing the dimensions of the flotation cell,

Fig. 6a and 6b are schematic drawings of flotation lines according to embodiments of the invention,

Fig. 7 shows schematic vertical cross-sections of 10 embodiments of flotation tanks according to the invention, and

Fig. 8 is a schematic presentation of forms of the bottom structure according to embodiments of the flotation cell.

DETAILED DESCRIPTION

Reference will now be made in detail to the embodiments of the present disclosure, an example of which is illustrated in the accompanying drawings .

The description below discloses some embodiments in such a detail that a person skilled in the art is able to utilize 20 the flotation cell, flotation line and its use based on the disclosure. Not all steps of the embodiments are discussed in detail, as many of the steps will be obvious for the person skilled in the art based on this disclosure.

For reasons of simplicity, item numbers will be 25 maintained in the following exemplary embodiments in the case of repeating components .

The enclosed figures 1-5 and 7-8 illustrate a flotation cell 1 in some detail. The figures are not drawn to proportion, and many of the components of the flotation cell 1 are omitted 30 for clarity. Figures 6a and 6b illustrate in a schematic manner embodiments of the flotation line. The direction of flows of slurry is shown in the figures by arrows.

The flotation cell 1 according to the invention is intended for treating mineral ore particles suspended in slurry 35 and for separating the slurry into an underflow 400 and an overflow 500, the overflow 500 comprising a concentrate of a desired mineral.

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Referring in particular to figures 1-5, the flotation cell 1 comprises a flotation tank 10 that has a centre 11, a perimeter 12, a bottom 13 and a side wall 14. The flotation cell 1 further comprises a launder 2 and a launder lip 21 surrounding 5 the perimeter 12 of the flotation tank 10.

In the accompanying figures, launder 2 is a perimeter launder. It is to be understood that a launder 2 may comprise, alternatively or additionally, a central launder arranged at the centre 11 of the flotation tank 10, as is known in the technical 10 field. A launder lip of a central launder may face towards the perimeter 12 of the flotation tank 10, or towards the centre 11 of the flotation tank 10, or both. The overflow 500 is collected into the launder 2 or launders as it passes over a launder lip 21, from a froth layer formed in the upper part of the flotation 15 tank 10. The froth layer comprises an open froth surface A_f at the top of the flotation tank 10.

Underflow 400 is removed from or led out of the flotation tank via a tailings outlet 140. According to an embodiment, the tailings outlet 140 may be arranged at the side 20 wall 14 of the flotation tank 10 (see Fig. 5) . The tailings outlet 140 may be arranged at the side wall 14 of the flotation tank 10 at a distance L₆ from the bottom 13 of the flotation tank 10. The distance is to be understood as the distance of the lowest point of the tailings outlet 140 or outlet opening in the 25 side wall 14 of the flotation tank 10 from the tank bottom 13.

The distance L₆ may be 1 to 15 % of the height H of the flotation tank 10. For example, the distance L₆ may be 2 %, or 5 % or 7,5 %, or 12 % of the height H. Alternatively, the tailings outlet 140 may be arranged at the bottom 13 of the flotation tank 10 30 (see Fig. 1). In any case, the tailing outlet 140 is arranged at a settling zone B, at the lower part of the flotation tank 10.

The tailings outlet 140 may be controlled by a dart valve, or by any other suitable manner known in the field, to control the flow rate of underflow from the flotation tank 10. Even if the 35 tailings outlet 140 is controlled by internal or external structures such as up-flow or down-flow, respectively, dart boxes, the tailings outlet 140 is ideally located at the lower

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2019100825 29 Jul 2019 part of the flotation tank 10, i.e. near or adjacent to the bottom 13 of the flotation tank, or even at the bottom 13 of the flotation tank 10. More specifically, underflow 400 or tailings are removed from the lower part of the flotation tank 10, and at 5 or near the side wall 14 of the flotation tank 10.

The flotation tank 10 has a height H, measured as the distance from the bottom 13 of the flotation tank 10 to the launder lip 21. At the perimeter 12 of the flotation tank 10, the height H is substantially equal to or greater than the height 10 H at the centre 11 of the flotation tank 10. In other words, the flotation tank 10 may have different vertical cross-sections (see Fig. 7) - for example, the side wall 14 of the flotation tank 10 may include at its lower part a section that is inclined towards the centre 11 of the flotation tank 10.

Further, the flotation tank 10 has a diameter D, measured at a distance hl of an outlet nozzle 43 from the bottom 13 of the flotation tank 10. In an embodiment, the height H to diameter D ratio H/D of the flotation tank 10 is 0,5 to 1,5.

The flotation tank 10 may have a volume of at least 20 20 m³ . The flotation tank 10 may have a volume ranging from 20 to 1000 m³. For example, the volume of the flotation tank 10 may be 100 m³, or 200 m³, or 450 m³, or 630 m³.

The flotation tank 10 comprises blast tubes 4 for introducing slurry infeed 100 into the flotation tank 10. A blast 25 tube 4 comprises an inlet nozzle 41 for feeding slurry infeed 100 into the blast tube 4; an inlet 42 for pressurized air or other gas, so that the slurry infeed 100 may be subjected to pressurized air or other gas as it is discharged from the inlet nozzle 41; an elongated chamber 40 arranged to receive under 30 pressure the slurry infeed 100; an outlet nozzle 43 configured to restrict flow of slurry infeed 100 from the outlet nozzle 43, and to maintain slurry infeed in the elongated chamber 40 under pressure .

Flotation gas is entrained through a turbulent mixing 35 action brought about by the jet, and is dispersed into small bubbles in the slurry infeed 100 as it travels downwards through the elongated chamber 40 to an outlet nozzle 43 configured to

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2019100825 29 Jul 2019 restrict the flow of slurry infeed 100 from the outlet nozzle 43, and further configured to maintain slurry infeed 100 under pressure in the elongated chamber 40.

According to an embodiment, the outlet nozzle 43 may further be configured to produce a supersonic shockwave into the slurry infeed, the supersonic shockwave inducing formation of flotation gas bubble - particle agglomerates. For example, and to the outlet nozzle 43 may induce a supersonic shockwave into the slurry infeed 100 as it exits the blast tube 40. In addition, 10 the supersonic shockwave may extend to the slurry adjacent or surrounding the outlet nozzle so that even outside the blast tube, the creation of small size flotation gas bubble - particle agglomerates is thus possible.

For restricting the flow, an outlet nozzle 43 may 15 comprise a throttle such as a throat-like restricting structure.

From the outlet nozzle 43, more specifically from the throttle, slurry infeed 100 issues under pressure into the flotation tank 10. As the slurry infeed 100 passes through the outlet nozzle 43, or through the throttle of the outlet nozzle 43, flotation 20 gas bubbles are reduced in size by the pressure changes, and by the high-shear environment downstream of the outlet nozzle 43.

The velocity of the gas-liquid mixture in outlet nozzle 43, or in the throttle, may exceed the speed of sound when the flow becomes a choked flow and flow downstream of the throttle becomes 25 supersonic, and a shockwave forms in the diverging section of the outlet nozzle 43. In other words, the outlet nozzle 43 is configured to induce a supersonic shockwave into slurry infeed 100. The flow of slurry infeed 100 becomes choked when the ratio of the absolute pressure upstream the outlet nozzle 43 to the 30 absolute pressure downstream of a throttle or other restricting structure of the outlet nozzle 43 exceeds a critical value. When the pressure ratio is above the critical value, flow of slurry infeed 100 downstream of the throttle of the outlet nozzle 43 becomes supersonic and a shockwave is formed. Small flotation 35 gas bubbles in slurry infeed 100 mixture are split into even smaller by being forced through the shockwave, and forced into

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2019100825 29 Jul 2019 contact with hydrophobic ore particles in slurry infeed 100, thus creating flotation gas bubble-ore particle agglomerates.

An outlet nozzle 43 may be disposed inside the flotation tank 10 at a desired depth. An outlet nozzle 43 may be positioned 5 at a vertical distance L₅ from the launder lip 21, the distance L₅ being at least 1,5 m. In other words, the length of the portion of a blast tube 4 disposed inside the flotation tank 10 below the launder lip 21 level is at least 1,5 m. In an embodiment, the distance L₅ is at least 1,7 m, and the distance hl of the 10 outlet nozzle 43 from the bottom 13 of the flotation tank 10 is at least 0,4 m. For example, the distance L₅ may be 1,55 m, or l, 75 m, or 1,8 m, or 2,2 m, or 2,45m, or 5,25 m; and the distance hx, irrespective of the distance L₅, may be 0,45 m, 0,55 m, 0,68 m, 0,9 m, or 1,2 m. Further, the ratio of the distance L₅ to the 15 height H of the flotation tank 10 may be 0,9 or lower. The depth at which the blast tubes 4 are disposed inside the flotation tank 10 may depend on a number of factors, for example on the characteristics of the slurry and/or valuable mineral to be treated in the flotation cell 1, or on the configuration of a 20 flotation line in which the flotation cell 1 is arranged. The ratio of a distance h_x of an outlet nozzle 43 from the bottom 13 of the flotation tank 10 to height H of the flotation tank 10, hx/H may be 0,1 to 0,75.

A diameter of an outlet nozzle 43 may be 10 to 30 % of 25 the diameter of an elongated chamber 40 of a blast tube 4. The diameter of an outlet nozzle 43 may be 40 to 100 mm. For example, the diameter of an outlet nozzle 43 may be 55 mm, or 62 mm, or 7 0 mm.

By arranging an outlet nozzle to have a certain 30 diameter, the velocity of the slurry infeed may be maintained at a level favourable for the creation of small size flotation gas bubbles, and for the probability of these bubbles to contact the ore particles in the slurry. Especially, to maintain a shockwave after the outlet nozzle, a slurry velocity of 10 m/s or higher 35 needs to be maintained. By designing the outlet nozzle in relation to the blast tube size, the effect of slurry infeed

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2019100825 29 Jul 2019 flow rate in different types of flotation cells may be accounted for .

A blast tube 4 may further comprise an impinger 44 configured to contact a flow of slurry infeed 100 from the outlet 5 nozzle 43 and to direct the flow of slurry infeed 100 radially outwards and upwards of the impinger 44. Slurry infeed 100 exiting from the outlet nozzle 43 is therefore directed to contact the impinger 44. A distance L₃ from a bottom 440 of the impinger 44 to the outlet nozzle 43 may be 2 to 20 times the 10 diameter of the outlet nozzle 43. For example, the distance L₃may be 5 times, 7 times, or 12 times, or 15 times the diameter of the outlet nozzle 43.

The ratio of the distance L₃ to the distance h₃ of an outlet nozzle 43 from the bottom 13 of the flotation tank 10, 15 L₃/hi, may be lower than 1,0. Further, a distance h₃ of a bottom 440 of the impinger 44 from the bottom 13 of the flotation tank 10 may be at least 0,3 m. For example the distance h₃ may be 0,4 m, or 0,55 m, or 0,75 m, or 1,0 m.

The impinger 44 may comprise an impingement surface 20 intended for contacting the flow of slurry infeed 100 exiting the outlet nozzle 43. The impingement surface may be made of wear-resistant material to reduce the need for replacements or maintenance .

The slurry, which in essence is a three-phase gas25 liquid-solids mixture, rising out of the impinger 44 enters the upper part of the flotation tank 10, and the flotation gas bubbles rise upwards and separate from the liquid to form a froth layer. The froth rises upwards and discharges over the launder lip 21 into the launder 2 and out of the flotation cell 1 as 30 overflow 500. The tailings or underflow 400, from which the desired material has substantially been removed, pass out from the flotation tank 10 through an outlet arranged at or near the bottom 13 of the flotation tank 10.

Some of the coarse hydrophobic particles that are 35 carried into the froth may subsequently disengage from flotation gas bubbles and drop back into the flotation tank 10, as a result of bubble coalescence in the froth. However, the majority of

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2019100825 29 Jul 2019 such particles fall back into the flotation tank 10 in such a way and position that they may be captured by bubbles newly entering the flotation tank 10 from the blast tubes 4, and carried once more into the froth layer.

There may be 2-40 blast tubes 4, or 4-24 blast tubes 4 arranged in a flotation cell 1. In an embodiment, there are 16 blast tubes 4. In another embodiment, there are 24 blast tubes 4. In yet another embodiment, there are 8 blast tubes 4. The exact number of blast tubes 4 may be chosen according to the 10 specific operation, for example the type of slurry being treated within the flotation cell 1, the volumetric feed flowrate to the flotation cell 1, the mass throughput feed to the flotation cell 1, or the volume or dimensions of the flotation tank 10. In order to properly disperse flotation gas within the flotation tank 10, 15 4 to 6 blast tubes 4 may be employed.

The blast tubes 4 may be arranged concentric to the perimeter 12 of the flotation tank 10 at a distance from the centre 11 of the flotation tank 10. This may be the case when the flotation tank 10 is circular in cross-section. The blast 20 tubes 4 may be further arranged so that each blast tube 4 is located at a distance Lx of an outlet nozzle 43 from the centre 11 of the flotation tank 10, the distance being preferably equal for each blast tube 4. For example, the distance Lx may be 10 to 40 % of the diameter D of the flotation tank 10. According to 25 different embodiments of the flotation cell 1, the distance LI may be 12,5 %, or 15 %, or 25 % or 32,5% of the diameter D of the flotation tank 10.

The blast tubes 4 may be arranged parallel to the side wall 14 of the flotation tank 10, at a distance from the side 30 wall 14 . This may be the case when the flotation tank 10 is rectangular in cross-section. A distance L2 of the outlet nozzle 43 of a blast tube 4 from the side wall 14 of the flotation tank 10 may be 10 to 40 % of the diameter D of the flotation tank 10. In an embodiment, the distance L₂ is 25 % of the diameter D of 35 the flotation tank 10. According to different embodiments of the flotation cell 10, the distance L₂ may be 12,5 %, or 15 %, or 27 % or 32,5% of the diameter D of the flotation tank 10.

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2019100825 29 Jul 2019

Additionally, the parallel arranged blast tubes 4 may be further arranged at a straight line within the flotation tank 10.

Further, in all the above mentioned embodiments, the blast tubes 4 may be arranged at equal distance from each other so that a distance between any two adjacent outlet nozzle 43 is the same.

The flotation tank 10 comprises a bottom structure 7 (see esp. Figs. 2, 4a, 4b, 5 and 8), arranged on the bottom (13), and having a shape that allows particles suspended in slurry to be mixed in a mixing zone A created by the flow of slurry infeed

100 from the outlet nozzles 43 of the blast tubes 4 over the bottom structure 7, and to settle down in a settling zone B surrounding the bottom structure 7.

The shape of the bottom structure 7 may be defined as follows (see Fig. 8): the vertical cross-section of the bottom structure may be understood to display a form of a functional triangle 700 that comprises a first (top) vertex 71, pointing away from the bottom 13 of the flotation tank 10; a second vertex 71a; and a third vertex 71b, the two latter disposed at the bottom 13 of the flotation tank 10. A first side a is formed between the first vertex 71 and the second vertex 71a. A second side b is formed between the first vertex 71 and the third vertex 71b. A base c is formed between the second vertex 71a and the third vertex 71b, the base c being thus parallel to and on the bottom 13 of the flotation tank 10. A central axis 70 of the functional triangle 700 is substantially concentric with the centre 11 of the flotation tank 10. Substantially in this context is to be understood so that during manufacturing and/or installation of the bottom structure 7, it is possible that slight deviations from the centre 11 of the flotation tank 10 may naturally occur. The intention is, nevertheless, that the two axes, central axis 70 of the functional triangle (which is also the central axis of the bottom structure 7) and the centre of the flotation tank 10 are coaxial.

A base angle a between the first side a and the base c (and/or between the second side b and the base c), in relation to the bottom 13 of the flotation tank 10 is 20 to 60°. For

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2019100825 29 Jul 2019 example, the angle a may be 22°, or 27,5° or 35°, or 45°, or 53,75°. Further, an included angle β between the first side a and the second side b is 20 to 100°. Preferably, the included angle β is 20 to 80°. For example, the included angle β may be 5 22°, or 33,5°, or 45°, or 57,75°, or 64°, or 85,5°. The functional triangle may therefore be an isosceles triangle or an equilateral triangle.

The functional triangle is in essence a form which may be identified though the abovementioned features, regardless of 10 the actual form of the bottom structure 7, which may be, depending on the cross-section and other structural details of the flotation tank 10, for example a cone, a truncated cone, a pyramid, or a truncated pyramid. A cone or a truncated cone may be suitable from for a flotation tank with a circular cross15 section. A pyramid or a truncated pyramid may be a suitable form for a flotation tank with a rectangular cross-section.

The bottom structure 7 comprises a base 73, corresponding to the base c of the functional triangle 700 (i.e. the base c of the functional triangle 700 defines the base 73 of 20 the bottom structure 7), and arranged on the bottom 13 of the flotation tank 10. Further, the bottom structure comprises a mantle 72. The mantle 72 is defined at least by the first vertex 71, the second vertex 71a and the third vertex 71b of the functional triangle 700. Therefore, irrespective of the actual 25 form of the bottom structure 7, the functional triangle 700 defines the extreme physical dimensions of the bottom structure 7. For example, in case the bottom structure 7 has an irregular form yet being rotationally symmetrical, it would fit into the functional triangle 700 in its entirety (see the last image of 30 Fig. 8) . In an embodiment, the mantle 72 is at least partly defined by the first side a and the second side b of the functional triangle. An example of such an embodiment is a bottom structure 7 having the form of a truncated cone (see the middle image of Fig. 8) . In an embodiment, the mantle 72 is defined 35 essentially entirely by the first side a and the second side b of the functional triangle 700, i.e. the bottom structure 7 has the form of a cone (see the first image of Fig. 8).

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2019100825 29 Jul 2019

The bottom structure 7 has a height h₄, measured from the topmost part of the bottom structure 7 to the bottom 13 of the flotation tank 10. In case the form of the bottom structure is a cone or a pyramid, the topmost part is also the first vertex 5 71 of the functional triangle 700. In case the bottom structure has some sort of truncated form, the height h₄ is measured from the level top of the truncated form (see middle image of Fig. 8) to the bottom 13 of the flotation tank 10. The height h₄ is greater than 1/5 and less than 3/4 of the height H of the 10 flotation tank 10. Further, the diameter d₃ of the base 73 of the bottom structure 7 may be 1/4 to 3/4 of a diameter d₄ of the bottom 13 of the flotation tank 10. In case a flotation tank 10 and/or the bottom structure 7 has a non-circular cross-section, the diameters are measured as the maximal diagonals of the 15 respective parts (base 73 and bottom 13). In an embodiment, the surface area of a base 73 of the bottom structure 7 is less than 80 % of the surface area of the bottom 13 of the flotation tank 10. The surface area of the base 73 may be 25 to 80 % of the surface area of the bottom 13 of the flotation tank 10.

Further, the volume of the flotation tank 10 taken by the bottom structure 7 may be 30 to 70 % of the volume of the flotation tank 10 taken by the mixing zone A.

The bottom structure 7 may additionally comprise any suitable support structures and/or connecting structures for 25 installing the bottom structure 7 into the flotation tank 10, on the bottom 13 of the flotation tank 10. The bottom structure 7 may be made of any suitable material such as metal, for example stainless steel.

The flotation tank 10 may further comprise a froth 30 crowder 6 shaped to direct froth in the open froth surface A_ftowards the launder lip 21, as shown in Figs. 4b and 5. The forth crowder 6 may be a central froth crowder 61, and/or an internal perimeter froth crowder arranged within the flotation tank 10 at a desired depth, at the sidewall of the flotation tank 10.

A central froth crowder 61 is arranged concentric to the centre 11 of the flotation tank 10. The central froth crowder 61 may have a shape of a cone or a truncated cone. The central

11564894_1 (GHMatters) P111728.AU

2019100825 29 Jul 2019 froth crowder 61 may have a shape of a pyramid or a truncated pyramid. In other words, a vertical cross-section of a central froth crowder 61 may be an inverted triangle with a vertex pointing towards the bottom 13 of the flotation tank. In case the central froth crowder 61 is has a truncated structure or shape, the vertex is only functional, i.e. it is to be visualised as the lowest point of the structure or shape as continued to a complete untruncated form, whereby a included angle a may be identified irrespective of the actual shape or form of the 10 central froth crowder. The included angle a may be 20 to 80°.

For example, the included angle a may be 22°, or 37,5° or 45°, or 55°, or 63,75°, or 74°. In an embodiment, the central froth crowder 61 is arranged to block 25 to 40 % of the open froth surface A_f .

Alternatively or additionally to the central froth crowder 61, the flotation tank may comprise an internal perimeter crowder 62, arranged in the side wall 14 of the flotation tank 10 so that a lowest point 620 of the internal perimeter crowder is located at a distance h₂ from the bottom 13 of the flotation 20 tank 10. The distance h₂ may be 1/2 to 2/3 of the height H of the flotation tank 10. The internal perimeter crowder 62 may be formed to comprise a diagonal intake 14c starting from the lowest point 620, and angled towards the centre 11 of the flotation tank 10, and extending between a first part 14a of the side wall 25 14 of the flotation tank 10 and a second part 14b of the side all 14 so that an angle of inclination β of the diagonal intake 14c in relation to the first part 14a of the side wall 14 is 20 to 80°. The angle of inclination β may be for example 22°, or 37,5° or 45°, or 55°, or 63,75°, or 74°. The internal perimeter 30 crowder 62 may be arranged to block 1/5 to M of a pulp area A_p, which is measured at a distance h₂ of an outlet nozzle 43 of a blast tube 4 from the bottom 13 of the flotation tank 10, at a mixing area A. The mixing area A, i.e. the part or zone of the flotation tank in vertical direction where the slurry is agitated 35 or otherwise induced to mix the ore particles suspended in the slurry with the flotation gas bubbles, is formed roughly at a

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2019100825 29 Jul 2019 vertical section of the flotation tank 10 around the lower parts of the blast tubes 4 and the impingement bowls 44 (see Fig. 5).

A slurry fraction 300 may be taken out from the flotation tank 10 via an outlet 31 arranged at the side wall 14 of the flotation tank 10. This slurry fraction 300 is recirculated into blast tubes 4 as infeed slurry. In an embodiment, the slurry infeed 100 comprises 40 % or less of slurry fraction 300. In an embodiment, the slurry infeed 100 comprises 50 % or less of slurry fraction 300. For example, the 10 slurry infeed may comprise 5 %, or 12,5%, or 20 %, or 30 %, or % of slurry fraction 300. Alternatively, the slurry infeed 100 may comprise 0 % of slurry fraction 300, i.e. no recirculation of slurry taken from the flotation tank 10 back to the flotation cell takes place, but the slurry infeed 100 15 comprises 100 % of fresh slurry 200, for example from a previous flotation cell (that is, underflow 400 from a previous flotation cell), or from a previous process step.

The slurry fraction 300 may be recirculated to all of the blast tubes 4 of the flotation tank 10, or, alternatively, 20 to some of the blast tubes 4, while other blast tubes 4 receive fresh slurry 200, comprising either the underflow 400 of a previous flotation cell, or a slurry flow from some preceding process step, depending on the location of the flotation cell 1 within a flotation line 8. The outlet 31 may be arranged at a 25 distance L₄ from the bottom 13 of the flotation tank 10. The distance is to be understood as the distance of the lowest point of the outlet or outlet opening in the side wall 14 of the flotation tank 10 from the tank bottom 13. The distance L₄ is 0 to 50 % of the height H of the flotation tank 10. The outlet 31 30 may advantageously be positioned at a settling zone where the particles suspended in slurry and not captured by the flotation gas bubbles and/or the upwards flow of slurry descend towards the bottom 13 of the flotation tank 10. In an embodiment, the outlet 31 is arranged at the lower part of the flotation tank 35 10. For example, the distance L₄ may be 2 %, or 8 %, or 12,5 %, or 17, or 25 % of the height H of the flotation tank 10. Even if the outlet 31 is controlled by internal or external structures

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2019100825 29 Jul 2019 such as up-flow or down-flow dart boxes, respectively, the outlet 31 is ideally located at the lower part of the flotation tank 10, i.e. near or adjacent to the bottom 13 of the flotation tank. More specifically, slurry fraction 300 is removed from the lower 5 part of the flotation tank 10.

The flotation cell 1 may also comprise a conditioning circuit 3. The conditioning circuit 3 may comprise a pump tank 30, or other such additional vessel, in fluid communication with the flotation tank 10. In the pump tank 30 infeed of fresh slurry 10 200 and a slurry fraction 300 taken from the flotation tank 10 via an outlet 31 are arranged to be combined into slurry infeed 100, which is then led into blast tubes 4 of the flotation tank 10. The fresh slurry 200 may be for example underflow 400 from a preceding flotation cell, or in case the flotation cell 1 is 15 the first flotation cell of a flotation line, an infeed of slurry coming from a grinding unit/step or a classification unit/step. It is also possible that slurry fraction 300 and fresh slurry 200 are distributed into the blast tubes 4 without being first combined in a pump tank 30.

The combined slurry may be recirculated to all of the blast tubes 4 of the flotation tank 10, or, alternatively, to some of the blast tubes 4, while other blast tubes 4 receive fresh slurry 200, comprising either the underflow 400 of a previous flotation cell, or a slurry flow from some preceding 25 process step, depending on the location of the flotation cell 1 within a flotation line 8.

The outlet 31 may be arranged at the side wall 14 of the flotation tank 10, at a distance L₄ from the bottom 13 of the flotation tank 10. The distance L₄ may be 0 to 50 % of the 30 height H of the flotation tank 10. For example, the distance L₄may be 2 %, or 8 %, or 12,5 %, or 20 %, or 33 % of the height H of the flotation tank 10.

Additionally, the conditioning circuit may comprise a pump 32 arranged to intake the slurry fraction 300 from the 35 flotation tank 10, and to forward slurry infeed 100 from the pump tank 30 to the blast tubes 4. The slurry fraction 300 may comprise low settling velocity particles such as fine, slow11564894_1 (GHMatters) P111728.AU

2019100825 29 Jul 2019 floating particles. The slurry fraction may be taken from or near the bottom of the flotation tank 10. Additionally or alternatively, the conditioning circuit 3 may further comprise a distribution unit (not shown in the figures), arranged to distribute slurry infeed 100 into the blast tubes 4. The pump 32 may also be used to forward the slurry infeed 100 into the blast tubes 4 . In order to distribute the slurry infeed 100 evenly into the blast tubes 4, a distribution unit may be utilized. The distribution unit may, for example, comprise a feed pipe inside 10 the flotation tank 10, configured to distribute slurry fraction

300 directly into the blast tubes 4. For example, the distribution unit may comprise conduits arranged outside the flotation tank 10, leading to a separate feed distributor configured to distribute slurry fraction 300, or a combination 15 of slurry fraction 300 and fresh slurry 200 into the blast tubes .

According to another aspect of the invention, flotation lines 8 is presented in figures 6a and 6b. A flotation line 8 comprises a number of fluidly connected flotation cells la, and 20 at least one of the flotation cells is a flotation cell 1 according to the above described embodiments of the flotation cell 1 according to the invention. In an embodiment of the flotation line 8, the flotation cell 1 according to the invention is preceded by a flotation cell la. A flotation cell la may be 25 of any type known in the field. Alternatively or additionally, the flotation cell 1 may be preceded by mechanical flotation cell lb (see Fig. 6a).

In an embodiment of the flotation line 8, it comprises a rougher part 81 with a flotation cell la; a scavenger part 82 with a flotation cell la arranged to receive underflow 400 for the rougher part 81; and a scavenger cleaner part 820 with a flotation cell la arranged to receive overflow 500 from the scavenger part 82 (see Fig. 6b) . In the flotation line 8, the last flotation cell 1 of the scavenger part 82, and alternatively 35 or additionally, the last flotation cell 1 of the scavenger cleaner part 820 is a flotation cell 1 according to the invention, with blast tubes 4. Additionally, in the flotation

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2019100825 29 Jul 2019 line 8, as described above, the flotation cell 1 according to the invention, with blast tubes 4, may be preceded by a mechanical flotation cell lb.

The flotation line 8 may be preceded by other processes 5 such as grinding, classification, screening, heavy-medium process, coarse particle recovery process, spirals, and other separation processes; and other flotation processes. A number of processes may follow the flotation line 8, such as regrinding, cleaner or other flotation processes, centrifuging, filtering, 10 screening or dewatering.

According to a further aspect of the invention, the flotation line 8 may be used in recovering particles comprising a valuable material suspended in slurry. In an embodiment, the use may be directed to recovering particles comprising nonpolar 15 minerals such as graphite, sulphur, molybdenite, coal, talc.

According to another embodiment, the use may be directed to recovering particles comprising polar minerals.

In a further embodiment, the use is directed to recovering particles from minerals having a Mohs hardness of 2 20 to 3, such as galena, sulfide minerals, PGMs, REO minerals. In a yet further embodiment, the use is specifically directed to recovering particles comprising platinum.

In a further embodiment, the use is directed to recovering particles comprising copper from mineral particles 25 having a Mohs hardness of 3 to 4. In a yet further embodiment, the use is specifically directed to recovering particles comprising copper from low grade ore.

The embodiments described hereinbefore may be used in any combination with each other. Several of the embodiments may 30 be combined together to form a further embodiment. A flotation cell to which the disclosure is related, may comprise at least one of the embodiments described hereinbefore. It is obvious to a person skilled in the art that with the advancement of technology, the basic idea of the invention may be implemented 35 in various ways. The invention and its embodiments are thus not limited to the examples described above; instead they may vary within the scope of the claims.

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In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary implication, the word comprise or variations such as comprises or comprising is used in an inclusive sense,

i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the invention.

Claims

1. A flotation cell for treating particles suspended in slurry and for separating the slurry into an underflow and an overflow, the flotation cell comprising

5 a flotation tank comprising a centre, a perimeter, a substantially horizontal level bottom, and a side wall;

a launder and a launder lip surrounding the perimeter of the tank; and a bottom structure arranged on the bottom, and having 10 a shape that allows particles suspended in slurry to be mixed in a mixing zone over the bottom structure, and to settle down in a settling zone surrounding the bottom structure, wherein the flotation tank further comprises blast tubes for introducing flurry infeed into the tank, a blast tube 15 comprising an inlet nozzle for feeding slurry infeed into the blast tube ;

an inlet for pressurized gas, the slurry infeed subjected to the pressurized gas as it is discharged from the 20 inlet nozzle;

an elongated chamber arranged to receive under pressure the slurry infeed;

an outlet nozzle configured to restrict flow of slurry infeed from the outlet nozzle, and to maintain slurry infeed in 25 the elongated chamber under pressure; and in that the blast tubes are disposed at a position relative to the bottom structure so as to induce mixing at the mixing zone.

2. The flotation cell according to claim 1, wherein

30 the outlet nozzle is configured to produce a supersonic shockwave into the slurry infeed, the supersonic shockwave inducing formation of flotation gas bubble - particle agglomerates.

3. The flotation cell according to claim 1 or 2,

35 wherein a height of the flotation tank, measured as the distance from the bottom of the flotation tank to the launder

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2019100825 29 Jul 2019 lip, at the perimeter of the flotation tank is at most 20 % lower than at the centre of the flotation tank.

4 . The flotation cell according to any one of claims 1

5 to 3, wherein the vertical cross-section of the bottom structure is a functional triangle comprising a first vertex pointing away from the bottom of the flotation tank, a second vertex and a third vertex; a first side between the first vertex and the second vertex; a second side between the first vertex 10 and the third vertex; and a base between the second and third vertexes on the bottom of the flotation tank; and a central axis substantially concentric with the centre of the flotation tank.

5. The flotation cell according to any one of claims 1 15 to 4, wherein a height of the bottom structure is greater than 1/5 and less than 3/4 of a height of the flotation tank, measured as the distance from the bottom to the launder lip.