AU2017413373B2 - Method and device for bioremediation of water body - Google Patents

Method and device for bioremediation of water body Download PDF

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Publication number
AU2017413373B2
AU2017413373B2 AU2017413373A AU2017413373A AU2017413373B2 AU 2017413373 B2 AU2017413373 B2 AU 2017413373B2 AU 2017413373 A AU2017413373 A AU 2017413373A AU 2017413373 A AU2017413373 A AU 2017413373A AU 2017413373 B2 AU2017413373 B2 AU 2017413373B2
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water body
bioremediation
water
oxygenation
micro
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AU2017413373A1 (en
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Lirong LEI
Guangsheng LI
Youming Li
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Liuwu Environmental Protection Technology Guangzhou Co Ltd
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Liuwu Environmental Protection Technology Guangzhou Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/348Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the way or the form in which the microorganisms are added or dosed
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

Provided is a water body bioremediation device, comprising a micro-pore aeration oxygen enrichment system, a carbon fiber ecological base (3), a compound micro-organism generating device (4), a circular fluidization activating and flushing system, and a case, wherein the micro-pore aeration oxygen enrichment system is composed of a vortex blower (7), a micro-pore tubular aerator (2) or an aeration oxygen enrichment grid, and a micro-pore aeration tube (5); and the case is divided into four regions from bottom to top, and is sequentially provided with the micro-pore tubular aerator (2) or the aeration oxygen enrichment grid, the carbon fiber ecological base (3), the compound micro-organism generating device (4), and the circular fluidization activating and flushing system. Further provided is a water body bioremediation method. The device is placed in a polluted water body of a river or a lake, and carries out bioremediation on black and odorous water bodies by using the natural water suction in an aeration and water flow direction; or the device is placed on the shore of a piece of land and carries out bioremediation by using a pump to suck up the black and odorous water body.

Description

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Method and device for bioremediation of water body
Field of invention
The invention relates to a method and device for bioremediation of
water body.
Background art
With the rapid development of economy, a large amount of industrial,
domestic and agricultural sewage are discharged, and various pollutants
flow into water body resulting from atmospheric deposition, precipitation
and run-off to cause pollution. The excessive nitrogen, phosphorus and
heavy metals in rivers and lakes lead to proliferation of algae, and the
original ecological balance and structure of water bodies are destroyed. In
recent years, cyanobacteria bloom frequently occurring in inland and
offshore of China is an ecological disaster caused by eutrophication of
water bodies caused by due to pollutant discharge. As a result, water
quality decreases, water becomes black and smelly, dissolved oxygen
exhausts, transparency lowers, fish die, humans and animals are toxicated,
leading to extremely serious environmental pollution problems.
Chinese Patent Application No. 201010539843.0 discloses a method and
system for remediation and treatment of polluted river body, while
Chinese Patent Application No. 201310006749.2 discloses a polluted
water body treatment system and a construction method thereof, both of
which deals with water pollution by conventional sewage treatment methods with large workload, low efficiency and high cost.
Summary of invention
In order to solve the shortcomings and deficiencies of the prior art, a
primary object of the present invention is to provide a device for
bioremediation of water body, which can rapidly improve the microbial
ecological environment of water body. The device is suitable for
remediation of black and odorous rivers and lakes, as well as oxygenation
and activation of aquaculture waters. It is also suitable for treating
industrial sewage, aerating and oxygenating urban domestic sewage, and
improving aeration of rivers and lakes.
Another object of the present invention is to provide a method for
bioremediation of water body. The method constructs a high biomass
biofilter composed of a microporous aeration and oxygenation system, a
carbon fiber ecological base, and a composite microbial generating device,
so as to rapidly increase dissolved oxygen content in water body, generate
high content biomass, agitate precipitated sludge and organic pollutants at
the bottom of rivers and lakes, allow rapid degradation, nitrification, and
ammoniation of organic matter, improve water quality, prohibit and
eliminate environmental conditions suitable for excessive proliferation of
cyanobacteria, achieve an effect of improving and remediating water
ecology, and recover self-purification function of water bodies.
The objects of the invention are achieved by the following technical solutions:
A water body bioremediation device comprises a microporous
aeration and oxygenation system, a carbon fiber ecological base, a
composite microbial generating device, a circulating fluidization and
activation flushing system, and a tank; wherein the microporous aeration
and oxygenation system consists of a vortex blower, a microporous
tubular aerator or an aerating oxygenation grid, and a microporous
aeration tube; the tank is divided into four regions from bottom to top and
is sequentially provided with the microporous tubular aerator or the
aerating oxygenation grid, the carbon fiber ecological base, the composite
microbial generating device, and the circulating fluidization and
activation flushing system; and wherein the vortex blower is disposed
outside the tank and is connected with the microporous tubular aerator or
the aerating oxygenation grid and the microporous aeration tube, the
microporous aeration tube being disposed in the region of the composite
microbial generating device.
The microporous aeration and oxygenation system consists of a
vortex blower, a microporous tubular aerator or an aerating oxygenation
grid (10 tubes for each grid, but the choice is not limited thereto), and a
microporous aeration tube. A membrane in the microporous tubular
aerator has a pore size of 80-100pm.
The composite microbial generating device is mainly composed of a porous cylindrical stainless steel tube or a porous sintered ceramic tube, a micro oxygenation tube, immobilized microorganism and a filter bed.
The filter bed consists of one or more of natural zeolite, ceramsite
and volcanic rock; the immobilized microorganism is one or more of
photosynthetic bacteria, Thiobacillus, actinomycetes, lactic acid bacteria,
yeast, Bacillus, denitrifying bacteria and nitrifying bacteria.
The carbon fiber ecological base has a specific surface area of
10003000 m2/g. The selected carbon fiber ecological base readily
forms a microbial film which may also easily fall off, the material thereof
is stable, acid and base resistant, anti-aging, and large in specific surface
area.
The circulating fluidization and activation flushing system
comprises a micro-circulating pump. The functions of the circulating
fluidization and activation flushing system are: firstly, to activate the
indigenous bacteria, accelerate water flow, increase dissolved oxygen
content of water body, activate the water body, reduce the loss and
consumption of the composite microorganisms; secondly, to inoculate and
proliferate the bacteria to keep the water body biologically balanced;
thirdly, to promote circulation and fluidization, so that the filter material
is loose and does not easily stuck the device.
The water body bioremediation device is further provided with a
floating body. The floating body which is a high-density foam rubber is optional according to practical use. The height of the water body bioremediation device in the polluted water body may be adjusted according to the water depth, and the floating body is usually placed outside the tank.
The biological filter, i.e., the tank, needs to be anti-corrosive, and
may be made by materials such as FRP for anti-corrosion or
corrosion-resistant stainless steel.
A lower part of the tank is provided with a polluted water inlet, and
an upper part of the tank is provided with a purified water outlet, wherein
the position of the polluted water inlet is higher than that of the
microporous tubular aerator or the aerating oxygenation grid, and the
position of the purified water outlet is higher than that of the composite
microbial generating device.
A method for bioremediation of water body comprises:
introducing water to be treated (polluted water) into a water body
bioremediation device, and increasing dissolved oxygen in the water body
by a microporous aeration and oxygenation system, wherein the dissolved
oxygen content is adjusted to be >2 mg/L, preferably 2.0 - 4.0 mg/L, so
as to allow steady degradation, nitrification, and ammoniation of organic
matter in the polluted water;
introducing the aerated and activated water body upward through a
carbon fiber ecological base to form a biofilm on the carbon fiber ecological base, so as to optimize the indigenous bacteria, keep in constant contact with the substrate in the polluted water, and purify the polluted water by absorption, mass transfer, metabolism and the like; then introducing the water body treated by biofilm on the carbon fiber ecological base to a composite microbial generating device to convert the organic macromolecules in the water body to soluble organic micromolecules, and activating indigenous bacteria through a circulating fluidization and activation flushing system, so as to effectively adsorb, transform and degrade nitrogen and phosphorus in the water body by microbials, inhibit reproduction of algae, and achieve bioremediation of the water body.
The method maintains the pH of the water body in a range of
equivalent to or larger than 7, and the temperature of the water body in a
range of 20-35°C during treatment.
The principle of the invention is as follows: dissolved oxygen
content in eutrophicated, smelly water body is increased through
microporous aeration, oxygenation and activation, and aerobic
microorganisms are activated, so as to allow steady degradation,
nitrification, and ammoniation of organic matter in the polluted water.
The polluted water enters the bioremediation device and is activated by
microporous aeration and oxygenation. Then through the carbon fiber
ecological base and the composite microbial generating device, macromolecular organic matter in the polluted water may be transformed into soluble organic small molecule by extracellular enzyme. The organic small molecules undergo primary decomposition and are absorbed and degraded through enzymatic reaction; the circulating fluidization and activation flushing system activates indigenous bacteria, accelerates the proliferation and reproduction thereof, utilizes the microorganisms to effectively adsorb, transform and degrade nitrogen and phosphorus in water, inhibits algae reproduction, biologically strengthen the self-cleaning function of the water body and maintain ecological balance.
Compared with the prior art, the present invention has the following
advantages and beneficial effects:
The water body bioremediation device of the invention can be
placed in a polluted river or lake, and water may be introduced naturally
along the direction of the aerated water flow to carry out bioremediation
of the black and odorous water body; or it may be placed on a shore and
suck the black and odorous water in for bioremediation by a pump.
Brief description of the drawings
Fig. 1 is a structural diagram of a water body bioremediation device
according to the present invention, wherein: 1-polluted water inlet,
2-microporous tubular aerator, 3-carbon fiber ecological base,
4-composite microbial generating device, 5-microporous aeration tube,
6-purified water outlet, 7-vortex blower, 8-micro-circulating pump,
9-floating body.
Detailed description of the embodiments
The present invention will be further described in detail below with
reference to the embodiments and drawings, but the embodiments of the
present invention are not limited thereto.
A water body bioremediation device as shown in Fig. 1 comprises a
microporous aeration and oxygenation system, a carbon fiber ecological
base 3, a composite microbial generating device 4, a circulating
fluidization and activation flushing system, and a tank; wherein the
microporous aeration and oxygenation system consists of a vortex blower
7, a microporous tubular aerator 2, and a microporous aeration tube 5; the
tank is divided into four regions from bottom to top and is sequentially
provided with the microporous tubular aerator 2, the carbon fiber
ecological base 3, the composite microbial generating device 4, and the
circulating fluidization and activation flushing system; and wherein the
vortex blower 7 is disposed outside the tank and is connected with the
microporous tubular aerator 2 and the microporous aeration tube 5, the
microporous aeration tube 5 being disposed in the region of the
composite microbial generating device.
A membrane in the microporous tubular aerator has a pore size of
-100 pm. Regarding the microporous aeration, the dissolved oxygen
content is adjusted to be 2.0 - 4.0 mg/L.
The composite microbial generating device 4 is mainly composed of
a porous cylindrical stainless steel tube or a porous sintered ceramic tube,
a micro oxygenation tube, immobilized microorganism and a filter bed.
The filter bed consists of one or more of natural zeolite, ceramsite
and volcanic rock; the immobilized microorganism is one or more of
photosynthetic bacteria, Thiobacillus, actinomycetes, lactic acid bacteria,
yeast, Bacillus, denitrifying bacteria and nitrifying bacteria.
The carbon fiber ecological base 3 has a specific surface area of
1000-3000 m2g.
The circulating fluidization and activation flushing system
comprises a micro-circulating pump 8.
The water body bioremediation device is further provided with a
floating body. The floating body which is a high-density foam rubber is
optional according to practical use. The height of the water body
bioremediation device in the polluted water body may be adjusted
according to the water depth, and the floating body is usually placed
outside the tank.
The tank needs to be anti-corrosive, and may be made by materials
such as FRP for anti-corrosion or corrosion-resistant stainless steel.
A lower part of the tank is provided with a polluted water inlet 1,
and an upper part of the tank is provided with a purified water outlet 6,
wherein the position of the polluted water inlet is higher than that of the microporous tubular aerator or the aerating oxygenation grid, and the position of the purified water outlet is higher than that of the composite microbial generating device.
Example 1
Two water bioremediation devices as described in Fig. 1 were used,
with a power of 0.85 kW and an oxygenation capacity of 1.2 to 3 kg to
remediate water body of a fish pond. The water body bioremediation
devices have a volume of 1m 3. The devices were placed on the bank of a
mu water body. With a water pump to draw water, after 2 months of
treatment, the ammonia nitrogen and nitrite content were decreased by 75%
and 91.7%, respectively, and the dissolved oxygen content of the water
body DO>4 mg/L. The pH values, ammonia nitrogen and nitrite contents
of the water body before and after treatment are shown in Table 1. The
main component of the filter material used in the example is natural
zeolites of 100 mesh to 200 mesh, and the immobilized microorganism is
mainly composed of photosynthetic bacteria, nitrifying bacteria, lactic
acid bacteria, and sulfur bacteria.
Table 1. pH values, ammonia nitrogen and nitrite contents of the
water body before and after treatment (unit: mg/L)
Items pH ammonia nitrogen nitrite
Before treated 8.3 0.4 0.6
Treated after 2 months 8.1 0.1 0.05
Example 2
Two water bioremediation devices as described in Fig. 1 were used,
with a power of 2.2 kW and an oxygenation capacity of 4.5 to 14 kg to
remediate a black and smelly ditch having a width of 6m, a length of
500m and a depth of 0.8-1.2m. The water body bioremediation devices
have a volume of 4m 3 . After 1 month of treatment, the water body has a
transparency larger than 25cm, an ammonia nitrogen and nitrite content
decreased by 75% and 91.7%, respectively, and a dissolved oxygen
content DO>4 mg/L. The BOD5 , CODcr, SS, NH 3-N, TN, and TP contents
of the water body before and after treatment are shown in Table 1. The
main component of the filter material used in the example is natural
zeolites and volcanic rock of 30 mesh to 80 mesh, and the immobilized
microorganism is composed of Photosynthetic bacteria, Thiobacillus,
nitrifying bacteria, denitrifying bacteria, yeast, and Bacillus.
Table 2. The BOD5 , CODcr, SS, NH 3-N, TN, and TP contents of the
water body before and after treatment (unit: mg/L)
Name BOD 5 CODer SS NH 3-N TN TP
Original water ( mg/L) 75 156 43 34.8 44.4 2.6
Water after 3 months of 12.2 31.2 20 2.6 11.2 0.6 treatment ( mg/L )
The above embodiments are preferred embodiments of the present
invention, but the embodiments of the present invention are not limited to the above embodiments, and any other changes, modifications, substitutions, combinations, and simplifications made without departing from the spirit and scope of the invention should all be equivalent replacements and be included in the scope of the present invention.
It will be understood that the term "comprise" and any of its
derivatives (eg comprises, comprising) as used in this specification is to
be taken to be inclusive of features to which it refers, and is not meant to
exclude the presence of any additional features unless otherwise stated or
implied.
The reference to any prior art in this specification is not, and should
not be taken as, an acknowledgement or any form of suggestion that such
prior art forms part of the common general knowledge.

Claims (9)

Claims
1. A water body bioremediation device, characterized by comprising:
a microporous aeration and oxygenation system, a carbon fiber ecological
base, a composite microbial generating device, a circulating fluidization
and activation flushing system, and a tank; wherein the microporous
aeration and oxygenation system consists of a vortex blower, a
microporous tubular aerator or an aerating oxygenation grid, and a
microporous aeration tube; the tank is divided into four regions from
bottom to top and is sequentially provided with the microporous tubular
aerator or the aerating oxygenation grid, the carbon fiber ecological base,
the composite microbial generating device, and the circulating fluidization
and activation flushing system; and wherein the vortex blower is disposed
outside the tank and is connected with the microporous tubular aerator or
the aerating oxygenation grid, and the microporous aeration tube, the
microporous aeration tube being disposed in the region of the composite
microbial generating device;
wherein the composite microbial generating device is mainly
composed of a porous cylindrical stainless steel tube or a porous sintered
ceramic tube, a micro oxygenation tube, immobilized microorganism and
a filter bed.
2. The water body bioremediation device according to claim 1, characterized in that, a membrane in the microporous tubular aerator has a pore size of 80-100 pm.
3. The water body bioremediation device according to claim 1,
characterized in that, the filter bed consists of one or more of natural
zeolite, ceramsite and volcanic rock; the immobilized microorganism is
one or more of photosynthetic bacteria, Thiobacillus, actinomycetes, lactic
acid bacteria, yeast, Bacillus, denitrifying bacteria and nitrifying bacteria.
4. The water body bioremediation device according to claim 1,
characterized in that, the carbon fiber ecological base has a specific
surface area of 1000-3000 m 2/g.
5. The water body bioremediation device according to claim 1,
characterized in that, the circulating fluidization and activation flushing
system comprises a micro-circulating pump.
6. The water body bioremediation device according to claim 1,
characterized in that, the water body bioremediation device is further
provided with a floating body.
7. The water body bioremediation device according to claim 1,
characterized in that, a lower part of the tank is provided with a polluted
water inlet, and an upper part of the tank is provided with a purified water
outlet, wherein the position of the polluted water inlet is higher than that
of the microporous tubular aerator or the aerating oxygenation grid, and
the position of the purified water outlet is higher than that of the composite microbial generating device.
8. A method for bioremediation of water body, characterized by
comprising:
introducing water to be treated into a water body bioremediation
device, and increasing dissolved oxygen in the water body by a
microporous aeration and oxygenation system, wherein the dissolved
oxygen content is adjusted to be >2 mg/L;
introducing the aerated and activated water body upward through a
carbon fiber ecological base to form a biofilm on the carbon fiber
ecological base; then introducing the water body treated by biofilm on the
carbon fiber ecological base to a composite microbial generating device to
convert the organic macromolecules in the water body to soluble organic
micromolecules, and activating indigenous bacteria through a circulating
fluidization and activation flushing system, so as to effectively adsorb,
transform and degrade nitrogen and phosphorus in the water body by
microbials, inhibit reproduction of algae, and achieve bioremediation of
the water body;
wherein the composite microbial generating device is mainly
composed of a porous cylindrical stainless steel tube or a porous sintered
ceramic tube, a micro oxygenation tube, immobilized microorganism and
a filter bed.
9. The method for bioremediation of water body according to claim
8, characterized in that, the method maintains the pH of the water body in
a range of equivalent to or larger than 7, and the temperature of the water
body in a range of 20-35°C during treatment.
AU2017413373A 2017-05-08 2017-11-30 Method and device for bioremediation of water body Active AU2017413373B2 (en)

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CN201710317496.9 2017-05-08
CN201710317496.9A CN107055753A (en) 2017-05-08 2017-05-08 A kind of method and device of bioremediation of waters
PCT/CN2017/113881 WO2018205566A1 (en) 2017-05-08 2017-11-30 Water body bioremediation method and device

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