AU2013360529B2 - Catalyst for manufacturing synthetic gas through steam-carbon dioxide reforming, and method for manufacturing synthetic gas by using same - Google Patents

Catalyst for manufacturing synthetic gas through steam-carbon dioxide reforming, and method for manufacturing synthetic gas by using same

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Publication number
AU2013360529B2
AU2013360529B2 AU2013360529A AU2013360529A AU2013360529B2 AU 2013360529 B2 AU2013360529 B2 AU 2013360529B2 AU 2013360529 A AU2013360529 A AU 2013360529A AU 2013360529 A AU2013360529 A AU 2013360529A AU 2013360529 B2 AU2013360529 B2 AU 2013360529B2
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AU
Australia
Prior art keywords
synthetic gas
catalyst
carbon dioxide
manufacturing synthetic
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
AU2013360529A
Other versions
AU2013360529A1 (en
Inventor
Jongtae CHUNG
Jihye Lee
Yonggi MO
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Gas Corp
Original Assignee
Korea Gas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Korea Gas Corp filed Critical Korea Gas Corp
Publication of AU2013360529A1 publication Critical patent/AU2013360529A1/en
Application granted granted Critical
Publication of AU2013360529B2 publication Critical patent/AU2013360529B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The present invention relates to a catalyst for manufacturing a synthetic gas from a natural gas by using carbon dioxide, and more specifically, to a catalyst useful for manufacturing a synthetic gas by means of steam-carbon dioxide reforming. The catalyst according to the present invention is manufactured by a method comprising the steps of: 1) manufacturing a zirconia and alumina support coated with cerium by using dry mixing; 2) preparing nickel and magnesium oxide powders; and 3) mixing and firing a powder of the support in step 1) and powders of metals in step 2). The ratio of hydrogen to carbon monoxide in the synthetic gas, which is manufactured by using the catalyst according to the present invention, can be controlled to 2.0±0.2, thereby easily providing the synthetic gas which is efficient for producing synthetic petrochemical products (such as wax, naphtha, and diesel).
AU2013360529A 2012-12-12 2013-12-12 Catalyst for manufacturing synthetic gas through steam-carbon dioxide reforming, and method for manufacturing synthetic gas by using same Active AU2013360529B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR20120144029A KR101421825B1 (en) 2012-12-12 2012-12-12 Catalysts for preparing syn-gas by steam-carbon dioxide reforming reaction and process for preparing syn-gas using same
KR10-2012-0144029 2012-12-12
PCT/KR2013/011516 WO2014092474A1 (en) 2012-12-12 2013-12-12 Catalyst for manufacturing synthetic gas through steam-carbon dioxide reforming, and method for manufacturing synthetic gas by using same

Publications (2)

Publication Number Publication Date
AU2013360529A1 AU2013360529A1 (en) 2015-07-16
AU2013360529B2 true AU2013360529B2 (en) 2016-09-22

Family

ID=50934672

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2013360529A Active AU2013360529B2 (en) 2012-12-12 2013-12-12 Catalyst for manufacturing synthetic gas through steam-carbon dioxide reforming, and method for manufacturing synthetic gas by using same

Country Status (5)

Country Link
KR (1) KR101421825B1 (en)
CN (1) CN104955570B (en)
AU (1) AU2013360529B2 (en)
MY (1) MY172598A (en)
WO (1) WO2014092474A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105944733B (en) * 2016-05-12 2019-04-16 中国科学院福建物质结构研究所 A kind of rare earth modified multi-stage porous loading type nickel-based catalyst, preparation method and application
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas
CN107098312B (en) * 2017-05-05 2021-04-13 湖南大学 Method for preparing synthesis gas by using flue gas
WO2020053715A1 (en) * 2018-09-12 2020-03-19 Sabic Global Technologies B.V. Bi-reforming of hydrocarbons to produce synthesis gas
CN110589765A (en) * 2019-10-09 2019-12-20 中石化南京工程有限公司 Method and system for preparing synthesis gas in different proportions by using natural gas
KR102540205B1 (en) * 2022-11-04 2023-06-09 (주)바이오프랜즈 Method for converting carbon dioxide of fuel gas to carbon monodioxide, Dimethyl ether production system using flue gas of cement kiln boiler using ths same and Manufacturing method of dimethyl ether using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100892033B1 (en) * 2007-10-08 2009-04-07 한국에너지기술연구원 High surface area spinel structured nano crystalline sized ymgo (1-y) al2o3-supported nano-sized nickel reforming catalysts and their use for producing synthesis gas from combined steam and carbon dioxide reforming of natural gas
KR100991263B1 (en) * 2008-08-01 2010-11-01 현대중공업 주식회사 Nickel based Catalyst for reforming of natural gas with mixture of steam and carbon dioxide

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3505236B2 (en) * 1994-10-05 2004-03-08 株式会社三徳 Composite oxide having oxygen absorbing / releasing ability and method for producing the same
US20050096215A1 (en) * 2003-10-31 2005-05-05 Conocophillips Company Process for producing synthesis gas using stabilized composite catalyst
KR100732784B1 (en) * 2005-06-17 2007-06-27 한국가스공사 Process for the production of dimethylether from hydrocarbon

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100892033B1 (en) * 2007-10-08 2009-04-07 한국에너지기술연구원 High surface area spinel structured nano crystalline sized ymgo (1-y) al2o3-supported nano-sized nickel reforming catalysts and their use for producing synthesis gas from combined steam and carbon dioxide reforming of natural gas
KR100991263B1 (en) * 2008-08-01 2010-11-01 현대중공업 주식회사 Nickel based Catalyst for reforming of natural gas with mixture of steam and carbon dioxide

Also Published As

Publication number Publication date
KR20140075996A (en) 2014-06-20
CN104955570B (en) 2017-06-13
AU2013360529A1 (en) 2015-07-16
CN104955570A (en) 2015-09-30
MY172598A (en) 2019-12-04
KR101421825B1 (en) 2014-07-22
WO2014092474A1 (en) 2014-06-19

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