AU2003200405B9

AU2003200405B9 - Nonwoven Fabric for Wiper

Info

Publication number: AU2003200405B9
Application number: AU2003200405A
Authority: AU
Inventors: Sumito Kiyooka; Hidetoshi Moriyasu; Masako Yokomizo
Original assignee: Kuraray Co Ltd
Current assignee: Kuraray Co Ltd
Priority date: 2002-02-08
Filing date: 2003-02-04
Publication date: 2007-03-15
Anticipated expiration: 2023-02-04
Also published as: KR20030068043A; JP2003301359A; SG128436A1; KR100494211B1; AU2003200405A1; US20030176132A1; TWI229158B; AU2003200405B2; CN1436886B; EP1342825B2; EP1342825B1; DE60304615T3; CN1436886A; EP1342825A1; DE60304615D1; JP4597487B2; DE60304615T2; TW200303384A

Description

S&F Ref: 623815

AUSTRALIA

PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT

ORIGINAL

Name and Address of Applicant: Actual Inventor(s): Address for Service: Invention Title: Kuraray Co., Ltd.

1621, Sakazu, Kurashiki-City Okayama-Pref.

Japan Hidetoshi Moriyasu Masako Yokomizo Sumito Kiyooka Spruson Ferguson St Martins Tower,Level 31 Market Street Sydney NSW 2000 (CCN 3710000177) Nonwoven Fabric for Wiper The following statement is a full description of this invention, including the best method of performing it known to me/us:- IP Australia

C,

Documents were received on: 0 t FEB 2003 Batch No: 5845c NONWOVEN FABRIC FOR WIPER BACKGROUND OF THE INVENTION Field of the Invention: The present invention relates to a nonwoven fabric for wipers, more precisely to that for wipers which has the ability to wipe off even oily stains and caked persistent stains, not so much fluffing even when used repeatedly, and of which the washing resistance is good.

Description of the Related Art: (0 Various nonwoven fabric wipers of extra-fine fibers have been proposed and are now widely used. For example, a wiping material is proposed, which is produced by hydroentangling and integrating heat-fusing fiber webs and extra-fine fiber webs followed by fusing the thus-entangled, heat-fusing fibers (JP-A 3-152255). The wiping material of the type may wipe off light dirt such as dust or the like but could not remove cakedpersistent stains. Anotherproblemwithit isthat,whenthewipingmaterial is washed, its surface often fluffs up and some fibers often drop away from it. Still another problem is that it is not AO flexible.

Disclosed is a nonwoven fabric for wipers, which includes mechanically divided extra-fine fibers and is bulky and of which the wiping performance and the long-term durability are good (JP-A 5-56903). The nonwoven fabric for wipers of the type is good for wiping off dust and the like but is still unsatisfactory for removing persistent stains.

On the other hand, a nonwoven fabric for wipers is proposed, which comprises Smixed fibres of extra-fine fibres and thick fibres for improving its ability to remove caked stains (JP-A 6-14860). Also proposed is a wiper produced by laminating and entangling t spunlaid webs and paper sheets for improving its washing resistance (JP-A 7-67820).

However, these wipers have a tough feel and are not flexible, and therefore they are not satisfactorily effective for wiping articles having a three-dimensionally patterned face.

As mentioned above, the current situation in the art is that no one has proposed as yet a nonwoven fabric for wipers which has the ability to wipe off even oily stains and caked persistent stains and has good washing resistance.

US-A-2001/037850, WO 96/41041, US-5,993,943, EP-A-1 175 863 and US- 4,525,411, each disclose nonwoven fabrics having bonded regions in accordance with the first part of present claim 1. In these prior art documents, the bonded regions are preferably formed by thermal bonding.

SUMMARY OF THE INVENTION The present invention is to solve the problems noted above, and its object is to provide a nonwoven fabric for wipers which has the ability to well wipe off even oily stains and caked persistent stains, capable of exhibiting its excellent cleaning capabilities in accordance with three-dimensionally patterned faces of the articles to be wiped, and which has good flexibility and good washing resistance.

Specifically, the invention is a nonwoven fabric for wipers which contains extrafine fibres having a single fibre fineness of 0.5 dtex or less comprising, linear and/or dotlike bonded regions and non-bonded regions on its surface, the bonded regions account for from 10 to 80% of the surface area of the nonwoven fabric, the distance between the neighboring bonded regions is at most 20mm, and the bonded regions are formed by an acrylic resin binder.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows some examples of the pattern of the gravure roll that may be used in the invention.

Fig. 2 shows one example of the surface of the nonwoven fabric of the invention.

[R:\IBF3FJ I13466.doc hjg DESCRIPTION OF THE PREFERRED EMBODIMENTS The nonwoven fabric for wipers of the invention contains extra-fine fibers and is Scharacterized in that its surface comprises linear and/or dot-like bonded regions and nonbonded regions. Having the bonded regions and the non-bonded regions in its surface, the nonwoven fabric of the invention has good cleaning capabilities of removing not only Slight dirt such as oily film or ink stains but also heavy dirt such as caked persistent stains, not giving so much fluff, and it is washable for repeated use.

The single fiber fineness of the extra-fine fibers for use in the nonwoven fabric of Cthe invention is at most 0.5 dtex, preferably from 0.05 to 0.04 dtex. The 0", [R:\L13FFj I 3466.doc:hjg extra-fine fibers of the type may be, for example, direct spun fibers or those obtained from splittable conjugated fibers. For the extra-fine fibers for use in the invention, preferred are splittable conjugated fibers. Especially preferably, the 4' extra-fine fibers are prepared by dividing splittable conjugated fibers each having a nearly circular cross-sectional profile.

This is because the cross-sectional profile of the extra-fine fibers derived from the splittable conjugated fibers of the type may have sharp shapes, and therefore, the nonwoven fabric that 1 0 contains the extra-fine fibers of the type is favorable for removing oily stains. Such splittable conjugated fibers may be mechanically processed by hydroentangling or by needlepunching or may be chemically processed for dissolution and removal or for swelling and shrinkage to give the extra-fine 14 fibers for use in the invention.

The splittable conjugated fibers for the invention may be formed of at least two different types of resin. The resin includes, for example, polyester polymers, polyolef in polymers, polyamide polymers, polystyrene polymers, polyacrylonitrile 1o polymers, polyvinyl alcohol polymers, and ethylene-vinyl alcohol copolymers. One or more such polymers may be used for one component of the fibers, but these are not limitative.

The polyesters may be fiber-forming polyesters, which are formed of, for example, aromatic dicarboxylic acids such as Ar terephthalic acid, isophthalic acid, naphthalene-2,6-dicarboxylic acid, phthalic acid, a,3-(4-carboxyphenoxy)ethane, 4,4-dicarboxydiphenyl, sulfoisophthalate; or aliphatic dicarboxylic acids such as azelaic acid, adipic acid, sebacic acid; or their esters; S and diols such as ethylene glycol, diethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,6-hexanediol, neopentyl glycol, cyclohexane-1,4-dimethanol, polyethylene glycol, polytetramethylene glycol. Preferably, at least 80 mol% of the constituent units of the polyesters are ethylene terephthalate Jo units.

The polyamides include, for example, aliphatic polyamides and semiaromatic polyamides of which the principal component is nylon 6, nylon 66 or nylon 12. They may contain a minor amount of a third component.

The conjugation morphology of these resin components to give the conjugated fibers is not specifically defined. For example, two resin components may be conjugated into bicomponent fibers having a chrysanthemum-patterned cross-sectional profile in which the two resin components are alternately radially aligned; into those having a bimetal-patterned cross-sectional profile in which the two resin components are alternately layered; or into those having a sea/island patterned cross-sectional profile in which islands of one resin component are dispersed in a sea matrix of the other resin component. Of v the splittable conjugated fibers of those types, chrysanthemum-patterned fibers and bimetal-patterned fibers are preferred for use herein, since the extra-fine fibers derived from them may have a sharp cross-sectional profile and Stherefore they are more effective for wiping off stains, especially for wiping off oily stains.

According to an example useful to understand the invention, heat-fusing fibers are t used. Containing heat-fusing fibers, the shape stability of the nonwoven fabric for wipers is improved. Preferably, the proportion of the extra-fine fibres in the nonwoven fabric that contain heat-fusing fibres is at least 50%. If it is smaller than 50%, the wiping Cc capability of the nonwoven fabric will worsen. Especially when the nonwoven fabric is used for wiping off oily stains, the proportion of the splittable conjugated fibres therein is at least 80%. In this, the heat-fusing fibres may be those of a single component, but are preferably side-by-side type or core-sheath type heat-fusing conjugated fibres of at least two resin components including those not fusing in heat treatment, since the non-fusing part of the fibres acts to retain the fibre strength. Regarding the melting point of the is fusing components of the fibres, it is desirable that the melting point difference between the extra-fine fibres and the heat-fusing fibres that constitute the nonwoven fabric is at least 10°C in order that the extra-fine fibres do not fuse with the heat-fusing fibres.

For the component for the heat-fusing fibres, various I R:\IIBFFJ 13466.doc:hjg combinations may be mentioned, including, for example, 6-nylon/polyethylene, polypropylene/polyethylene, polypropylene/ethylene-vinyl acetate copolymer, polyester/polypropylene, polyester/polyethylene, 6-nylon/66-nylon, and high-density polyester/low-density polyester, but these are not limitative.

The nonwoven fabric for wipers of the invention contains the extra-fine fibers mentioned above. For realizing excellent oil-removing capabilities and flexibility thereof, it is more t0 desirable that the nonwoven fabric is composed of 100% extra-fine fibers. The other fibers thatmaybe combinedwith the extra-fine fibers in the invention are not specifically defined, and may be any of various natural fibers and synthetic fibers.

The method of producing the nonwoven fabric for wipers of the invention is not specifically defined. For example, it may be formed of fiber webs that are prepared according to drylaying of carding, air-laying, spun-bonding or to wetlaying.

The fiber webs are preferably random-laid webs, semirandom-laid webs or parallel-laid webs.

^A In the invention, it is especially preferable that the fiber webs are formed by mixing various fibers such as extra-fine fibers and heat-fusing fibers mentioned above followed by processing them into fiber webs according to a carding process or an air-laying process.

In case where the extra-fine fibers are derived from splittable conjugated fibers by mechanically dividing them, the splittable conjugated fibers may be processed into the intended extra-fine fibers before they are formed into fiber webs, but it is desirable that the splittable conjugated fibers are formed 4 into fiber webs and, after the resulting fiber webs are layered, they are mechanically processed by needle-punching or water-jet treatment whereby the splittable conjugated fibers in the layered webs are divided to give the intended extra-fine fibers therein and the resulting extra-fine fibers are entangled at the same time through the treatment. In this process, the fiber-to-fiber bonding in the nonwoven fabric produced may be more strengthened.

The nonwoven fabric for wipers of the invention has, in its surface, linearand/ordot-likebondedregions andnon-bonded regions, and therefore has the ability to wipe off various dirt.

Specifically, the non-bonded regions of the nonwoven fabric act to wipe off light dirt such as oily stains, and the bonded regions thereof act to wipe off caked persistent stains. Therefore, the nonwoven fabric exhibits its ability to wipe off various types of dirt. In the bonded regions, the fibers are partly fixed and are harder than those in the non-bonded regions.

Therefore, the fibers in these regions are more effective for wiping off persistent stains. In addition, the bonded regions enhance the wiping performance with the nonwoven fabric. This is because, as having the fixed and toughened, bonded regions, M the nonwoven fabric is, as a whole, toughened in some degree and it well fits to the hand .while used for wiping operation.

In addition, the nonwoven fabric also has the non-bonded regions and it keeps its softness. Accordingly, the nonwoven fabric Swell follows even three-dimensionally patterned faces of the 0 articles to be cleaned with it.

It is a matter of importance that the bonded regions account Sfor from 10 to 80% of the surface area of the nonwoven fabric.

If the area of the bonded regions exceeds 80%, the nonwoven fabric will be too hard, and the its feel to the hand and its wiping performance will worsen. If so, in addition, the extra-fine fibers that are effective for wiping off light dirt such as oily stains will be coveredwith resin, and, asaresult, theoil-wiping capability of the nonwoven fabric will worsen. On the other hand, if the area of the bonded regions is smaller than the fibers could not be satisfactorily fixed, and the surface of the nonwoven fabric will readily fluff up. If so, the nonwoven fabric could not resist to external physical shock such as washing, and the nonwoven fabric will be readily deformed and could not be used repeatedly. For better wiping capability, surface .6 fluffingresistance andwashing resistance of the nonwoven fabric, the bonded regions preferably account for from 10 to 50%, more preferably from 10 to The bonded regions in the invention are formed by the use of an acrylic resin binder. For example, a resin binder of emulsion may be used. Generally, binder resins include, for example, acrylic resins, acrylate copolymer resins, polyurethane resins, vinyl acetate copolymer resins, epoxy resins and styrene-acrylic copolymer resins.

f The method of forming the bonded regions is not u/ specifically defined. For example, the layered fiber webs may CI' be partly bonded by emboss-rolling, or a resin binder may be transferred onto them through gravure-rolling. In the invention, when a gravure roll is used, it is desirable that a pattern of continuous lines is formed. For example, the IC patterns of to (III) in Fig. 1 are preferred as they improve the wiping capability and the design of the nonwoven fabric.

In addition, it is desirable that at least a part of the fibers in the non-bonded regions of the nonwoven fabric may be embedded in the bonded regions for further improving the washing resistance of the nonwoven fabric. For this, the bonded regions are so formed that the distance between the neighboring bonded regions can be at most 20 mm, preferably at most 10 mm, more preferably from 2 to 8 mm.

In the invention, the bonded regions may be formed to have 0 adot-likepatternof, for example, (IV) to of Fig. i. Having the pattern, the nonwoven fabric may be more flexible, and its ability to wipe off oily stains may be improved. The bonded regions maybe a combination of the linear pattern and the dot -like pattern mentioned above, and various patterns may be employed for the bonded regions in accordance with the object thereof.

The binder having permeated through the thickness of the nonwoven fabric for wipers may be localized around both faces of the nonwoven fabric or may be uniformly permeated through the depth of the nonwoven fabric, depending on the drying S condition after the binder resin application.

Inanycasewhere thebinder resin has been localizedaround both faces of the nonwoven fabric or uniformly permeated through the depth thereof, the nonwoven fabric is preventedfrom fluffing up and its washing resistance is good. However, the binder resin Io localized around the faces of the nonwoven fabric is more effective for increasing the surface strength of the nonwoven fabric and for enhancing the wiping capability thereof to remove persistent strains. In that condition, in addition, the nonwoven fabric is soft and may well fit to the hand, and it j may well follow even three-dimensionally patterned faces of the articles to be cleaned with it. To that effect, the wiping capability of the nonwoven fabric of the type is better.

In the nonwoven fabric for wipers of the invention, it is desirable that at least a part of the individual fibers in the non-bonded regions are fixed by the bonded regions.

Concretely, some fibers in the non-bondedregionsofthe nonwoven fabric are embedded in the bonded regions and are thereby fixed.

In that condition, the nonwoven fabric well keeps its soft feel and its wiping capability, not so much fluffing up to leave its fluff, and its washing resistance is good. The nonwoven fabric of the type is very favorable for wipers.

The nonwoven fabric for wipers of the invention has the above-mentioned, linear and/or dot-like bonded regions. For better wiping capability and better washing resistance of the nonwoven fabric, the bonded regions are so formed that the distance between the neighboring bonded regions can be at most mm, preferably 2 to 10 mm. If the distance between the neighboring bonded regions is larger than 20mm, the dimensional stability of the nonwoven fabric will lower and the washing resistance thereof will also lower. On the other hand, if the distance between them is smaller than 2 mm, the nonwoven fabric will have a hard feel. For keeping the oil-wiping capability of the extra-fine fibers as such and for ensuring better washing resistance of the nonwoven fabric, the distance between the neighboring bonded regions is most preferably from 2 to 8 mm.

The distance between the neighboring bonded regions referred to in the invention is the shortest distance therebetween, and it is obtained by measuring the shortest distance between the ends of the neighboring bonded regions.

a The surface of the nonwoven fabric for wipers of the invention may be flat, but is preferably further processed to have a perforated or embossed pattern for further enhancing the wiping capability of the nonwoven fabric. Specifically, owing to the synergistic effect of the embossed pattern and the bonded 2c regions in the surface of the nonwoven fabric, the wiping capability of the nonwoven fabric is further improved. Another c' advantage thereof is that the nonwoven fabric thus having such an embossed surface well follows even three-dimensionally Spatterned faces of the articles to be wiped with it to exhibit S its wiping effect and, in addition, it is believed that the CI extra-fine fibers could more readily appear on the surface of the nonwoven fabric of the type to act to wipe off light dirt such as oily stains. For processing the surface of the nonwoven fabric to make it have an embossed pattern, for example, employable is a method of hydroentangling that comprises spreading fiber webs on a belt support of a meshed resin net or metal net followed by applying water jets to them to thereby make the constituent fibers entangled. In this process, the height difference between the knuckles of the weft and those of the warp of the mesh belt is transferred onto the nonwoven fabric webs, and the nonwoven fabric thus processed is to have the intended embossed pattern on its surface. Also employable for it is another method of applying an embossing roll to the nonwoven fabric under pressure to thereby make the nonwoven fabric have the intended embossed pattern. In the invention, preferred is the method of hydroentangling, since the nonwoven fabric processed therein may have a soft feel and, even after washed, it well keeps the embossed pattern. The nonwoven fabric thus having such an embossed pattern may also be processed with S a binder resin or the like to form the bonded regions therein.

The embossed pattern referred to herein may be formed according to the methods mentioned hereinabove. For example, a nonwoven fabric having a pattern as in Fig. 2 may be used in the invention. In case where the nonwoven fabric of the type having such an embossed pattern is used in the invention, it is desirable that the height difference between the hills and the valleys of the pattern is at least 20% of the thickness of the nonwoven fabric. If having the height difference of at least the surface area of the nonwoven fabric increases and 0 therefore the length thereof to be in contact with dirt is prolonged. Having the advantages, the nonwoven fabric is more easily handled when used for wiping off dirt. In addition, the dirt to be wiped off may be physically caught by the hills of the embossed pattern of the nonwoven fabric and it may therefore well adhere to thenonwovenfabric. For these reasons, thewiping capability of the nonwoven fabric is much more enhanced.

Moreover, some dirt may be kept caught in the valleys of the nonwoven fabric, and do not move to other articles to stain them that are leaned with the nonwoven fabric. If the height will be flat, and if so, the nonwoven fabric could not well catch dirt and its wiping capability could not be so good. If so, in addition, the dirt once caught by the nonwoven fabric will move to other articles to stain them.

In the invention, it is further desirable that the hills are formed to be both in the bonded regions and the non-bonded regions. Thus formed to be both in the bonded regions and the non-bonded regions, the hills improve the wiping capability of the nonwoven fabric to well follow even the surfaces of non-flat articles to be wiped with it, and, in addition, the nonwoven fabric of the type has much improved washing resistance.

Moreover, the hills overlap with the bonded regions, and they are more hardened as the constituent fibers are concentrated therein. Accordingly, the thus-hardened hills are more o0 effective for wiping off persistent stains.

Assomentionedhereinabove, the nonwovenfabricforwipers of the invention has bonded regions in which the surface of the nonwovenfabricispreventedfrom fluffingup. Evenafterwashed, the entangled points of the constituent fibers of the nonwoven fabric do not shift and the nonwoven fabric is therefore not deformed. Accordingly, the nonwoven fabric can be used repeatedly. In case where extra-fine fibers having edges are used therein, the nonwoven fabric is effective even for wiping off extremely fine dirt. The advantage of the nonwoven fabric s of the type is that it may well catch such fine dirt and may readily hold it on its surface.

The nonwoven fabric of the invention is usable for various wipers, which are, for example, for wiping noble metal articles such as jellies and for wiping dishes, tables, glass articles, electric appliances, furniture, gas cookers, etc.

The wipers to be obtained in the invention are highly resistant to washing and can be used repeatedly, and therefore they are economical.

EXAMPLES

S The invention is described in more detail with reference to the following Examples, which, however, are not intended to restrict the scope of the invention. In the Examples, the physical properties were measured according to the methods mentioned below.

Thickness of nonwoven fabric: The thickness of a sample is measured at 10 points under a load of 12 gf/cm 2 applied thereto, and the data are averaged.

Height difference in embossed pattern of nonwoven fabric: A CCD laser dislocation sensor, LK-2000 (by Keyence) is used. With no load applied thereto, the thickness of a sample is measured at 6 hill peaks and 6 valley bottoms thereof. The data are averaged, and the difference between the two averages is divided by the thickness of the hill peaks. This indicates the height difference.

Example 1: Splittable conjugated fibers having a cross-sectional profile of alternately-layered nylon 6 and polyethylene terephthalate (Kuraray's WRAMP, having a fineness of 3.8 dtex and a fiber length of 51 mm) alone (100%) were fed into a carding machine and processed into fiber webs. The resulting webs were processed byhydroentangling whereby the constituent fibers were divided into extra-fine fibers and the thus-split extra-fine fibers were entangled. After thus processed by hydroentangling, S the webs were coated with an acrylic resin (by Nippon Carbide) with a gravure roll having a waved pattern of II in Fig. 1. The area ratio of the pattern is 13%, the binder pitch is 3.2 mm, and the binder amount is 2 g/m 2 The process gave a nonwoven fabric for wipers, having a mass per unit area of 80 g/m 2 The nonwoven fabric was observed, and was found to have linear bonded regions formed of the acrylic resin and non-bonded regions. The nonwoven fabric was observed in more detail, and it was confirmed that some ends of the extra-fine fibers in the non-bonded regions were embedded in the bonded regions and were fixed therein. The distance between the neighboring bonded regions was 3.0 mm. The data of the nonwoven fabric are given in Table 1.

Example 2: A nonwoven fabric for wipers having a mass per unit area of 80 g/m 2 was produced in the same manner as in Example 1 except JO for the following changes: The webs obtained in Example 1 were processed by hydroentangling on a herringbone-patterned net so that the net pattern was transferred onto the webs, and the webs therefore had the embossed herringbone pattern. Thus obtained, the nonwoven fabric was observed, and was found to have linear -W bonded regions formed of the acrylic resin and non-bonded regions.

The nonwoven fabric was observed in more detail, and it was confirmed that some ends of the extra-fine fibers in the non-bonded regions were embedded in the bonded regions and were fixed therein. The distance between the neighboring bonded S regions was 3.0 mm. See Table 1.

Example 3: A nonwoven fabric for wipers having a unit weight of g/m 2 was produced in the same manner as in Example 2 except for the following changes: Splittable conjugated fibers having a I0 cross-sectional profile of alternately-layered nylon 6 and polyethylene terephthalate (Kuraray's WRAMP, having a fineness of 3.8 dtex and a fiber length of 51 mm) 85% and core/sheath bicomponent binder fibers of which the core is polypropylene and the sheath is polyethylene (Daiwabo's NBF(H), 2.2 dtex, 51 Smm) 15% were fed into a carding machine and processed into fiber webs. The resulting webs were processed by hydroentangling whereby the splittable fibers were divided into extra-fine fibers and the resulting fibers were entangled. Thus processed, the webs were heat-set and the binder fibers therein were thereby fused. The distance between the neighboring bonded regions in the nonwoven fabric thus produced was 3.0 mm. See Table 1.

Comparative Example 1: A nonwoven fabric for wipers having a mass per unit area of 80 g/m 2 was produced in the same manner as in Example 2, to which, however, the acrylic resin was not applied. See Table 1.

Comparative Example 2: A nonwoven fabric for wipers having a mass per unit area of 80 g/m 2 was produced in the same manner as in Example 3, to which, however, the acrylic resin was not applied. See Table 1.

Comparative Example 3: Splittable conjugated fibers having a chrysanthemum-patterned cross-sectional profile of Io radially-aligned nylon 6 and polyethylene terephthalate (having a fineness of 2.2 dtex and a fiber length of 38 mm) 40% and polyethylene terephthalate fibers (having a fineness of 16.5 dtex and a fiber length of 51 mm) 60% were fed into a carding machine and processed into fiber webs. The resulting fibers webs were sprayed with an acrylic emulsion (15 g/m 2 in terms of the solid content of the emulsion), and then heat-set at 150°C for 3 minutes whereby the constituent fibers were bonded to each other to give a nonwoven fabric for wipers. See Table 1.

Table 1 mass per unit area Thickness Bonded Regions Height Difference (g/m 2 (mm) in Embossed Pattern Example 1 80 0.54 13 Example 2 80 0.52 13 38 Example 3 80 0.51 13 33 Comp. Ex. 1 80 0.57 0 41 Comp. Ex. 2 80 0.54 0 39 Comp. Ex. 3 150 2.6 100 The nonwoven fabrics for wipers obtained in the above-mentioned Examples and Comparative Examples were worked into wipers, and evaluated in the manner mentioned below. The results are given in Table 2.

Evaluation of fluffing resistance: 0.1 g of water is dropped onto a mirror face through a syringe. A wiper sample of 15 cm x 15 cm is folded in four.

An operator carries the wiper sample in the hand, and circularly moves it 10 times on the mirror face to wipe up the water. Then, the thus wiped mirror face is checked for the fiber leavings thereon from the wiper sample. Thus tried, the wiper sample is evaluated in 5 ranks as follows: No fluff found.

4: 1 to 5 fiber leavings found.

1 3: 6 to 25 fiber leavings found.

2: 26 to 50 fiber leavings found.

1: 51 or more fiber leavings found.

Evaluation of washing resistance: A square of 20 cm x 20 cm is marked on a wiper sample, and the sample is washed 5 times according to the washing test method of JIS L1096. After washed, the shrinkage percentage of the sample is measured. Based on the CD (cross direction) shrinkage percentage thereof, the sample is evaluated in 3 ranks as follows: .4 A: less than 3%.

B: 3% to C: more than Evaluation of wiping capability to remove oily stains: On a glass sheet, a circular seal is impressed with oily C ink. A wiper sample of 15 cm x 15 cm is folded in four. An operator carries the wiper sample in the hand, and completely wipes off the oily film with the wiper sample. The number of wipingoperationsthat hasbeendonebeforethefilmis completely wiped off is counted.

t Evaluation of wiping capability to remove persistent stains: Theabsorbance(A) of a glasssheetismeasured. Moriwiper (by Sumiko Lubricant) is circularly applied to the glass sheet, and dried. After dried, the absorbance of the glass sheet is measured. The glass sheet is set on the sample stand of a rubbing fastness tester. A wiper sample having a controlled water content of 100% is fitted to the friction probe of the tester, and this is moved once back and forth on the glass sheet to wipe off the stain. After this, the absorbance of the glass sheet is measured.

0 According to the following equation, the degree of stain removal is obtained.

Degree of stain removal (C B) x 100.

Evaluation of feel: The feel of each wiper sample in the hand is evaluated 2 in 3 ranks as follows: A: Soft to the hand.

B: A little hard to the hand.

C: Hard to the hand.

Table 2 Fluffing Washing Oil Stains Wiping Persistent Stains Feel Resistance resistance Capability Wiping Capability Example 1 5 A 9 56.4 A Example 2 5 A 9 57.0 A Example 3 5 A 8 51.2 AtoB Comp. Example 1 2 C 8 6.6 B Comp. Example 2 3 B 9 10.2 B Comp. Example 3 3 to 4 B 7 16.4 C As is obvious from Table 2, it is understood that the wipers formed of the nonwoven fabric of the invention have good wiping capabilities and washing resistance.

As described in detail with reference to its preferred Id embodiments, the nonwoven fabric of the invention exhibits excellent wiping capabilities to remove any and every dirt including oily stains and persistent stains under any cleaning conditions. While used for wiping off dirt, the wipers formed of the nonwoven fabric fluff up little. As their washing ce resistance is good, the wipers are usable repeatedly.

Claims

1. A nonwoven fabric for wipers which contains extra-fine fibres having a single Sfibre fineness of 0.5 dtex or less, comprising linear and/or dot-like bonded regions and non-bonded regions on its surface, wherein the bonded regions account for from 10 to 80% of the surface area of the nonwoven fabric and the distance between the tin neighbouring bonded regions is at most 20mm, characterised in that the bonded regions O are formed by an acrylic resin binder.

2. The nonwoven fabric of claim 1, wherein the surface of the fabric has (N 0C embossed patterns, and the height difference between the hills and the valleys of the pattern is at least 20% of the thickness of the nonwoven fabric.

3. The nonwoven fabric of claim 1 or 2, which is formed of 100% extra-fine fibres.

4. A wiper made of the nonwoven fabric of any one of claims 1 to 3. Dated 17 July, 2006 Kuraray Co., Ltd. Patent Attorneys for the Applicant/Nominated Person SPRUSON FERGUSON IR:\LIBFF 13466.doc:hjg