AU2002235194A1 - Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers - Google Patents

Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers

Info

Publication number
AU2002235194A1
AU2002235194A1 AU2002235194A AU3519402A AU2002235194A1 AU 2002235194 A1 AU2002235194 A1 AU 2002235194A1 AU 2002235194 A AU2002235194 A AU 2002235194A AU 3519402 A AU3519402 A AU 3519402A AU 2002235194 A1 AU2002235194 A1 AU 2002235194A1
Authority
AU
Australia
Prior art keywords
plasticizers
halogen
containing polymers
organic thiol
free stabilizers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2002235194A
Inventor
Bin Du
William H. Starnes Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
College of William and Mary
Original Assignee
College of William and Mary
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/737,973 external-priority patent/US6667357B2/en
Application filed by College of William and Mary filed Critical College of William and Mary
Publication of AU2002235194A1 publication Critical patent/AU2002235194A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/10—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C323/11—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/12—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and singly-bound oxygen atoms bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
AU2002235194A 2000-12-15 2001-12-14 Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers Abandoned AU2002235194A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US09/737,973 2000-12-15
US09/737,973 US6667357B2 (en) 2000-12-15 2000-12-15 Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers
US09/884,306 2001-06-19
US09/884,306 US6762231B2 (en) 2000-12-15 2001-06-19 Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers
PCT/US2001/048086 WO2002048250A2 (en) 2000-12-15 2001-12-14 Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers

Publications (1)

Publication Number Publication Date
AU2002235194A1 true AU2002235194A1 (en) 2002-06-24

Family

ID=27113284

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2002235194A Abandoned AU2002235194A1 (en) 2000-12-15 2001-12-14 Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers

Country Status (5)

Country Link
US (3) US6762231B2 (en)
AU (1) AU2002235194A1 (en)
CA (1) CA2430033A1 (en)
MX (1) MXPA03005154A (en)
WO (1) WO2002048250A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7312266B2 (en) * 2000-12-15 2007-12-25 The College Of William And Mary Organic thiol metal-free stabilizers and plasticizers for halogen-containing polymers
US8487018B2 (en) 2005-01-24 2013-07-16 Biotech Products, Llc Heavy metal-free and anaerobically compostable vinyl halide compositions, articles and landfill biodegradation
US7553897B2 (en) * 2006-01-11 2009-06-30 College Of William And Mary Organic thiol stabilizers and plasticizers for halogen-containing polymers
DE102007040376A1 (en) * 2007-08-20 2009-02-26 Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg Paint, flexible laminate with a support and a paint layer applied thereto and their use
ES2341524B1 (en) * 2008-12-18 2011-04-28 Consejo Superior De Investigaciones Cientificas (Csic) NEW ADDITIVES BASED ON PHTALATES FOR INTERNAL PLASTIFICATION DEPOLIMEROS CLORADOS.
CN102718690A (en) * 2012-06-26 2012-10-10 复旦大学 Polyvinyl chloride plasticizer and preparation method thereof
CN112724558B (en) * 2020-12-30 2022-08-05 杭州朝盛塑业有限公司 Composite PVC heat stabilizer and preparation method thereof

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2483984A (en) 1946-08-30 1949-10-04 American Cyanamid Co Phenyl thiosalicylate as a catalytic plasticizer for rubber
NL253378A (en) * 1959-07-08
NL121580C (en) * 1961-01-26
NL123211C (en) 1961-11-27
BE658003A (en) 1964-01-10 1965-07-07 Argus Chem
DE1545155A1 (en) 1964-01-31 1970-01-22 Glanzstoff Ag Process to improve the stability of polyolefins
US3585038A (en) 1964-04-29 1971-06-15 Du Pont Selected hexaarylbiimidazole oxidation systems
US3445419A (en) * 1966-01-21 1969-05-20 Dow Corning Room temperature vulcanizable silicones
US3507827A (en) 1967-01-27 1970-04-21 Argus Chem Stabilizer composition for lessening early discoloration of polyvinyl chloride resins when heated
US3734753A (en) * 1969-02-04 1973-05-22 Stauffer Chemical Co Plasticized sulfur compositions
GB1270114A (en) * 1969-02-13 1972-04-12 Grace W R & Co Improvements relating to plasticised thermoplastic polymer compositions
US3919359A (en) * 1970-08-03 1975-11-11 Exxon Research Engineering Co Alkoxyalkyl phosphonates
US3917553A (en) 1971-04-22 1975-11-04 Celanese Corp Stabilized polyacrylonitrile compositions with sulfur containing stabilizer and method of forming same
US3966794A (en) * 1972-06-02 1976-06-29 W. R. Grace & Co. Curable polyene-polythiol compounds
AU5957873A (en) * 1972-09-01 1975-02-27 Ciba-Geigy Ag Foamed materials and their preparation
US3979359A (en) * 1974-11-15 1976-09-07 Cincinnati Milacron Chemicals, Inc. Carbofunctional sulfur and carboxylate bridged tin compounds
US3928285A (en) 1975-01-16 1975-12-23 Cincinnati Milacron Inc Synergistic organotin borate stabilizer composition and resins containing same
US4098763A (en) 1976-09-08 1978-07-04 Bell Telephone Laboratories, Incorporated Technique for stabilization of vinyl chloride polymers using organic thiols
US4132812A (en) * 1977-09-02 1979-01-02 W. R. Grace & Co. Photocurable imidizable polyene-polythiol compositions
GB1597688A (en) 1977-04-22 1981-09-09 Koei Chemical Co Stabilizer for chlorine-containing resins
JPS5453002A (en) 1977-10-03 1979-04-26 Mitsubishi Paper Mills Ltd Improved correcting liquid for offset printing plate
US4198305A (en) * 1978-06-14 1980-04-15 Mobil Oil Corporation Lubricant compositions
US4338226A (en) 1979-10-13 1982-07-06 Neynaber Chemie Gmbh Process for the stabilization of polyvinyl chloride and stabilizer compositions
US4264482A (en) * 1979-12-03 1981-04-28 Dow Corning Corporation Oxygen-curable mercapto-functional organic compound compositions possessing rapid surface reaction and method of forming higher molecular weight products therefrom
US4333987A (en) * 1979-12-19 1982-06-08 Harold Kwart Methods for bonding dissimilar synthetic polymeric materials and the products involved in and resulting from such methods
FR2491871A1 (en) * 1980-10-10 1982-04-16 Ato Chimie IMPROVEMENT IN STERILIZATION OF OBJECTS IN HALOGENO-VINYL POLYMERS BY IONIZING RADIATION, AND RESINS FOR THEIR PRODUCTION
FR2491936A1 (en) * 1980-10-13 1982-04-16 Ato Chimie PROCESS FOR MAKING POLYMERS RESISTANT TO IONIZING RADIATION, AND COMPOSITIONS OBTAINED
US4576984A (en) 1982-02-04 1986-03-18 Morton Thiokol, Inc. Stabilizer compositions for PVC resins
FR2524474A1 (en) 1982-03-30 1983-10-07 Rhone Poulenc Spec Chim METHOD FOR STABILIZING POLYMERS BASED ON VINYL CHLORIDE, STABILIZING COMPOSITIONS FOR CARRYING OUT THE METHOD AND POLYMERS SO STABILIZED
DE3247736A1 (en) * 1982-12-23 1984-07-05 Henkel KGaA, 4000 Düsseldorf STABILIZED POLYVINYL CHLORIDE MOLDS
JPS606635A (en) * 1983-06-24 1985-01-14 Mitsubishi Petrochem Co Ltd Purification of 1,2-unsaturated carboxylic acid and/or its ester
EP0133130B1 (en) 1983-08-02 1987-12-09 Societe Nationale Elf Aquitaine Process for the heat stabilisation of polyvinyl halides, and the resins so stabilized
CA1273192A (en) * 1985-06-10 1990-08-28 Nuno A. Vaz Liquid crystal droplets dispersed in thin films of uv- curable polymers
DE3542862A1 (en) 1985-12-04 1987-06-11 Huels Chemische Werke Ag STABILIZED MOLDS BASED ON VINYL CHLORIDE POLYMERISATS AND USE OF ONE OR MORE COMPOUNDS AS COSTABILIZERS FOR MOLDS BASED ON VINYL CHLORIDE POLYMERS
US4711920A (en) * 1986-07-23 1987-12-08 Morton Thiokol, Inc. Stabilizers for halogen-containing polymers comprising the product of a diorganotin oxide, an ethylenically unsaturated dicarboxylic acid ester and a mercaptan
JPS63128002A (en) 1986-11-18 1988-05-31 Toagosei Chem Ind Co Ltd Production of macromonomer having polycondensation property
US5594088A (en) * 1986-12-15 1997-01-14 Mitsui Toatsu Chemicals, Inc. Plastic lenses having a high-refractive index, process for the preparation thereof and casting polymerization process for preparing sulfur containing urethane resin lens and lens prepared thereby
US4873005A (en) 1987-02-04 1989-10-10 Morton Thiokol, Inc. Extrusion lubricant comprising a hydrocarbon wax, fatty acid salt and an organic mercaptan
JPS63241055A (en) 1987-03-28 1988-10-06 Sakai Chem Ind Co Ltd Chlorinated polymer composition
JP2541582B2 (en) 1987-09-29 1996-10-09 三井東圧化学株式会社 Polythiol
US5006436A (en) * 1988-09-20 1991-04-09 Atochem North America, Inc. UV curable compositions for making tentable solder mask coating
EP0365483B1 (en) 1988-10-20 1993-12-29 Ciba-Geigy Ag Mercaptobenzoic-acid esters used as stabilizers for chlorine-containing polymers
FR2638743B1 (en) 1988-11-08 1991-07-12 Hoechst France METHYL-2 TERTIOBUTYL-5 THIOPHENOL, ITS PREPARATION METHOD AND ITS APPLICATION
US5057622A (en) 1989-08-16 1991-10-15 Witco Corporation 3-alkylthiopropionic acids and derivatives
US5057567A (en) 1990-01-22 1991-10-15 Witco Corporation Mixed 3-alkylthiopropionic acid esters with pentaerythritol
JP3115371B2 (en) * 1991-09-03 2000-12-04 ホーヤ株式会社 Polymer for optical material and method for producing the same
JP3064611B2 (en) 1991-12-24 2000-07-12 住友化学工業株式会社 Agricultural coating film
US5216058A (en) 1992-04-02 1993-06-01 Vista Chemical Company Stabilizer compositions for halogen-containing polymers and polymer compositions containing same
TW258744B (en) 1993-05-05 1995-10-01 Morton Int Inc
US6232380B1 (en) 1995-05-10 2001-05-15 Morton International Inc. Latent mercaptan stabilizers for improved weatherability of clear halogen-containing polymer compositions
AU682287B2 (en) 1995-05-10 1997-09-25 Morton International, Inc. Latent mercaptans as multi-functional additives for halogen-containing polymer compositions
US20020103277A1 (en) 1995-05-10 2002-08-01 Tod C. Duvall Synergistic blend of a metal-based stabilizer or lewis acid and a free mercaptan for enhanced pvc stabilization
TW498096B (en) 1997-07-09 2002-08-11 Morton Int Inc Stabilizer composition comprising a blocked mercaptan and polymer composition comprising said stabilizer composition
AU9199698A (en) 1997-08-21 1999-03-08 Henkel Corporation Beta-hydroxy mercaptans as costabilizers for halogenated resins
DE60009142T2 (en) * 1999-12-22 2004-09-16 Akzo Nobel Coatings International B.V. COATING COMPOSITION CONTAINING AN OXIDATIVELY DRYING MULTIPLE UNSATURATED CONDENSATION PRODUCT, A POLYTHIOL AND A DRYING AGENT

Also Published As

Publication number Publication date
CA2430033A1 (en) 2002-06-20
US20020115769A1 (en) 2002-08-22
US6747081B2 (en) 2004-06-08
US6762231B2 (en) 2004-07-13
US20030055141A1 (en) 2003-03-20
WO2002048250A2 (en) 2002-06-20
US7250457B2 (en) 2007-07-31
US20040220310A1 (en) 2004-11-04
MXPA03005154A (en) 2004-10-14
WO2002048250A3 (en) 2003-12-31

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