AU2001287612A1 - Method for producing polyisobutylenes - Google Patents
Method for producing polyisobutylenesInfo
- Publication number
- AU2001287612A1 AU2001287612A1 AU2001287612A AU8761201A AU2001287612A1 AU 2001287612 A1 AU2001287612 A1 AU 2001287612A1 AU 2001287612 A AU2001287612 A AU 2001287612A AU 8761201 A AU8761201 A AU 8761201A AU 2001287612 A1 AU2001287612 A1 AU 2001287612A1
- Authority
- AU
- Australia
- Prior art keywords
- isobutene
- boron trifluoride
- deactivator
- prim
- quat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/08—Butenes
- C08F10/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/08—Presence of a deactivator
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The production of polyisobutene by liquid-phase, cationic polymerization of isobutene in the presence of a boron trifluoride catalyst followed by the addition of a solid deactivator at a required point in time uses a deactivator (I) containing boron trifluoride-binding prim., sec., tert. and/or quat. nitrogen atoms, which is insoluble in the reaction mixture. In the production of polyisobutenes (PIB) by liquid-phase, cationic polymerization of isobutene or hydrocarbon streams containing isobutene in the presence of boron trifluoride as catalyst, the catalytic activity of the BF3 is partly or completely eliminated at a required point in time by means of a solid deactivator which contains BF3-binding prim., sec., tert. and/or quat. nitrogen atoms and is insoluble in the reaction mixture.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10035298 | 2000-07-18 | ||
DE10035298A DE10035298A1 (en) | 2000-07-18 | 2000-07-18 | Highly reactive polyisobutene production involves polymerization of isobutene with boron trifluoride catalyst, using solid amine-type deactivator which is insoluble in reaction mixture |
PCT/EP2001/008109 WO2002006359A1 (en) | 2000-07-18 | 2001-07-13 | Method for producing polyisobutylenes |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001287612A1 true AU2001287612A1 (en) | 2002-01-30 |
Family
ID=7649588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001287612A Abandoned AU2001287612A1 (en) | 2000-07-18 | 2001-07-13 | Method for producing polyisobutylenes |
Country Status (6)
Country | Link |
---|---|
US (1) | US6846903B2 (en) |
EP (1) | EP1301546B1 (en) |
AT (1) | ATE266682T1 (en) |
AU (1) | AU2001287612A1 (en) |
DE (2) | DE10035298A1 (en) |
WO (1) | WO2002006359A1 (en) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6562913B1 (en) * | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
US6884858B2 (en) * | 1999-10-19 | 2005-04-26 | Texas Petrochemicals Lp | Process for preparing polyolefin products |
JP4156837B2 (en) * | 1999-09-16 | 2008-09-24 | テキサス ペトロケミカルズ リミティド パートナーシップ | Manufacturing method of polyolefin products |
US7037999B2 (en) | 2001-03-28 | 2006-05-02 | Texas Petrochemicals Lp | Mid-range vinylidene content polyisobutylene polymer product and process for producing the same |
US6992152B2 (en) * | 1999-10-19 | 2006-01-31 | Texas Petrochemicals Lp | Apparatus and method for controlling olefin polymerization process |
DE10040618A1 (en) | 2000-08-16 | 2002-02-28 | Basf Ag | Process for the preparation of polyisobutenes |
DE10118181A1 (en) | 2001-04-11 | 2002-10-17 | Basf Ag | Removing unreacted isobutene in the production of polyisobutene by cationic polymerisation involves evaporating the liquid reaction product and separating the foam with a baffle or circulating loop |
JP4894265B2 (en) * | 2004-01-29 | 2012-03-14 | 株式会社カネカ | Method for producing isobutylene resin particles |
JP4748060B2 (en) * | 2004-06-15 | 2011-08-17 | 株式会社カネカ | Method for producing isobutylene polymer |
US7420019B2 (en) | 2004-08-20 | 2008-09-02 | Chevron Oronite Company Llc | Method for preparation of polyolefins containing exo-olefin chain ends |
US7705090B2 (en) * | 2004-08-20 | 2010-04-27 | Chevron Oronite Company Llc | Method for preparing polyolefins containing a high percentage of exo-olefin chain ends |
JP5033626B2 (en) * | 2004-08-20 | 2012-09-26 | シェブロン・オロナイト・カンパニー・エルエルシー | Process for producing polyolefins containing exo-olefin chain ends |
US8013073B2 (en) * | 2005-12-30 | 2011-09-06 | Chevron Oronite Company Llc | Method for preparing polyolefins containing vinylidine end groups using nonaromatic heterocyclic compounds |
US7816459B2 (en) * | 2005-12-30 | 2010-10-19 | Chevron Oronite Company Llc | Method for preparing polyolefins containing vinylidine end groups using polymeric nitrogen compounds |
ATE545662T1 (en) * | 2006-11-14 | 2012-03-15 | Basf Se | METHOD FOR REMOVAL OF ISOBUTENE OLIGOMERS FROM AN ISOBUTENE POLYMER |
US8394897B2 (en) * | 2008-03-25 | 2013-03-12 | Chevron Oronite Company Llc | Production of vinylidene-terminated polyolefins via quenching with monosulfides |
US8063154B2 (en) * | 2008-06-24 | 2011-11-22 | The University Of Southern Mississippi | Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers |
US8133954B2 (en) | 2008-10-22 | 2012-03-13 | Chevron Oronite Company Llc | Production of vinylidene-terminated and sulfide-terminated telechelic polyolefins via quenching with disulfides |
US8344073B2 (en) | 2009-01-16 | 2013-01-01 | The University Of Southern Mississippi | Functionalization of polyolefins with phenoxy derivatives |
WO2010096392A2 (en) | 2009-02-20 | 2010-08-26 | Marine Power Products Corporation | Method and apparatus for efficient on-demand production of h2 and o2 from water using waste heat and environmentally safe metals |
US20100298507A1 (en) * | 2009-05-19 | 2010-11-25 | Menschig Klaus R | Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby |
MX340883B (en) | 2010-05-12 | 2016-07-29 | Basf Se | Emulsions of polyisobutenes, substance and process. |
US8492491B2 (en) | 2010-06-10 | 2013-07-23 | Chevron Oronite Company Llc | Methods for producing telechelic polyolefins from terpene initiators |
US8592527B2 (en) | 2010-06-14 | 2013-11-26 | University Of Southern Mississippi | Vinyl ether end-functionalized polyolefins |
US8969484B2 (en) | 2011-07-08 | 2015-03-03 | Chevron Oronite Company Llc | Methods of producing mono- and multi-functional polymers from terpene-based initiators |
CA2853248A1 (en) | 2011-11-11 | 2013-05-16 | Basf Se | Self-emulsifiable polyolefine compositions |
US20130118531A1 (en) | 2011-11-11 | 2013-05-16 | The Procter & Gamble Company | Emulsions containing polymeric cationic emulsifiers, substance and process |
WO2013068384A2 (en) | 2011-11-11 | 2013-05-16 | Basf Se | Emulsions containing polymeric cationic emulsifiers, substance and process |
US8759274B2 (en) | 2011-11-11 | 2014-06-24 | Basf Se | Self-emulsifiable polyolefine compositions |
WO2013068272A1 (en) | 2011-11-11 | 2013-05-16 | Basf Se | Self-emulsifiable polyolefine compositions |
US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US9156924B2 (en) | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US9631038B2 (en) | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US9771442B2 (en) | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10047174B1 (en) | 2017-06-28 | 2018-08-14 | Infineum International Limited | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10167352B1 (en) | 2017-06-28 | 2019-01-01 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
US10174138B1 (en) | 2018-01-25 | 2019-01-08 | University Of Massachusetts | Method for forming highly reactive olefin functional polymers |
US10829573B1 (en) | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2291510A (en) * | 1940-04-20 | 1942-07-28 | Jasco Inc | Polymerization quenching process |
DE2702604C2 (en) | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutenes |
US4213001A (en) | 1978-10-27 | 1980-07-15 | Gulf Research & Development Company | Oligomerizing alpha-olefins with a heterogeneous catalyst |
US4384162A (en) | 1982-07-08 | 1983-05-17 | Gulf Research & Development Company | Removing boron trifluoride contaminant from organic liquids with polyvinyl alcohol |
US4433197A (en) | 1982-07-08 | 1984-02-21 | Gulf Research & Development Company | Removing boron trifluoride from coordination compound contaminants in organic liquids |
JPS59157035A (en) * | 1983-02-28 | 1984-09-06 | Kyowa Chem Ind Co Ltd | Removal of halogen component from organic compound containing halogen-containing catalyst |
GB8329082D0 (en) | 1983-11-01 | 1983-12-07 | Bp Chem Int Ltd | Low molecular weight polymers of 1-olefins |
US4849572A (en) | 1987-12-22 | 1989-07-18 | Exxon Chemical Patents Inc. | Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647) |
US5196630A (en) * | 1991-04-25 | 1993-03-23 | Mobil Oil Corporation | Process for the removal of catalyst residues from olefin polymerization products |
US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
DE4306384A1 (en) | 1993-03-02 | 1994-09-08 | Basf Ag | Chlorine-free, non-drying isobutene-diene copolymers |
DE69700536T2 (en) | 1996-02-20 | 2000-05-18 | Nippon Petrochemicals Co., Ltd. | Process for the separation and recovery of boron trifluoride |
DE19952031A1 (en) | 1999-10-28 | 2001-05-03 | Basf Ag | Process for the production of highly reactive polyisobutenes |
-
2000
- 2000-07-18 DE DE10035298A patent/DE10035298A1/en not_active Withdrawn
-
2001
- 2001-07-13 AU AU2001287612A patent/AU2001287612A1/en not_active Abandoned
- 2001-07-13 AT AT01967167T patent/ATE266682T1/en not_active IP Right Cessation
- 2001-07-13 WO PCT/EP2001/008109 patent/WO2002006359A1/en active IP Right Grant
- 2001-07-13 DE DE50102277T patent/DE50102277D1/en not_active Expired - Fee Related
- 2001-07-13 EP EP01967167A patent/EP1301546B1/en not_active Expired - Lifetime
- 2001-07-13 US US10/312,591 patent/US6846903B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1301546B1 (en) | 2004-05-12 |
WO2002006359A1 (en) | 2002-01-24 |
EP1301546A1 (en) | 2003-04-16 |
DE10035298A1 (en) | 2002-01-31 |
US6846903B2 (en) | 2005-01-25 |
ATE266682T1 (en) | 2004-05-15 |
DE50102277D1 (en) | 2004-06-17 |
US20030191257A1 (en) | 2003-10-09 |
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