AU2001281937A1 - Improved catalyst and method for producing polytetrahydrofurane - Google Patents

Improved catalyst and method for producing polytetrahydrofurane

Info

Publication number
AU2001281937A1
AU2001281937A1 AU2001281937A AU8193701A AU2001281937A1 AU 2001281937 A1 AU2001281937 A1 AU 2001281937A1 AU 2001281937 A AU2001281937 A AU 2001281937A AU 8193701 A AU8193701 A AU 8193701A AU 2001281937 A1 AU2001281937 A1 AU 2001281937A1
Authority
AU
Australia
Prior art keywords
improved catalyst
polytetrahydrofurane
producing
producing polytetrahydrofurane
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001281937A
Inventor
Gerd Bohner
Gerhard Cox
Rolf-Hartmuth Fischer
Martin Haubner
Michael Hesse
Hartmut Hibst
Gerd Linden
Thomas Narbeshuber
Ekkehard Schwab
Christoph Sigwart
Ulrich Steinbrenner
Andreas Tenten
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10032268A external-priority patent/DE10032268A1/en
Priority claimed from DE10032267A external-priority patent/DE10032267A1/en
Priority claimed from DE10105970A external-priority patent/DE10105970A1/en
Application filed by BASF SE filed Critical BASF SE
Publication of AU2001281937A1 publication Critical patent/AU2001281937A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C08G65/20—Tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2666—Hetero polyacids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2693—Supported catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
AU2001281937A 2000-07-03 2001-07-02 Improved catalyst and method for producing polytetrahydrofurane Abandoned AU2001281937A1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE10032268A DE10032268A1 (en) 2000-07-03 2000-07-03 New supported catalyst containing oxygenated molybdenum or tungsten compounds, useful for preparation of tetrahydrofuran polymers and copolymers
DE10032267A DE10032267A1 (en) 2000-07-03 2000-07-03 New supported catalyst containing oxygenated molybdenum or tungsten compounds, useful for preparation of tetrahydrofuran polymers and copolymers
DE10032267 2000-07-03
DE10032268 2000-07-03
DE10105970 2001-02-09
DE10105970A DE10105970A1 (en) 2001-02-09 2001-02-09 New supported catalyst containing oxygenated molybdenum or tungsten compounds, useful for preparation of tetrahydrofuran polymers and copolymers
PCT/EP2001/007545 WO2002002671A1 (en) 2000-07-03 2001-07-02 Improved catalyst and method for producing polytetrahydrofurane

Publications (1)

Publication Number Publication Date
AU2001281937A1 true AU2001281937A1 (en) 2002-01-14

Family

ID=27213941

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001281937A Abandoned AU2001281937A1 (en) 2000-07-03 2001-07-02 Improved catalyst and method for producing polytetrahydrofurane

Country Status (9)

Country Link
US (1) US6870014B2 (en)
EP (1) EP1297051A1 (en)
JP (1) JP2004502807A (en)
KR (1) KR20030045770A (en)
CN (1) CN1451023A (en)
AU (1) AU2001281937A1 (en)
CA (1) CA2414989A1 (en)
MY (1) MY134052A (en)
WO (1) WO2002002671A1 (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10130782A1 (en) * 2001-06-26 2003-01-02 Basf Ag Catalyst and process for making polytetrahydrofuran
DE10261484A1 (en) * 2002-12-23 2004-07-01 Basf Ag Process for the polymerization of cyclic ethers
AR043243A1 (en) * 2003-02-24 2005-07-20 Shell Int Research CATALYST COMPOSITION, ITS PREPARATION AND USE
CN101035881B (en) * 2004-09-08 2010-10-13 国际壳牌研究有限公司 Hydrocracking catalyst composition
US7491676B2 (en) * 2004-10-19 2009-02-17 Millennium Inorganic Chemicals High activity titania supported metal oxide DeNOx catalysts
KR100682515B1 (en) * 2005-05-19 2007-02-15 주식회사 엘지화학 Method for Preparing Catalyst for Partial Oxidation of Methylbenzenes
DE102005052016B4 (en) * 2005-10-31 2009-05-20 Süd-Chemie AG Process for the preparation of porous moldings and moldings obtainable by the process
KR100758377B1 (en) * 2005-11-22 2007-09-14 주식회사 엘지화학 Method for preparing catalyst for partial oxidation of methylbenzenes by wet milling
CN102015808B (en) * 2008-09-26 2012-12-12 Dic株式会社 Urethane-forming reaction catalyst and method for producing urethane material
CN102698809A (en) * 2012-05-11 2012-10-03 沈阳化工大学 Preparation method of H3PW12O40/ nanometer TiO2 composite photocatalyst
CN103755944B (en) * 2014-01-10 2015-12-02 大连工业大学 The preparation method of complex metal oxides modified titanic oxide type solid acid and the synthetic method of catalysis PTMG thereof
BR112018010229A2 (en) * 2015-11-19 2018-11-21 Shell Int Research catalyst system and process for glycol production
CN112169789B (en) * 2020-11-09 2023-03-21 南京溙科新材料科技有限公司 Three-dimensional through multistage pore channel environmental catalytic material and preparation method thereof

Family Cites Families (24)

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US4051172A (en) * 1971-01-08 1977-09-27 Institut Francais Du Petrole, Des Carburants Et Lubrifiants Molybdenum and tungsten compounds, their manufacture and their use as catalysts in the stereospecific polymerization of unsaturated organic compounds
JPS5058200A (en) * 1973-09-25 1975-05-20
US4016106A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
US4269737A (en) * 1978-07-25 1981-05-26 Exxon Research & Engineering Company Method for preparing a group IVB, VB or VIB metal oxide on inorganic refractory oxide support catalyst and the product prepared by said method
US4225421A (en) * 1979-03-13 1980-09-30 Standard Oil Company (Indiana) Process for hydrotreating heavy hydrocarbons
US4257922A (en) 1979-03-13 1981-03-24 Electric Power Research Institute, Inc. Process for coal liquefaction and catalyst
US4886594A (en) * 1982-12-06 1989-12-12 Amoco Corporation Hydrotreating catalyst and process
US4789654A (en) * 1985-03-29 1988-12-06 Catalysts & Chemicals Industries Co., Ltd. Hydrotreating catalysts
US4720472A (en) * 1985-08-08 1988-01-19 Phillips Petroleum Company Hydrocracking catalyst for middle distillates
US4769429A (en) * 1985-12-06 1988-09-06 Mobil Oil Corporation Process for polymerizing alpha-olefins
US4810361A (en) * 1987-05-18 1989-03-07 Mobil Oil Corporation Resid hydrotreating process using lanthana-alumina-aluminum phosphate catalyst
US4886582A (en) * 1988-06-29 1989-12-12 Union Oil Company Of California Resid hydroprocessing catalyst and method of preparation
US5037791A (en) * 1988-07-28 1991-08-06 Hri, Inc. Porous metal oxide supported carbon-coated catalysts and method for producing same
US5384297A (en) * 1991-05-08 1995-01-24 Intevep, S.A. Hydrocracking of feedstocks and catalyst therefor
US5192734A (en) * 1991-10-25 1993-03-09 W. R. Grace & Co.- Conn. Hydroprocessing catalyst composition
DE4433606A1 (en) 1994-09-21 1996-03-28 Basf Ag Process for the preparation of polyetrahydrofuran
US5578740A (en) * 1994-12-23 1996-11-26 The Dow Chemical Company Process for preparation of epoxy compounds essentially free of organic halides
EP0768110B1 (en) * 1995-10-09 2002-02-20 Shell Internationale Researchmaatschappij B.V. Catalyst and process for converting nitrogen oxide compounds
DE19612783A1 (en) * 1996-03-29 1997-10-02 Degussa Phosphoric acid catalyst and its use
DE19641481A1 (en) 1996-10-09 1998-04-16 Basf Ag Improved process for the production of polytetrahydrofuran
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Also Published As

Publication number Publication date
WO2002002671A1 (en) 2002-01-10
MY134052A (en) 2007-11-30
JP2004502807A (en) 2004-01-29
EP1297051A1 (en) 2003-04-02
KR20030045770A (en) 2003-06-11
CA2414989A1 (en) 2003-01-02
US6870014B2 (en) 2005-03-22
US20030186806A1 (en) 2003-10-02
CN1451023A (en) 2003-10-22

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