AU1598995A - Extruded polymer foam with filler particles and method - Google Patents
Extruded polymer foam with filler particles and methodInfo
- Publication number
- AU1598995A AU1598995A AU15989/95A AU1598995A AU1598995A AU 1598995 A AU1598995 A AU 1598995A AU 15989/95 A AU15989/95 A AU 15989/95A AU 1598995 A AU1598995 A AU 1598995A AU 1598995 A AU1598995 A AU 1598995A
- Authority
- AU
- Australia
- Prior art keywords
- extruder
- polyol
- screw
- mixture
- conveyor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/60—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
- B29B7/603—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material in measured doses, e.g. proportioning of several materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7476—Systems, i.e. flow charts or diagrams; Plants
- B29B7/748—Plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/823—Temperature control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/826—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3442—Mixing, kneading or conveying the foamable material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/46—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
- B29C44/50—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying
- B29C44/505—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length using pressure difference, e.g. by extrusion or by spraying extruding the compound through a flat die
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/40—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft
- B29B7/42—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with single shaft with screw or helix
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7404—Mixing devices specially adapted for foamable substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Molding Of Porous Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
A method for preparing a thermosetting foam, such as polyisocyanurate or polyurethane foam, includes introducing polyol and isocyanate to a screw of an extruder and mixing in the extruder screw. Catalyst is then added and mixed with the already formed mixture in the extruder screw. This mixture is extruded onto a conveyor and foamed on the conveyor. Finely divided carbon black, dispersing agent and/or surfactant may be mixed with polyol before introducing to the screw of the extruder or carbon black may be dispersed in polyol in the extruder and a polyol premix made before the remainder of the polyol is added. Foam cell size is decreased when extruder speed is increased. The foaming agent, which is preferably HCFC or water, may be mixed with one of the components, preferably the polyol, before introducing to the screw of the extruder. The mixture is cooled before extruding onto a conveyor to delay the foaming step until the mixture is outside the extruder. A carbon black dispersion may also be made, for future use. The process described may be used for making foam boards or bunstock.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/144,621 US5424014A (en) | 1992-09-18 | 1993-11-01 | Method for extruding foamable polymer material |
PCT/US1995/000175 WO1996020966A1 (en) | 1993-11-01 | 1995-01-06 | Extruded polymer foam with filler particles and method |
Publications (1)
Publication Number | Publication Date |
---|---|
AU1598995A true AU1598995A (en) | 1996-07-24 |
Family
ID=26789444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU15989/95A Abandoned AU1598995A (en) | 1993-11-01 | 1995-01-06 | Extruded polymer foam with filler particles and method |
Country Status (10)
Country | Link |
---|---|
US (1) | US5424014A (en) |
EP (1) | EP0801660B1 (en) |
JP (1) | JP3226927B2 (en) |
AT (1) | ATE206443T1 (en) |
AU (1) | AU1598995A (en) |
CA (1) | CA2209563C (en) |
DE (1) | DE69523070T2 (en) |
ES (1) | ES2164760T3 (en) |
MX (1) | MX9704957A (en) |
WO (1) | WO1996020966A1 (en) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE37095E1 (en) * | 1992-09-18 | 2001-03-13 | Apache Products Company | Extruded polymer foam with filler particles and method |
US5723506A (en) * | 1992-09-18 | 1998-03-03 | Apache Products Company | Extruded polymer foam with filler particles and method |
US5846461A (en) * | 1996-11-26 | 1998-12-08 | National Foam Cushion Manufacturing, Inc. | Method of manufacturing carpet pads from a polyurethane foam composition |
US5981611A (en) * | 1997-11-24 | 1999-11-09 | Prince Corporation | Thermoformable foam with infrared receptors |
US6022912A (en) * | 1998-09-22 | 2000-02-08 | Bayer Corporation | Expansion of polymeric microspheres insitu in a rigid PUR/PIR foam formulation using a twin screw extruder |
US6403663B1 (en) | 1999-09-20 | 2002-06-11 | North Carolina State University | Method of making foamed materials using surfactants and carbon dioxide |
WO2001046523A2 (en) * | 1999-12-20 | 2001-06-28 | Advanced Plastics Technologies, Ltd. | Hydroxy-phenoxyether polymers in papermaking |
WO2001072863A1 (en) * | 2000-03-27 | 2001-10-04 | Apache Products Company | Fire resistant foam and foam products, method and dispersions for making same |
DE10056251B4 (en) * | 2000-11-14 | 2006-06-08 | Basf Ag | Process for the production of polyurethane foams |
AU2002257127A1 (en) | 2001-04-04 | 2002-10-21 | Advanced Plastics Technologies, Ltd. | Process for coating paper, paperboard, and molded fiber with a water-dispersible polyester polymer |
DE10123002C1 (en) * | 2001-05-11 | 2002-08-08 | Basf Ag | Reaction apparatus for the production of reaction plastics |
US7363244B2 (en) * | 2002-11-08 | 2008-04-22 | Palo Alto Research Center Incorporated | Methods, apparatus, and program products for inferring service usage |
US20040102830A1 (en) * | 2002-11-22 | 2004-05-27 | Williams Terrell M. | System for coupling an implanatable medical device to an epicardial site |
US20040219317A1 (en) * | 2003-01-22 | 2004-11-04 | Wellstream International Limited | Process for manufacturing a flexible tubular pipe having extruded layers made of crosslinked polyethylene |
US7763341B2 (en) | 2004-01-23 | 2010-07-27 | Century-Board Usa, Llc | Filled polymer composite and synthetic building material compositions |
WO2006012149A2 (en) | 2004-06-24 | 2006-02-02 | Century-Board Usa, Llc | Continuous forming apparatus for three-dimensional foamed products |
US7794224B2 (en) | 2004-09-28 | 2010-09-14 | Woodbridge Corporation | Apparatus for the continuous production of plastic composites |
US7329374B2 (en) * | 2004-12-15 | 2008-02-12 | Lung-Wen Chou | Method for manufacturing resing films |
JP4694191B2 (en) * | 2004-12-17 | 2011-06-08 | 住化バイエルウレタン株式会社 | Production method of polyurethane foam moldings |
US8138234B2 (en) | 2006-03-24 | 2012-03-20 | Century-Board Usa, Llc | Polyurethane composite materials |
EP2072564B1 (en) * | 2007-12-19 | 2013-07-03 | Sika Technology AG | One-component moisture-curable polymer foam |
WO2009086459A1 (en) * | 2007-12-28 | 2009-07-09 | Bostik, Inc. | A continuous process for the production of moisture-cure, polyurethane sealants and adhesives |
US8846776B2 (en) | 2009-08-14 | 2014-09-30 | Boral Ip Holdings Llc | Filled polyurethane composites and methods of making same |
US9481759B2 (en) | 2009-08-14 | 2016-11-01 | Boral Ip Holdings Llc | Polyurethanes derived from highly reactive reactants and coal ash |
JP2013072038A (en) * | 2011-09-28 | 2013-04-22 | Nitto Denko Corp | Method for producing thermoplastic resin foam |
CA2851349C (en) | 2011-10-07 | 2020-01-21 | Russell L. Hill | Inorganic polymer/organic polymer composites and methods of making same |
US9932457B2 (en) | 2013-04-12 | 2018-04-03 | Boral Ip Holdings (Australia) Pty Limited | Composites formed from an absorptive filler and a polyurethane |
TWI667285B (en) | 2013-10-18 | 2019-08-01 | 德商巴斯夫歐洲公司 | Production of expanded thermoplastic elastomer |
JP6321404B2 (en) * | 2014-02-26 | 2018-05-09 | 株式会社ジェイテクト | Electric storage material manufacturing apparatus and manufacturing method |
WO2016018226A1 (en) | 2014-07-28 | 2016-02-04 | Crocco Guy | The use of evaporative coolants to manufacture filled polyurethane composites |
WO2016022103A1 (en) | 2014-08-05 | 2016-02-11 | Amitabha Kumar | Filled polymeric composites including short length fibers |
US9988512B2 (en) | 2015-01-22 | 2018-06-05 | Boral Ip Holdings (Australia) Pty Limited | Highly filled polyurethane composites |
US10030126B2 (en) | 2015-06-05 | 2018-07-24 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with lightweight fillers |
WO2017082914A1 (en) | 2015-11-12 | 2017-05-18 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with size-graded fillers |
KR102154867B1 (en) * | 2020-02-07 | 2020-09-10 | 최규술 | Polyurethane Foam And Manufacturing Method of the Same |
EP4001335A1 (en) | 2020-11-18 | 2022-05-25 | Covestro Deutschland AG | Method for producing polyurethane foams |
JP2022159929A (en) * | 2021-04-05 | 2022-10-18 | 積水化学工業株式会社 | Polyol composition, polyurethane resin composition, and polyurethane foam |
CN113563555A (en) * | 2021-08-17 | 2021-10-29 | 长虹美菱股份有限公司 | Polyurethane foaming material and foaming process thereof |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3466705A (en) * | 1966-03-07 | 1969-09-16 | Owens Illinois Inc | Apparatus for extruding foamable plastic materials in tubular form |
DE2649996A1 (en) * | 1976-10-30 | 1978-05-03 | Bayer Ag | PROCESS AND APPARATUS FOR PRODUCING A FILLER-CONTAINING REACTION MIXTURE FROM AT LEAST TWO FLOWABLE COMPONENTS, IN PARTICULAR FOR PRODUCING POLYURETHANE |
DE2707026A1 (en) * | 1977-02-18 | 1978-08-24 | Bayer Ag | METHOD AND DEVICE FOR CONTINUOUSLY EXTRUDING PLASTIC PROFILES FROM POLYURETHANE RAW MATERIALS |
DE2828506C2 (en) * | 1978-06-29 | 1980-04-17 | Bayer Ag, 5090 Leverkusen | Method and device for producing a foamable mixture of at least two flowable, foam-forming reaction components and additives |
DE2854409A1 (en) * | 1978-12-16 | 1980-06-26 | Bayer Ag | METHOD FOR PRODUCING THERMOPLASTIC CHEMICAL MATERIALS |
DE2854406A1 (en) * | 1978-12-16 | 1980-06-26 | Bayer Ag | THERMOPLASTIC CHEMICAL MATERIALS AND METHOD FOR THEIR PRODUCTION |
US4395214A (en) * | 1981-08-27 | 1983-07-26 | U.C. Industries | Foam extrusion apparatus having downstream upper and lower hinged shaping means and side restraining means |
DE3224324A1 (en) * | 1982-06-30 | 1984-01-05 | Basf Ag, 6700 Ludwigshafen | TWO-STAGE PROCESS FOR PRODUCING THERMOPLASTIC POLYURETHANE ELASTOMERS |
DK157908C (en) * | 1982-12-22 | 1990-09-03 | John Schmidt | BUILDING MATERIAL FOR BUILDING ELEMENTS AND PROCEDURES AND PLANTS FOR PRODUCING IT. |
US4496625A (en) * | 1983-10-12 | 1985-01-29 | The Celotex Corporation | Alkoxylated aromatic amine-aromatic polyester polyol blend and polyisocyanurate foam therefrom |
US4795763A (en) * | 1988-04-18 | 1989-01-03 | The Celotex Corporation | Carbon black-filled foam |
US4948859A (en) * | 1988-10-28 | 1990-08-14 | Minnesota Mining And Manufacturing Company | Extruder polymerization of polyurethanes |
US5137930A (en) * | 1991-08-28 | 1992-08-11 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5149722A (en) * | 1991-08-28 | 1992-09-22 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5192607A (en) * | 1991-08-28 | 1993-03-09 | The Celotex Corporation | Dispersant for carbon black-filled foam |
US5373026A (en) * | 1992-12-15 | 1994-12-13 | The Dow Chemical Company | Methods of insulating with plastic structures containing thermal grade carbon black |
-
1993
- 1993-11-01 US US08/144,621 patent/US5424014A/en not_active Expired - Lifetime
-
1995
- 1995-01-06 MX MX9704957A patent/MX9704957A/en not_active IP Right Cessation
- 1995-01-06 AT AT95907992T patent/ATE206443T1/en not_active IP Right Cessation
- 1995-01-06 AU AU15989/95A patent/AU1598995A/en not_active Abandoned
- 1995-01-06 EP EP95907992A patent/EP0801660B1/en not_active Expired - Lifetime
- 1995-01-06 CA CA002209563A patent/CA2209563C/en not_active Expired - Fee Related
- 1995-01-06 WO PCT/US1995/000175 patent/WO1996020966A1/en active IP Right Grant
- 1995-01-06 JP JP52092396A patent/JP3226927B2/en not_active Expired - Fee Related
- 1995-01-06 ES ES95907992T patent/ES2164760T3/en not_active Expired - Lifetime
- 1995-01-06 DE DE69523070T patent/DE69523070T2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP3226927B2 (en) | 2001-11-12 |
US5424014A (en) | 1995-06-13 |
ATE206443T1 (en) | 2001-10-15 |
CA2209563A1 (en) | 1996-07-11 |
MX9704957A (en) | 1998-02-28 |
EP0801660A4 (en) | 1998-04-08 |
EP0801660B1 (en) | 2001-10-04 |
JPH10502415A (en) | 1998-03-03 |
ES2164760T3 (en) | 2002-03-01 |
DE69523070D1 (en) | 2001-11-08 |
DE69523070T2 (en) | 2002-07-04 |
CA2209563C (en) | 2002-06-25 |
WO1996020966A1 (en) | 1996-07-11 |
EP0801660A1 (en) | 1997-10-22 |
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