AU1593588A

AU1593588A - Process for the reduction of nitrogen oxides in an effluent using a heterocyclic hydrocarbon

Info

Publication number: AU1593588A
Application number: AU15935/88A
Authority: AU
Inventors: William Robert Epperly; James Christopher Sullivan
Original assignee: Fuel Tech Inc
Current assignee: Fuel Tech Inc
Priority date: 1987-03-13
Filing date: 1988-03-11
Publication date: 1988-11-02
Also published as: WO1988007497A1; EP0305503A4; EP0305503A1; FI885167A; JPH01503126A; FI885167A0

Description

DESCRIPTION

PROCESS FOR THE REDUCTION OF NITROGEN OXIDES IN AN EFFLUENT USING A HETEROCYCLIC HYDROCARBON

Technical Field

The present invention relates to a process for the reduction of nitrogen oxides (NO_χ) in the* effluent, especially the oxygen-rich effluent, from the combustion of a carbonaceous fuel by injection of a treatment agent comprising a heterocyclic hydrocarbon having at least one cyclic oxygen into the effluent.

Carbonaceous fuels can be made to burn more completely, and with reduced emissions of carbon monoxide and unburned hydrocarbons, when the oxygen concentrations and air/fuel ratios employed are those which permit high flame temperatures. When fossil fuels are used to fire large utility boilers, temperatures above about 2000°F. and typically about 2200°F. to about 3000°F. are generated. Unfortunately, such high temperatures, as well as hot spots of higher temperatures, tend to cause the production of thermal NO_χ, the temperatures being so high that free radicals of oxygen and nitrogen are formed and chemically combine as nitrogen oxides. Nitrogen oxides can form even in circulating fluidized bed boilers which operate at temperatures which typically range from 1300°F. to 1700°F. Nitrogen oxides, especially N0₂, are troublesome pollutants which are found in the combustion effluent streams of boilers when fired as described above, and comprise a major irritant in smog. It is further believed that nitrogen oxides can undergo a process known as photo-chemical smog formation, through a series of reactions in the presence of sunlight and hydrocarbons. Moreover, nitrogen oxides comprise a major portion of acid rain.

Unfortunately, the temperatures within a utility or circulating fluidized bed boiler render most common methods of reducing NO_χ concentrations, such as effluent scrubbing or catalyst grids, either uneconomical, infeasible, or both.

BacKgrounfl Art

Various methods and compositions for reducing the NO_χ concentration in the effluent from the combustion of a carbonaceous fuel have been proposed. For instance, Arand et al, in U.S. Patent No. 4,208,386, disclose a method for reducing NO_χ in combustion effluents by injecting urea, either as a solid powder or in solution, at effluent temperatures in excess of 1300°F. The preferred urea solutions are those having at least 10 weight percent urea. For operation at temperatures below 1600°F., the use of reducing materials such as paraffinic, olefinic, aromatic and oxygenated hydrocarbons, as well as hydrogen, are required.

Bowers, in copending and commonly assigned U.S. Patent Application Serial Number 906,671, filed September 10,

1986, discloses the use of a solution which comprises urea and hexamethylenetetramine (HMTA) to reduce the N0_χ concentration in oxygen-rich effluents having temperatures above 1300°F. Similarly, Bowers, in copending and commonly assigned U.S. Patent Application Serial Number 784,828, filed October 4, 1985, discloses a solution comprising urea and an oxygenated hydrocarbon solvent which is disclosed as being effective at reducing NO_χ concentrations with reduced ammonia slippage in effluents at temperatures above 1600°F.

In copending and commonly assigned U.S. Patent

Application entitled "Process for Reducing Nitrogen Oxides in an Effluent Using a Hydrocarbon or Hydrogen Peroxide" having Attorney's Docket Number 937-0069, filed March 6,

1987, Sullivan discloses the use of hydrocarbons to reduce NO_χ levels in effluents at low temperatures (i.e., below 1450°F., especially below 1300°F.).

Although the prior art processes for reducing nitrogen oxides concentrations are generally effective, there exists a present need for a process which elicits still further NO_χ reductions in an economical and convenient manner.

Disclosure of Invention

The present invention relates to a process for reducing nitrogen oxides in the effluent from the combustion of a carbonaceous fuel. More particularly, the present invention relates to a process which comprises injecting into the effluent from the combustion of a carbonaceous fuel a treatment agent comprising a heterocyclic hydrocarbon having at least one cyclic oxygen under conditions effective to reduce the nitrogen oxides concentration in the effluent. Most preferably, the heterocyclic hydrocarbon comprises furfural.

Brief Description of the Drawings

The present invention will be better understood and its advantages more apparent in view of the following detailed description, especially when read with reference to the appended drawings, wherein:

FIGURE 1 is a graphic representation of the results of Example I, illustrating the broadened range of 0. effectiveness with respect to temperature dependency elicited by use of the present invention; and

FIGURE 2 is a schematic representation of a circulating fluidized bed boiler used to perform Example m.

is

As discussed above, the present invention relates to the reduction of nitrogen oxides in the effluent, especially the oxygen-rich . effluent, from the combustion of a carbonaceous fuel using a treatment agent which 2QP comprises a heterocyclic hydrocarbon having at least one cyc iσ oxygen, preferably furfural.

For the purposes of this description, all temperatures herein are measured using an unshielded K-type thermocouple. Unless otherwise indicated, all parts and

25 percentages are based on the weight of the composition at the particular point of reference.

The term "heterocyclic hydrocarbon having at least one cyclic oxygen" as used in this description refers to a ringed hydrocarbon compound having at least one ring oxygen. The term "furfural" as used in this description is meant to include furfural itself as well as substituted furfural. Typical substituents include side chains 5 comprising straight and branched-chain, substituted and unsubstituted aliphatic groups, oxygenated hydrocarbon groups and amino groups. Preferred substituted furfural compounds include hydroxymethyl furfural and furfural acetone.

10 The treatment agent of this invention most preferably further comprises urea. The term "urea" as used in this description includes the compound urea itself, as well as compounds equivalent in effect. Thus, unless otherwise specified, reference in this disclosure to urea should not

15 be taken as limiting to urea itself, but should extend to urea and all of its equivalents. It is pointed out that the term equivalent is not limited to exact equivalents, and various equivalents will be optimally operable at some conditions which are different than those for other 0 equivalents. Moreover, some equivalents may be more effective than others.

Advantageously, the treatment agent of this invention is injected into the effluent in solution or as a dispersion or mixture in a suitable solvent. Water is a 5 preferred solvent due to the economy of aqueous solutions, dispersions and mixtures and the fact that they can be employed with suitable effectiveness in most situations. For ease of description, the term "mixture" will be used to denote mixtures, dispersions and solutions. The 0. effective mixture comprising the treatment agent of this invention will range from saturated to dilute. While water is an effective solvent for most applications, it will be recognized that there may be instances where other solvents may be advantageously used, either alone or in combination with water, as would be known to the skilled artisan.

The level of heterocyclic hydrocarbon present in the mixture is advantageously in the range of about 0.5% to about 25% by weight, preferably about 5% to about 15% by weight. Where urea is employed in the treatment agent, it should preferably be present in the mixture in the range of about 2% to about 60%, most preferably about 5% to about 30% by weight. The weight ratio of heterocyclic hydrocarbon to urea, when urea is used with the heterocyclic hydrocarbon as the treatment agent in mixture, should advantageously be about 1:10 to about 4:1, more preferably about 1:5 to about 3:1. The most preferred weight ratio of heterocyclic hydrocarbon to urea in the mixture is about 1:4 to about 2.5:1.

The temperature of the effluent at the point .of injection will have an influence on the concentration of the mixture. At temperatures of about 1300°F. to about 1700°F., the mixture will tend to operate effectively at high concentration, e.g., about 10% to about 65% by weight treatment agent. On the other hand, at temperatures in excess of about 1700°F., the solution will tend more towards dilute. At these higher temperatures, water (or the solvent in case of non-aqueous solutions) may comprise greater than 80%, 85% or even 90% by weight of the solution.

The treatment agent of this invention is preferably injected into the effluent in an amount effective to elicit a reduction in the nitrogen oxides concentration in the effluent. Advantageously, the treatment agent of this invention is injected into the effluent in an amount sufficient to provide a molar ratio of the nitrogen contained in the treatment agent to the baseline nitrogen oxides level of about 1:5 to about 10:1. More preferably, the treatment agent is injected into the effluent to provide a molar ratio of treatment agent nitrogen to baseline nitrogen oxides level of about 1:3 to about 5:1, 5 most preferably about 1:2 to about 3:1.

In situations where the treatment agent comprises urea as well as the heterocyclic hydrocarbon, the injection ratio can alternatively be expressed as the normalized stoichiometric ratio (NSR) of the treatment agent to the

10 baseline nitrogen oxides level. Normalized stoichiometric ratio is the ratio of the concentration of NH_χ radicals (NH_χ radicals, with x being an integer, are believed to be the moiety contributed by urea which facilitates the series of reactions resulting in NO_χ breakdown) to the

15 concentration of nitrogen oxides in the effluent and can be expressed as [NH_χ]/[NO_χ].

The treatment agent, whether in a mixture or injected in pure form, is preferably injected into the effluent gas stream at a point where the effluent is at a temperature

20 above about 1300°F. , more preferably above about 1400°F.and most preferably above about 1450°F. Large industrial and circulating fluidized bed boilers of the types employed for utility power plants and other large facilities will typically have access only at limited

25 points. In the most typical situations, the boiler interior in the area above the flame operates at temperatures which at full load approach 1900°F., even 2000°F. After subsequent heat exchange, the temperature will be lower, usually in the range between about

30. 1300°F. and about 1900°F. At these temperatures, the treatment agent of this invention can be effectively introduced to accomplish substantial reduction of nitrogen oxides in the effluent. The treatment agent utilized according to this invention is preferably injected at a number of spaced positions from nozzles or other apparatus which are effective to uniformly distribute the treatment agent through the combustion effluent.

The effluent into which the treatment agent of this invention is injected is preferably oxygen-rich, meaning that there is an excess of oxygen in the effluent. Advantageously, the excess of oxygen is greater than about 1% by volume. Most preferably, the excess of oxygen is in the range of about 1% to about 12% or greater by volume.

It will be understood that the NO_χ reducing treatment agents of this invention are useful not only where substantial nitrogen oxides reductions are accomplished by directly applying the disclosed method as the principal NO_χ reducing method, but can also be employed as a discrete step in combination with other chemical, catalytic or other procedures for reducing nitrogen oxides concentrations as well as other pollutants such as sulfur dioxide (S0₂) , while preferably controlling levels of residual pollutants such as ammonia and/or carbon monoxide. Such a suitable "multi-step" process is disclosed in copending and commonly assigned U.S. Patent Application entitled "Multi-stage Process for Reducing the Concentration of Pollutants in an Effluent" having Attorney's Docket Number 937-00671, filed in the names of Epperly, Peter-Hoblyn, Shulof and Sullivan on March 6, 1987, the disclosure of which is incorporated herein by reference.

It is a surprising and advantageous result that the use of a heterocyclic hydrocarbon having at least one cyclic oxygen in the treatment agent of this invention will operate to increase the range of temperatures at which urea is found to be most^' effective at the reduction of NO_x in an effluent. As illustrated in Figure l, urea, when used alone or in combination with a compound disclosed in the prior art as being an enhancer for urea, such as ethylene glycol, will reduce the effluent nitrogen oxides concentration in a temperature dependent manner, with the optimal NO_χ-reduction within a relatively narrow range of temperatures. As also illustrated in Figure 1, when furfural, the most preferred heterocyclic hydrocarbon having at least one cyclic oxygen according to this invention, is injected as a treatment agent along with urea, the N0_χ reduction curve is significantly broader with respect to temperature. This broadened reduction curve is extremely desirable in practical applications, because a commercial boiler is not always operated at the same load, and, even when operated at the same load over a period of time, temperature variations are not uncommon which would take the urea curve out of its optimal range if the heterocyclic hydrocarbon were not employed.

A further advantageous aspect of the practice of this invention is in the reduced production of other pollutants, such as ammonia and carbon monoxide, during the nitrogen oxides reduction process. The presence of ammonia in the effluent should be avoided because, among other reasons, it can react with 0₃ ^s to form ammonium bisulfate which can foul heat exchange surfaces in a boiler. Moreover, ammonia has detrimental effects on ambient air quality, as has carbon monoxide. The reason f r the lower levels of ammonia and carbon monoxide is not fully understood but is probably because the series of reactions involving the heterocyclic hydrocarbon, urea and N0_χ which lead to the reduction of N0_χ concentrations simply does not produce substantial amounts of other pollutants as byproducts. The following examples further illustrate and explain the invention by detailing the operation of a treatment agent comprising a heterocyclic hydrocarbon having at least one cyclic oxygen in the reduction of nitrogen oxides emissions.

Exam le I

The burner used is a burner having an effluent flue conduit, known as a combustion tunnel, approximately 209 inches in length and having an internal diameter of 8 inches and walls 2 inches thick. The burner has a flame area adjacent the effluent entry port and flue gas monitors adjacent the effluent exit port to measure the concentration of compositions such as nitrogen oxides, sulfur oxides, ammonia, carbon monoxide, carbon dioxide, percent excess oxygen and other compounds of interest which may be present in the effluen . The effluent flue conduit additionally has thermocouple ports for temperature measurement at various locations. The temperature of the effluent into which the treatment agents are injected is measured at the point of injection utilizing a K-type thermocouple. Atomizing injectors described in copending and commonly assigned U.S. Patent Application entitled "Process and Apparatus for Reducing -the Concentration of Pollutants in an Effluent" having Serial Number 009,696, filed in the name of Burton on February 2, 1987, the disclosure of which is incorporated herein by reference, are positioned through ports in the effluent flue conduit in order to introduce and distribute the treatment agents into the effluent stream. The agents are injected into the effluent at a rate of 300 ml/hr. The burner fuel is a Number 2 fuel oil, and the burner is fired at a rate of 9.6 lbs/hr to 12.0 lbs/hr.

A baseline nitrogen oxides concentration reading is taken prior to beginning each run to calculate the injection ratio of treatment agent to baseline nitrogen oxides and the NSR, and a final nitrogen oxides reading is taken during and downstream from injection of the treatment agents to calculate the reduction in the nitrogen oxides concentration in the effluent elicited by each of the treatment agents injected.

The treatment agent injected is an aqueous solution which comprises 10% by weight of urea, 15% by weight of furfural, and 0.1% by weight of a commercially available surfactant. The injection temperature, % excess oxygen, NSR, baseline NO_x, final N0_χ and % reduction of N0_χ for each run is set out in Table 1 and reproduced ^•graphically in Figure 1.

Table 1

Run Temp. 0 % NSR NO_x (ppm) % Red. °F. Base- Final line

1 1400 3.1 1.83 195 137 29.7

2 1470 3.0 1.73 208 85 59.1

1510 3.0 2.11 170 71 58.2

1565 3.0 2.11 170 74 56.5

1615 3.0 2.11 170 80 52.9

1665 3.0 2.11 170 82 51.8

1690 3.0 2.11 170 86 49.4 Table 1 fcont.l

Run Temp. °2* NSR NO_χ (ppm) % Red. •°F. Base- Final line

8 1715 3.0 2.08 173 88 49.1

1755 3.1 2.06 145 70 51.7

10 1825 3.1 2.06 145 78 46.2

11 1875 3.0 2.07 145 110 24.1

12 1910 3.0 1.97 152 137 9.9

13 1940 3.0 1.97 152 203 -33.6

Example la

The procedure of Example I is repeated except that the treatment agent which is injected is an aqueous solution comprising 10% by weight of urea and 0.1% by weight of a commercially available surfactant. The results are set out in Table la and reproduced graphically in Figure 1.

Table la

Run Temp, O₂% NSR NO_χ (ppm) % Red. °F. Base- Final line

1660 3.2 2.22 166 145 12.7

1695 3.0 1.54 167 73 56.3 Table la (cont. )

Run Temp. o₂% NSR NO_χ (ppm) % Red.

'F. Base- Final JJIS

1750 3.0 1.92 150 70 53.3

1800 3.0 1.89 152 60 60.5

1850 3.0 1.85 155 68 56.1

1950 3.0 1.85 155 96 38.1

1980 3.0 1.81 159 107 32.7

Example lb

The procedure of Example I is repeated except that the treatment agent injected is an aqueous solution comprising 10% urea by weight, 15% ethylene glycol (disclosed as being an enhancer for urea in copending and commonly assigned U.S. Patent Application having serial Number 784,828, filed on October 4, 1985, the disclosure of which is incorporated herein by reference) by weight and 0.1% of a commercially available surfactant. The results are set out in Table lb and reproduced graphically in Figure 1.

Table lb

Run Temp. O₂% NSR NO_x (ppm) % Red. °F. Base- Final line

1450 7.0 1.69 145 125 13.8 Table lb fcont.ϊ

Run Temp, o₂% NSR NO_χ (ppm) % Red. °F. Base- Final line

1515 3.1 1.76 178 98 44.9

1555 3.2 1.79 174 62 64.4

1650 3.0 1.91 165 70 57.6

1710 3.0 1.53 167 85 49.1

1720 3.0 1.45 167 112 32.9

It is clear from Tables 1, la and lb, as well as Figure 1, that the inclusion of a heterocyclic hydrocarbon having at least one cyclic oxygen, such as furfural, in a treatment agent with urea significantly broadens the optimum nitrogen oxides reducing curve.

Example II

The following example illustrates the ability of treatment agents which comprise a heterocyclic hydrocarbon having at least one cyclic oxygen to reduce N0_χ concentrations in an effluent without producing a substantial amount of other pollutants, such as ammonia and carbon monoxide. The procedure is similar to that of Example I, except that the treatment agent injected is an aqueous solution comprising 10% by weight of urea, 0.1% by weight of a commercially available surfactant and furfural at the concentrations shown in Table 2. The fuel supply rate is 9.6 lbs/hr. and the excess oxygen is 3.0%. The results of each run are set out in Table 2. Tafrle 2

% Furfural Temp. NSR NO_χ (ppm) %Red. NH₃ CO

°F Base- Final (ppm) (ppm) lins

1575 2.39 168 70 58.3 61 125

10 1580 2.26 168 65 61.3 32 79

15 1570 2.14 168 77 54.2 12.5 25

1695 2.37 169 57 66.3 32 16

It is clear from Table 2 that substantial reductions in nitrogen oxides concentrations can be elicited while avoiding substantial production of other pollutants by use of the treatment agent of this invention.

Example III

The boiler used is a circulating fluidized bed boiler having a configuration substantially as schematically illustrated in Figure 2. The boiler has a heat input of 1.2 mbtu/hr., firing bituminous coal. The effluent 0 temperature is measured using a K-type thermocouple at the point of injection, which is at a location at the top of the cyclone. Atomizing injectors described in copending U.S. Patent Application entitled "Process and Apparatus for Reducing the Concentration of Pollutants in an 5 Effluent" having Serial Number 009,696, filed in the name of Burton on February 2, 1987, the disclosure of which is

, incorporated herein by reference, are positioned at the injection point on top of the cyclone to inject the treatment agents into the effluent. The boiler also has flue gas monitors inserted in a sampler located between the gas duct and the heat exchangers to measure the concentration of compositions such as nitrogen oxides, sulfur oxides, ammonia, carbon monoxide, carbon dioxide, percent excess oxygen and other compounds of interest which may be present in the effluent.

A baseline nitrogen oxides concentration reading is taken prior to beginning each run to calculate the injection ratio of treatment agent to baseline nitrogen oxides and the NSR, and a final nitrogen oxides reading is taken during and downstream from injection of the treatment agents to calculate the reduction in the nitrogen oxides concentration in the effluent elicited by each of the treatment agents injected. All nitrogen oxides level are corrected to 3.0% oxygen.

The following runs are made:

1. An aqueous solution comprising 25% by weight of urea, 10% by weight of furfural and 0.1% by weight of a commercially available surfactant is injected into the effluent at an effluent temperature of 1596°F. and an excess of oxygen of 7.0%. The rate of injection is 11.0 ml/min. to provide an NSR of 1.5. The results are set out in Table 3.

2. An aqueous solution comprising 25% by weight of urea, 10% by weight of furfural and 0.1% by weight of a commercially available surfactant is injected into the effluent at an effluent temperature of 1609°F. and an excess of oxygen of 6.2%. The rate of injection is 14.4 ml/min. to provide an NSR of 2.0. The results are set out in Table 3.

3. An aqueous solution comprising 17.5% by weight of urea, 7.5% by weight of hexamethylenetetramine (disclosed as being an enhancer for urea in copending and commonly assigned U.S. Patent Application entitled "Reduction of Nitrogen- and Carbon-Based Pollutants", Serial Number 906,671, filed in the name of Bowers on September 10, 1986, the disclosure of which is incorporated herein by reference) , 10% by weight of furfural and 0.1% by weight of a commercially available surfactant is injected into the effluent at an effluent temperature of 1512°F. and an excess of oxygen of 10.3%. The rate of injection is 12.4 ml/min. to provide an NSR of 1.9. The results are set out in Table 3.

4. An aqueous solution comprising 25% by weight of urea, 10% by weight of furfural and 0.1% by weight of a commercially available surfactant is injected into the effluent at an effluent temperature of 1596°F. and an excess of oxygen of 3.1%. The rate of injection is 7.0 ml/min. to provide an NSR of 1.9. The results are set out in Table 3.

Table ?

Run NO_χ (ppm) N0_χ (ppm) % Red. Baseline final

1 141 48 65.8

2 141 56 60.5

3 153 59 61.4

4 76 27 64.6

It is clear from Table 3 that the inclusion of a heterocyclic hydrocarbon having at least one cyclic oxygen, such as furfural, in a treatment agent with urea elicits significant nitrogen oxides reductions, even in an effluent having extremely high excess oxygen.

The above description is for the purpose of teaching the person of ordinary skill in the art how to practice the present invention, and it is not intended to detail all of those obvious modifications and variations of it which will become apparent to the skilled worker upon reading the description. It is intended, however, that all such obvious modifications and variations be included within the scope of the present invention which is defined y the following claims.

Claims

Qlsάms.

1. A process for the reduction of the concentration of nitrogen oxides in the effluent from the combustion of a carbonaceous fuel, the process comprising injecting a treatment agent which comprises a heterocyclic hydrocarbon having at least one cyclic oxygen into the effluent under conditions effective to reduce the concentration of nitrogen oxides in the effluent.

2. The process of claim 1 wherein said treatment agent further comprises urea.

3. The process of claim 2 wherein said heterocyclic hydrocarbon comprises furfural.

4. The process of claim 3 wherein the temperature of the effluent is greater than about 1300°F.

5. The process of claim 4 wherein the temperature of the effluent is greater than about 1450°F.

6. The process of claim 3 wherein the temperature of the effluent is below about 2000°F.

7. The process of claim 4 wherein said treatment agent is injected into the effluent at a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen oxides level of 1:5 to about 10:1.

8. The process of claim 7 wherein the molar ratio of treatment agent nitrogen to the baseline nitrogen oxides level is about 1:3 to about 5:1.

9. The process of claim 3 wherein said treatment agent is in solution, in a mixture or in a dispersion.

10. The process of claim 9 wherein the solvent used in said solution, mixture or dispersion comprises water.

11. The process of claim 10 wherein urea is present in said solution, mixture or dispersion in an amount of about 2% to about 60% by weight.

12. The process of claim 11 wherein furfural is present in said solution, mixture or dispersion in an amount of about 0.5% to about 25% by weight.

13. The process of claim 1 wherein the effluent is comprises an excess of oxygen.

14. The process of claim 13 wherein said effluent has an excess of oxygen of no greater than about 12% by volume.

15. The process of claim 14 wherein said excess of oxygen in the effluent is about 1% to about 6% by volume.

16. A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel, the process comprising injecting a treatment agent which comprises urea and a heterocyclic hydrocarbon having at least one cyclic oxygen into an effluent having a temperature of greater than about 1300°F. under conditions effective to reduce the concentration of nitrogen oxides in the effluent.

17. The process of claim 16 wherein said heterocyclic hydrocarbon comprises furfural.

18. The process of claim 17 wherein the effluent is at a temperature of greater than about 1450°F.

19. The process of claim 17 wherein the temperature of the effluent is below about 2000°F.

20. The process of claim 17 wherein said treatment agent is in solution, in a mixture or in a dispersion.

21. The process of claim 20 wherein the solvent used in said solution, mixture or dispersion comprises water.

22. The process of claim 21 wherein urea is present in said solution, mixture or dispersion in an amount of about 2% to about 60% by weight.

23. The process of claim 22 wherein furfural is present in said solution, mixture or dispersion in an amount of about 0.5% to about 25% by weight.

24. The process of claim 17 wherein said treatment agent is injected into the effluent at a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen oxides level of about 1:5 to about 10:1.

25. The process of claim 24 wherein the molar ratio of treatment agent nitrogen to baseline nitrogen oxides level is about 1:3 to about 5:1.

26. The process of claim 16 wherein said effluent has an excess of oxygen of no greater than about 12% by volume.

27. A process for the reduction of the concentration of nitrogen oxides in the oxygen-rich effluent from the combustion of a carbonaceous fuel, the process comprising injecting a treatment agent which comprises an aqueous solution, mixture or dispersion of about 2% to about 60% urea by weight and about 0.5% to about 25% furfural by weight into an effluent having an excess of oxygen of about 1% to about 6% by volume and a temperature of about 1450°F. to about 1900°F. in an amount sufficient to provide a molar ratio of the nitrogen contained in said treatment agent to the baseline nitrogen oxides level of about 1:3 to about 5:1, under conditions effective to reduce the nitrogen oxides level in the effluent.