ATE848T1 - PROCESS FOR THE PREPARATION OF METHYLENE BRIDGE POLYARYLAMINES. - Google Patents

PROCESS FOR THE PREPARATION OF METHYLENE BRIDGE POLYARYLAMINES.

Info

Publication number
ATE848T1
ATE848T1 AT79102584T AT79102584T ATE848T1 AT E848 T1 ATE848 T1 AT E848T1 AT 79102584 T AT79102584 T AT 79102584T AT 79102584 T AT79102584 T AT 79102584T AT E848 T1 ATE848 T1 AT E848T1
Authority
AT
Austria
Prior art keywords
mda
polyarylamines
preparation
pmppa
perfluoro
Prior art date
Application number
AT79102584T
Other languages
German (de)
Inventor
Efim Biller
Original Assignee
Gebrueder Sulzer Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gebrueder Sulzer Aktiengesellschaft filed Critical Gebrueder Sulzer Aktiengesellschaft
Application granted granted Critical
Publication of ATE848T1 publication Critical patent/ATE848T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08G12/06—Amines
    • C08G12/08—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Through condensation ortho- and para-isomers of methylene dianiline (MDA) as well as PMPPA are produced as condensation products from arylamines, especially from aniline, and formaldehyde in the presence of acid catalysts, in which at least one component is a perfluoro-carbonic acid. From this mixture of the condensation products, 4,4'-MDA (p-isomer) of high purity is obtained by crystallization while the homogeneous aqueous solution obtained is being cooled down. It has been discovered that the 4,4'-MDA salts of the perfluoro-carbonic acids are less soluble in water than the corresponding salts of the o-isomers and the PMPPA.
AT79102584T 1978-09-12 1979-07-21 PROCESS FOR THE PREPARATION OF METHYLENE BRIDGE POLYARYLAMINES. ATE848T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH953778 1978-09-12
EP79102584A EP0009094B1 (en) 1978-09-12 1979-07-21 Process for the preparation of methylene-bridge polyaryl amines

Publications (1)

Publication Number Publication Date
ATE848T1 true ATE848T1 (en) 1982-04-15

Family

ID=4353041

Family Applications (1)

Application Number Title Priority Date Filing Date
AT79102584T ATE848T1 (en) 1978-09-12 1979-07-21 PROCESS FOR THE PREPARATION OF METHYLENE BRIDGE POLYARYLAMINES.

Country Status (8)

Country Link
US (1) US4297511A (en)
EP (1) EP0009094B1 (en)
JP (1) JPS5555144A (en)
AT (1) ATE848T1 (en)
BR (1) BR7905790A (en)
DD (1) DD145911A5 (en)
DE (1) DE2962512D1 (en)
PT (1) PT70004A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3142529A1 (en) * 1981-10-27 1983-05-05 Lentia GmbH Chem. u. pharm. Erzeugnisse - Industriebedarf, 8000 München METHOD FOR PRODUCING DIAMINES OF THE DIPHENYLMETHANE SERIES
DE19513269A1 (en) * 1995-04-07 1996-10-10 Bayer Ag Fractionation and purification of aromatic polyamine mixtures and their use

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2938054A (en) * 1958-02-18 1960-05-24 Allied Chem Process for purification of 4, 4'-methylenedianiline
FR1549769A (en) * 1966-12-20 1968-12-13
US3954867A (en) * 1969-10-20 1976-05-04 Funk Jr Bernard D Continuous process for preparing methylene dianilines
DE2127263A1 (en) * 1971-06-02 1973-01-04 Bayer Ag PROCESS FOR THE PRODUCTION OF AROMATIC POLYAMINES
US4025557A (en) * 1972-06-03 1977-05-24 Bayer Aktiengesellschaft Process for the production of polyamines
CA1004234A (en) * 1972-08-04 1977-01-25 Bayer Aktiengesellschaft Process for the production of polyamines
DE2500573A1 (en) * 1975-01-09 1976-07-15 Bayer Ag PROCESS FOR PRODUCING POLYAMINES
DE2528694C2 (en) * 1975-06-27 1982-04-22 Bayer Ag, 5090 Leverkusen Process for the preparation of polynuclear aromatic polyamines
DE2648982C2 (en) * 1975-11-11 1985-07-11 Efim Zürich Biller Process for the preparation of polyarylamines containing methylene bridges
US4201722A (en) * 1976-06-04 1980-05-06 The Upjohn Company Process for separating 4,4'-diaminodiphenylmethane
DE2748968A1 (en) * 1976-11-06 1978-05-11 Elprochine Ag PROCESS FOR THE PRODUCTION OF METHYLENE BRIDGES POLYARYLAMINES
US4130588A (en) * 1977-02-02 1978-12-19 The Dow Chemical Company Process for producing methylene dianiline

Also Published As

Publication number Publication date
EP0009094A3 (en) 1980-04-16
BR7905790A (en) 1980-07-15
US4297511A (en) 1981-10-27
EP0009094B1 (en) 1982-04-14
DE2962512D1 (en) 1982-05-27
JPS5555144A (en) 1980-04-22
PT70004A (en) 1979-08-01
DD145911A5 (en) 1981-01-14
EP0009094A2 (en) 1980-04-02

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Legal Events

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