ATE433793T1 - Verfahren zur entfernung von cos aus einem h2s und cos enthaltenden synthesegasstrom - Google Patents

Verfahren zur entfernung von cos aus einem h2s und cos enthaltenden synthesegasstrom

Info

Publication number
ATE433793T1
ATE433793T1 AT05767964T AT05767964T ATE433793T1 AT E433793 T1 ATE433793 T1 AT E433793T1 AT 05767964 T AT05767964 T AT 05767964T AT 05767964 T AT05767964 T AT 05767964T AT E433793 T1 ATE433793 T1 AT E433793T1
Authority
AT
Austria
Prior art keywords
cos
gas stream
synthesis gas
removal
stream containing
Prior art date
Application number
AT05767964T
Other languages
English (en)
Inventor
Hardeveld Robert Martijn Van
Rudolf Henri Herold
Adriaan Johannes Kodde
Thijme Last
Cornelis Jacobus Smit
Rudolf Robert Gouman
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Application granted granted Critical
Publication of ATE433793T1 publication Critical patent/ATE433793T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/52—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
    • C01B3/54—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids including a catalytic reaction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/30—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AT05767964T 2004-07-22 2005-07-22 Verfahren zur entfernung von cos aus einem h2s und cos enthaltenden synthesegasstrom ATE433793T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04254366 2004-07-22
PCT/EP2005/053563 WO2006008317A1 (en) 2004-07-22 2005-07-22 Process for the removal of cos from a synthesis gas stream comprising h2s and cos

Publications (1)

Publication Number Publication Date
ATE433793T1 true ATE433793T1 (de) 2009-07-15

Family

ID=34930513

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05767964T ATE433793T1 (de) 2004-07-22 2005-07-22 Verfahren zur entfernung von cos aus einem h2s und cos enthaltenden synthesegasstrom

Country Status (10)

Country Link
US (1) US7846325B2 (de)
EP (1) EP1791622B1 (de)
CN (1) CN101031350A (de)
AT (1) ATE433793T1 (de)
AU (1) AU2005263776B2 (de)
DE (1) DE602005015007D1 (de)
EA (1) EA010025B1 (de)
MY (1) MY140997A (de)
WO (1) WO2006008317A1 (de)
ZA (1) ZA200700161B (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1973841A1 (de) * 2006-01-18 2008-10-01 Shell Internationale Research Maatschappij B.V. Verfahren zur entfernung von carbonylsulfid und schwefelwasserstoff aus einem synthesegasstrom
CN101553303B (zh) * 2006-12-08 2011-12-28 国际壳牌研究有限公司 用于生产纯化的合成气物流的方法
MY149141A (en) 2007-06-18 2013-07-15 Shell Int Research Process for removal of hydrogen cyanide and ammonia from synthesis gas
CN101121123B (zh) * 2007-07-25 2010-05-19 太原理工大学 中温二硫化碳水解催化剂及其制备方法与用途
CN101918111B (zh) * 2007-10-26 2014-10-08 赫多特普索化工设备公司 用于降低合成气中含硫化合物、氰化氢和甲酸的量的方法
US7682424B2 (en) * 2008-01-31 2010-03-23 Conocophillips Company Contaminant removal from a gas stream
CN101224871B (zh) * 2008-02-03 2011-02-16 湖北省化学研究院 合成气的深度净化方法
DE102008032166A1 (de) * 2008-07-08 2010-01-14 Karl-Heinz Tetzlaff Verfahren und Vorrichtung zur Herstellung von teerfreiem Synthesgas aus Biomasse
US7909913B2 (en) 2008-07-17 2011-03-22 Air Products And Chemicals, Inc. Gas purification by adsorption of hydrogen sulfide
DK200801093A (en) * 2008-08-13 2010-02-14 Topsoe Haldor As Process and system for removing impurities from a gas stream
FR2940919B1 (fr) * 2009-01-12 2011-12-09 Inst Francais Du Petrole Utilisation d'une composition a base de tio2 pour la captation de composes halogenes contenus dans un melange gazeux
FR2940920B1 (fr) * 2009-01-12 2011-10-21 Inst Francais Du Petrole Procede d'elimination d'impuretes soufrees, azotees et halogenees contenues dans un gaz de synthese
US20120095119A1 (en) * 2009-03-30 2012-04-19 Isaac Cormelis Van Den Born Process for producing purified synthesis gas
CN102378735A (zh) * 2009-03-30 2012-03-14 国际壳牌研究有限公司 用于生产纯化的合成气物流的方法
US8974758B2 (en) * 2009-05-07 2015-03-10 American Air Liquide, Inc. Methods of purifying COS
CN102463129B (zh) * 2010-11-17 2013-12-04 中国石油化工股份有限公司 用于羰基硫水解的催化剂
CA2782944C (en) * 2012-02-17 2014-11-04 Archon Technologies Ltd. Process for the removal of sulfur compounds from gas streams
CN103055661A (zh) * 2012-12-31 2013-04-24 东南大学 一种高温脱除烟气中酸性气体的装置及其方法
JP6122664B2 (ja) * 2013-03-05 2017-04-26 三菱重工業株式会社 ガス精製装置およびガス精製方法
CN106563475B (zh) * 2016-11-04 2020-04-03 昆明理工大学 一种同时催化水解羰基硫和二硫化碳的改性硅基催化剂的制备方法
CN107649176B (zh) * 2017-09-22 2019-12-24 昆明理工大学 一种用于氰化氢催化水解的催化剂及制备方法
US20190233734A1 (en) * 2018-01-26 2019-08-01 Greyrock Energy, Inc. Micro-scale process for the direct production of liquid fuels from gaseous hydrocarbon resources
US20210300766A1 (en) * 2018-07-17 2021-09-30 Sabic Global Technologies B.V. Process for removal of sulfides from carbon monoxide rich gas stream at ambient temperatures
US11508490B2 (en) 2020-03-11 2022-11-22 Henry Crichlow Managing volatiles in nuclear waste vitrification

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GB1068588A (en) * 1963-12-23 1967-05-10 Gas Council Method of treating gases
US3441370A (en) * 1966-04-25 1969-04-29 Catalysts & Chem Inc Method of removing sulfur compounds from gases
US3974256A (en) * 1974-05-07 1976-08-10 Exxon Research And Engineering Company Sulfide removal process
US4254094A (en) * 1979-03-19 1981-03-03 Air Products And Chemicals, Inc. Process for producing hydrogen from synthesis gas containing COS
GB8610196D0 (en) * 1986-04-25 1986-05-29 Ici Plc Sulphur compounds removal
US4888131A (en) * 1988-03-28 1989-12-19 Exxon Research And Engineering Company Synthesis gas preparation and catalyst therefor
NL9002661A (nl) 1990-12-04 1992-07-01 Pacques Bv Werkwijze voor de verwijdering van h2s uit gas.
ZA935964B (en) * 1992-08-18 1994-03-15 Shell Res Ltd Process for the preparation of hydrocarbon fuels
DE4321542C1 (de) * 1993-06-29 1994-09-01 Bfi Entsorgungstech Verfahren zur getrennten Entfernung von Schwefelverbindungen und CO¶2¶ aus Gas
GB9404191D0 (en) 1994-03-04 1994-04-20 Imperial College Preparations and uses of polyferric sulphate
US5463168A (en) * 1994-08-17 1995-10-31 Mobil Oil Corporation Process for the removal of hydrogen cyanide from FCC hydrocarbon product gas streams
DE4431788A1 (de) 1994-09-07 1996-03-14 Huels Chemische Werke Ag Katalysator und Verfahren zur Zersetzung von HCN in Gasen
DE69607423T2 (de) 1995-08-08 2000-08-03 Exxon Research Engineering Co Verfahren zur Beseitigung von Cyanwasserstoff aus Synthesegas
FR2740704B1 (fr) * 1995-11-03 1997-12-26 Elf Aquitaine Procede d'elimination quasi totale des composes soufres h2s, so2, cos et/ou cs2 contenus dans un gaz residuaire d'usine a soufre, avec recuperation desdits composes sous la forme de soufre
WO1999034917A1 (en) 1997-12-30 1999-07-15 Shell Internationale Research Maatschappij B.V. Cobalt based fisher-tropsch catalyst
US6168768B1 (en) * 1998-01-23 2001-01-02 Exxon Research And Engineering Company Production of low sulfer syngas from natural gas with C4+/C5+ hydrocarbon recovery
US5882614A (en) * 1998-01-23 1999-03-16 Exxon Research And Engineering Company Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes
US6322763B1 (en) * 1998-12-15 2001-11-27 Teco, Inc. Method and apparatus for removing carbonyl sulfide from a gas stream via wet scrubbing
GB0118416D0 (en) 2001-07-30 2001-09-19 Ici Plc Desulphurisation

Also Published As

Publication number Publication date
EA200700095A1 (ru) 2007-06-29
AU2005263776B2 (en) 2008-07-31
MY140997A (en) 2010-02-12
CN101031350A (zh) 2007-09-05
EP1791622A1 (de) 2007-06-06
WO2006008317A1 (en) 2006-01-26
US7846325B2 (en) 2010-12-07
AU2005263776A1 (en) 2006-01-26
ZA200700161B (en) 2008-06-25
US20080242749A1 (en) 2008-10-02
EA010025B1 (ru) 2008-06-30
DE602005015007D1 (de) 2009-07-30
EP1791622B1 (de) 2009-06-17

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