ATE323788T1 - SEPARATION OF METALS - Google Patents
SEPARATION OF METALSInfo
- Publication number
- ATE323788T1 ATE323788T1 AT03778571T AT03778571T ATE323788T1 AT E323788 T1 ATE323788 T1 AT E323788T1 AT 03778571 T AT03778571 T AT 03778571T AT 03778571 T AT03778571 T AT 03778571T AT E323788 T1 ATE323788 T1 AT E323788T1
- Authority
- AT
- Austria
- Prior art keywords
- metal
- oxides
- metals
- metal oxides
- hafnium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/14—Obtaining zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Electrolytic Production Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention provides a process for the separation of metals, the metals being comprised as the metal oxides in a mixed oxide sample, the process comprising: (i) adding the mixed oxide to a molten salt electrolyte and cathodically electrolysing the oxide, the potential of the cathode being controlled so as to favour oxygen ionisation over deposition of metal from the cations present in the molten salt, and the applied potential difference being such as to facilitate selective reduction of one metal oxide at the expense of other metal oxides; and (ii) separating the metal from the remaining metal oxides, wherein the metal oxides comprise oxides of metals from at least one of the transition metal, lanthanide or actinide series The process is applicable to mixed oxide samples comprising mixtures of two or more metal oxides, and a particular application is in the separation of zirconium and hafnium comprised in mixed zirconium and hafnium oxides, the removal of hafnium facilitating the use of the zirconium in fuel cladding for use in the nuclear power industry.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0228322A GB2395958A (en) | 2002-12-05 | 2002-12-05 | Electrolytic separation of metals |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE323788T1 true ATE323788T1 (en) | 2006-05-15 |
Family
ID=9949081
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT03778571T ATE323788T1 (en) | 2002-12-05 | 2003-12-02 | SEPARATION OF METALS |
Country Status (8)
Country | Link |
---|---|
US (1) | US20060137992A1 (en) |
EP (1) | EP1570114B1 (en) |
JP (1) | JP2006509104A (en) |
AT (1) | ATE323788T1 (en) |
AU (1) | AU2003285572A1 (en) |
DE (1) | DE60304738D1 (en) |
GB (1) | GB2395958A (en) |
WO (1) | WO2004050955A2 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0113749D0 (en) * | 2001-06-06 | 2001-07-25 | British Nuclear Fuels Plc | Actinide production |
GB0601697D0 (en) * | 2006-01-27 | 2006-03-08 | Pryde Neil Ltd | Garment affording protection against knocks or blows |
JP2010013668A (en) * | 2008-06-30 | 2010-01-21 | Toshiba Corp | Method for producing metallic zirconium |
US20100219344A1 (en) * | 2009-02-27 | 2010-09-02 | Battelle Memorial Institute | Electrochemically Modulated Separations for In-line and At-line Monitoring of Actinides in High-Volume Process Streams |
JP5534700B2 (en) * | 2009-04-06 | 2014-07-02 | 株式会社東芝 | Electrolytic production apparatus and production method for metal |
CN108277507A (en) * | 2018-02-06 | 2018-07-13 | 北京科技大学 | A kind of method of vanadium and chromium in electrolytic separation containing vanadium and chromium fused salt |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3011865A (en) * | 1960-08-22 | 1961-12-05 | Glen E Benedict | Separation of uranium and plutonium oxides |
US4762694A (en) * | 1987-05-01 | 1988-08-09 | The United States Of America As Represented By The United States Department Of Energy | Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals |
US4923577A (en) * | 1988-09-12 | 1990-05-08 | Westinghouse Electric Corp. | Electrochemical-metallothermic reduction of zirconium in molten salt solutions |
US4995948A (en) * | 1989-07-24 | 1991-02-26 | The United States Of America As Represented By The United States Department Of Energy | Apparatus and process for the electrolytic reduction of uranium and plutonium oxides |
KR970007520B1 (en) * | 1993-04-05 | 1997-05-09 | 산도쿠긴조쿠 고교 가부시키가이샤 | Method for collecting valuable metal from nickel hydrogen secondary cell |
US5454914A (en) * | 1993-12-23 | 1995-10-03 | The United States Of America As Represented By The United States Department Of Energy | Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing |
GB9812169D0 (en) * | 1998-06-05 | 1998-08-05 | Univ Cambridge Tech | Purification method |
GB9928655D0 (en) * | 1999-12-03 | 2000-02-02 | British Nuclear Fuels Plc | Actinide production |
GB2359564B (en) * | 2000-02-22 | 2004-09-29 | Secr Defence | Improvements in the electrolytic reduction of metal oxides |
GB0104253D0 (en) * | 2001-02-21 | 2001-04-11 | British Nuclear Fuels Plc | Process for separating metals |
GB0113749D0 (en) * | 2001-06-06 | 2001-07-25 | British Nuclear Fuels Plc | Actinide production |
-
2002
- 2002-12-05 GB GB0228322A patent/GB2395958A/en not_active Withdrawn
-
2003
- 2003-12-02 WO PCT/GB2003/005238 patent/WO2004050955A2/en active IP Right Grant
- 2003-12-02 DE DE60304738T patent/DE60304738D1/en not_active Expired - Lifetime
- 2003-12-02 AU AU2003285572A patent/AU2003285572A1/en not_active Abandoned
- 2003-12-02 JP JP2004556519A patent/JP2006509104A/en active Pending
- 2003-12-02 EP EP03778571A patent/EP1570114B1/en not_active Expired - Lifetime
- 2003-12-02 AT AT03778571T patent/ATE323788T1/en not_active IP Right Cessation
- 2003-12-02 US US10/537,744 patent/US20060137992A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
GB2395958A (en) | 2004-06-09 |
WO2004050955A2 (en) | 2004-06-17 |
EP1570114A2 (en) | 2005-09-07 |
JP2006509104A (en) | 2006-03-16 |
DE60304738D1 (en) | 2006-05-24 |
GB0228322D0 (en) | 2003-01-08 |
EP1570114B1 (en) | 2006-04-19 |
AU2003285572A1 (en) | 2004-06-23 |
WO2004050955A3 (en) | 2005-01-13 |
US20060137992A1 (en) | 2006-06-29 |
AU2003285572A8 (en) | 2004-06-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |