ATE23867T1 - POLYMERIZATION PROCESS OF VINYLIDE FLUORIDE IN AN AQUEOUS SUSPENSION. - Google Patents

POLYMERIZATION PROCESS OF VINYLIDE FLUORIDE IN AN AQUEOUS SUSPENSION.

Info

Publication number
ATE23867T1
ATE23867T1 AT84200275T AT84200275T ATE23867T1 AT E23867 T1 ATE23867 T1 AT E23867T1 AT 84200275 T AT84200275 T AT 84200275T AT 84200275 T AT84200275 T AT 84200275T AT E23867 T1 ATE23867 T1 AT E23867T1
Authority
AT
Austria
Prior art keywords
vinylidene fluoride
aqueous suspension
polymerization process
alkyl
polymerization
Prior art date
Application number
AT84200275T
Other languages
German (de)
Inventor
Joseph Dumoulin
Original Assignee
Solvay
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solvay filed Critical Solvay
Application granted granted Critical
Publication of ATE23867T1 publication Critical patent/ATE23867T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/22—Vinylidene fluoride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Process for the polymerization, in an aqueous suspending medium, of vinylidene fluoride with the aid of an oil-soluble free radical polymerization initiator in the presence of a suspending agent and a chain regulator chosen from the bis(alkyl) carbonates, the alkyl groupings of which contain not more that five carbon atoms wherein the molecular weight of vinylidene fluoride polymers are effectively regulated without having a detrimental effect on the polymerization yield, thus the vinylidene fluoride polymers have a good stability to heat.
AT84200275T 1983-03-10 1984-02-28 POLYMERIZATION PROCESS OF VINYLIDE FLUORIDE IN AN AQUEOUS SUSPENSION. ATE23867T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8304106A FR2542319B1 (en) 1983-03-10 1983-03-10 PROCESS FOR POLYMERIZATION IN AN AQUEOUS SUSPENSION MEDIUM OF VINYLIDENE FLUORIDE
EP84200275A EP0120524B1 (en) 1983-03-10 1984-02-28 Process to polymerize vinylidene fluoride in an aqueous suspension

Publications (1)

Publication Number Publication Date
ATE23867T1 true ATE23867T1 (en) 1986-12-15

Family

ID=9286814

Family Applications (1)

Application Number Title Priority Date Filing Date
AT84200275T ATE23867T1 (en) 1983-03-10 1984-02-28 POLYMERIZATION PROCESS OF VINYLIDE FLUORIDE IN AN AQUEOUS SUSPENSION.

Country Status (7)

Country Link
US (1) US4524194A (en)
EP (1) EP0120524B1 (en)
JP (1) JPS59174605A (en)
AT (1) ATE23867T1 (en)
DE (1) DE3461469D1 (en)
ES (1) ES530448A0 (en)
FR (1) FR2542319B1 (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2652089B1 (en) * 1989-09-15 1993-03-19 Solvay PROCESS FOR THE DISCONTINUOUS POLYMERIZATION IN AN AQUEOUS SUSPENSION MEDIUM OF VINYLIDENE FLUORIDE AND USE OF THE RESULTING VINYLIDENE FLUORIDE POLYMERS FOR COATING ARTICLES BY POWDERING.
IT1265223B1 (en) * 1993-11-25 1996-10-31 Ausimont Spa PROCESS FOR THE PREPARATION OF POLYMERS OF VINYLIDENFLUORIDE
IT1271621B (en) * 1994-03-21 1997-06-04 Ausimont Spa PROCESS FOR THE PREPARATION OF THERMOPLASTIC FLUOROPOLYMERS CONTAINING HYDROGEN
IT1271622B (en) * 1994-03-21 1997-06-04 Ausimont Spa SUSPENSION (CO) POLYMERIZATION PROCESS FOR THE PREPARATION OF THERMOPLASTIC FLUOROPOLYMERS CONTAINING HYDROGEN
IT1274711B (en) * 1994-08-04 1997-07-24 Ausimont Spa PROCESS FOR THE PREPARATION OF FLUOROPOLYMERS CONTAINING HYDROGEN THROUGH (CO) SUSPENSION POLYMERIZATION
IT1270703B (en) 1994-11-17 1997-05-07 Ausimont Spa MICROEMULSIONS OF FLUOROPOLYXIALKYLENES IN A MIXTURE WITH HYDROCARBONS, AND THEIR USE IN PROCESSES OF (CO) POLYMERIZATION OF FLUORINATED MONOMERS
IT1276072B1 (en) 1995-10-31 1997-10-24 Ausimont Spa PROCESS OF (CO) POLYMERIZATION OF FLUORINATED MONOMERS TO OBTAIN HYDROGEN CONTAINING POLYMERS
IT1286028B1 (en) 1996-07-09 1998-07-07 Ausimont Spa SUSPENSION POLYMERIZATION PROCESS OF FLUORINATED MONOMERS
BE1011294A3 (en) * 1997-07-22 1999-07-06 Solvay Peroxydicarbonate organic solution dialkyl, method for obtaining, preparing halogenated polymers for intervention thereof and halogenated polymers obtained.
IT1298091B1 (en) * 1998-01-09 1999-12-20 Ausimont Spa PROCESS FOR THE PREPARATION OF DICHLOROFLUOROACETYL HALIDES
FR2804438A1 (en) * 2000-01-31 2001-08-03 Atofina Preparation of reduced-yellowing fluorinated polymer is carried out by aqueous emulsion polymerisation of vinylidene fluoride (and other monomers) using a lithium perfluoroalkanoate as surfactant
FR2850387B1 (en) * 2003-01-23 2005-03-04 Atofina PROCESS FOR PRODUCING PVDF
EP1743920A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic fluoropolymer composition
EP1743921A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic halopolymer composition
KR20080034164A (en) * 2005-08-19 2008-04-18 솔베이(소시에떼아노님) Process for manufacturing a plastic-based cellular structure and device for implementing this process
EP1795565B1 (en) * 2005-12-06 2016-05-18 Solvay Specialty Polymers Italy S.p.A. Water-based fluoropolymer composition
US8318819B2 (en) * 2007-08-03 2012-11-27 Cable Components Group, Llc Compositions for compounding foamable, fluropolymer pellets for use in melt processing cellular or foamed fluoropolymer applications
ATE540057T1 (en) * 2007-10-11 2012-01-15 Kureha Corp VINYLIDE FLUORIDE POLYMER POWDER AND USE THEREOF
JP5783902B2 (en) * 2008-10-16 2015-09-24 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア Opaque fluoropolymer compositions containing white pigments for photovoltaic elements of solar cells
KR101924660B1 (en) * 2010-12-22 2018-12-03 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. Hydrophilic vinylidene fluoride polymers
EP2631260A1 (en) 2012-02-27 2013-08-28 Solvay Sa Process for Producing Graphene-Polymer Nanocomposites
JP5938279B2 (en) * 2012-06-19 2016-06-22 株式会社クレハ Method for producing aqueous cellulose solution
US10032542B2 (en) 2014-11-07 2018-07-24 Cable Components Group, Llc Compositions for compounding, extrusion and melt processing of foamable and cellular halogen-free polymers
US10031301B2 (en) 2014-11-07 2018-07-24 Cable Components Group, Llc Compositions for compounding, extrusion, and melt processing of foamable and cellular polymers
JP7144298B2 (en) * 2018-03-06 2022-09-29 株式会社クレハ Method for producing vinylidene fluoride polymer

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL127087C (en) * 1964-10-21 1900-01-01
GB1094558A (en) * 1965-12-10 1967-12-13 Kureha Chemical Ind Co Ltd Polyvinylidene fluoride
US3780007A (en) * 1969-12-23 1973-12-18 Diamond Shamrock Corp Polymerization of vinylidene fluoride in aqueous suspension
US3708463A (en) * 1971-03-18 1973-01-02 Diamond Shamrock Corp Process for preparing vinylidene fluoride polymers for coating applications
US3723387A (en) * 1971-05-12 1973-03-27 Du Pont Preparation of curable and cured fluoropolymer products
US3781265A (en) * 1972-10-17 1973-12-25 Pennwalt Corp Method of preparing consistently high-quality vinylidene fluoride polymer
US4360652A (en) * 1981-08-31 1982-11-23 Pennwalt Corporation Method of preparing high quality vinylidene fluoride polymer in aqueous emulsion

Also Published As

Publication number Publication date
EP0120524A1 (en) 1984-10-03
FR2542319B1 (en) 1985-07-19
EP0120524B1 (en) 1986-11-26
US4524194A (en) 1985-06-18
ES8505703A1 (en) 1985-06-01
JPS59174605A (en) 1984-10-03
DE3461469D1 (en) 1987-01-15
JPH0348924B2 (en) 1991-07-26
FR2542319A1 (en) 1984-09-14
ES530448A0 (en) 1985-06-01

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Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
EEFA Change of the company name
REN Ceased due to non-payment of the annual fee