AT351254B - METHOD AND DEVICE FOR CONTINUOUS VAPOR PHASE POLYMERIZATION - Google Patents

METHOD AND DEVICE FOR CONTINUOUS VAPOR PHASE POLYMERIZATION

Info

Publication number
AT351254B
AT351254B AT956475A AT956475A AT351254B AT 351254 B AT351254 B AT 351254B AT 956475 A AT956475 A AT 956475A AT 956475 A AT956475 A AT 956475A AT 351254 B AT351254 B AT 351254B
Authority
AT
Austria
Prior art keywords
vapor phase
phase polymerization
continuous vapor
continuous
polymerization
Prior art date
Application number
AT956475A
Other languages
German (de)
Other versions
ATA956475A (en
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/533,019 external-priority patent/US3957448A/en
Priority claimed from US05/533,021 external-priority patent/US3971768A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of ATA956475A publication Critical patent/ATA956475A/en
Application granted granted Critical
Publication of AT351254B publication Critical patent/AT351254B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1868Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836Heating and cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/36Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed through which there is an essentially horizontal flow of particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/382Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it with a rotatable device only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00026Controlling or regulating the heat exchange system
    • B01J2208/00035Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/0007Pressure measurement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00026Controlling or regulating the heat exchange system
    • B01J2208/00035Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00088Flow rate measurement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00327Controlling the temperature by direct heat exchange
    • B01J2208/00336Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/00353Non-cryogenic fluids
    • B01J2208/00362Liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00389Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/0084Stationary elements inside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • B01J2219/00765Baffles attached to the reactor wall
    • B01J2219/00768Baffles attached to the reactor wall vertical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/182Details relating to the spatial orientation of the reactor horizontal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/194Details relating to the geometry of the reactor round
    • B01J2219/1941Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT956475A 1974-12-16 1975-12-16 METHOD AND DEVICE FOR CONTINUOUS VAPOR PHASE POLYMERIZATION AT351254B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US53302074A 1974-12-16 1974-12-16
US05/533,019 US3957448A (en) 1974-12-16 1974-12-16 Divided horizontal reactor for the vapor phase polymerization of monomers at different hydrogen levels
US05/533,021 US3971768A (en) 1974-12-16 1974-12-16 Vapor phase reactor off-gas recycle system for use in the vapor state polymerization of monomers

Publications (2)

Publication Number Publication Date
ATA956475A ATA956475A (en) 1978-12-15
AT351254B true AT351254B (en) 1979-07-10

Family

ID=27415110

Family Applications (1)

Application Number Title Priority Date Filing Date
AT956475A AT351254B (en) 1974-12-16 1975-12-16 METHOD AND DEVICE FOR CONTINUOUS VAPOR PHASE POLYMERIZATION

Country Status (13)

Country Link
JP (1) JPS5921321B2 (en)
AR (1) AR219479A1 (en)
AT (1) AT351254B (en)
BR (1) BR7508335A (en)
DD (1) DD124882A5 (en)
DE (1) DE2556418C2 (en)
ES (1) ES443515A1 (en)
FR (1) FR2335526A1 (en)
GB (1) GB1525978A (en)
IN (1) IN145649B (en)
IT (1) IT1052588B (en)
NL (1) NL183891C (en)
NO (1) NO144570C (en)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS532585A (en) * 1976-06-29 1978-01-11 Sumitomo Chem Co Ltd Preparation of polyethylene
US4130699A (en) * 1977-11-25 1978-12-19 Standard Oil Company (Indiana) Vapor phase polymerization with temporarily inactive titanium catalyst
JPS56159205A (en) * 1980-05-14 1981-12-08 Nippon Oil Co Ltd Equipment for olefin gas-phase polymerization
JPS56129204A (en) * 1980-03-14 1981-10-09 Nippon Oil Co Ltd Apparatus for vapor-phase polymerization of olefin
JPS59124911A (en) * 1982-12-29 1984-07-19 Chisso Corp Production of polypropylene
US4535134A (en) * 1983-03-31 1985-08-13 Standard Oil Company (Indiana) Method and apparatus for controlling the discharge of product from vapor phase polymerization of monomers in a horizontal stirred-bed reactor
EP0156060B1 (en) * 1984-03-15 1988-11-17 Hoxan Corporation Apparatus for producing polyacetylene film
DE3514367A1 (en) * 1985-04-20 1986-10-23 Basf Ag, 6700 Ludwigshafen DEVICE FOR SOLID BED POLYMERIZATION OF MONOMERS
DE3736316A1 (en) * 1987-10-27 1989-05-11 Loedige Maschbau Gmbh Geb REACTOR FOR TREATING Bulk goods or the like
JP2857916B2 (en) * 1990-07-20 1999-02-17 日本石油化学株式会社 Catalyst supply method for gas-phase polymerization fluidized bed
DE10014046A1 (en) 2000-03-23 2001-09-27 Basell Polypropylen Gmbh Chemical compound, process for its preparation and its use in catalyst systems for the production of polyolefins
DE10016625A1 (en) * 2000-04-04 2001-10-11 Basell Polyolefine Gmbh Gas phase polymerization process with direct cooling system
ATE464329T1 (en) 2001-11-19 2010-04-15 Ineos Europe Ltd POLYMERIZATION CONTROL METHOD
JP5308797B2 (en) 2007-12-11 2013-10-09 住友化学株式会社 Olefin polymerization reaction apparatus, polyolefin production system, and polyolefin production method
JP5249730B2 (en) 2007-12-11 2013-07-31 住友化学株式会社 Olefin polymerization reaction apparatus and polyolefin production method
JP5308795B2 (en) 2007-12-11 2013-10-09 住友化学株式会社 Polyolefin production method and polyolefin production system provided with spouted bed apparatus
JP5427396B2 (en) 2007-12-11 2014-02-26 住友化学株式会社 Powder transfer apparatus and polyolefin production method
JP5308794B2 (en) 2007-12-11 2013-10-09 住友化学株式会社 Polyolefin production method using spouted bed apparatus
US7799866B2 (en) 2007-12-28 2010-09-21 Sumitomo Chemical Company, Limited Method for producing propylene-ethylene block copolymer
CN102203140B (en) * 2008-08-21 2014-07-02 陶氏环球技术有限责任公司 High melt flow propylene impact copolymer and method
EP2344551B1 (en) 2008-09-25 2014-05-28 Basell Polyolefine GmbH Impact resistant lldpe composition and films made thereof
KR20110061584A (en) 2008-09-25 2011-06-09 바젤 폴리올레핀 게엠베하 Impact resistant lldpe composition and films made thereof
CN102325798A (en) * 2009-02-20 2012-01-18 伊内奥斯美国公司 Broadening the molecular weight distribution of polyolefins materials made in a horizontal stirred gas phase reactor
JP5545800B2 (en) 2009-06-08 2014-07-09 住友化学株式会社 Jet-fluidized bed type olefin polymerization reactor, polyolefin production system, and polyolefin production method
WO2014048892A1 (en) 2012-09-28 2014-04-03 Ineos Europe Ag Method for production of polymer
EP2909241B2 (en) 2012-10-16 2019-08-21 Ineos Europe AG Process for the production of a polymer in a gas phase fluidised bed reactor
JP6902337B2 (en) 2016-08-03 2021-07-14 住友化学株式会社 Method for producing heterophasic propylene polymerized material

Also Published As

Publication number Publication date
IT1052588B (en) 1981-07-20
NL183891B (en) 1988-09-16
NO754245L (en) 1976-06-17
AR219479A1 (en) 1980-08-29
FR2335526A1 (en) 1977-07-15
NO144570B (en) 1981-06-15
NL183891C (en) 1989-02-16
DD124882A5 (en) 1977-03-16
FR2335526B1 (en) 1979-07-27
DE2556418C2 (en) 1985-01-03
BR7508335A (en) 1976-08-24
GB1525978A (en) 1978-09-27
DE2556418A1 (en) 1976-06-24
NO144570C (en) 1981-09-23
ATA956475A (en) 1978-12-15
NL7514637A (en) 1976-06-18
JPS5921321B2 (en) 1984-05-19
IN145649B (en) 1985-01-05
JPS5186584A (en) 1976-07-29
ES443515A1 (en) 1977-08-01

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Legal Events

Date Code Title Description
EFA Change in the company name
ELA Expired due to lapse of time
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties