AT126110B - Process for improving the corrosion resistance of fittings made of magnesium alloys by treatment with bichromates. - Google Patents

Process for improving the corrosion resistance of fittings made of magnesium alloys by treatment with bichromates.

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Publication number
AT126110B
AT126110B AT126110DA AT126110B AT 126110 B AT126110 B AT 126110B AT 126110D A AT126110D A AT 126110DA AT 126110 B AT126110 B AT 126110B
Authority
AT
Austria
Prior art keywords
treatment
bichromates
improving
corrosion resistance
magnesium alloys
Prior art date
Application number
Other languages
German (de)
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Application granted granted Critical
Publication of AT126110B publication Critical patent/AT126110B/en

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  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

  

   <Desc/Clms Page number 1> 
 
 EMI1.1 
 



     Werkstücke   aus hochprozentigen   Magnesiumlegierungen   besitzen häufig oberflächliche Verunreinigungen, welche zu einer beschleunigten Korrosion Veranlassung geben. So z. B. sind   Gussstücke   mit einer Gusshaut überzogen, welche leicht angreifbare Verbindungen des Magnesiums enthält. Gepresste, gewalzte oder durch andere Mittel verformte Teile haben häufig eine Haut, welche Eisen oder verkohlte organische Produkte enthält, durch deren Gegenwart selbst nur in Spuren, wahrscheinlich infolge der Bildung von Lokalelementen. die korrodierende Wirkung der angreifenden Substanzen erhöht wird. 



   Es ist gefunden worden, dass diese Unbeständigkeit gegen Korrosion, z. B. im Falle der Gussstücke, beseitigt werden kann, wenn diese in einer wässerigen Lösung von Bichromaten (mit bis etwa 100   9   Cr03 im Liter) einige Zeit, beispielsweise eine oder mehrere Stunden, gekocht werden. Es lässt sich diese   Oberflächenbehandlung   noch durch eine Vorbehandlung der Stücke in verdünnter, beispielsweise   10 obiger Salpetersäure   verbessern, durch welche die Formstücke zunächst blank gebeizt und von verschiedenen vom Giessen in den Sandformen herstammenden Verunreinigungen befreit werden. 



   Im Falle der durch Walzen, Pressen, Spritzguss und andere Mittel verformten Werkstücke aus diesen Legierungen können ebenfalls die Oberflächen durch Behandlung mit dem kochenden Bichromatbad, welchem gegebenenfalls eine Vorbeize mit Salpetersäure vorausgegangen ist, in einen gegen den Angriff von wässerigen Lösungen aussergewöhnlich beständigen Zustand übergeführt werden. Die durch die Bichromatbehandlung entstehende veränderte Oberfläche weist ausserdem die vorteilhafte Eigenschaft auf, aufgetragene Lackschichten dauerhaft festzuhalten. 

**WARNUNG** Ende DESC Feld kannt Anfang CLMS uberlappen**.



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     Workpieces made from high-percentage magnesium alloys often have superficial impurities, which give rise to accelerated corrosion. So z. B. castings are covered with a cast skin, which contains easily attackable compounds of magnesium. Pressed, rolled or deformed parts by other means often have a skin containing iron or charred organic products, due to their presence even in traces, probably due to the formation of local elements. the corrosive effect of the attacking substances is increased.



   It has been found that this instability to corrosion, e.g. B. in the case of castings can be eliminated if they are boiled in an aqueous solution of bichromates (with up to about 100 9 Cr03 per liter) for some time, for example one or more hours. This surface treatment can be improved by pretreating the pieces in dilute, for example 10, nitric acid, by means of which the shaped pieces are initially pickled bright and freed from various impurities resulting from casting in the sand molds.



   In the case of workpieces made of these alloys by rolling, pressing, injection molding and other means, the surfaces can also be converted into an exceptionally resistant state against attack by aqueous solutions by treatment with the boiling bichromate bath, which may have been preceded by a pre-pickling with nitric acid . The changed surface resulting from the bichromate treatment also has the advantageous property of permanently holding on to the applied lacquer layers.

** WARNING ** End of DESC field may overlap beginning of CLMS **.

 

Claims (1)

PATENT-ANSPRUCH : Verfahren zur Verbesserung der Korrosionsbeständigkeit von Formstücken aus Magnesiumlegierungen durch Behandlung mit Bichromaten, dadurch gekennzeichnet, dass die Formstücke in einer wässerigen Lösung von Bichromat während einer Stunde oder mehr gekocht werden, gegebenenfalls nach einer vorausgehenden Beizung mit verdünnter Salpetersäure. **WARNUNG** Ende CLMS Feld Kannt Anfang DESC uberlappen**. PATENT CLAIM: Process for improving the corrosion resistance of fittings made of magnesium alloys by treatment with bichromates, characterized in that the fittings are boiled in an aqueous solution of bichromate for one hour or more, optionally after a previous pickling with dilute nitric acid. ** WARNING ** End of CLMS field may overlap beginning of DESC **.
AT126110D 1928-02-02 1929-01-07 Process for improving the corrosion resistance of fittings made of magnesium alloys by treatment with bichromates. AT126110B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE126110X 1928-02-02

Publications (1)

Publication Number Publication Date
AT126110B true AT126110B (en) 1932-01-11

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ID=5658972

Family Applications (1)

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AT126110D AT126110B (en) 1928-02-02 1929-01-07 Process for improving the corrosion resistance of fittings made of magnesium alloys by treatment with bichromates.

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AT (1) AT126110B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2956602A (en) * 1954-08-09 1960-10-18 Gronberg Anton Bertil Straw cutter for combines

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2956602A (en) * 1954-08-09 1960-10-18 Gronberg Anton Bertil Straw cutter for combines

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