AR107647A1 - DERIVATIVES OF QUINAZOLINDION-6-CARBONILO AND ITS USE AS HERBICIDES - Google Patents
DERIVATIVES OF QUINAZOLINDION-6-CARBONILO AND ITS USE AS HERBICIDESInfo
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- AR107647A1 AR107647A1 ARP170100398A ARP170100398A AR107647A1 AR 107647 A1 AR107647 A1 AR 107647A1 AR P170100398 A ARP170100398 A AR P170100398A AR P170100398 A ARP170100398 A AR P170100398A AR 107647 A1 AR107647 A1 AR 107647A1
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- alkyl
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- alkoxy
- cycloalkyl
- carbonyl
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/70—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings condensed with carbocyclic rings or ring systems
- C07D239/72—Quinazolines; Hydrogenated quinazolines
- C07D239/95—Quinazolines; Hydrogenated quinazolines with hetero atoms directly attached in positions 2 and 4
- C07D239/96—Two oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Se describen derivados de quinazolindion-6-carbonilo como herbicidas. Reivindicación 1: Derivados de quinazolindion-6-carbonilo de la fórmula (1) y sus sales, en la que X significa nitro, halógeno, ciano, formilo, rodano, alquilo C₁₋₆, halógenoalquilo C₁₋₆, alquenilo C₂₋₆, halógenoalquenilo C₂₋₆, alquinilo C₂₋₆, halógenoalquinilo C₃₋₆, cicloalquilo C₃₋₆, halógenocicloalquilo C₃₋₆, cicloalquilo C₃₋₆-alquilo C₁₋₆, halógenocicloalquilo C₃₋₆-alquilo C₁₋₆, COR¹, OR¹, OCOR¹, OSO₂R², S(O)ₙR², SO₂OR¹, SO₂N(R¹)₂, NR¹SO₂R², NR¹COR¹, alquilo C₁₋₆-S(O)ₙR², alquilo C₁₋₆-OR¹, alquilo C₁₋₆-OCOR¹, alquilo C₁₋₆-OSO₂R², alquilo C₁₋₆-COOR¹, alquilo C₁₋₆-SO₂OR¹, alquilo C₁₋₆-CON(R¹)₂, alquilo C₁₋₆-SO₂N(R¹)₂, alquilo C₁₋₆-NR¹COR¹, alquilo C₁₋₆-NR¹SO₂R² o NR¹R²; Z significa O ó S; W significa hidrógeno, nitro, halógeno, ciano, alquilo C₁₋₄, halógenoalquilo C₁₋₄ o alcoxi C₁₋₄; R¹ significa alquilo C₁₋₁₀, alquenilo C₂₋₁₀, alquinilo C₂₋₁₀, halógeno-alquilo C₁₋₁₀, halógeno-alquenilo C₂₋₁₀, halógeno-alquinilo C₂₋₁₀, cicloalquilo C₃₋₁₀, halógeno-cicloalquilo C₃₋₁₀, alquilo C₁₋₄-cicloalquilo C₃₋₇, cicloalquilo C₃₋₇-alquilo C₁₋₆, cicloalquilo C₃₋₇-cicloalquilo C₃₋₇, halógeno-cicloalquilo C₃₋₇-alquilo C₁₋₆, alquilo C₁₋₆-cicloalquilo C₃₋₇-alquilo C₁₋₆, cicloalquenilo C₃₋₁₂, halógeno-cicloalquenilo C₃₋₁₂, alcoxi C₁₋₆-alquilo C₁₋₆, alcoxi C₁₋₆-alquenilo C₂₋₆, alquilo C₁₋₆-cicloalquilo C₃₋₇, alcoxi C₁₋₆-cicloalquilo C₃₋₇, di-alcoxi C₁₋₆-cicloalquilo C₃₋₇, cicloalcoxi C₃₋₇-alquilo C₁₋₆, cicloalcoxi C₃₋₇-alcoxi C₁₋₆-alquilo C₁₋₆, alcoxi C₁₋₆-alcoxi C₁₋₆-alquilo C₁₋₆, alquiltio C₁₋₆-alquilo C₁₋₆, alquilsulfinilo C₁₋₆-alquilo C₁₋₆, alquilsulfonilo C₁₋₆-alquilo C₁₋₆, alquilamino C₁₋₆-alquilo C₁₋₆, di-alquilamino C₁₋₆ -alquilo C₁₋₆, halógeno-alquilamino C₁₋₆-alquilo C₁₋₆, cicloalquilamino C₃₋₇-alquilo C₁₋₆, alquilo C₁₋₆-carbonilo, halógeno-alquilo C₁₋₆-carbonilo, cicloalquilo C₃₋₇-carbonilo, alcoxi C₁₋₆-carbonilo, cicloalcoxi C₃₋₇-carbonilo, cicloalquilo C₃₋₇-alcoxi C₁₋₆-carbonilo, alquilamino C₁₋₆-carbonilo, di-alquilamino C₁₋₆-carbonilo, cicloalquilamino C₃₋₇-carbonilo, ciano-alquilo C₁₋₆, hidroxi-alquilo C₁₋₆, cicloalquenilo C₃₋₇-alquilo C₁₋₆, halógeno-alcoxi C₁₋₆-alquilo C₁₋₆, alcoxi C₁₋₆-halógeno-alquilo C₁₋₆, halógeno-alcoxi C₁₋₆-halógeno-alquilo C₁₋₆, halógeno-cicloalcoxi C₃₋₇-alquilo C₁₋₆, cicloalqueniloxi C₃₋₇-alquilo C₁₋₆, halógeno-cicloalqueniloxi C₃₋₇-alquilo C₁₋₆, di-alcoxi C₁₋₆-alquilo C₁₋₆, alcoxi C₁₋₆-alquilo C₁₋₆-carbonilo, alcoxi C₁₋₆-carbonil-alquilo C₁₋₆, halógeno-alcoxi C₁₋₆-carbonilo, alcoxi C₁₋₁₀, halógeno-alcoxi C₁₋₁₀, cicloalcoxi C₃₋₁₂, halógeno-cicloalcoxi C₃₋₇, cicloalquilo C₃₋₇-alcoxi C₁₋₆, alqueniloxi C₂₋₁₂, halógeno-alqueniloxi C₂₋₁₀, alquiniloxi C₂₋₁₀, halógeno-alquiniloxi C₃₋₁₀, alcoxi C₁₋₆-alcoxi C₁₋₆, alquilo C₁₋₆-carboniloxi, halógeno-alquilo C₂₋₁₂-carboniloxi, cicloalquilo C₃₋₇-carboniloxi, alquilo C₁₋₆-carbonil-alcoxi C₁₋₆, alquilamino C₁₋₆, di-alquilamino C₁₋₆, halógeno-alquilamino C₁₋₆, halógeno-di-alquilamino C₁₋₆, cicloalquilamino C₃₋₁₂, alquilo C₁₋₆-carbonilamino, halógeno-alquilo C₁₋₆-carbonilamino, alquilsulfonilamino C₁₋₁₀, halógeno-alquilsulfonilamino C₁₋₁₀, cicloalquilo C₃₋₇-alquilo C₁₋₆-amino, hidroxi, amino, NHCHO, o R¹ significa fenilo, fenilsulfonilo, W¹-(fenilo), W¹-(O-fenilo), W¹-(S-fenilo), W¹-(SO₂-fenilo), W²-(SO₂CH₂-fenilo) o W²-(SCH₂-fenilo), donde los anillos fenilo de los ocho restos antes mencionados portan en cada caso s sustituyentes R⁶; R² significa hidrógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₆, halógenoalquenilo C₂₋₆, alquinilo C₂₋₆, halógenoalquinilo C₂₋₆, cicloalquilo C₃₋₆, halógenocicloalquilo C₃₋₆, alquilo C₁₋₆-O-alquilo C₁₋₆, cicloalquilo C₃₋₆-alquilo C₁₋₆, fenilo, fenil-alquilo C₁₋₆, piridilo o alquilpiridilo C₁₋₆, donde los anillos fenilo o piridilo de los cuatro restos antes mencionados portan en cada caso s sustituyentes R⁶; Q significa un resto Q¹, Q², Q³, Q⁴ o Q⁵ del grupo de fórmulas (2); Rᶜ¹ significa hidroxi o SR⁴; Rᶜ², Rᶜ³, Rᶜ⁴, Rᶜ⁵, Rᶜ⁶ y Rᶜ⁷ significan independientemente entre sí en cada caso hidrógeno o alquilo C₁₋₄; Rᵖ¹ significa hidrógeno, alquilsulfonilo C₁₋₆, alcoxi C₁₋₄-alquilsulfonilo C₁₋₆, o fenilsulfonilo, tiofenil-2-sulfonilo, benzoilo, benzoil-alquilo C₁₋₆ o bencilo sustituidos respectivamente con n restos iguales o diferentes del grupo que se compone de halógeno, alquilo C₁₋₄ y alcoxi C₁₋₄; Rᵖ² significa alquilo C₁₋₄; Rᵖ³ significa hidrógeno, alquilo C₁₋₄, cicloalquilo C₃₋₈, alquilo C₁₋₄ -cicloalquilo C₃₋₈ o halógenocicloalquilo C₃₋₆; Rⁿ¹ significa alquilo C₁₋₄, cicloalquilo C₃₋₈, alquilo C₁₋₄-cicloalquilo C₃₋₈ o halógenocicloalquilo C₃₋₆; Rⁿ² significa hidrógeno, CO₂-alquilo C₁₋₆ o S(O)ₙ-alquilo C₁₋₆; Y significa O ó CO; Y¹ significa un grupo etileno o vinileno; Y² significa O, CO o CH₂; W¹ significa alquileno C₁₋₁₀, alquenileno C₂₋₆ o alquinileno C₂₋₆; W² significa alquileno C₁₋₁₀; R³ significa halógeno, ciano, hidroxi, amino, nitro, -C(=O)R³ᵃ, -C(=O)OR³ᵃ, -C(=O)(NR³ᵃ)₂, -C(=S)NH₂, -C(=O)NHCN, -C(=O)NHOH, -SH, -SO₂(NR³ᵃ)₂, -SO₂NHCN, -SO₂NHOH, -OCN, -SCN, -SF₅, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, halógeno-alquilo C₁₋₆, halógeno-alquenilo C₂₋₆, halógeno-alquinilo C₂₋₆, cicloalquilo C₃₋₈, halógeno-cicloalquilo C₃₋₈, alquilo C₁₋₆-cicloalquilo C₃₋₇, cicloalquilo C₃₋₇-alquilo C₁₋₆,cicloalquenilo C₃₋₈, halógeno-cicloalquenilo C₃₋₈, alcoxi C₁₋₆-alquilo C₁₋₆, cicloalcoxi C₃₋₇-alquilo C₁₋₆, alcoxi C₁₋₆-alcoxi C₁₋₆-alquilo C₁₋₆, alquiltio C₁₋₆-alquilo C₁₋₆, alquilsulfinilo C₁₋₈-alquilo C₁₋₆, alcoxi C₁₋₈-halógeno-alquilo C₁₋₆, ciano-alquilo C₁₋₆, hidroxi-alquilo C₁₋₆, alcoxi C₁₋₆, halógeno-alcoxi C₁₋₆, cicloalcoxi C₃₋₈, halógeno-cicloalcoxi C₃₋₈, cicloalquilo C₃₋₈-alcoxi C₁₋₆, alqueniloxi C₂₋₆, halógeno-alqueniloxi C₂₋₆, alcoxi C₁₋₆-alcoxi C₁₋₆, alquilcarboniloxi C₂₋₆, alquiltio C₁₋₆, halógeno-alquiltio C₁₋₆, cicloalquiltio C₃₋₈, alquilsulfinilo C₁₋₆, halógeno-alquilsulfinilo C₁₋₆, alquilsulfonilo C₁₋₆, halógeno-alquilsulfonilo C₁₋₆, cicloalquilsulfonilo C₃₋₈, alquilamino C₁₋₆, di-alquilamino C₁₋₆, halógeno-alquilamino C₁₋₆, halógeno-di-alquilamino C₁₋₆ o cicloalquilamino C₃₋₆, o dos restos R³ adjuntos forman junto con los dos átomos de carbono a los que están unidos, un anillo de 5 a 7 miembros, que porta v átomos de carbono y contiene p átomos iguales o diferentes del grupo oxígeno, azufre o nitrógeno, y porta t grupos oxo; R³ᵃ significa hidrógeno, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₆, cicloalquilo C₃₋₆-alquilo C₁₋₆ o fenilo; R⁴ significa alquilo C₁₋₄ o fenilo sustituido con p restos del grupo halógeno, nitro, ciano, alquilo C₁₋₄, halógenoalquilo C₁₋₄, alcoxi C₁₋₄ y halógenoalcoxi C₁₋₄; n significa 0, 1 ó 2; p significa 0, 1, 2, 3 ó 4; s significa 0, 1, 2, 3, 4 ó 5; t significa 0, 1, 2, 3, 4; v significa 2, 3, 4, 5, 6 ó 7.Quinazolindion-6-carbonyl derivatives are described as herbicides. Claim 1: Quinazolindion-6-carbonyl derivatives of the formula (1) and their salts, wherein X means nitro, halogen, cyano, formyl, rhodan, C₁₋₆ alkyl, C₁₋₆ halogen, C₂₋₆ alkenyl, C₂₋₆ halogenoalkenyl, C₂₋₆ alkynyl, C₃₋₆ halogenoalkynyl, C ciclo cycloalkyl, C₃₋₆ halocycloalkyl, C₃₋₆ cycloalkyl-C alquilo alkyl, halogen C₃₋₆-C₁₋₆ -cycloalkyl alkyl, COR¹, OR¹, OCOR¹ , OSO₂R², S (O) ₙR², SO₂OR¹, SO₂N (R¹) ₂, NR¹SO₂R², NR¹COR¹, C₁₋₆-S (O) alkyl ₙR², C₁₋₆-OR¹ alkyl, C₁₋₆-OCOR¹ alkyl, C₁₋₆ alkyl -OSO₂R², C₁₋₆-COOR¹ alkyl, C₁₋₆-SO₂OR¹ alkyl, C₁₋₆-CON (R¹) ₂ alkyl, C₁₋₆-SO₂N (R¹) ₂ alkyl, C₁₋₆-NR¹COR¹ alkyl, C₁₋₆ alkyl -NR¹SO₂R² or NR¹R²; Z means O or S; W means hydrogen, nitro, halogen, cyano, C₁₋₄ alkyl, halogen Cógeno alkyl or C₁₋₄ alkoxy; R¹ means C₁₋₁₀ alkyl, C₂₋₁₀ alkenyl, C₂₋₁₀ alkynyl, halogen-C alquilo alkyl, halogen-C₂₋₁₀ alkenyl, halogen-C₂₋₁₀ alkynyl, C₃₋₁₀ cycloalkyl, halogen-C₃₋₁₀ cycloalkyl, C₁₋₄-C₃₋₇-cycloalkyl alkyl, Cal-cycloalkyl-C₁₋₆-alkyl, C₃₋₇-cycloalkyl-C₃₋₇, halogen-C₃₋₇-cycloalkyl-C₁₋₆-alkyl, C₁₋₆-C alquilo-cycloalkyl-alkyl ₇-C₁₋₆ alkyl, C₃₋₁₂ cycloalkenyl, C₃₋₁₂ halogen-cycloalkenyl, C₁₋₆-C₁₋₆-alkoxy, C₁₋₆-C alco-alkenyl alkoxy, C alquilo-C₃₋₇-cycloalkyl alkyl, alkoxy C₁₋₆-C₃₋₇ cycloalkyl, C di di-alkoxy-C alco -cycloalkyl, C₃₋₇-cycloalkoxy-C₁₋₆-alkyl, C₃₋₇-cycloalkoxy-C₁₋₆-alkoxy-C alquilo-alkyl -C₁₋₆-Cco-Cco-alkyl alkoxy, C₁₋₆-alkyl C-alkyl Cfin-Cfin-Cfin-C alquilo-C alquilo-alkyl alkylsulfonyl, C₁₋₆-alkylamino-C₁₋₆-di-alkylamino-C₁₋₆-alkyl, halogen-C₁₋₆-alkylamino C₁₋₆, C₃₋₇-C₁₋₆-cycloalkylamino, C₁₋₆-carbonyl alkyl, halogen-C₁₋₆-carbonyl alkyl, C₃₋₇-carbonyl cycloalkyl, C₁₋₆-carbonyl alkoxy, C₃₋₇-carbonyl cycloalkoxy , C₃₋₇-C₁₋₆-carbonyl cycloalkyl, C₁₋₆-carbonyl alkylamino, C₁₋₆-carbonyl di-alkylamino, C₃₋₇-carbonyl cycloalkylamino, C₁₋₆-Ciano-alkyl, hydroxy-C₁₋₆ alkyl, C₃₋₇ cycloalkenyl-C₁₋₆-alkyl, halogen-C₁₋₆-alkoxy-C alquilo-alkyl, C₁₋₆-alkoxy-halo-C alquilo-alkyl, halogen-C₁₋₆-alkoxy-halogen-C₁₋₆-alkyl, halogen- C₃₋₇ cycloalkoxy-C₁₋₆ alkyl, C₃₋₇ cycloalkenyloxy-C₁₋₆ alkyl, halogen-C₃₋₇ cycloalkenyloxy -C₁₋₆ alkyl, di-C₁₋₆-alkoxy-C alquilo-alkyl, C₁₋₆-alkoxy-C₁₋₆-carbonyl alkyl, C₁₋₆-carbonyl-C₁₋₆-alkoxy, halogen-C₁₋₆-carbonyl alkoxy , C₁₋₁₀ alkoxy, C₁₋₁₀ halogen-alkoxy, C₃₋₁₂ cycloalkoxy, Cógeno halogen-cycloalkoxy, C₃₋₇ cycloalkyl, C al alkenyloxy, C₂₋₁₀ halogen-alkenyloxy, C₂₋ alkynyloxy ₁₀, halogen-C₃₋₁₀ alkynyloxy, C₁₋₆-alkoxy-C₁₋₆ alkoxy, C alquilo-carbonyloxy alkyl, halogen-C₂₋₁₂-carbonyloxy alkyl, C₃₋₇-carbonyloxycycloalkyl, C₁₋₆-carbonyl-alkoxy alkyl C₁₋₆, C₁₋₆ alkylamino, C₁₋₆ di-alkylamino, C₁₋₆ halogen-Cila alkylamino, C di cycloalkylamino, C₁₋₆-carbonylamino alkyl, halogen-C₁₋₆ alkyl -carbonylamino, Culf alkylsulfonylamino, halogen-C-alkylsulfonylamino, cycloalq C₃₋₇-C₁₋₆-C alquilo-amino alkyl, hydroxy, amino, NHCHO, or R¹ means phenyl, phenylsulfonyl, W¹- (phenyl), W¹- (O-phenyl), W¹- (S-phenyl), W¹- ( SO₂-phenyl), W²- (SO₂CH₂-phenyl) or W²- (SCH₂-phenyl), where the phenyl rings of the eight aforementioned moieties carry in each case s substituents R⁶; R² means hydrogen, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₂₋₆ alkenyl, C₂₋₆ halogenalkenyl, C₂₋₆ alkynyl, C₂₋₆ halogenoalkyl, C₃₋₆ cycloalkyl, C₃₋₆ halogenocycloalkyl, C₁₋₆-O alkyl -C₁₋₆ alkyl, C₃₋₆ cycloalkyl-C₁₋₆ alkyl, phenyl, phenyl-C₁₋₆ alkyl, pyridyl or C₁₋₆ alkyl pyridyl, where the phenyl or pyridyl rings of the four moieties mentioned above carry in each case s substituents R⁶; Q means a remainder Q¹, Q², Q³, Q⁴ or Q⁵ of the group of formulas (2); Rᶜ¹ means hydroxy or SR⁴; Rᶜ², Rᶜ³, Rᶜ⁴, Rᶜ⁵, Rᶜ⁶ and Rᶜ⁷ independently mean each other in each case hydrogen or C₁₋₄ alkyl; Rᵖ¹ means hydrogen, C₁₋₆ alkylsulfonyl, C₁₋₄ alkoxy sulfonyl C₁₋₆, or phenylsulfonyl, thiophenyl-2-sulfonyl, benzoyl, benzoyl-C₁₋₆ alkyl or benzyl substituted respectively with n equal or different moieties of the group to be it comprises halogen, C₁₋₄ alkyl and C₁₋₄ alkoxy; Rᵖ² means C₁₋₄ alkyl; Rᵖ³ means hydrogen, C₁₋₄ alkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkyl-Ciclo cycloalkyl or C hal halogenocycloalkyl; Rⁿ¹ means C₁₋₄ alkyl, C₃₋₈ cycloalkyl, C₁₋₄ alkyl-C₃₋₈ cycloalkyl or Cógeno halocycloalkyl; Rⁿ² means hydrogen, CO₂-C₁₋₆ alkyl or S (O) ₙ-C₁₋₆ alkyl; Y means O or CO; Y¹ means an ethylene or vinyl group; Y² means O, CO or CH₂; W¹ means C₁₋₁₀ alkylene, C₂₋₆ alkenylene or C₂₋₆ alkynylene; W² means C₁₋₁₀ alkylene; R³ means halogen, cyano, hydroxy, amino, nitro, -C (= O) R³ᵃ, -C (= O) OR³ᵃ, -C (= O) (NR³ᵃ) ₂, -C (= S) NH₂, -C ( = O) NHCN, -C (= O) NHOH, -SH, -SO₂ (NR³ᵃ) ₂, -SO₂NHCN, -SO₂NHOH, -OCN, -SCN, -SF₅, C₁₋₆ alkyl, C₂₋₆ alkenyl, C₂ alkynyl ₋₆, halogen-C₁₋₆ alkyl, halogen-C₂₋₆ alkenyl, halogen-C₂₋₆ alkynyl, C₃₋₈ cycloalkyl, halogen-C₃₋₈ cycloalkyl, C₁₋₆-alkyl C₃₋₇-cycloalkyl, C₃₋₇ cycloalkyl -C₁₋₆ alkyl, C₃₋₈ cycloalkenyl, C₃₋₈ halogen-cycloalkenyl, C₁₋₆-C₁₋₆ alkoxy, C₃₋₇-cycloalkoxy-C₁₋₆-alkyl, C₁₋₆-alkoxy-C₁₋₆-alkoxy-C alquilo-alkyl ₋₆, C₁₋₆ alkylthio-C₁₋₆ alkyl, C₁₋₈ alkylsulfinyl-C₁₋₆ alkyl, C₁₋₈ alkoxy-C₁₋₆ alkyl, cyano-C₁₋₆ alkyl, hydroxy-C₁₋₆ alkyl, alkoxy C₁₋₆, halogen-C₁₋₆ alkoxy, C₃₋₈ cycloalkoxy, halogen-cycloalkoxy C₃₋₈, C₃₋₈-C₁₋₆-cycloalkyl, C₂₋₆ alkenyloxy, C₂₋₆ halogen-alkenyloxy, C₁₋₆-C₁₋₆ alkoxy, C₂₋₆ alkylcarbonyloxy, C₁₋₆ alkylthio, C₁ halogen-alkylthio ₋₆, C₃₋₈ cycloalkylthio, C₁₋₆ alkylsulfinyl, C₁₋₆ halogen-alkylsulfinyl, C₁₋₆ alkylsulfonyl, C₁₋₆ halogen-alkylsulfonyl, C₃₋₈ cycloalkylsulfonyl, C₁₋₆ alkylamino, C₁₋₆ di-alkylamino -C₁₋₆ alkylamino, halogen-di-C₁₋₆ alkylamino or C₃₋₆ cycloalkylamino, or two attached R³ moieties together with the two carbon atoms to which they are attached, a 5 to 7-membered ring, which carries v carbon atoms and contains p equal or different atoms of the oxygen, sulfur or nitrogen group, and carries t oxo groups; R³ᵃ means hydrogen, C₁₋₆ alkyl, C₂₋₆ alkenyl, C₂₋₆ alkynyl, C₃₋₆ cycloalkyl, C₃₋₆ cycloalkyl-C₁₋₆ alkyl or phenyl; R⁴ means C₁₋₄ alkyl or phenyl substituted with p residues of the halogen, nitro, cyano, C₁₋₄ alkyl, C₁₋₄ haloalkyl, C₁₋₄ alkoxy and C₁₋₄ halogenalkoxy group; n means 0, 1 or 2; p means 0, 1, 2, 3 or 4; s means 0, 1, 2, 3, 4 or 5; t means 0, 1, 2, 3, 4; v means 2, 3, 4, 5, 6 or 7.
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US20200196601A1 (en) * | 2017-05-04 | 2020-06-25 | Bayer Cropscience Aktiengesellschaft | Herbicide safener compositions containing quinazolinedione-6carbonyl derivatives |
CN110357860B (en) * | 2018-04-11 | 2020-12-15 | 山东先达农化股份有限公司 | Quinazoline diketone compound and application thereof as well as pesticide herbicide |
CN110669016B (en) * | 2018-09-29 | 2021-05-25 | 山东先达农化股份有限公司 | Triketone compound, preparation method and application thereof, and herbicide |
CN110963973B (en) * | 2018-09-29 | 2023-04-25 | 山东先达农化股份有限公司 | Triketone compound containing quinazoline diketone fragment, preparation method and application thereof, and herbicide |
CN111820231A (en) * | 2019-04-16 | 2020-10-27 | 山东先达农化股份有限公司 | Weeding composition, application thereof and herbicide |
CN112574128B (en) * | 2019-09-29 | 2022-08-09 | 山东先达农化股份有限公司 | Quinazoline diketone compound, preparation method and application thereof, and herbicide |
CN112608282B (en) * | 2019-12-20 | 2022-07-26 | 山东先达农化股份有限公司 | Compound containing quinazolinedione and N-O structure and preparation method and application thereof |
CN113149913B (en) * | 2020-01-07 | 2022-09-02 | 山东先达农化股份有限公司 | alpha-C position modified benzyl substituted quinazoline diketone compound, preparation method and application thereof, and HPPD herbicide |
CN113439750A (en) * | 2020-03-27 | 2021-09-28 | 辽宁先达农业科学有限公司 | Herbicide composition, application thereof and herbicide |
CN114573516B (en) * | 2020-11-30 | 2023-10-24 | 山东先达农化股份有限公司 | Trione-quinazolinone compound, preparation method and application thereof, and herbicide |
WO2024008191A1 (en) * | 2022-07-08 | 2024-01-11 | 山东先达农化股份有限公司 | Quinazolinedione-containing compound, method for preparing same, and use thereof |
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EP0131624B1 (en) | 1983-01-17 | 1992-09-16 | Monsanto Company | Plasmids for transforming plant cells |
BR8404834A (en) | 1983-09-26 | 1985-08-13 | Agrigenetics Res Ass | METHOD TO GENETICALLY MODIFY A PLANT CELL |
BR8600161A (en) | 1985-01-18 | 1986-09-23 | Plant Genetic Systems Nv | CHEMICAL GENE, HYBRID, INTERMEDIATE PLASMIDIO VECTORS, PROCESS TO CONTROL INSECTS IN AGRICULTURE OR HORTICULTURE, INSECTICIDE COMPOSITION, PROCESS TO TRANSFORM PLANT CELLS TO EXPRESS A PLANTINIDE TOXIN, PRODUCED BY CULTURES, UNITED BY BACILLA |
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EP0242236B2 (en) | 1986-03-11 | 1996-08-21 | Plant Genetic Systems N.V. | Plant cells resistant to glutamine synthetase inhibitors, made by genetic engineering |
IL83348A (en) | 1986-08-26 | 1995-12-08 | Du Pont | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
US5013659A (en) | 1987-07-27 | 1991-05-07 | E. I. Du Pont De Nemours And Company | Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase |
WO1991013972A1 (en) | 1990-03-16 | 1991-09-19 | Calgene, Inc. | Plant desaturases - compositions and uses |
CA2081885C (en) | 1990-06-18 | 2000-10-31 | Ganesh M. Kishore | Increased starch content in plants |
JP3173784B2 (en) | 1990-06-25 | 2001-06-04 | モンサント カンパニー | Glyphosate-tolerant plants |
SE467358B (en) | 1990-12-21 | 1992-07-06 | Amylogene Hb | GENETIC CHANGE OF POTATISE BEFORE EDUCATION OF AMYLOPECT TYPE STARCH |
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AU6267898A (en) * | 1997-02-14 | 1998-09-08 | E.I. Du Pont De Nemours And Company | Bicyclic hydrazone herbicides |
CA2346065A1 (en) * | 1998-10-06 | 2000-04-13 | Idemitsu Kosan Co., Ltd. | Triketone derivative and herbicide |
JP5300225B2 (en) | 2007-08-03 | 2013-09-25 | バイエル・クロップサイエンス・アーゲー | Herbicide triazolyl pyridine ketones |
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CA3014687A1 (en) | 2017-08-24 |
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