AR064674A2 - Un proceso de polimerizacion en fase liquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular - Google Patents

Un proceso de polimerizacion en fase liquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular

Info

Publication number
AR064674A2
AR064674A2 ARP070105843A ARP070105843A AR064674A2 AR 064674 A2 AR064674 A2 AR 064674A2 AR P070105843 A ARP070105843 A AR P070105843A AR P070105843 A ARP070105843 A AR P070105843A AR 064674 A2 AR064674 A2 AR 064674A2
Authority
AR
Argentina
Prior art keywords
reaction zone
molecular weight
low molecular
highly reactive
preparation
Prior art date
Application number
ARP070105843A
Other languages
English (en)
Inventor
Christopher Lobue
Timothy Lowry
Armen Abazajian
Gilbert Valdez
C Edward Baxter Jr
Original Assignee
Texas Petrochemicals Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27387564&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR064674(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US09/515,790 external-priority patent/US6562913B1/en
Application filed by Texas Petrochemicals Lp filed Critical Texas Petrochemicals Lp
Publication of AR064674A2 publication Critical patent/AR064674A2/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00058—Temperature measurement
    • B01J2219/00063—Temperature measurement of the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00065—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00069—Flow rate measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
    • B01J2219/00114—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/92—Apparatus for use in addition polymerization processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/922—Polymerization process of ethylenic monomers using manipulative technique

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Un proceso de polimerizacion en fase líquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular, que comprende: la provision de un caudal base que comprende isobutileno; provision de una composicion catalizadora constituida por un complejo de BF3 y un agente formador de complejos; la introduccion de dicho caudal base y dicha composicion catalizadora en una mezcla de reaccion residual en una zona de reaccion; la mezcla íntima de dicha mezcla de reaccion residual, dicho caudal base y dicha composicion catalizadora al efecto de obtener una mezcla de reaccion combinada íntimamente en la mencionada zona de reaccion; el mantenimiento de la mezcla de reaccion intimamente combinada en este estado a una temperatura de por lo menos aproximadamente 0 grados C mientras se encuentra en la mencionada zona de reaccion, con lo cual el isobutileno es sometido a una polimerizacion para formar dicho poliisobutileno; la extraccion de un caudal de producto que comprende poliisobutileno altamente reactivo de bajo peso molecular de dicha zona de reaccion; y el control de la introduccion de dicho caudal base en dicha zona de reaccion y la extraccion de dicho caudal de producto de la zona de reaccion de modo que el tiempo de residencia del isobutileno sometido a polimerizacion en la zona de reaccion no supere aproximadamente los 4 minutos.
ARP070105843A 1999-09-16 2007-12-21 Un proceso de polimerizacion en fase liquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular AR064674A2 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US15426399P 1999-09-16 1999-09-16
US16035799P 1999-10-19 1999-10-19
US09/515,790 US6562913B1 (en) 1999-09-16 2000-02-29 Process for producing high vinylidene polyisobutylene

Publications (1)

Publication Number Publication Date
AR064674A2 true AR064674A2 (es) 2009-04-15

Family

ID=27387564

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP000104848A AR025682A1 (es) 1999-09-16 2000-09-15 Proceso de preparacion de productos poliolefinicos
ARP070105843A AR064674A2 (es) 1999-09-16 2007-12-21 Un proceso de polimerizacion en fase liquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ARP000104848A AR025682A1 (es) 1999-09-16 2000-09-15 Proceso de preparacion de productos poliolefinicos

Country Status (12)

Country Link
US (1) US6525149B1 (es)
EP (1) EP1242464B1 (es)
JP (2) JP4156837B2 (es)
KR (1) KR100600256B1 (es)
CN (1) CN1188430C (es)
AR (2) AR025682A1 (es)
AT (1) ATE507247T1 (es)
AU (1) AU7123700A (es)
CA (2) CA2660742C (es)
DE (1) DE60045897D1 (es)
MX (1) MXPA02001334A (es)
WO (1) WO2001019873A1 (es)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6884858B2 (en) 1999-10-19 2005-04-26 Texas Petrochemicals Lp Process for preparing polyolefin products
MXPA02001334A (es) 1999-09-16 2004-07-16 Texas Petrochemicals Lp Procedimiento para la preparacion de productos de poliolefina.
JP5670874B2 (ja) * 1999-09-16 2015-02-18 ティーピーシー グループ リミティド ライアビリティ カンパニー ポリイソブチレンの液相重合方法
US6858188B2 (en) * 2003-05-09 2005-02-22 Texas Petrochemicals, Lp Apparatus for preparing polyolefin products and methodology for using the same
US6992152B2 (en) * 1999-10-19 2006-01-31 Texas Petrochemicals Lp Apparatus and method for controlling olefin polymerization process
US7037999B2 (en) 2001-03-28 2006-05-02 Texas Petrochemicals Lp Mid-range vinylidene content polyisobutylene polymer product and process for producing the same
AU2002257288A1 (en) * 2001-06-08 2002-12-23 Texas Petrochemicals Lp Improved cling film with enhanced polyisobutylene tackifier
DE10152267A1 (de) 2001-10-20 2003-04-30 Cognis Deutschland Gmbh Verfahren zur Herstellung von Poly-alpha-Olefinen
US6933351B2 (en) 2003-06-20 2005-08-23 Infineum International Limited Process for forming polyalkenyl acylating agents
US7339007B2 (en) 2003-06-20 2008-03-04 Infineum International Limited Low sediment process for thermally reacting highly reactive polymers and enophiles
US20050016899A1 (en) * 2003-07-21 2005-01-27 Syntroleum Corporation Synthetic lubricant basestock and an integrated fischer-tropsch process for its production
US7323529B2 (en) * 2003-11-26 2008-01-29 Pp6 Industries Ohio, Inc. Method of making copolymers containing olefinic type monomers
US7407918B2 (en) * 2003-12-11 2008-08-05 Afton Chemical Corporation Lubricating oil compositions
US6988022B2 (en) * 2004-04-13 2006-01-17 Univation Technologies, Llc Method for online estimation of reactor split for multimodal polyolefins
ITMI20061476A1 (it) 2006-07-27 2008-01-28 Eni Spa Procedimento per la preparazione di agenti acilanti polialchenilici
US20100298507A1 (en) * 2009-05-19 2010-11-25 Menschig Klaus R Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby
US9040645B2 (en) 2010-03-11 2015-05-26 Petrochemical Supply, Inc. Catalyst system for heterogenous catalysis of an isobutylene polymerization reaction
CA2723515C (en) 2010-12-01 2018-05-15 Nova Chemicals Corporation Heat management in ethylene oligomerization
US9309339B2 (en) 2011-10-26 2016-04-12 Tpc Group Llc Mid-range vinylidene content, high viscosity polyisobutylene polymers
US8946361B2 (en) 2011-10-26 2015-02-03 Tpc Group Llc Polyisobutylene prepared at high velocity and circulation rate
US9074026B2 (en) 2011-10-26 2015-07-07 Tpc Group Llc Polyisobutylene prepared with low diluent content reaction medium
MX2014015459A (es) 2012-06-18 2015-07-14 Petrochemical Supply Inc Composicion de poliisobutileno que tiene vinilideno interno y proceso para preparar la composicion polimerica de poliisobutileno.
SG11201509878RA (en) * 2013-06-05 2016-01-28 Daelim Ind Co Ltd Apparatus and method for preparing polybutene having various molecular weights
EP3022239B1 (de) * 2013-07-17 2017-04-05 Basf Se Hochreaktives polyisobutylen mit einem hohen gehalt an vinyliden-doppelbindungen in den seitenketten
JP6005091B2 (ja) * 2014-03-19 2016-10-12 Ｊｘエネルギー株式会社 オレフィン重合体の製造方法。
WO2017151341A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
JP6954922B2 (ja) 2016-04-08 2021-10-27 イネオス ユーロープ アクチェンゲゼルシャフト 重合設備及び重合方法
EP3481547B1 (en) 2016-07-06 2023-06-07 Ineos Europe AG Polymerisation process
KR101969581B1 (ko) 2016-11-17 2019-08-13 주식회사 엘지화학 올레핀계 단량체의 회수 장치
BR112019017261B1 (pt) 2017-02-21 2023-01-31 Ntp Tec, Llc Sistema catalisador e método de fabricação de uma composição de polímero
CN109593151B (zh) * 2017-09-30 2022-04-08 中国石油化工股份有限公司 制备聚α-烯烃的方法和***、聚α-烯烃及连续反应器
ES2973829T3 (es) 2017-10-14 2024-06-24 Tpc Group Llc Copolímeros de isobutileno no aleatorios
CA3105355C (en) 2018-06-29 2023-04-25 Ntp Tec, Llc Processes for the manufacture of isobutylene, polyisobutylene, and derivatives thereof
EP3970848A4 (en) * 2019-05-16 2023-01-25 Nisso Engineering Co., Ltd. CHEMICAL REACTION SYSTEM AND DEVICE SUITABLE FOR LOW-FLOW REACTIONS
CN111939846B (zh) * 2019-05-17 2023-01-03 中国石化工程建设有限公司 一种合成聚α-烯烃的装置及方法
CN111760544B (zh) * 2020-07-06 2023-07-25 上海济俭工业设备有限公司 连续式活塞流漩涡流反应装置

Family Cites Families (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US132264A (en) 1872-10-15 Improvement in treating ammoniacal liquors of gas-works,gc
US2139038A (en) 1935-02-07 1938-12-06 Standard Oil Dev Co Process for producing polymers of olefines
US2379656A (en) * 1940-08-23 1945-07-03 Robert F Ruthruff Catalytic polymerization of unsaturated organic compounds
US2407494A (en) 1941-01-02 1946-09-10 Jasco Inc Low-temperature process of polymerizing isoolefinic material
US2411097A (en) 1944-03-16 1946-11-12 American Locomotive Co Heat exchanger
US2559062A (en) * 1945-11-27 1951-07-03 Standard Oil Dev Co Friedel-crafts metal halide-ether complexes as polymerization catalysts
US2559984A (en) 1947-11-21 1951-07-10 Gulf Research Development Co Process of preparing polymeric lubricating oils
US2727022A (en) 1952-04-16 1955-12-13 Standard Oil Co Process for polymerizing iso-olefin polymers with isopentane diluent
US2856395A (en) 1954-05-12 1958-10-14 Monsanto Chemicals Control of polyethylene process
US2833840A (en) 1954-06-21 1958-05-06 Exxon Research Engineering Co Process for contacting immiscible liquids
US2889370A (en) 1955-05-18 1959-06-02 Callery Chemical Co Production of alkanol-boron fluoride complex
US2918508A (en) 1957-12-02 1959-12-22 Standard Oil Co Polyisobutylene production
US3024226A (en) 1959-11-23 1962-03-06 Texaco Inc Polymerization process
US3166546A (en) 1961-06-09 1965-01-19 Texaco Inc Vapor phase process for the polymerization of isobutylene
US3306907A (en) 1963-04-29 1967-02-28 Standard Oil Co Process for preparing n n-di
US3346354A (en) 1963-07-02 1967-10-10 Chvron Res Company Long-chain alkenyl succinic acids, esters, and anhydrides as fuel detergents
US3284537A (en) 1965-01-14 1966-11-08 Stratford Eng Corp Method of charging reactants through concentric feed tubes
US3382291A (en) 1965-04-23 1968-05-07 Mobil Oil Corp Polymerization of olefins with bf3
US3634383A (en) 1969-07-28 1972-01-11 Nasa Method of forming difunctional polyisobutylene
JPS5410590B1 (es) 1970-04-18 1979-05-08
US3778487A (en) 1970-07-06 1973-12-11 Sun Research Development Polyisobutylene oil having a high viscosity index
US3780128A (en) 1971-11-03 1973-12-18 Ethyl Corp Synthetic lubricants by oligomerization and hydrogenation
US3935249A (en) 1973-05-10 1976-01-27 Standard Oil Company Tar reduction by inorganic halide for reaction of unsaturated anhydride and polybutene
US3927041A (en) 1973-10-01 1975-12-16 Standard Oil Co Process of making alkenyl succinic anhydride
US3991129A (en) 1974-09-23 1976-11-09 Cosden Technology, Inc. Production of polybutene with static mixer
DE2702604C2 (de) * 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
US4110521A (en) 1977-09-21 1978-08-29 Calgon Corporation Continuous polymerization apparatus and process
US4242531A (en) * 1978-08-14 1980-12-30 Phillips Petroleum Company Olefin dimerization
DE2904314A1 (de) * 1979-02-05 1980-08-14 Basf Ag Verfahren zur herstellung von polyisobutenen
US4227027A (en) 1979-11-23 1980-10-07 Allied Chemical Corporation Recyclable boron trifluoride catalyst and method of using same
DE3010870A1 (de) 1980-03-21 1981-10-01 Basf Ag, 6700 Ludwigshafen Verfahren zur polymerisation von isobutylen
JPS57101A (en) 1980-06-04 1982-01-05 Mitsui Petrochem Ind Ltd Method and apparatus for polymerization
US4400493A (en) 1982-04-07 1983-08-23 Cosden Technology, Inc. Polymerization of isobutylene
US4433197A (en) 1982-07-08 1984-02-21 Gulf Research & Development Company Removing boron trifluoride from coordination compound contaminants in organic liquids
DE3300155A1 (de) * 1983-01-05 1984-07-05 Basf Ag, 6700 Ludwigshafen Verfahren zur kontinuierlichen herstellung von isobutylenpolymerisaten
GB8329082D0 (en) 1983-11-01 1983-12-07 Bp Chem Int Ltd Low molecular weight polymers of 1-olefins
DE3509272A1 (de) 1985-03-15 1986-09-18 Basf Ag, 6700 Ludwigshafen Katalysatorsystem fuer die kationische polymerisation von isobutylen
DE3527551A1 (de) 1985-08-01 1987-02-05 Basf Ag Verfahren zur polymerisation von isobutylen
DE3535401A1 (de) * 1985-10-03 1987-04-09 Baskirskij G Uni Im 40 Letija Verfahren zur gewinnung von isobutylenpolymeren und einrichtung zur durchfuehrung dieses verfahrens
US4973733A (en) 1987-02-09 1990-11-27 Texaco Inc. Method of functionalizing polymers
JPH0651752B2 (ja) 1987-02-20 1994-07-06 鐘淵化学工業株式会社 官能性末端を有するイソブチレン系ポリマ−の製造法
FI80891C (fi) 1987-11-12 1990-08-10 Neste Oy Foerfarande foer framstaellning av smoerjmedel av poly- -olefintyp.
US4849572A (en) * 1987-12-22 1989-07-18 Exxon Chemical Patents Inc. Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647)
US4914166A (en) 1988-01-20 1990-04-03 The University Of Akron Non-fouling liquid nitrogen cooled polymerization process
US4943616A (en) 1988-07-26 1990-07-24 Polysar Limited Living cationic polymerization process
CA1336281C (en) 1988-07-26 1995-07-11 Munmaya Kumar Mishra Polymerization process and catalyst system therefor
US4982042A (en) 1988-10-17 1991-01-01 Idemitsu Petrochemical Co., Ltd. Process for manufacture of olefin oligomer
US4883847A (en) 1988-10-27 1989-11-28 Amoco Corporation Process to terminate an olefin polymerization reaction
GB8912271D0 (en) 1989-05-27 1989-07-12 Bp Chem Int Ltd Cationic polymerisation of 1-olefins
US5068490A (en) 1989-08-18 1991-11-26 Amoco Corporation BF3-tertiary etherate complexes for isobutylene polymerization
DE4033195A1 (de) 1990-10-19 1992-04-23 Basf Ag Verfahren zur herstellung von polyisobuten
DE4033196C1 (es) 1990-10-19 1992-04-16 Basf Ag, 6700 Ludwigshafen, De
US5254649A (en) 1990-11-28 1993-10-19 Bp Chemicals Limited Cationic polymerization of 1-olefins
FI91970C (fi) 1990-12-21 1994-09-12 Neste Oy Menetelmä kaasumaisen booritrifluoridin BF3 talteenottamiseksi ja menetelmässä syntyvän tuotteen käyttö
BE1006694A5 (fr) 1991-06-22 1994-11-22 Basf Ag Procede de preparation de polyisobutenes extremement reactifs.
US5288677A (en) 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
US5144097A (en) * 1991-09-27 1992-09-01 Western Design Corporation Carrier clip apparatus for linear linkless ammunition systems
DE69127473T2 (de) 1991-11-18 1998-02-19 Amoco Corp Bf3-tertiäre etheratkomplexe zur isobuthylen-polymerisation
GB9313442D0 (en) 1993-06-30 1993-08-11 Bp Chem Int Ltd Method of mixing heterogegeous systems
GB9404368D0 (en) 1994-03-07 1994-04-20 Bp Chem Int Ltd Production of polyisobutenes
ES2119141T5 (es) 1994-06-24 2005-03-16 Fortum Oil And Gas Oy Metodo para retirar el catalizador de un producto oligomero.
DE4425834A1 (de) 1994-07-21 1996-01-25 Basf Ag Umsetzungsprodukte aus Polyisobutenen und Stickoxiden oder Gemischen aus Stickoxiden und Sauerstoff und ihre Verwendung als Kraft- und Schmierstoffadditive
US5448001A (en) 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene
DE19520078A1 (de) * 1995-06-07 1996-12-12 Basf Ag Verfahren zur Herstellung von niedermolekularem, hochreaktivem Polyisobuten
US5811616A (en) 1995-06-13 1998-09-22 Amoco Corporation BF3 gas recovery process
US5977251A (en) * 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
DE19619267A1 (de) 1996-05-13 1997-11-20 Basf Ag Verfahren zur Herstellung von mittelmolekularem, hochreaktivem Polyisobuten
US5779742A (en) 1996-08-08 1998-07-14 The Lubrizol Corporation Acylated nitrogen compounds useful as additives for lubricating oil and fuel compositions
US5792729A (en) 1996-08-20 1998-08-11 Chevron Chemical Corporation Dispersant terpolymers
US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
US5733993A (en) 1996-11-14 1998-03-31 Ethyl Corporation Polymeric dispersants via novel terpolymers
US5731379A (en) 1997-01-03 1998-03-24 Dow Corning Corporation Copolymers of polyorganosiloxane, polyisobutylene, and alkyl acrylates or methacrylates
JP3795666B2 (ja) * 1997-03-07 2006-07-12 新日本石油化学株式会社 ブテンポリマーの製造方法
US6407186B1 (en) * 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
DE19825334A1 (de) * 1998-06-05 1999-12-09 Basf Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
MXPA02001334A (es) 1999-09-16 2004-07-16 Texas Petrochemicals Lp Procedimiento para la preparacion de productos de poliolefina.
DE19948947A1 (de) * 1999-10-11 2001-04-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Polyisobutenen
DE19952030A1 (de) * 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
DE10035298A1 (de) * 2000-07-18 2002-01-31 Basf Ag Verfahren zur Herstellung von Polysiobutenen
DE10040618A1 (de) * 2000-08-16 2002-02-28 Basf Ag Verfahren zur Herstellung von Polyisobutenen

Also Published As

Publication number Publication date
US6525149B1 (en) 2003-02-25
EP1242464B1 (en) 2011-04-27
KR20020063162A (ko) 2002-08-01
CA2660742A1 (en) 2001-03-22
JP2007197734A (ja) 2007-08-09
CN1377372A (zh) 2002-10-30
JP5064878B2 (ja) 2012-10-31
EP1242464A1 (en) 2002-09-25
JP4156837B2 (ja) 2008-09-24
JP2003509544A (ja) 2003-03-11
DE60045897D1 (de) 2011-06-09
AU7123700A (en) 2001-04-17
ATE507247T1 (de) 2011-05-15
AR025682A1 (es) 2002-12-11
CA2385576C (en) 2012-05-01
CA2385576A1 (en) 2001-03-22
MXPA02001334A (es) 2004-07-16
CA2660742C (en) 2012-05-15
CN1188430C (zh) 2005-02-09
KR100600256B1 (ko) 2006-07-13
EP1242464A4 (en) 2004-06-16
WO2001019873A1 (en) 2001-03-22

Similar Documents

Publication Publication Date Title
AR064674A2 (es) Un proceso de polimerizacion en fase liquida para la preparacion de un poliisobutileno altamente reactivo de bajo peso molecular
ES2087967T3 (es) Procedimiento de preparacion de una resina absorbente de agua.
CA2438068A1 (en) Mid-range vinylidene content polyisobutylene and production thereof
EP2284198A3 (en) Process for preparing polyolefin products
AR007713A1 (es) Un metodo para polimerizar en fase de vapor al 1.3 butadieno en cis-1,4- polibutadieno
MX236541B (es) Metodos para tratar cancer ovarico, composiciones de poli (fosfoester) y articulos biodegradables para los mismos.
AR029106A1 (es) Composiciones de polimero de propileno, procedimiento de polimerizacion para prepararlas y botellas y recipientes que las comprenden
JPS5258785A (en) Process for preparing acrylonitrile polymer melts
Stocklin et al. Phase Dependence of Carbon-11 Recoil Products in Ethane and Propane; Evidence for Methylene Insertion
JPS5618607A (en) Polymerization of ethylene
GB1477189A (en) Method for removing heat of polymerization
JPS5219790A (en) Process for the preparation of ethylene polymer
Offenbach et al. The Initiation of Polymerization by Di-t-butyl Peroxide
CO4930305A1 (es) Proceso para la preparacion de un gel de copolimero reticula do de anhidrido maleico
CA2036473A1 (en) Process of producing linear .alpha.-olefins
ES2071290T3 (es) Masa de recubrimiento, procedimiento para su preparacion y su utilizacion.
Ciutacu et al. On the thermal stability of some macromolecular compounds
JPS5242592A (en) Process for preparing styene-acrylonitrile copolymers
Carlsson et al. Absolute Rate Constants for the Combination of Trichloromethyl Radicals and for Their Reaction with t-Butyl Hypochlorite1
Ivin et al. The heats of formation of the isomeric butene polysulphones
Lu Reversal of oxidative stress in neural cells by an injectable curcumin/thermosensitive hydrogel
Razimov et al. Thermal polymerization of p-benzoquinone
JPS5439494A (en) Continuous preparation of poly-para-phenylene terephthalamide
JPS5392886A (en) Preparation of hydroxyl-terminated liquid chloroprene polymer
JPS539900A (en) Improved preparation of ring opening polymers

Legal Events

Date Code Title Description
FC Refusal