AR034837A1 - Proceso para preparar intermedios de 4-aminodifenilamina. - Google Patents
Proceso para preparar intermedios de 4-aminodifenilamina.Info
- Publication number
- AR034837A1 AR034837A1 ARP020102747A ARP020102747A AR034837A1 AR 034837 A1 AR034837 A1 AR 034837A1 AR P020102747 A ARP020102747 A AR P020102747A AR P020102747 A ARP020102747 A AR P020102747A AR 034837 A1 AR034837 A1 AR 034837A1
- Authority
- AR
- Argentina
- Prior art keywords
- aminodiphenylamine
- mixture
- nitrobenzene
- aniline
- base
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
- C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
- C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
La presente se refiere a un método para preparar/producir 4-aminodifenilamina o sus derivados sustituidos; el método comprende, por un lado, poner en contacto reactivo a una anilina o un derivado anilínico y un nitrobenceno o un derivado de nitrobenceno, y por el otro, hacer que la anilina y el nitrobenceno reaccionen en una zona confinada, en un tiempo y a una temperatura adecuados, en presencia de una mezcla que comprenda una base fuerte y un catalizador de transferencia de fase adecuado, y de un oxidante; el resultado de esa reacción es un producto intermedio de 4-aminodifenilamina. En otro caso, la mezcla puede comprender una sal inorgánica o una sal orgánica metálica, con un catión que sería un catión adecuado de una base inorgánica fuerte, y una base orgánica y oxidante; la mezcla no incluye un producto reactivo de betaína y una base inorgánica fuerte. El producto intermedio de aminodifenilamina se reduce luego para producir 4-aminodifenilamina o sus derivados sustituidos.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/911,058 US6395933B1 (en) | 2001-07-23 | 2001-07-23 | Process for preparing 4-aminodiphenylamine intermediates |
Publications (1)
Publication Number | Publication Date |
---|---|
AR034837A1 true AR034837A1 (es) | 2004-03-17 |
Family
ID=25429699
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP020102747A AR034837A1 (es) | 2001-07-23 | 2002-07-22 | Proceso para preparar intermedios de 4-aminodifenilamina. |
Country Status (12)
Country | Link |
---|---|
US (2) | US6395933B1 (es) |
EP (2) | EP2210871B1 (es) |
JP (2) | JP5259534B2 (es) |
KR (1) | KR100895141B1 (es) |
CN (1) | CN101665437B (es) |
AR (1) | AR034837A1 (es) |
CA (2) | CA2675685A1 (es) |
GE (1) | GEP20074205B (es) |
PL (2) | PL213693B1 (es) |
RO (1) | RO122778B1 (es) |
UA (1) | UA86566C2 (es) |
ZA (1) | ZA200400487B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6395933B1 (en) * | 2001-07-23 | 2002-05-28 | Flexsys America, L.P. | Process for preparing 4-aminodiphenylamine intermediates |
US7183439B2 (en) | 2002-12-10 | 2007-02-27 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamine intermediates |
US8486223B2 (en) * | 2003-07-04 | 2013-07-16 | Jiangsu Sinorgchem Technology Co., Ltd. | Falling film evaporator |
WO2005003079A1 (fr) * | 2003-07-04 | 2005-01-13 | Shi, Guangqiang | Procede de production d'une 4-aminodiphenylamine |
US7084302B2 (en) * | 2003-07-04 | 2006-08-01 | Sinorgchem Shandong Co., Ltd. | Process for preparing 4-aminodiphenylamine |
US8686188B2 (en) | 2003-07-04 | 2014-04-01 | Jiangsu Sinorgchem Technology Co., Ltd. | Process for preparing 4-aminodiphenylamine |
KR100621310B1 (ko) * | 2005-05-16 | 2006-09-06 | 금호석유화학 주식회사 | 4-아미노디페닐아민의 제조방법 |
CN102259029B (zh) | 2010-05-24 | 2014-12-10 | 江苏圣奥化学科技有限公司 | 固体碱催化剂 |
IN2014KN01593A (es) | 2012-03-07 | 2015-10-23 | Nocil Ltd | |
CN109232275B (zh) * | 2018-10-26 | 2021-06-11 | 科迈化工股份有限公司 | 一种4-硝基二苯胺和4-亚硝基二苯胺的制备方法 |
US20240117149A1 (en) | 2022-09-28 | 2024-04-11 | The Goodyear Tire & Rubber Company | Rubber - forming additives from end of life tires through syngas production |
US20240124683A1 (en) | 2022-09-28 | 2024-04-18 | The Goodyear Tire & Rubber Company | Rubber - forming additives from biomass through syngas production |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5117063A (en) * | 1991-06-21 | 1992-05-26 | Monsanto Company | Method of preparing 4-aminodiphenylamine |
EP0566783A1 (en) | 1992-04-21 | 1993-10-27 | Akzo N.V. | Process for the production of nitrodiarylamines |
DE4427249A1 (de) * | 1994-08-02 | 1996-02-08 | Bayer Ag | Verfahren zur Herstellung nitrosubstituierter Arylamine |
DE19600722A1 (de) * | 1996-01-11 | 1997-07-17 | Bayer Ag | Verfahren zur Herstellung von gegebenenfalls substituierten 4-Aminodiphenylaminen |
US5977411A (en) | 1997-06-10 | 1999-11-02 | Flexsys America L.P. | Catalytic hydrogeneration of nitrobenzene to 4-aminodiphenylamine in the presence of a hydroxyl compound and a solvent |
TW500712B (en) | 1997-08-06 | 2002-09-01 | Bayer Ag | Process for the preparation of 4-aminodiphenylamine |
DE19810929A1 (de) | 1998-03-13 | 1999-09-16 | Bayer Ag | Verfahren zur Herstellung von 4-Aminodiphenylamin |
US6140538A (en) * | 1998-05-18 | 2000-10-31 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamines |
SK283209B6 (sk) * | 1998-12-11 | 2003-03-04 | Duslo, A. S. | Spôsob prípravy 4-aminodifenylamínu |
KR100298572B1 (ko) | 1999-08-19 | 2001-09-22 | 박찬구 | 카바아닐라이드로부터 4-니트로디페닐아민과 4-니트로소디페닐아민의 제조방법 |
US6395933B1 (en) * | 2001-07-23 | 2002-05-28 | Flexsys America, L.P. | Process for preparing 4-aminodiphenylamine intermediates |
EP1414782A1 (en) * | 2001-07-23 | 2004-05-06 | Flexsys America L.P. | Process for preparing 4-aminodiphenylamines |
-
2001
- 2001-07-23 US US09/911,058 patent/US6395933B1/en not_active Expired - Lifetime
-
2002
- 2002-05-10 US US10/143,478 patent/US6583320B2/en not_active Expired - Lifetime
- 2002-07-09 PL PL389001A patent/PL213693B1/pl unknown
- 2002-07-09 CN CN200910167072.4A patent/CN101665437B/zh not_active Expired - Lifetime
- 2002-07-09 CA CA002675685A patent/CA2675685A1/en not_active Abandoned
- 2002-07-09 EP EP09168191.6A patent/EP2210871B1/en not_active Expired - Lifetime
- 2002-07-09 RO ROA200400065A patent/RO122778B1/ro unknown
- 2002-07-09 CA CA2690106A patent/CA2690106A1/en not_active Abandoned
- 2002-07-09 KR KR1020047001000A patent/KR100895141B1/ko active IP Right Grant
- 2002-07-09 PL PL389015A patent/PL213699B1/pl unknown
- 2002-07-09 UA UA2004021277A patent/UA86566C2/ru unknown
- 2002-07-09 EP EP09168209.6A patent/EP2202217B1/en not_active Expired - Lifetime
- 2002-07-09 GE GE5458A patent/GEP20074205B/en unknown
- 2002-07-22 AR ARP020102747A patent/AR034837A1/es not_active Application Discontinuation
-
2004
- 2004-01-22 ZA ZA200400487A patent/ZA200400487B/en unknown
-
2009
- 2009-09-03 JP JP2009203474A patent/JP5259534B2/ja not_active Expired - Fee Related
-
2010
- 2010-01-05 JP JP2010000730A patent/JP2010143931A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
CN101665437B (zh) | 2014-01-22 |
EP2210871A1 (en) | 2010-07-28 |
KR20040029376A (ko) | 2004-04-06 |
ZA200400487B (en) | 2005-08-29 |
UA86566C2 (en) | 2009-05-12 |
JP2010143931A (ja) | 2010-07-01 |
CN101665437A (zh) | 2010-03-10 |
JP5259534B2 (ja) | 2013-08-07 |
JP2010013465A (ja) | 2010-01-21 |
US6395933B1 (en) | 2002-05-28 |
US6583320B2 (en) | 2003-06-24 |
EP2202217B1 (en) | 2013-06-26 |
EP2202217A1 (en) | 2010-06-30 |
CA2690106A1 (en) | 2003-02-06 |
EP2210871B1 (en) | 2015-03-18 |
KR100895141B1 (ko) | 2009-05-04 |
US20030088127A1 (en) | 2003-05-08 |
CA2675685A1 (en) | 2003-02-06 |
GEP20074205B (en) | 2007-10-10 |
PL213693B1 (pl) | 2013-04-30 |
PL213699B1 (pl) | 2013-04-30 |
RO122778B1 (ro) | 2010-01-29 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant, registration | ||
FD | Application declared void or lapsed, e.g., due to non-payment of fee |