AR010468A2 - Un metodo para polimerizar en fase de vapor un monomero de diolefina conjugada en polimero de goma. - Google Patents
Un metodo para polimerizar en fase de vapor un monomero de diolefina conjugada en polimero de goma.Info
- Publication number
- AR010468A2 AR010468A2 ARP970102963A ARP970102963A AR010468A2 AR 010468 A2 AR010468 A2 AR 010468A2 AR P970102963 A ARP970102963 A AR P970102963A AR P970102963 A ARP970102963 A AR P970102963A AR 010468 A2 AR010468 A2 AR 010468A2
- Authority
- AR
- Argentina
- Prior art keywords
- rubber polymer
- polymerizing
- steam phase
- reaction zone
- conjugated diolefin
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
- B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
- B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/36—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed through which there is an essentially horizontal flow of particles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F13/00—Illuminated signs; Luminous advertising
- G09F13/28—Signs formed by filament-type lamp
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F21/00—Mobile visual advertising
- G09F21/06—Mobile visual advertising by aeroplanes, airships, balloons, or kites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/00108—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Theoretical Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Accounting & Taxation (AREA)
- Marketing (AREA)
- Business, Economics & Management (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Un método para polimerizar en fase vapor un monomero de diolefina conjugada en un polímero de goma en un proceso que se compone de los siguientes pasos:(1)cargar dicho monomero de diolefina conjugada, un catalizador y un antioxidante de diarilaminaen una zona de reaccion; donde el monomero de diolefinaconjugada se mantiene en la fase de vapor en dicha zona de reaccion; (2) dejar que dicho monomero de diolefina conjugada polimeriza en dicha zona de reaccionen un polímero de goma; y (3)retirar dicho polímero de goma de dicha zona de reaccion.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US308995P | 1995-08-31 | 1995-08-31 | |
US578195P | 1995-10-20 | 1995-10-20 | |
US08/663,803 US5652304A (en) | 1995-08-31 | 1996-06-28 | Vapor phase synthesis of rubbery polymers |
Publications (1)
Publication Number | Publication Date |
---|---|
AR010468A2 true AR010468A2 (es) | 2000-06-28 |
Family
ID=27357307
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP960104049A AR003308A1 (es) | 1995-08-31 | 1996-08-20 | Un metodo para polimerizar en fase vapor al isopreno en cis-1,4- poliisopreno. |
ARP970102962A AR007713A1 (es) | 1995-08-31 | 1997-07-02 | Un metodo para polimerizar en fase de vapor al 1.3 butadieno en cis-1,4- polibutadieno |
ARP970102963A AR010468A2 (es) | 1995-08-31 | 1997-07-02 | Un metodo para polimerizar en fase de vapor un monomero de diolefina conjugada en polimero de goma. |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP960104049A AR003308A1 (es) | 1995-08-31 | 1996-08-20 | Un metodo para polimerizar en fase vapor al isopreno en cis-1,4- poliisopreno. |
ARP970102962A AR007713A1 (es) | 1995-08-31 | 1997-07-02 | Un metodo para polimerizar en fase de vapor al 1.3 butadieno en cis-1,4- polibutadieno |
Country Status (9)
Country | Link |
---|---|
US (2) | US5652304A (es) |
EP (1) | EP0805823B1 (es) |
AR (3) | AR003308A1 (es) |
AU (1) | AU6951096A (es) |
CA (1) | CA2212729A1 (es) |
DE (1) | DE69616510T2 (es) |
ES (1) | ES2167599T3 (es) |
MY (1) | MY132302A (es) |
WO (1) | WO1997008211A1 (es) |
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US5652304A (en) * | 1995-08-31 | 1997-07-29 | The Goodyear Tire & Rubber Company | Vapor phase synthesis of rubbery polymers |
US5859156A (en) * | 1995-08-31 | 1999-01-12 | The Goodyear Tire & Rubber Company | Vapor phase synthesis of rubbery polymers |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3047559A (en) * | 1961-09-11 | 1962-07-31 | Goodyear Tire & Rubber | Method of making polymer |
DE1251029B (de) * | 1964-11-10 | 1967-09-28 | Farbenfabriken Baver Aktiengeseü schaft Leverkusen | Verfah ren zur Polymerisation \on Isopren |
US3458490A (en) * | 1964-12-31 | 1969-07-29 | Phillips Petroleum Co | Polymerization |
US3458940A (en) * | 1967-02-10 | 1969-08-05 | Edgar Schmued | Level-establishing device |
US3770710A (en) * | 1971-08-23 | 1973-11-06 | Firestone Tire & Rubber Co | Bulk polymerization of diolefins |
US4155880A (en) * | 1971-11-24 | 1979-05-22 | The Goodyear Tire & Rubber Company | Catalyst composition comprising an organoaluminum compound/an organonickel compound/a hydrogen fluoride complex compound |
US3856764A (en) * | 1971-11-24 | 1974-12-24 | Goodyear Tire & Rubber | Polymerization process |
US4098980A (en) * | 1976-06-24 | 1978-07-04 | The Goodyear Tire & Rubber Company | Non-aqueous dispersion polymerization of conjugated diolefins |
US4250083A (en) * | 1979-02-05 | 1981-02-10 | Denka Chemical Corporation | Viscosity stabilized chloroprene-sulfur copolymers |
US4983695A (en) * | 1982-04-26 | 1991-01-08 | The Goodyear Tire & Rubber Company | Molecular weight control of polybutadiene |
US4452960A (en) * | 1982-09-20 | 1984-06-05 | The Goodyear Tire & Rubber Company | Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents |
US5317036A (en) * | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
US5453471B1 (en) * | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
US5451646A (en) * | 1994-12-05 | 1995-09-19 | The Goodyear Tire & Rubber Company | Technique for reducing the molecular weight and improving the processability of cis-1,4-polybutadiene |
US5652304A (en) * | 1995-08-31 | 1997-07-29 | The Goodyear Tire & Rubber Company | Vapor phase synthesis of rubbery polymers |
-
1996
- 1996-06-28 US US08/663,803 patent/US5652304A/en not_active Expired - Fee Related
- 1996-08-02 CA CA002212729A patent/CA2212729A1/en not_active Abandoned
- 1996-08-02 ES ES96930494T patent/ES2167599T3/es not_active Expired - Lifetime
- 1996-08-02 AU AU69510/96A patent/AU6951096A/en not_active Abandoned
- 1996-08-02 DE DE69616510T patent/DE69616510T2/de not_active Expired - Fee Related
- 1996-08-02 EP EP96930494A patent/EP0805823B1/en not_active Expired - Lifetime
- 1996-08-02 WO PCT/US1996/012787 patent/WO1997008211A1/en active IP Right Grant
- 1996-08-20 AR ARP960104049A patent/AR003308A1/es unknown
- 1996-08-22 MY MYPI96003472A patent/MY132302A/en unknown
-
1997
- 1997-05-02 US US08/850,314 patent/US6066705A/en not_active Expired - Fee Related
- 1997-07-02 AR ARP970102962A patent/AR007713A1/es unknown
- 1997-07-02 AR ARP970102963A patent/AR010468A2/es unknown
Also Published As
Publication number | Publication date |
---|---|
EP0805823B1 (en) | 2001-10-31 |
EP0805823A1 (en) | 1997-11-12 |
AR003308A1 (es) | 1998-07-08 |
MY132302A (en) | 2007-10-31 |
ES2167599T3 (es) | 2002-05-16 |
DE69616510T2 (de) | 2002-05-16 |
AR007713A1 (es) | 1999-11-10 |
EP0805823A4 (en) | 1998-05-06 |
WO1997008211A1 (en) | 1997-03-06 |
US5652304A (en) | 1997-07-29 |
CA2212729A1 (en) | 1997-03-06 |
AU6951096A (en) | 1997-03-19 |
US6066705A (en) | 2000-05-23 |
DE69616510D1 (de) | 2001-12-06 |
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